Articles | Volume 10, issue 5
https://doi.org/10.5194/tc-10-2057-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/tc-10-2057-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Direct visualization of solute locations in laboratory ice samples
Ted Hullar
Department of Land, Air, and Water Resources, University of California, Davis, USA
Department of Land, Air, and Water Resources, University of California, Davis, USA
Related authors
Ted Hullar, Theo Tran, Zekun Chen, Fernanda Bononi, Oliver Palmer, Davide Donadio, and Cort Anastasio
Atmos. Chem. Phys., 22, 5943–5959, https://doi.org/10.5194/acp-22-5943-2022, https://doi.org/10.5194/acp-22-5943-2022, 2022
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Chemicals are commonly found in snowpacks throughout the world and may be degraded by sunlight; some previous research has reported faster decay rates for chemicals on the surface of snow and ice compared to in water. We found photodegradation on snow can be as much as 30 times faster than in solution for the three dimethoxybenzene isomers. Our computational modeling found light absorbance by dimethoxybenzenes increases on the snow surface, but this only partially explains the decay rate.
Michael Oluwatoyin Sunday, Laura Marie Dahler Heinlein, Junwei He, Allison Moon, Sukriti Kapur, Ting Fang, Kasey C. Edwards, Fangzhou Guo, Jack Dibb, James H. Flynn III, Becky Alexander, Manabu Shiraiwa, and Cort Anastasio
EGUsphere, https://doi.org/10.5194/egusphere-2024-3272, https://doi.org/10.5194/egusphere-2024-3272, 2024
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Hydrogen peroxide (HOOH) is an important oxidant that forms atmospheric sulfate. We demonstrate that illumination of brown carbon can rapidly form HOOH within particles, even under the low sunlight conditions of Fairbanks, Alaska during winter. This in-particle formation of HOOH is fast enough that it forms sulfate at significant rates. In contrast, the formation of HOOH in the gas phase during the campaign is expected to be negligible because of high NOx levels.
Stephanie Arciva, Lan Ma, Camille Mavis, Chrystal Guzman, and Cort Anastasio
Atmos. Chem. Phys., 24, 4473–4485, https://doi.org/10.5194/acp-24-4473-2024, https://doi.org/10.5194/acp-24-4473-2024, 2024
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We measured changes in light absorption during the aqueous oxidation of six phenols with hydroxyl radical (●OH) or an organic triplet excited state (3C*). All the phenols formed light-absorbing secondary brown carbon (BrC), which then decayed with continued oxidation. Extrapolation to ambient conditions suggest ●OH is the dominant sink of secondary phenolic BrC in fog/cloud drops, while 3C* controls the lifetime of this light absorption in particle water.
Aaron Lieberman, Julietta Picco, Murat Onder, and Cort Anastasio
Atmos. Chem. Phys., 24, 4411–4419, https://doi.org/10.5194/acp-24-4411-2024, https://doi.org/10.5194/acp-24-4411-2024, 2024
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We developed a method that uses aqueous S(IV) to quantitatively convert NO2 to NO2−, which allows both species to be quantified using the Griess method. As an example of the utility of the method, we quantified both photolysis channels of nitrate, with and without a scavenger for hydroxyl radical (·OH). The results show that without a scavenger, ·OH reacts with nitrite to form nitrogen dioxide, suppressing the apparent quantum yield of NO2− and enhancing that of NO2.
Lan Ma, Reed Worland, Laura Heinlein, Chrystal Guzman, Wenqing Jiang, Christopher Niedek, Keith J. Bein, Qi Zhang, and Cort Anastasio
Atmos. Chem. Phys., 24, 1–21, https://doi.org/10.5194/acp-24-1-2024, https://doi.org/10.5194/acp-24-1-2024, 2024
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We measured concentrations of three photooxidants – the hydroxyl radical, triplet excited states of organic carbon, and singlet molecular oxygen – in fine particles collected over a year. Concentrations are highest in extracts of fresh biomass burning particles, largely because they have the highest particle concentrations and highest light absorption. When normalized by light absorption, rates of formation for each oxidant are generally similar for the four particle types we observed.
Lan Ma, Reed Worland, Wenqing Jiang, Christopher Niedek, Chrystal Guzman, Keith J. Bein, Qi Zhang, and Cort Anastasio
Atmos. Chem. Phys., 23, 8805–8821, https://doi.org/10.5194/acp-23-8805-2023, https://doi.org/10.5194/acp-23-8805-2023, 2023
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Although photooxidants are important in airborne particles, little is known of their concentrations. By measuring oxidants in a series of particle dilutions, we predict their concentrations in aerosol liquid water (ALW). We find •OH concentrations in ALW are on the order of 10−15 M, similar to their cloud/fog values, while oxidizing triplet excited states and singlet molecular oxygen have ALW values of ca. 10−13 M and 10−12 M, respectively, roughly 10–100 times higher than in cloud/fog drops.
Wenqing Jiang, Christopher Niedek, Cort Anastasio, and Qi Zhang
Atmos. Chem. Phys., 23, 7103–7120, https://doi.org/10.5194/acp-23-7103-2023, https://doi.org/10.5194/acp-23-7103-2023, 2023
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We studied how aqueous-phase secondary organic aerosol (aqSOA) form and evolve from a phenolic carbonyl commonly present in biomass burning smoke. The composition and optical properties of the aqSOA are significantly affected by photochemical reactions and are dependent on the oxidants' concentration and identity in water. During photoaging, the aqSOA initially becomes darker, but prolonged aging leads to the formation of volatile products, resulting in significant mass loss and photobleaching.
Ted Hullar, Theo Tran, Zekun Chen, Fernanda Bononi, Oliver Palmer, Davide Donadio, and Cort Anastasio
Atmos. Chem. Phys., 22, 5943–5959, https://doi.org/10.5194/acp-22-5943-2022, https://doi.org/10.5194/acp-22-5943-2022, 2022
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Chemicals are commonly found in snowpacks throughout the world and may be degraded by sunlight; some previous research has reported faster decay rates for chemicals on the surface of snow and ice compared to in water. We found photodegradation on snow can be as much as 30 times faster than in solution for the three dimethoxybenzene isomers. Our computational modeling found light absorbance by dimethoxybenzenes increases on the snow surface, but this only partially explains the decay rate.
Richie Kaur, Jacqueline R. Labins, Scarlett S. Helbock, Wenqing Jiang, Keith J. Bein, Qi Zhang, and Cort Anastasio
Atmos. Chem. Phys., 19, 6579–6594, https://doi.org/10.5194/acp-19-6579-2019, https://doi.org/10.5194/acp-19-6579-2019, 2019
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We measured hydroxyl radical (•OH), singlet oxygen (1O2*), and organic triplets (3C*) in illuminated aqueous particle extracts. After measuring the impact of dilution on oxidant concentrations, we extrapolated our results to predict them in ambient particles – 1O2* and 3C* concentrations appear to be greatly enhanced, while •OH appears largely unchanged. Two of these oxidants (1O2*, 3C*) are not yet included in atmospheric models, and our results make it possible to include them in the future.
Richie Kaur, Brandi M. Hudson, Joseph Draper, Dean J. Tantillo, and Cort Anastasio
Atmos. Chem. Phys., 19, 5021–5032, https://doi.org/10.5194/acp-19-5021-2019, https://doi.org/10.5194/acp-19-5021-2019, 2019
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Organic triplets are an important class of aqueous photooxidants, but little is known about their reactions with most atmospheric organic compounds. We measured the reaction rate constants of a model triplet with 17 aliphatic alkenes; using their correlation with oxidation potential, we predicted rate constants for some atmospherically relevant alkenes. Depending on their reactivities, triplets can be minor to important sinks for isoprene- and limonene-derived alkenes in cloud or fog drops.
Zeyuan Chen, Liang Chu, Edward S. Galbavy, Keren Ram, and Cort Anastasio
Atmos. Chem. Phys., 16, 9579–9590, https://doi.org/10.5194/acp-16-9579-2016, https://doi.org/10.5194/acp-16-9579-2016, 2016
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We made the first measurements of the concentrations of hydroxyl radical (•OH), a dominant environmental oxidant, in snow grains. Concentrations of •OH in snow at Summit, Greenland, are comparable to values reported for midlatitude cloud and fog drops, even though impurity levels in the snow are much lower. At these concentrations, the lifetimes of organics and bromide in Summit snow are approximately 3 days and 7 h, respectively, suggesting that OH is a major oxidant for both species.
Lu Yu, Jeremy Smith, Alexander Laskin, Katheryn M. George, Cort Anastasio, Julia Laskin, Ann M. Dillner, and Qi Zhang
Atmos. Chem. Phys., 16, 4511–4527, https://doi.org/10.5194/acp-16-4511-2016, https://doi.org/10.5194/acp-16-4511-2016, 2016
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The chemical evolution of SOA formed during aqueous reactions of phenolic compounds is studied via combined bulk and molecular analysis. Phenolic SOA evolve dynamically during photochemical aging, with different reaction mechanisms (oligomerization, fragmentation, and functionalization) leading to different generations of products that span an enormous range in volatilities and a large range in oxidation state and composition. Aqueous reactions of phenols are likely an important source of ELVOC.
J. G. Charrier, N. K. Richards-Henderson, K. J. Bein, A. S. McFall, A. S. Wexler, and C. Anastasio
Atmos. Chem. Phys., 15, 2327–2340, https://doi.org/10.5194/acp-15-2327-2015, https://doi.org/10.5194/acp-15-2327-2015, 2015
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We measured the oxidative potential of airborne particles – a property that has been linked to health problems caused by particles – from different emission source mixtures in Fresno, CA. Copper was responsible for the majority of the oxidative potential (as measured by the DTT assay), followed by unknown species (likely organics) and manganese. Sources of copper-rich particles, including vehicles, had higher oxidative potentials.
L. Yu, J. Smith, A. Laskin, C. Anastasio, J. Laskin, and Q. Zhang
Atmos. Chem. Phys., 14, 13801–13816, https://doi.org/10.5194/acp-14-13801-2014, https://doi.org/10.5194/acp-14-13801-2014, 2014
Related subject area
Atmospheric Interactions
Extending the Center for Western Weather and Water Extremes (CW3E) atmospheric river scale to the polar regions
Identifying airborne snow metamorphism with stable water isotopes
Seasonal snow–atmosphere modeling: let's do it
On the importance to consider the cloud dependence in parameterizing the albedo of snow on sea ice
Dynamic and thermodynamic processes related to sea-ice surface melt advance in the Laptev Sea and East Siberian Sea
Understanding the drivers of near-surface winds in Adélie Land, East Antarctica
Understanding snow saltation parameterizations: lessons from theory, experiments and numerical simulations
Brief communication: Significant biases in ERA5 output for the McMurdo Dry Valleys region, Antarctica
Effects of Arctic sea-ice concentration on turbulent surface fluxes in four atmospheric reanalyses
A novel framework to investigate wind-driven snow redistribution over an Alpine glacier: combination of high-resolution terrestrial laser scans and large-eddy simulations
Control of the temperature signal in Antarctic proxies by snowfall dynamics
From atmospheric water isotopes measurement to firn core interpretation in Adélie Land: a case study for isotope-enabled atmospheric models in Antarctica
Atmospheric drivers of melt-related ice speed-up events on the Russell Glacier in southwest Greenland
Amundsen Sea Embayment accumulation variability measured with GNSS-IR
Attributing near-surface atmospheric trends in the Fram Strait region to regional sea ice conditions
Foehn winds at Pine Island Glacier and their role in ice changes
Black carbon concentrations and modeled smoke deposition fluxes to the bare-ice dark zone of the Greenland Ice Sheet
Dynamics of the snow grain size in a windy coastal area of Antarctica from continuous in situ spectral-albedo measurements
Forcing and impact of the Northern Hemisphere continental snow cover in 1979–2014
Climatology and surface impacts of atmospheric rivers on West Antarctica
Multi-annual temperature evolution and implications for cave ice development in a sag-type ice cave in the Austrian Alps
Estimating a mean transport velocity in the marginal ice zone using ice–ocean prediction systems
The role of föhn winds in eastern Antarctic Peninsula rapid ice shelf collapse
On the energy budget of a low-Arctic snowpack
The role of sublimation as a driver of climate signals in the water isotope content of surface snow: laboratory and field experimental results
Continuous monitoring of surface water vapour isotopic compositions at Neumayer Station III, East Antarctica
The distribution and evolution of supraglacial lakes on 79° N Glacier (north-eastern Greenland) and interannual climatic controls
Synoptic control on snow avalanche activity in central Spitsbergen
Mapping the aerodynamic roughness of the Greenland Ice Sheet surface using ICESat-2: evaluation over the K-transect
Atmospheric extremes caused high oceanward sea surface slope triggering the biggest calving event in more than 50 years at the Amery Ice Shelf
Interfacial supercooling and the precipitation of hydrohalite in frozen NaCl solutions as seen by X-ray absorption spectroscopy
Spatio-temporal flow variations driving heat exchange processes at a mountain glacier
Measurements and modeling of snow albedo at Alerce Glacier, Argentina: effects of volcanic ash, snow grain size, and cloudiness
The influence of föhn winds on annual and seasonal surface melt on the Larsen C Ice Shelf, Antarctica
Reconciling the surface temperature–surface mass balance relationship in models and ice cores in Antarctica over the last 2 centuries
Tracing devastating fires in Portugal to a snow archive in the Swiss Alps: a case study
Systematic bias of Tibetan Plateau snow cover in subseasonal-to-seasonal models
Towards understanding the pattern of glacier mass balances in High Mountain Asia using regional climatic modelling
Warm-air entrainment and advection during alpine blowing snow events
Quantifying the impact of synoptic weather types and patterns on energy fluxes of a marginal snowpack
Radar measurements of blowing snow off a mountain ridge
Brief communication: Rare ambient saturation during drifting snow occurrences at a coastal location of East Antarctica
Understanding snow bedform formation by adding sintering to a cellular automata model
Decadal changes in the leading patterns of sea level pressure in the Arctic and their impacts on the sea ice variability in boreal summer
Evaluation of snow depth and snow cover over the Tibetan Plateau in global reanalyses using in situ and satellite remote sensing observations
Contributions of advection and melting processes to the decline in sea ice in the Pacific sector of the Arctic Ocean
A multi-season investigation of glacier surface roughness lengths through in situ and remote observation
Potential faster Arctic sea ice retreat triggered by snowflakes' greenhouse effect
Brief communication: Analysis of organic matter in surface snow by PTR-MS – implications for dry deposition dynamics in the Alps
Variability in individual particle structure and mixing states between the glacier–snowpack and atmosphere in the northeastern Tibetan Plateau
Zhenhai Zhang, F. Martin Ralph, Xun Zou, Brian Kawzenuk, Minghua Zheng, Irina V. Gorodetskaya, Penny M. Rowe, and David H. Bromwich
The Cryosphere, 18, 5239–5258, https://doi.org/10.5194/tc-18-5239-2024, https://doi.org/10.5194/tc-18-5239-2024, 2024
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Atmospheric rivers (ARs) are long, narrow corridors of strong water vapor transport in the atmosphere. ARs play an important role in extreme weather in polar regions, including heavy rain and/or snow, heat waves, and surface melt. The standard AR scale is developed based on the midlatitude climate and is insufficient for polar regions. This paper introduces an extended version of the AR scale tuned to polar regions, aiming to quantify polar ARs objectively based on their strength and impact.
Sonja Wahl, Benjamin Walter, Franziska Aemisegger, Luca Bianchi, and Michael Lehning
The Cryosphere, 18, 4493–4515, https://doi.org/10.5194/tc-18-4493-2024, https://doi.org/10.5194/tc-18-4493-2024, 2024
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Wind-driven airborne transport of snow is a frequent phenomenon in snow-covered regions and a process difficult to study in the field as it is unfolding over large distances. Thus, we use a ring wind tunnel with infinite fetch positioned in a cold laboratory to study the evolution of the shape and size of airborne snow. With the help of stable water isotope analyses, we identify the hitherto unobserved process of airborne snow metamorphism that leads to snow particle rounding and growth.
Dylan Reynolds, Louis Quéno, Michael Lehning, Mahdi Jafari, Justine Berg, Tobias Jonas, Michael Haugeneder, and Rebecca Mott
The Cryosphere, 18, 4315–4333, https://doi.org/10.5194/tc-18-4315-2024, https://doi.org/10.5194/tc-18-4315-2024, 2024
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Information about atmospheric variables is needed to produce simulations of mountain snowpacks. We present a model that can represent processes that shape mountain snowpack, focusing on the accumulation of snow. Simulations show that this model can simulate the complex path that a snowflake takes towards the ground and that this leads to differences in the distribution of snow by the end of winter. Overall, this model shows promise with regard to improving forecasts of snow in mountains.
Lara Foth, Wolfgang Dorn, Annette Rinke, Evelyn Jäkel, and Hannah Niehaus
The Cryosphere, 18, 4053–4064, https://doi.org/10.5194/tc-18-4053-2024, https://doi.org/10.5194/tc-18-4053-2024, 2024
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It is demonstrated that the explicit consideration of the cloud dependence of the snow surface albedo in a climate model results in a more realistic simulation of the surface albedo during the snowmelt period in late May and June. Although this improvement appears to be relatively insubstantial, it has significant impact on the simulated sea-ice volume and extent in the model due to an amplification of the snow/sea-ice albedo feedback, one of the main contributors to Arctic amplification.
Hongjie Liang and Wen Zhou
The Cryosphere, 18, 3559–3569, https://doi.org/10.5194/tc-18-3559-2024, https://doi.org/10.5194/tc-18-3559-2024, 2024
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This study identifies the metric of springtime sea-ice surface melt advance in the Laptev Sea and East Siberian Sea, which can be defined on the same date each year and has the potential to be used in the practical seasonal prediction of summer sea ice cover instead of average melt onset. Detailed analysis of dynamic and thermodynamic processes related to different melt advance scenarios in this region imply considerable interannual and interdecadal variability in springtime conditions.
Cécile Davrinche, Anaïs Orsi, Cécile Agosta, Charles Amory, and Christoph Kittel
The Cryosphere, 18, 2239–2256, https://doi.org/10.5194/tc-18-2239-2024, https://doi.org/10.5194/tc-18-2239-2024, 2024
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Coastal surface winds in Antarctica are amongst the strongest winds on Earth. They are either driven by the cooling of the surface air mass by the ice sheet (katabatic) or by large-scale pressure systems. Here we compute the relative contribution of these drivers. We find that seasonal variations in the wind speed come from the katabatic acceleration, but, at a 3-hourly timescale, none of the large-scale or katabatic accelerations can be considered as the main driver.
Daniela Brito Melo, Armin Sigmund, and Michael Lehning
The Cryosphere, 18, 1287–1313, https://doi.org/10.5194/tc-18-1287-2024, https://doi.org/10.5194/tc-18-1287-2024, 2024
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Snow saltation – the transport of snow close to the surface – occurs when the wind blows over a snow-covered surface with sufficient strength. This phenomenon is represented in some climate models; however, with limited accuracy. By performing numerical simulations and a detailed analysis of previous works, we show that snow saltation is characterized by two regimes. This is not represented in climate models in a consistent way, which hinders the quantification of snow transport and sublimation.
Ricardo Garza-Girón and Slawek M. Tulaczyk
The Cryosphere, 18, 1207–1213, https://doi.org/10.5194/tc-18-1207-2024, https://doi.org/10.5194/tc-18-1207-2024, 2024
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By analyzing temperature time series over more than 20 years, we have found a discrepancy between the 2 m temperature values reported by the ERA5 reanalysis and the automatic weather stations in the McMurdo Dry Valleys, Antarctica.
Tereza Uhlíková, Timo Vihma, Alexey Yu Karpechko, and Petteri Uotila
The Cryosphere, 18, 957–976, https://doi.org/10.5194/tc-18-957-2024, https://doi.org/10.5194/tc-18-957-2024, 2024
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A prerequisite for understanding the local, regional, and hemispherical impacts of Arctic sea-ice decline on the atmosphere is to quantify the effects of sea-ice concentration (SIC) on the sensible and latent heat fluxes in the Arctic. We analyse these effects utilising four data sets called atmospheric reanalyses, and we evaluate uncertainties in these effects arising from inter-reanalysis differences in SIC and in the sensitivity of the latent and sensible heat fluxes to SIC.
Annelies Voordendag, Brigitta Goger, Rainer Prinz, Tobias Sauter, Thomas Mölg, Manuel Saigger, and Georg Kaser
The Cryosphere, 18, 849–868, https://doi.org/10.5194/tc-18-849-2024, https://doi.org/10.5194/tc-18-849-2024, 2024
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Wind-driven snow redistribution affects glacier mass balance. A case study of Hintereisferner glacier in Austria used high-resolution observations and simulations to model snow redistribution. Simulations matched observations, showing the potential of the model for studying snow redistribution on other mountain glaciers.
Aymeric P. M. Servettaz, Cécile Agosta, Christoph Kittel, and Anaïs J. Orsi
The Cryosphere, 17, 5373–5389, https://doi.org/10.5194/tc-17-5373-2023, https://doi.org/10.5194/tc-17-5373-2023, 2023
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It has been previously observed in polar regions that the atmospheric temperature is warmer during precipitation events. Here, we use a regional atmospheric model to quantify the temperature changes associated with snowfall events across Antarctica. We show that more intense snowfall is statistically associated with a warmer temperature anomaly compared to the seasonal average, with the largest anomalies seen in winter. This bias may affect water isotopes in ice cores deposited during snowfall.
Christophe Leroy-Dos Santos, Elise Fourré, Cécile Agosta, Mathieu Casado, Alexandre Cauquoin, Martin Werner, Benedicte Minster, Frédéric Prié, Olivier Jossoud, Leila Petit, and Amaëlle Landais
The Cryosphere, 17, 5241–5254, https://doi.org/10.5194/tc-17-5241-2023, https://doi.org/10.5194/tc-17-5241-2023, 2023
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In the face of global warming, understanding the changing water cycle and temperatures in polar regions is crucial. These factors directly impact the balance of ice sheets in the Arctic and Antarctic. By studying the composition of water vapor, we gain insights into climate variations. Our 2-year study at Dumont d’Urville station, Adélie Land, offers valuable data to refine models. Additionally, we demonstrate how modeling aids in interpreting signals from ice core samples in the region.
Timo Schmid, Valentina Radić, Andrew Tedstone, James M. Lea, Stephen Brough, and Mauro Hermann
The Cryosphere, 17, 3933–3954, https://doi.org/10.5194/tc-17-3933-2023, https://doi.org/10.5194/tc-17-3933-2023, 2023
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The Greenland Ice Sheet contributes strongly to sea level rise in the warming climate. One process that can affect the ice sheet's mass balance is short-term ice speed-up events. These can be caused by high melting or rainfall as the water flows underneath the glacier and allows for faster sliding. In this study we found three main weather patterns that cause such ice speed-up events on the Russell Glacier in southwest Greenland and analyzed how they induce local melting and ice accelerations.
Andrew O. Hoffman, Michelle Maclennan, Jan Lenaerts, Kristine M. Larson, and Knut Chrsitianson
The Cryosphere Discuss., https://doi.org/10.5194/tc-2023-114, https://doi.org/10.5194/tc-2023-114, 2023
Revised manuscript accepted for TC
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Traditionally, glaciologists have used GNSS to measure the surface elevation, and velocity of glaciers to understand processes associated with ice flow. Using the interference of GNSS signals that bounce off of the ice sheet surface, we measure the surface height change of several receivers in the Amundsen Sea Embayment. From surface height change, we infer accumulation records and use these records to understand the drivers of extreme precipitation on Thwaites Glacier.
Amelie U. Schmitt and Christof Lüpkes
The Cryosphere, 17, 3115–3136, https://doi.org/10.5194/tc-17-3115-2023, https://doi.org/10.5194/tc-17-3115-2023, 2023
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In the last few decades, the region between Greenland and Svalbard has experienced the largest loss of Arctic sea ice in winter. We analyze how changes in air temperature, humidity and wind in this region differ for winds that originate from sea ice covered areas and from the open ocean. The largest impacts of sea ice cover are found for temperatures close to the ice edge and up to a distance of 500 km. Up to two-thirds of the observed temperature variability is related to sea ice changes.
Diana Francis, Ricardo Fonseca, Kyle S. Mattingly, Stef Lhermitte, and Catherine Walker
The Cryosphere, 17, 3041–3062, https://doi.org/10.5194/tc-17-3041-2023, https://doi.org/10.5194/tc-17-3041-2023, 2023
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Role of Foehn Winds in ice and snow conditions at the Pine Island Glacier, West Antarctica.
Alia L. Khan, Peng Xian, and Joshua P. Schwarz
The Cryosphere, 17, 2909–2918, https://doi.org/10.5194/tc-17-2909-2023, https://doi.org/10.5194/tc-17-2909-2023, 2023
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Ice–albedo feedbacks in the ablation region of the Greenland Ice Sheet are difficult to constrain and model. Surface samples were collected across the 2014 summer melt season from different ice surface colors. On average, concentrations were higher in patches that were visibly dark, compared to medium patches and light patches, suggesting that black carbon aggregation contributed to snow aging, and vice versa. High concentrations are likely due to smoke transport from high-latitude wildfires.
Sara Arioli, Ghislain Picard, Laurent Arnaud, and Vincent Favier
The Cryosphere, 17, 2323–2342, https://doi.org/10.5194/tc-17-2323-2023, https://doi.org/10.5194/tc-17-2323-2023, 2023
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To assess the drivers of the snow grain size evolution during snow drift, we exploit a 5-year time series of the snow grain size retrieved from spectral-albedo observations made with a new, autonomous, multi-band radiometer and compare it to observations of snow drift, snowfall and snowmelt at a windy location of coastal Antarctica. Our results highlight the complexity of the grain size evolution in the presence of snow drift and show an overall tendency of snow drift to limit its variations.
Guillaume Gastineau, Claude Frankignoul, Yongqi Gao, Yu-Chiao Liang, Young-Oh Kwon, Annalisa Cherchi, Rohit Ghosh, Elisa Manzini, Daniela Matei, Jennifer Mecking, Lingling Suo, Tian Tian, Shuting Yang, and Ying Zhang
The Cryosphere, 17, 2157–2184, https://doi.org/10.5194/tc-17-2157-2023, https://doi.org/10.5194/tc-17-2157-2023, 2023
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Snow cover variability is important for many human activities. This study aims to understand the main drivers of snow cover in observations and models in order to better understand it and guide the improvement of climate models and forecasting systems. Analyses reveal a dominant role for sea surface temperature in the Pacific. Winter snow cover is also found to have important two-way interactions with the troposphere and stratosphere. No robust influence of the sea ice concentration is found.
Michelle L. Maclennan, Jan T. M. Lenaerts, Christine A. Shields, Andrew O. Hoffman, Nander Wever, Megan Thompson-Munson, Andrew C. Winters, Erin C. Pettit, Theodore A. Scambos, and Jonathan D. Wille
The Cryosphere, 17, 865–881, https://doi.org/10.5194/tc-17-865-2023, https://doi.org/10.5194/tc-17-865-2023, 2023
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Atmospheric rivers are air masses that transport large amounts of moisture and heat towards the poles. Here, we use a combination of weather observations and models to quantify the amount of snowfall caused by atmospheric rivers in West Antarctica which is about 10 % of the total snowfall each year. We then examine a unique event that occurred in early February 2020, when three atmospheric rivers made landfall over West Antarctica in rapid succession, leading to heavy snowfall and surface melt.
Maria Wind, Friedrich Obleitner, Tanguy Racine, and Christoph Spötl
The Cryosphere, 16, 3163–3179, https://doi.org/10.5194/tc-16-3163-2022, https://doi.org/10.5194/tc-16-3163-2022, 2022
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We present a thorough analysis of the thermal conditions of a sag-type ice cave in the Austrian Alps using temperature measurements for the period 2008–2021. Apart from a long-term increasing temperature trend in all parts of the cave, we find strong interannual and spatial variations as well as a characteristic seasonal pattern. Increasing temperatures further led to a drastic decrease in cave ice. A first attempt to model ablation based on temperature shows promising results.
Graig Sutherland, Victor de Aguiar, Lars-Robert Hole, Jean Rabault, Mohammed Dabboor, and Øyvind Breivik
The Cryosphere, 16, 2103–2114, https://doi.org/10.5194/tc-16-2103-2022, https://doi.org/10.5194/tc-16-2103-2022, 2022
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The marginal ice zone (MIZ), which is the transition region between the open ocean and the dense pack ice, is a very dynamic region comprising a mixture of ice and ocean conditions. Using novel drifters deployed in various ice conditions in the MIZ, several material transport models are tested with two operational ice–ocean prediction systems. A new general transport equation, which uses both the ice and ocean solutions, is developed that reduces the error in drift prediction for our case study.
Matthew K. Laffin, Charles S. Zender, Melchior van Wessem, and Sebastián Marinsek
The Cryosphere, 16, 1369–1381, https://doi.org/10.5194/tc-16-1369-2022, https://doi.org/10.5194/tc-16-1369-2022, 2022
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The collapses of the Larsen A and B ice shelves on the Antarctic Peninsula (AP) occurred while the ice shelves were covered with large melt lakes, and ocean waves damaged the ice shelf fronts, triggering collapse. Observations show föhn winds were present on both ice shelves and increased surface melt and drove sea ice away from the ice front. Collapsed ice shelves experienced enhanced surface melt driven by föhn winds, whereas extant ice shelves are affected less by föhn-wind-induced melt.
Georg Lackner, Florent Domine, Daniel F. Nadeau, Annie-Claude Parent, François Anctil, Matthieu Lafaysse, and Marie Dumont
The Cryosphere, 16, 127–142, https://doi.org/10.5194/tc-16-127-2022, https://doi.org/10.5194/tc-16-127-2022, 2022
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The surface energy budget is the sum of all incoming and outgoing energy fluxes at the Earth's surface and has a key role in the climate. We measured all these fluxes for an Arctic snowpack and found that most incoming energy from radiation is counterbalanced by thermal radiation and heat convection while sublimation was negligible. Overall, the snow model Crocus was able to simulate the observed energy fluxes well.
Abigail G. Hughes, Sonja Wahl, Tyler R. Jones, Alexandra Zuhr, Maria Hörhold, James W. C. White, and Hans Christian Steen-Larsen
The Cryosphere, 15, 4949–4974, https://doi.org/10.5194/tc-15-4949-2021, https://doi.org/10.5194/tc-15-4949-2021, 2021
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Water isotope records in Greenland and Antarctic ice cores are a valuable proxy for paleoclimate reconstruction and are traditionally thought to primarily reflect precipitation input. However,
post-depositional processes are hypothesized to contribute to the isotope climate signal. In this study we use laboratory experiments, field experiments, and modeling to show that sublimation and vapor–snow isotope exchange can rapidly influence the isotopic composition of the snowpack.
Saeid Bagheri Dastgerdi, Melanie Behrens, Jean-Louis Bonne, Maria Hörhold, Gerrit Lohmann, Elisabeth Schlosser, and Martin Werner
The Cryosphere, 15, 4745–4767, https://doi.org/10.5194/tc-15-4745-2021, https://doi.org/10.5194/tc-15-4745-2021, 2021
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In this study, for the first time, water vapour isotope measurements in Antarctica for all seasons of a year are performed. Local temperature is identified as the main driver of δ18O and δD variability. A similar slope of the temperature–δ18O relationship in vapour and surface snow points to the water vapour isotope content as a potential key driver. This dataset can be used as a new dataset to evaluate the capability of isotope-enhanced climate models.
Jenny V. Turton, Philipp Hochreuther, Nathalie Reimann, and Manuel T. Blau
The Cryosphere, 15, 3877–3896, https://doi.org/10.5194/tc-15-3877-2021, https://doi.org/10.5194/tc-15-3877-2021, 2021
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We assess the climatic controls of melt lake development, melt duration, melt extent, and the spatial distribution of lakes of 79°N Glacier. There is a large interannual variability in the areal extent of the lakes and the maximum elevation of lake development, which is largely controlled by the summertime air temperatures and the snowpack thickness. Late-summer lake development can be prompted by spikes in surface mass balance. There is some evidence of inland expansion of lakes over time.
Holt Hancock, Jordy Hendrikx, Markus Eckerstorfer, and Siiri Wickström
The Cryosphere, 15, 3813–3837, https://doi.org/10.5194/tc-15-3813-2021, https://doi.org/10.5194/tc-15-3813-2021, 2021
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We investigate how snow avalanche activity in central Spitsbergen, Svalbard, is broadly controlled by atmospheric circulation. Avalanche activity in this region is generally associated with atmospheric circulation conducive to increased precipitation, wind speeds, and air temperatures near Svalbard during winter storms. Our results help place avalanche activity on Spitsbergen in the wider context of Arctic environmental change and provide a foundation for improved avalanche forecasting here.
Maurice van Tiggelen, Paul C. J. P. Smeets, Carleen H. Reijmer, Bert Wouters, Jakob F. Steiner, Emile J. Nieuwstraten, Walter W. Immerzeel, and Michiel R. van den Broeke
The Cryosphere, 15, 2601–2621, https://doi.org/10.5194/tc-15-2601-2021, https://doi.org/10.5194/tc-15-2601-2021, 2021
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We developed a method to estimate the aerodynamic properties of the Greenland Ice Sheet surface using either UAV or ICESat-2 elevation data. We show that this new method is able to reproduce the important spatiotemporal variability in surface aerodynamic roughness, measured by the field observations. The new maps of surface roughness can be used in atmospheric models to improve simulations of surface turbulent heat fluxes and therefore surface energy and mass balance over rough ice worldwide.
Diana Francis, Kyle S. Mattingly, Stef Lhermitte, Marouane Temimi, and Petra Heil
The Cryosphere, 15, 2147–2165, https://doi.org/10.5194/tc-15-2147-2021, https://doi.org/10.5194/tc-15-2147-2021, 2021
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The unexpected September 2019 calving event from the Amery Ice Shelf, the largest since 1963 and which occurred almost a decade earlier than expected, was triggered by atmospheric extremes. Explosive twin polar cyclones provided a deterministic role in this event by creating oceanward sea surface slope triggering the calving. The observed record-anomalous atmospheric conditions were promoted by blocking ridges and Antarctic-wide anomalous poleward transport of heat and moisture.
Thorsten Bartels-Rausch, Xiangrui Kong, Fabrizio Orlando, Luca Artiglia, Astrid Waldner, Thomas Huthwelker, and Markus Ammann
The Cryosphere, 15, 2001–2020, https://doi.org/10.5194/tc-15-2001-2021, https://doi.org/10.5194/tc-15-2001-2021, 2021
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Chemical reactions in sea salt embedded in coastal polar snow impact the composition and air quality of the atmosphere. Here, we investigate the phase changes of sodium chloride. This is of importance as chemical reactions proceed faster in liquid solutions compared to in solid salt and the precise precipitation temperature of sodium chloride is still under debate. We focus on the upper nanometres of sodium chloride–ice samples because of their role as a reactive interface in the environment.
Rebecca Mott, Ivana Stiperski, and Lindsey Nicholson
The Cryosphere, 14, 4699–4718, https://doi.org/10.5194/tc-14-4699-2020, https://doi.org/10.5194/tc-14-4699-2020, 2020
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The Hintereisferner Experiment (HEFEX) investigated spatial and temporal dynamics of the near-surface boundary layer and associated heat exchange processes close to the glacier surface during the melting season. Turbulence data suggest that strong changes in the local thermodynamic characteristics occur when westerly flows disturbed prevailing katabatic flow, forming across-glacier flows and facilitating warm-air advection from the surrounding ice-free areas, which potentially promote ice melt.
Julián Gelman Constantin, Lucas Ruiz, Gustavo Villarosa, Valeria Outes, Facundo N. Bajano, Cenlin He, Hector Bajano, and Laura Dawidowski
The Cryosphere, 14, 4581–4601, https://doi.org/10.5194/tc-14-4581-2020, https://doi.org/10.5194/tc-14-4581-2020, 2020
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We present the results of two field campaigns and modeling activities on the impact of atmospheric particles on Alerce Glacier (Argentinean Andes). We found that volcanic ash remains at different snow layers several years after eruption, increasing light absorption on the glacier surface (with a minor contribution of soot). This leads to 36 % higher annual glacier melting. We find remarkably that volcano eruptions in 2011 and 2015 have a relevant effect on the glacier even in 2016 and 2017.
Jenny V. Turton, Amélie Kirchgaessner, Andrew N. Ross, John C. King, and Peter Kuipers Munneke
The Cryosphere, 14, 4165–4180, https://doi.org/10.5194/tc-14-4165-2020, https://doi.org/10.5194/tc-14-4165-2020, 2020
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Föhn winds are warm and dry downslope winds in the lee of a mountain range, such as the Antarctic Peninsula. Föhn winds heat the ice of the Larsen C Ice Shelf at the base of the mountains and promote more melting than during non-föhn periods in spring, summer and autumn in both model output and observations. Especially in spring, when they are most frequent, föhn winds can extend the melt season by over a month and cause a similar magnitude of melting to that observed in summer.
Marie G. P. Cavitte, Quentin Dalaiden, Hugues Goosse, Jan T. M. Lenaerts, and Elizabeth R. Thomas
The Cryosphere, 14, 4083–4102, https://doi.org/10.5194/tc-14-4083-2020, https://doi.org/10.5194/tc-14-4083-2020, 2020
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Surface mass balance (SMB) and surface air temperature (SAT) are correlated at the regional scale for most of Antarctica, SMB and δ18O. Areas with low/no correlation are where wind processes (foehn, katabatic wind warming, and erosion) are sufficiently active to overwhelm the synoptic-scale snow accumulation. Measured in ice cores, the link between SMB, SAT, and δ18O is much weaker. Random noise can be removed by core record averaging but local processes perturb the correlation systematically.
Dimitri Osmont, Sandra Brugger, Anina Gilgen, Helga Weber, Michael Sigl, Robin L. Modini, Christoph Schwörer, Willy Tinner, Stefan Wunderle, and Margit Schwikowski
The Cryosphere, 14, 3731–3745, https://doi.org/10.5194/tc-14-3731-2020, https://doi.org/10.5194/tc-14-3731-2020, 2020
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In this interdisciplinary case study, we were able to link biomass burning emissions from the June 2017 wildfires in Portugal to their deposition in the snowpack at Jungfraujoch, Swiss Alps. We analysed black carbon and charcoal in the snowpack, calculated backward trajectories, and monitored the fire evolution by remote sensing. Such case studies help to understand the representativity of biomass burning records in ice cores and how biomass burning tracers are archived in the snowpack.
Wenkai Li, Shuzhen Hu, Pang-Chi Hsu, Weidong Guo, and Jiangfeng Wei
The Cryosphere, 14, 3565–3579, https://doi.org/10.5194/tc-14-3565-2020, https://doi.org/10.5194/tc-14-3565-2020, 2020
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Understanding the forecasting skills of the subseasonal-to-seasonal (S2S) model on Tibetan Plateau snow cover (TPSC) is the first step to applying the S2S model to hydrological forecasts over the Tibetan Plateau. This study conducted a multimodel comparison of the TPSC prediction skill to learn about their performance in capturing TPSC variability. S2S models can skillfully forecast TPSC within a lead time of 2 weeks but show limited skill beyond 3 weeks. Systematic biases of TPSC were found.
Remco J. de Kok, Philip D. A. Kraaijenbrink, Obbe A. Tuinenburg, Pleun N. J. Bonekamp, and Walter W. Immerzeel
The Cryosphere, 14, 3215–3234, https://doi.org/10.5194/tc-14-3215-2020, https://doi.org/10.5194/tc-14-3215-2020, 2020
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Glaciers worldwide are shrinking, yet glaciers in parts of High Mountain Asia are growing. Using models of the regional climate and glacier growth, we reproduce the observed patterns of glacier growth and shrinkage in High Mountain Asia of the last decades. Increases in snow, in part from water that comes from lowland agriculture, have probably been more important than changes in temperature to explain the growing glaciers. We now better understand changes in the crucial mountain water cycle.
Nikolas O. Aksamit and John W. Pomeroy
The Cryosphere, 14, 2795–2807, https://doi.org/10.5194/tc-14-2795-2020, https://doi.org/10.5194/tc-14-2795-2020, 2020
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In cold regions, it is increasingly important to quantify the amount of water stored as snow at the end of winter. Current models are inconsistent in their estimates of snow sublimation due to atmospheric turbulence. Specific wind structures have been identified that amplify potential rates of surface and blowing snow sublimation during blowing snow storms. The recurrence of these motions has been modeled by a simple scaling argument that has its foundation in turbulent boundary layer theory.
Andrew J. Schwartz, Hamish A. McGowan, Alison Theobald, and Nik Callow
The Cryosphere, 14, 2755–2774, https://doi.org/10.5194/tc-14-2755-2020, https://doi.org/10.5194/tc-14-2755-2020, 2020
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This study measured energy available for snowmelt during the 2016 and 2017 snow seasons in Kosciuszko National Park, NSW, Australia, and identified common traits for days with similar weather characteristics. The analysis showed that energy available for snowmelt was highest in the days before cold fronts passed through the region due to higher air temperatures. Regardless of differences in daily weather characteristics, solar radiation contributed the highest amount of energy to snowpack melt.
Benjamin Walter, Hendrik Huwald, Josué Gehring, Yves Bühler, and Michael Lehning
The Cryosphere, 14, 1779–1794, https://doi.org/10.5194/tc-14-1779-2020, https://doi.org/10.5194/tc-14-1779-2020, 2020
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We applied a horizontally mounted low-cost precipitation radar to measure velocities, frequency of occurrence, travel distances and turbulence characteristics of blowing snow off a mountain ridge. Our analysis provides a first insight into the potential of radar measurements for determining blowing snow characteristics, improves our understanding of mountain ridge blowing snow events and serves as a valuable data basis for validating coupled numerical weather and snowpack simulations.
Charles Amory and Christoph Kittel
The Cryosphere, 13, 3405–3412, https://doi.org/10.5194/tc-13-3405-2019, https://doi.org/10.5194/tc-13-3405-2019, 2019
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Snow mass fluxes and vertical profiles of relative humidity are used to document concurrent occurrences of drifting snow and near-surface air saturation at a site dominated by katabatic winds in East Antarctica. Despite a high prevalence of drifting snow conditions, we demonstrate that saturation is reached only in the most extreme wind and transport conditions and discuss implications for the understanding of surface mass and atmospheric moisture budgets of the Antarctic ice sheet.
Varun Sharma, Louise Braud, and Michael Lehning
The Cryosphere, 13, 3239–3260, https://doi.org/10.5194/tc-13-3239-2019, https://doi.org/10.5194/tc-13-3239-2019, 2019
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Snow surfaces, under the action of wind, form beautiful shapes such as waves and dunes. This study is the first ever study to simulate these shapes using a state-of-the-art numerical modelling tool. While these beautiful and ephemeral shapes on snow surfaces are fascinating from a purely aesthetic point of view, they are also critical in regulating the transfer of heat and mass between the atmosphere and snowpacks, thus being of huge importance to the Earth system.
Nakbin Choi, Kyu-Myong Kim, Young-Kwon Lim, and Myong-In Lee
The Cryosphere, 13, 3007–3021, https://doi.org/10.5194/tc-13-3007-2019, https://doi.org/10.5194/tc-13-3007-2019, 2019
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This study compares the decadal changes of the leading patterns of sea level pressure between the early (1982–1997) and the recent (1998–2017) periods as well as their influences on the Arctic sea ice extent (SIE) variability. The correlation between the Arctic Dipole (AD) mode and SIE becomes significant in the recent period, not in the past, due to its spatial pattern change. This tends to enhance meridional wind over the Fram Strait and sea ice discharge to the Atlantic.
Yvan Orsolini, Martin Wegmann, Emanuel Dutra, Boqi Liu, Gianpaolo Balsamo, Kun Yang, Patricia de Rosnay, Congwen Zhu, Wenli Wang, Retish Senan, and Gabriele Arduini
The Cryosphere, 13, 2221–2239, https://doi.org/10.5194/tc-13-2221-2019, https://doi.org/10.5194/tc-13-2221-2019, 2019
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The Tibetan Plateau region exerts a considerable influence on regional climate, yet the snowpack over that region is poorly represented in both climate and forecast models due a large precipitation and snowfall bias. We evaluate the snowpack in state-of-the-art atmospheric reanalyses against in situ observations and satellite remote sensing products. Improved snow initialisation through better use of snow observations in reanalyses may improve medium-range to seasonal weather forecasts.
Haibo Bi, Qinghua Yang, Xi Liang, Liang Zhang, Yunhe Wang, Yu Liang, and Haijun Huang
The Cryosphere, 13, 1423–1439, https://doi.org/10.5194/tc-13-1423-2019, https://doi.org/10.5194/tc-13-1423-2019, 2019
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The Arctic sea ice extent is diminishing, which is deemed an immediate response to a warmer Earth. However, quantitative estimates about the contribution due to transport and melt to the sea ice loss are still vague. This study mainly utilizes satellite observations to quantify the dynamic and thermodynamic aspects of ice loss for nearly 40 years (1979–2016). In addition, the potential impacts on ice reduction due to different atmospheric circulation pattern are highlighted.
Noel Fitzpatrick, Valentina Radić, and Brian Menounos
The Cryosphere, 13, 1051–1071, https://doi.org/10.5194/tc-13-1051-2019, https://doi.org/10.5194/tc-13-1051-2019, 2019
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Measurements of surface roughness are rare on glaciers, despite being an important control for heat exchange with the atmosphere and surface melt. In this study, roughness values were determined through measurements at multiple locations and seasons and found to vary across glacier surfaces and to differ from commonly assumed values in melt models. Two new methods that remotely determine roughness from digital elevation models returned good performance and may facilitate improved melt modelling.
Jui-Lin Frank Li, Mark Richardson, Wei-Liang Lee, Eric Fetzer, Graeme Stephens, Jonathan Jiang, Yulan Hong, Yi-Hui Wang, Jia-Yuh Yu, and Yinghui Liu
The Cryosphere, 13, 969–980, https://doi.org/10.5194/tc-13-969-2019, https://doi.org/10.5194/tc-13-969-2019, 2019
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Observed summer Arctic sea ice retreat has been faster than simulated by the average CMIP5 models, most of which exclude falling ice particles from their radiative calculations.
We use controlled CESM1-CAM5 simulations to show for the first time that snowflakes' radiative effects can accelerate sea ice retreat. September retreat rates are doubled above current CO2 levels, highlighting falling ice radiative effects as a high priority for inclusion in future modelling of the Arctic.
Dušan Materić, Elke Ludewig, Kangming Xu, Thomas Röckmann, and Rupert Holzinger
The Cryosphere, 13, 297–307, https://doi.org/10.5194/tc-13-297-2019, https://doi.org/10.5194/tc-13-297-2019, 2019
Zhiwen Dong, Shichang Kang, Dahe Qin, Yaping Shao, Sven Ulbrich, and Xiang Qin
The Cryosphere, 12, 3877–3890, https://doi.org/10.5194/tc-12-3877-2018, https://doi.org/10.5194/tc-12-3877-2018, 2018
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This study aimed to provide a first and unique record of physicochemical properties and mixing states of LAPs at the glacier and atmosphere interface over the northeastern Tibetan Plateau to determine the individual LAPs' structure aging and mixing state changes through the atmospheric deposition process from atmosphere to glacier–snowpack surface, thereby helping to characterize the LAPs' radiative forcing and climate effects in the cryosphere region.
Cited articles
Barnes, P. R. F., Wolff, E. W., Mallard, D. C., and Mader, H. M.: SEM studies of the morphology and chemistry of polar ice, Microsc. Res. Techniq., 62, 62–69, https://doi.org/10.1002/jemt.10385, 2003.
Barret, M., Domine, F., Houdier, S., Gallet, J. C., Weibring, P., Walega, J., Fried, A., and Richter, D.: Formaldehyde in the Alaskan Arctic snowpack: Partitioning and physical processes involved in air-snow exchanges, J. Geophys. Res.-Atmos., 116, D00R03, https://doi.org/10.1029/2011jd016038, 2011.
Bartels-Rausch, T., Jacobi, H.-W., Kahan, T. F., Thomas, J. L., Thomson, E. S., Abbatt, J. P. D., Ammann, M., Blackford, J. R., Bluhm, H., Boxe, C., Domine, F., Frey, M. M., Gladich, I., Guzmán, M. I., Heger, D., Huthwelker, Th., Klán, P., Kuhs, W. F., Kuo, M. H., Maus, S., Moussa, S. G., McNeill, V. F., Newberg, J. T., Pettersson, J. B. C., Roeselová, M., and Sodeau, J. R.: A review of air–ice chemical and physical interactions (AICI): liquids, quasi-liquids, and solids in snow, Atmos. Chem. Phys., 14, 1587–1633, https://doi.org/10.5194/acp-14-1587-2014, 2014.
Beine, H., Anastasio, C., Esposito, G., Patten, K., Wilkening, E., Domine, F., Voisin, D., Barret, M., Houdier, S., and Hall, S.: Soluble, light-absorbing species in snow at Barrow, Alaska, J. Geophys. Res.-Atmos., 116, D00R05, https://doi.org/10.1029/2011jd016181, 2011.
Beine, H. J., Domine, F., Simpson, W., Honrath, R. E., Sparapani, R., Zhou, X. L., and King, M.: Snow-pile and chamber experiments during the Polar Sunrise Experiment “Alert 2000”: exploration of nitrogen chemistry, Atmos. Environ., 36, 2707–2719, https://doi.org/10.1016/s1352-2310(02)00120-6, 2002.
Blanke, A., Beckmann, F., and Misof, B.: The head anatomy of Epiophlebia superstes (Odonata: Epiophlebiidae), Org. Divers. Evol., 13, 55–66, https://doi.org/10.1007/s13127-012-0097-z, 2013.
Carte, A. E.: Air bubbles in ice, P. Phys. Soc. Lond., 77, 757–768, https://doi.org/10.1088/0370-1328/77/3/327, 1961.
Chen, S. and Baker, I.: Evolution of individual snowflakes during metamorphism, J. Geophys. Res.-Atmos., 115, D21114, https://doi.org/10.1029/2010jd014132, 2010.
Cheng, J., Soetjipto, C., Hoffmann, M. R., and Colussi, A. J.: Confocal Fluorescence Microscopy of the Morphology and Composition of Interstitial Fluids in Freezing Electrolyte Solutions, J. Phys. Chem. Lett., 1, 374–378, https://doi.org/10.1021/jz9000888, 2010.
Cho, H., Shepson, P. B., Barrie, L. A., Cowin, J. P., and Zaveri, R.: NMR investigation of the quasi-brine layer in ice/brine mixtures, J. Phys. Chem. B, 106, 11226–11232, https://doi.org/10.1021/jp020449+, 2002.
Chu, L. and Anastasio, C.: Quantum yields of hydroxyl radical and nitrogen dioxide from the photolysis of nitrate on ice, J. Phys. Chem. A, 107, 9594–9602, https://doi.org/10.1021/jp0349132, 2003.
Chu, L. and Anastasio, C.: Formation of hydroxyl radical from the photolysis of frozen hydrogen peroxide, J. Phys. Chem. A, 109, 6264–6271, https://doi.org/10.1021/jp051415f, 2005.
Dadic, R., Light, B., and Warren, S. G.: Migration of air bubbles in ice under a temperature gradient, with application to “Snowball Earth”, J. Geophys. Res.-Atmos., 115, D18125, https://doi.org/10.1029/2010jd014148, 2010.
Dibb, J. E. and Arsenault, M.: Shouldn't snowpacks be sources of monocarboxylic acids?, Atmos. Environ., 36, 2513–2522, 2002.
Domine, F. and Shepson, P. B.: Air-snow interactions and atmospheric chemistry, Science, 297, 1506–1510, 2002.
Domine, F., Albert, M., Huthwelker, T., Jacobi, H.-W., Kokhanovsky, A. A., Lehning, M., Picard, G., and Simpson, W. R.: Snow physics as relevant to snow photochemistry, Atmos. Chem. Phys., 8, 171–208, https://doi.org/10.5194/acp-8-171-2008, 2008.
Douglas, T. A. and Sturm, M.: Arctic haze, mercury and the chemical composition of snow across northwestern Alaska, Atmos. Environ., 38, 805–820, https://doi.org/10.1016/j.atmosenv.2003.10.042, 2004.
Evans, N. J., McInnes, B. I. A., Squelch, A. P., Austin, P. J., McDonald, B. J., and Wu, Q. H.: Application of X-ray micro-computed tomography in (U-Th)/He thermochronology, Chem. Geol., 257, 101–113, https://doi.org/10.1016/j.chemgeo.2008.08.021, 2008.
Grannas, A. M., Jones, A. E., Dibb, J., Ammann, M., Anastasio, C., Beine, H. J., Bergin, M., Bottenheim, J., Boxe, C. S., Carver, G., Chen, G., Crawford, J. H., Dominé, F., Frey, M. M., Guzmán, M. I., Heard, D. E., Helmig, D., Hoffmann, M. R., Honrath, R. E., Huey, L. G., Hutterli, M., Jacobi, H. W., Klán, P., Lefer, B., McConnell, J., Plane, J., Sander, R., Savarino, J., Shepson, P. B., Simpson, W. R., Sodeau, J. R., von Glasow, R., Weller, R., Wolff, E. W., and Zhu, T.: An overview of snow photochemistry: evidence, mechanisms and impacts, Atmos. Chem. Phys., 7, 4329–4373, https://doi.org/10.5194/acp-7-4329-2007, 2007.
Gross, G. W., Wu, C. H., Bryant, L., and McKee, C.: Concentration dependent solute redistribution at ice-water phase boundary. 2. Experimental investigation, J. Chem. Phys., 62, 3085–3092, https://doi.org/10.1063/1.430909, 1975.
Hallett, J.: Experimental studies of the crystallization of supercooled water, J. Atmos. Sci., 21, 671–682, https://doi.org/10.1175/1520-0469(1964)021<0671:esotco>2.0.co;2, 1964.
Haynes, W. M. E.: CRC Handbook of Chemistry and Physics, 95 ed., CRC Press, Boca Raton, Florida, USA, 2014.
Heger, D., Jirkovsky, J., and Klan, P.: Aggregation of methylene blue in frozen aqueous solutions studied by absorption spectroscopy, J. Phys. Chem. A, 109, 6702–6709, https://doi.org/10.1021/jp050439j, 2005.
Heger, D., Klanova, J., and Klan, P.: Enhanced protonation of cresol red in acidic aqueous solutions caused by freezing, J. Phys. Chem. B, 110, 1277–1287, https://doi.org/10.1021/jp0553683, 2006.
Heggli, M., Kochle, B., Matzl, M., Pinzer, B. R., Riche, F., Steiner, S., Steinfeld, D., and Schneebeli, M.: Measuring snow in 3-D using X-ray tomography: assessment of visualization techniques, Ann. Glaciol., 52, 231–236, 2011.
Hobbs, P. V.: Ice Physics, Oxford University Press, Oxford, England, 1974.
Hullar, T. and Anastasio, C.: Yields of hydrogen peroxide from the reaction of hydroxyl radical with organic compounds in solution and ice, Atmos. Chem. Phys., 11, 7209–7222, https://doi.org/10.5194/acp-11-7209-2011, 2011.
Hullar, T., Paige, D. F., Rowland, D. J., and Anastasio, C.: Compact cold stage for micro-computerized tomography imaging of chilled or frozen samples, Rev. Sci. Instrum., 85, 043708, https://doi.org/10.1063/1.4871473, 2014.
Jacobi, H. W., Bales, R. C., Honrath, R. E., Peterson, M. C., Dibb, J. E., Swanson, A. L., and Albert, M. R.: Reactive trace gases measured in the interstitial air of surface snow at Summit, Greenland, Atmos. Environ., 38, 1687–1697, https://doi.org/10.1016/j.atmosenv.2004.01.004, 2004.
Jacobi, H. W., Annor, T., and Quansah, E.: Investigation of the photochemical decomposition of nitrate, hydrogen peroxide, and formaldehyde in artificial snow, J. Photoch. Photobio. A, 179, 330–338, https://doi.org/10.1016/j.jphotochem.2005.09.001, 2006.
Kahan, T. F. and Donaldson, D. J.: Photolysis of polycyclic aromatic hydrocarbons on water and ice surfaces, J. Phys. Chem. A, 111, 1277–1285, https://doi.org/10.1021/jp066660t, 2007.
Kahan, T. F. and Donaldson, D. J.: Benzene photolysis on ice: Implications for the fate of organic contaminants in the winter, Environ. Sci. Technol., 44, 3819–3824, https://doi.org/10.1021/es100448h, 2010.
Kahan, T. F., Zhao, R., Jumaa, K. B., and Donaldson, D. J.: Anthracene photolysis in aqueous solution and ice: Photon flux dependence and comparison of kinetics in bulk ice and at the air-ice interface, Environ. Sci. Technol., 44, 1302–1306, https://doi.org/10.1021/es9031612, 2010.
Kurkova, R., Ray, D., Nachtigallova, D., and Klan, P.: Chemistry of small organic molecules on snow grains: The applicability of artificial snow for environmental studies, Environ. Sci. Technol., 45, 3430–3436, https://doi.org/10.1021/es104095g, 2011.
Lake, R. A. and Lewis, E. L.: Salt rejection by sea ice during growth, J. Geophys. Res., 75, 583–597, https://doi.org/10.1029/JC075i003p00583, 1970.
Light, B., Brandt, R. E., and Warren, S. G.: Hydrohalite in cold sea ice: Laboratory observations of single crystals, surface accumulations, and migration rates under a temperature gradient, with application to “Snowball Earth”, J. Geophys. Res.-Oceans, 114, C07018, https://doi.org/10.1029/2008jc005211, 2009.
Lomonaco, R., Albert, M., and Baker, I.: Microstructural evolution of fine-grained layers through the firn column at Summit, Greenland, J. Glaciol., 57, 755–762, 2011.
Lomonaco, R. W., Chen, S., and Baker, I.: Characterization of porous snow with SEM and Micro CT, Microsc. Microanal., 15, 1110–1111, https://doi.org/10.1017/s1431927609093313, 2009.
McFall, A. S. and Anastasio, C.: Photon flux dependence on solute environment in water ices, Environ. Chem., 13, 682–687, https://doi.org/10.1071/EN15199, 2016.
Miedaner, M.: Characterization of inclusions and their distribution in natural and artificial ice samples by synchrotron cryo-micro-tomography (SCXRTM), thesis, Johannes Gutenberg Universität, Mainz, Germany, 2007.
Miedaner, M. M., Huthwelker, T., Enzmann, F., Kersten, M., Stampanoni, M., and Ammann, M.: X-ray tomographic characterization of impurities in polycrystalline ice, Physics and Chemistry of Ice, edited by: Kuhs, W. F., Royal Society of Chemistry, Cambridge, UK, 399–407, 2007.
Neckers, D. C.: Rose Bengal, J. Photoch. Photobio. A, 47, 1–29, https://doi.org/10.1016/1010-6030(89)85002-6, 1989.
NIST: X-ray form factor, attenuation, and scattering tables, available at: http://physics.nist.gov/PhysRefData/FFast/html/form.html, last access: 5 July 2015.
Notz, D. and Worster, M. G.: Desalination processes of sea ice revisited, J. Geophys. Res.-Oceans, 114, C05006, https://doi.org/10.1029/2008jc004885, 2009.
NIH: PubChem Open Chemistry Database, available at: http://pubchem.ncbi.nlm.nih.gov, last access: 7 July 2015.
Obbard, R. W., Troderman, G., and Baker, I.: Imaging brine and air inclusions in sea ice using micro-X-ray computed tomography, J. Glaciol., 55, 1113–1115, 2009.
Petrenko, V. F. and Whitworth, R. W.: Physics of Ice, Oxford University Press, Oxford, England, 1999.
Phillips, G. J. and Simpson, W. R.: Verification of snowpack radiation transfer models using actinometry, J. Geophys. Res.-Atmos., 110, D08306 https://doi.org/10.1029/2004jd005552, 2005.
Pruppacher, H. R. and Klett, J. D.: Microphysics of clouds and precipitation, Vol. 18 of Atmospheric and oceanographic sciences library, Kluwer Acadamics Publ., Dordrecht, the Netherlands, 2010.
Ram, K. and Anastasio, C.: Photochemistry of phenanthrene, pyrene, and fluoranthene in ice and snow, Atmos. Environ., 43, 2252–2259, https://doi.org/10.1016/j.atmosenv.2009.01.044, 2009.
Rohatgi, P. and Adams, C.: Ice-brine dendritic aggregate formed on freezing of aqueous solutions, J. Glaciol., 6, 663–679, 1967.
Rosenthal, W., Saleta, J., and Dozier, J.: Scanning electron microscopy of impurity structures in snow, Cold Reg. Sci. Technol., 47, 80–89, https://doi.org/10.1016/j.coldregions.2006.08.006, 2007.
Shumskii, P. A.: Principles of Structural Glaciology, Dover Publications, Inc., New York, USA, 1964.
Sumner, A. L. and Shepson, P. B.: Snowpack production of formaldehyde and its effect on the Arctic troposphere, Nature, 398, 230–233, 1999.
Wettlaufer, J. S., Worster, M. G., and Huppert, H. E.: Natural convection during solidification of an alloy from above with application to the evolution of sea ice, J. Fluid Mech., 344, 291–316, https://doi.org/10.1017/s0022112097006022, 1997.
Yang, Q., Mayewski, P. A., Linder, E., Whitlow, S., and Twickler, M.: Chemical species spatial distribution and relationship to elevation and snow accumulation rate over the Greenland Ice Sheet, J. Geophys. Res.-Atmos., 101, 18629–18637, https://doi.org/10.1029/96jd01061, 1996.
Short summary
We study chemical reactions in snow and ice by freezing solutions in the laboratory. Although it is important to know where these chemicals are in the frozen sample (at the surface or buried in the ice), we do not understand this well. In this paper, we used X-rays to look at the chemical location in frozen samples. We found chemical location is sensitive to freezing method, sample container, and chemical characteristics, requiring careful experimental design and interpretation of results.
We study chemical reactions in snow and ice by freezing solutions in the laboratory. Although it...