Articles | Volume 8, issue 1
https://doi.org/10.5194/tc-8-245-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/tc-8-245-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
17 Feb 2014
Research article |
| 17 Feb 2014
Diffusive equilibration of N2, O2 and CO2 mixing ratios in a 1.5-million-years-old ice core
B. Bereiter
Climate and Environmental Physics, Physics Institute, University of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland
Oeschger Centre for Climate Change Research, University of Bern, 3012 Bern, Switzerland
Climate and Environmental Physics, Physics Institute, University of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland
Oeschger Centre for Climate Change Research, University of Bern, 3012 Bern, Switzerland
H. Fischer
Climate and Environmental Physics, Physics Institute, University of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland
Oeschger Centre for Climate Change Research, University of Bern, 3012 Bern, Switzerland
Climate and Environmental Physics, Physics Institute, University of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland
Oeschger Centre for Climate Change Research, University of Bern, 3012 Bern, Switzerland
J. Schwander
Climate and Environmental Physics, Physics Institute, University of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland
Oeschger Centre for Climate Change Research, University of Bern, 3012 Bern, Switzerland
Climate and Environmental Physics, Physics Institute, University of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland
Oeschger Centre for Climate Change Research, University of Bern, 3012 Bern, Switzerland
T. F. Stocker
Climate and Environmental Physics, Physics Institute, University of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland
Oeschger Centre for Climate Change Research, University of Bern, 3012 Bern, Switzerland
Climate and Environmental Physics, Physics Institute, University of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland
Oeschger Centre for Climate Change Research, University of Bern, 3012 Bern, Switzerland
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We identify signatures of large bipolar volcanic eruptions in Greenland and Antarctic ice cores during the last glacial period, which allows for a precise temporal alignment of the ice cores. Thereby the exact timing of unexplained, abrupt climatic changes occurring during the last glacial period can be determined in a global context. The study thus provides a step towards a full understanding of elements of the climate system that may also play an important role in the future.
Ece Satar, Peter Nyfeler, Bernhard Bereiter, Céline Pascale, Bernhard Niederhauser, and Markus Leuenberger
Atmos. Meas. Tech., 13, 101–117, https://doi.org/10.5194/amt-13-101-2020, https://doi.org/10.5194/amt-13-101-2020, 2020
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Good-quality measurements of atmospheric trace gases are only possible with regular calibrations and stable measurements from the standard cylinders. This study investigates instabilities due to surface effects on newly built aluminum and steel cylinders. We present measurements over a set of temperature and pressure ranges for the amount fractions of CO2, CO, CH4 and H2O using a commercial and a novel laser spectroscopic analyzer.
Svante Björck, Jesper Sjolte, Karl Ljung, Florian Adolphi, Roger Flower, Rienk H. Smittenberg, Malin E. Kylander, Thomas F. Stocker, Sofia Holmgren, Hui Jiang, Raimund Muscheler, Yamoah K. K. Afrifa, Jayne E. Rattray, and Nathalie Van der Putten
Clim. Past, 15, 1939–1958, https://doi.org/10.5194/cp-15-1939-2019, https://doi.org/10.5194/cp-15-1939-2019, 2019
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Southern Hemisphere westerlies play a key role in regulating global climate. A lake sediment record on a mid-South Atlantic island shows changes in the westerlies and hydroclimate 36.4–18.6 ka. Before 31 ka the westerlies shifted in concert with the bipolar seesaw mechanism in a fairly warm climate, followed by southerly westerlies and falling temperatures. After 27.5 ka temperatures dropped 3 °C with drier conditions and with shifting westerlies possibly triggering the variable LGM CO2 levels.
Andreas Born, Michael A. Imhof, and Thomas F. Stocker
The Cryosphere, 13, 1529–1546, https://doi.org/10.5194/tc-13-1529-2019, https://doi.org/10.5194/tc-13-1529-2019, 2019
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We present a new numerical model to simulate the surface energy and mass balance of snow and ice. While similar models exist and cover a wide range of complexity from empirical models to those that simulate the microscopic structure of individual snow grains, we aim to strike a balance between physical completeness and numerical efficiency. This new model will enable physically accurate simulations over timescales of hundreds of millennia, a key requirement of investigating ice age cycles.
Christoph C. Raible, Martina Messmer, Flavio Lehner, Thomas F. Stocker, and Richard Blender
Clim. Past, 14, 1499–1514, https://doi.org/10.5194/cp-14-1499-2018, https://doi.org/10.5194/cp-14-1499-2018, 2018
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Extratropical cyclones in winter and their characteristics are investigated in depth for the Atlantic European region from 850 to 2100 CE. During the Common Era, cyclone characteristics show pronounced variations mainly caused by internal variability of the coupled climate system. When anthropogenic forcing becomes dominant, a strong increase of extreme cyclone-related precipitation is found due to thermodynamics, though dynamical processes can play an important role during the last millennium.
Andreas Plach, Kerim H. Nisancioglu, Sébastien Le clec'h, Andreas Born, Petra M. Langebroek, Chuncheng Guo, Michael Imhof, and Thomas F. Stocker
Clim. Past, 14, 1463–1485, https://doi.org/10.5194/cp-14-1463-2018, https://doi.org/10.5194/cp-14-1463-2018, 2018
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The Greenland ice sheet is a huge frozen water reservoir which is crucial for predictions of sea level in a warming future climate. Therefore, computer models are needed to reliably simulate the melt of ice sheets. In this study, we use climate model simulations of the last period where it was warmer than today in Greenland. We test different melt models under these climatic conditions and show that the melt models show very different results under these warmer conditions.
Peter Köhler, Christoph Nehrbass-Ahles, Jochen Schmitt, Thomas F. Stocker, and Hubertus Fischer
Earth Syst. Sci. Data, 9, 363–387, https://doi.org/10.5194/essd-9-363-2017, https://doi.org/10.5194/essd-9-363-2017, 2017
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We document our best available data compilation of published ice core records of the greenhouse gases CO2, CH4, and N2O and recent measurements on firn air and atmospheric samples covering the time window from 156 000 years BP to the beginning of the year 2016 CE. A smoothing spline method is applied to translate the discrete and irregularly spaced data points into continuous time series. The radiative forcing for each greenhouse gas is computed using well-established, simple formulations.
Kathrin M. Keller, Sebastian Lienert, Anil Bozbiyik, Thomas F. Stocker, Olga V. Churakova (Sidorova), David C. Frank, Stefan Klesse, Charles D. Koven, Markus Leuenberger, William J. Riley, Matthias Saurer, Rolf Siegwolf, Rosemarie B. Weigt, and Fortunat Joos
Biogeosciences, 14, 2641–2673, https://doi.org/10.5194/bg-14-2641-2017, https://doi.org/10.5194/bg-14-2641-2017, 2017
Johannes C. Laube, Norfazrin Mohd Hanif, Patricia Martinerie, Eileen Gallacher, Paul J. Fraser, Ray Langenfelds, Carl A. M. Brenninkmeijer, Jakob Schwander, Emmanuel Witrant, Jia-Lin Wang, Chang-Feng Ou-Yang, Lauren J. Gooch, Claire E. Reeves, William T. Sturges, and David E. Oram
Atmos. Chem. Phys., 16, 15347–15358, https://doi.org/10.5194/acp-16-15347-2016, https://doi.org/10.5194/acp-16-15347-2016, 2016
Stefan Muthers, Christoph C. Raible, Eugene Rozanov, and Thomas F. Stocker
Earth Syst. Dynam., 7, 877–892, https://doi.org/10.5194/esd-7-877-2016, https://doi.org/10.5194/esd-7-877-2016, 2016
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The Atlantic Meridional Overturning Circulation (AMOC) is an important oceanic circulation system which transports large amounts of heat from the tropics to the north. This circulation is strengthened when less solar irradiance reaches the Earth, e.g. due to reduced solar activity or geoengineering techniques. In climate models, however, this response is overestimated when chemistry–climate interactions and the following shift in the atmospheric circulation systems are not considered.
Niklaus Merz, Andreas Born, Christoph C. Raible, and Thomas F. Stocker
Clim. Past, 12, 2011–2031, https://doi.org/10.5194/cp-12-2011-2016, https://doi.org/10.5194/cp-12-2011-2016, 2016
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The last (Eemian) interglacial is studied with a global climate model focusing on Greenland and the adjacent high latitudes. A set of model experiments demonstrates the crucial role of changes in sea ice and sea surface temperatures for the magnitude of Eemian atmospheric warming. Greenland temperatures are found highly sensitive to sea ice changes in the Nordic Seas but rather insensitive to changes in the Labrador Sea. This behavior has important implications for Greenland ice core signals.
Olivier Eicher, Matthias Baumgartner, Adrian Schilt, Jochen Schmitt, Jakob Schwander, Thomas F. Stocker, and Hubertus Fischer
Clim. Past, 12, 1979–1993, https://doi.org/10.5194/cp-12-1979-2016, https://doi.org/10.5194/cp-12-1979-2016, 2016
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A new high-resolution total air content record over the NGRIP ice core, spanning 0.3–120 kyr is presented. In agreement with Antarctic ice cores, we find a strong local insolation signature but also 3–5 % decreases in total air content as a local response to Dansgaard–Oeschger events, which can only partly be explained by changes in surface pressure and temperature. Accordingly, a dynamic response of firnification to rapid climate changes on the Greenland ice sheet must have occurred.
Cathy M. Trudinger, Paul J. Fraser, David M. Etheridge, William T. Sturges, Martin K. Vollmer, Matt Rigby, Patricia Martinerie, Jens Mühle, David R. Worton, Paul B. Krummel, L. Paul Steele, Benjamin R. Miller, Johannes Laube, Francis S. Mani, Peter J. Rayner, Christina M. Harth, Emmanuel Witrant, Thomas Blunier, Jakob Schwander, Simon O'Doherty, and Mark Battle
Atmos. Chem. Phys., 16, 11733–11754, https://doi.org/10.5194/acp-16-11733-2016, https://doi.org/10.5194/acp-16-11733-2016, 2016
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Perfluorocarbons (PFCs) are potent, long-lived and mostly man-made greenhouse gases released to the atmosphere mainly during aluminium production and semiconductor manufacture. Here we present the first continuous histories of three PFCs from 1800 to 2014, derived from measurements of these PFCs in the atmosphere and in air bubbles in polar ice. The records show how human actions have affected these important greenhouse gases over the past century.
Basil Neff, Andreas Born, and Thomas F. Stocker
Earth Syst. Dynam., 7, 397–418, https://doi.org/10.5194/esd-7-397-2016, https://doi.org/10.5194/esd-7-397-2016, 2016
T. Kobashi, T. Ikeda-Fukazawa, M. Suwa, J. Schwander, T. Kameda, J. Lundin, A. Hori, H. Motoyama, M. Döring, and M. Leuenberger
Atmos. Chem. Phys., 15, 13895–13914, https://doi.org/10.5194/acp-15-13895-2015, https://doi.org/10.5194/acp-15-13895-2015, 2015
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We find that argon/nitrogen ratios of trapped air in the GISP2 ice core on “gas ages” are significantly negatively correlated with accumulation rate changes over the past 6000 years. Lines of evidence indicate that changes in overloading pressure at bubble closeoff depths induced the gas fractionation in closed bubbles. Further understanding of the fractionation processes may lead to a new proxy for the past temperature and accumulation rate.
J.-L. Tison, M. de Angelis, G. Littot, E. Wolff, H. Fischer, M. Hansson, M. Bigler, R. Udisti, A. Wegner, J. Jouzel, B. Stenni, S. Johnsen, V. Masson-Delmotte, A. Landais, V. Lipenkov, L. Loulergue, J.-M. Barnola, J.-R. Petit, B. Delmonte, G. Dreyfus, D. Dahl-Jensen, G. Durand, B. Bereiter, A. Schilt, R. Spahni, K. Pol, R. Lorrain, R. Souchez, and D. Samyn
The Cryosphere, 9, 1633–1648, https://doi.org/10.5194/tc-9-1633-2015, https://doi.org/10.5194/tc-9-1633-2015, 2015
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The oldest paleoclimatic information is buried within the lowermost layers of deep ice cores. It is therefore essential to judge how deep these records remain unaltered. We study the bottom 60 meters of the EPICA Dome C ice core from central Antarctica to show that the paleoclimatic signal is only affected at the small scale (decimeters) in terms of some of the global ice properties. However our data suggest that the time scale has been considerably distorted by mechanical stretching.
F. Lehner, F. Joos, C. C. Raible, J. Mignot, A. Born, K. M. Keller, and T. F. Stocker
Earth Syst. Dynam., 6, 411–434, https://doi.org/10.5194/esd-6-411-2015, https://doi.org/10.5194/esd-6-411-2015, 2015
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We present the first last-millennium simulation with the Community Earth System Model (CESM) including an interactive carbon cycle in both ocean and land component. Volcanic eruptions emerge as the strongest forcing factor for the preindustrial climate and carbon cycle. We estimate the climate-carbon-cycle feedback in CESM to be at the lower bounds of empirical estimates (1.3ppm/°C). The time of emergence for interannual global land and ocean carbon uptake rates are 1947 and 1877, respectively.
S. J. Allin, J. C. Laube, E. Witrant, J. Kaiser, E. McKenna, P. Dennis, R. Mulvaney, E. Capron, P. Martinerie, T. Röckmann, T. Blunier, J. Schwander, P. J. Fraser, R. L. Langenfelds, and W. T. Sturges
Atmos. Chem. Phys., 15, 6867–6877, https://doi.org/10.5194/acp-15-6867-2015, https://doi.org/10.5194/acp-15-6867-2015, 2015
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Stratospheric ozone protects life on Earth from harmful UV-B radiation. Chlorofluorocarbons (CFCs) are man-made compounds which act to destroy this barrier.
This paper presents (1) the first measurements of the stratospheric δ(37Cl) of CFCs -11 and -113; (2) the first quantification of long-term trends in the tropospheric δ(37Cl) of CFCs -11, -12 and -113.
This study provides a better understanding of source and sink processes associated with these destructive compounds.
N. Merz, A. Born, C. C. Raible, H. Fischer, and T. F. Stocker
Clim. Past, 10, 1221–1238, https://doi.org/10.5194/cp-10-1221-2014, https://doi.org/10.5194/cp-10-1221-2014, 2014
P. Kindler, M. Guillevic, M. Baumgartner, J. Schwander, A. Landais, and M. Leuenberger
Clim. Past, 10, 887–902, https://doi.org/10.5194/cp-10-887-2014, https://doi.org/10.5194/cp-10-887-2014, 2014
M. Baumgartner, P. Kindler, O. Eicher, G. Floch, A. Schilt, J. Schwander, R. Spahni, E. Capron, J. Chappellaz, M. Leuenberger, H. Fischer, and T. F. Stocker
Clim. Past, 10, 903–920, https://doi.org/10.5194/cp-10-903-2014, https://doi.org/10.5194/cp-10-903-2014, 2014
S. Schüpbach, U. Federer, P. R. Kaufmann, S. Albani, C. Barbante, T. F. Stocker, and H. Fischer
Clim. Past, 9, 2789–2807, https://doi.org/10.5194/cp-9-2789-2013, https://doi.org/10.5194/cp-9-2789-2013, 2013
H. Fischer, J. Severinghaus, E. Brook, E. Wolff, M. Albert, O. Alemany, R. Arthern, C. Bentley, D. Blankenship, J. Chappellaz, T. Creyts, D. Dahl-Jensen, M. Dinn, M. Frezzotti, S. Fujita, H. Gallee, R. Hindmarsh, D. Hudspeth, G. Jugie, K. Kawamura, V. Lipenkov, H. Miller, R. Mulvaney, F. Parrenin, F. Pattyn, C. Ritz, J. Schwander, D. Steinhage, T. van Ommen, and F. Wilhelms
Clim. Past, 9, 2489–2505, https://doi.org/10.5194/cp-9-2489-2013, https://doi.org/10.5194/cp-9-2489-2013, 2013
N. Merz, C. C. Raible, H. Fischer, V. Varma, M. Prange, and T. F. Stocker
Clim. Past, 9, 2433–2450, https://doi.org/10.5194/cp-9-2433-2013, https://doi.org/10.5194/cp-9-2433-2013, 2013
V. V. Petrenko, P. Martinerie, P. Novelli, D. M. Etheridge, I. Levin, Z. Wang, T. Blunier, J. Chappellaz, J. Kaiser, P. Lang, L. P. Steele, S. Hammer, J. Mak, R. L. Langenfelds, J. Schwander, J. P. Severinghaus, E. Witrant, G. Petron, M. O. Battle, G. Forster, W. T. Sturges, J.-F. Lamarque, K. Steffen, and J. W. C. White
Atmos. Chem. Phys., 13, 7567–7585, https://doi.org/10.5194/acp-13-7567-2013, https://doi.org/10.5194/acp-13-7567-2013, 2013
A. Svensson, M. Bigler, T. Blunier, H. B. Clausen, D. Dahl-Jensen, H. Fischer, S. Fujita, K. Goto-Azuma, S. J. Johnsen, K. Kawamura, S. Kipfstuhl, M. Kohno, F. Parrenin, T. Popp, S. O. Rasmussen, J. Schwander, I. Seierstad, M. Severi, J. P. Steffensen, R. Udisti, R. Uemura, P. Vallelonga, B. M. Vinther, A. Wegner, F. Wilhelms, and M. Winstrup
Clim. Past, 9, 749–766, https://doi.org/10.5194/cp-9-749-2013, https://doi.org/10.5194/cp-9-749-2013, 2013
A. Born, T. F. Stocker, and A. B. Sandø
Ocean Sci. Discuss., https://doi.org/10.5194/osd-10-555-2013, https://doi.org/10.5194/osd-10-555-2013, 2013
Revised manuscript not accepted
B. Bereiter, T. F. Stocker, and H. Fischer
Atmos. Meas. Tech., 6, 251–262, https://doi.org/10.5194/amt-6-251-2013, https://doi.org/10.5194/amt-6-251-2013, 2013
Related subject area
Ice Cores
The grain-scale signature of isotopic diffusion in ice
Combining traditional and novel techniques to increase our understanding of the lock-in depth of atmospheric gases in polar ice cores – results from the EastGRIP region
Scientific history, sampling approach, and physical characterization of the Camp Century subglacial material, a rare archive from beneath the Greenland Ice Sheet
Novel approach to estimate the water isotope diffusion length in deep ice cores with an application to Marine Isotope Stage 19 in the Dome C ice core
The potential of in situ cosmogenic 14CO in ice cores as a proxy for galactic cosmic ray flux variations
Characterization of in situ cosmogenic 14CO production, retention and loss in firn and shallow ice at Summit, Greenland
Research into mechanical modeling based on characteristics of the fracture mechanics of ice cutting for scientific drilling in polar regions
Temporal markers in a temperate ice core: insights from 3H and 137Cs profiles from the Adamello Glacier
Review article: Melt-affected ice cores for polar research in a warming world
Impact of subsurface crevassing on the depth–age relationship of high-Alpine ice cores extracted at Col du Dôme between 1994 and 2012
Fifty years of firn evolution on Grigoriev ice cap, Tien Shan, Kyrgyzstan
Climate change is rapidly deteriorating the climatic signal in Svalbard glaciers
Laser Ablation – ICP-MS measurements for high resolution chemical ice core analyses with a first application to an ice core from Skytrain Ice Rise (Antarctica)
Identifying atmospheric processes favouring the formation of bubble-free layers in the Law Dome ice core, East Antarctica
Millennial and orbital-scale variability in a 54 000-year record of total air content from the South Pole ice core
Investigating the spatial representativeness of East Antarctic ice cores: a comparison of ice core and radar-derived surface mass balance over coastal ice rises and Dome Fuji
Early Holocene ice on the Begguya plateau (Mt. Hunter, Alaska) revealed by ice core 14C age constraints
Greenland and Canadian Arctic ice temperature profiles database
Isotopic diffusion in ice enhanced by vein-water flow
A one-dimensional temperature and age modeling study for selecting the drill site of the oldest ice core near Dome Fuji, Antarctica
Chemical and visual characterisation of EGRIP glacial ice and cloudy bands within
Using ice core measurements from Taylor Glacier, Antarctica, to calibrate in situ cosmogenic 14C production rates by muons
Detection of ice core particles via deep neural networks
Development of crystal orientation fabric in the Dome Fuji ice core in East Antarctica: implications for the deformation regime in ice sheets
Gas isotope thermometry in the South Pole and Dome Fuji ice cores provides evidence for seasonal rectification of ice core gas records
Chronostratigraphy of the Larsen blue-ice area in northern Victoria Land, East Antarctica, and its implications for paleoclimate
A quantitative method of resolving annual precipitation for the past millennia from Tibetan ice cores
Regional variability of diatoms in ice cores from the Antarctic Peninsula and Ellsworth Land, Antarctica
Microstructure, micro-inclusions, and mineralogy along the EGRIP (East Greenland Ice Core Project) ice core – Part 2: Implications for palaeo-mineralogy
Microstructure, micro-inclusions, and mineralogy along the EGRIP ice core – Part 1: Localisation of inclusions and deformation patterns
Fractionation of O2∕N2 and Ar∕N2 in the Antarctic ice sheet during bubble formation and bubble–clathrate hydrate transition from precise gas measurements of the Dome Fuji ice core
Deep ice as a geochemical reactor: insights from iron speciation and mineralogy of dust in the Talos Dome ice core (East Antarctica)
Two-dimensional impurity imaging in deep Antarctic ice cores: snapshots of three climatic periods and implications for high-resolution signal interpretation
Acoustic velocity measurements for detecting the crystal orientation fabrics of a temperate ice core
Brief communication: New evidence further constraining Tibetan ice core chronologies to the Holocene
Brief communication: New radar constraints support presence of ice older than 1.5 Myr at Little Dome C
Pervasive diffusion of climate signals recorded in ice-vein ionic impurities
Radiocarbon dating of alpine ice cores with the dissolved organic carbon (DOC) fraction
Giant dust particles at Nevado Illimani: a proxy of summertime deep convection over the Bolivian Altiplano
Physical properties of shallow ice cores from Antarctic and sub-Antarctic islands
Stable water isotopes and accumulation rates in the Union Glacier region, Ellsworth Mountains, West Antarctica, over the last 35 years
Multi-tracer study of gas trapping in an East Antarctic ice core
Very old firn air linked to strong density layering at Styx Glacier, coastal Victoria Land, East Antarctica
Apparent discrepancy of Tibetan ice core δ18O records may be attributed to misinterpretation of chronology
Challenges associated with the climatic interpretation of water stable isotope records from a highly resolved firn core from Adélie Land, coastal Antarctica
Glaciological characteristics in the Dome Fuji region and new assessment for “Oldest Ice”
Age ranges of the Tibetan ice cores with emphasis on the Chongce ice cores, western Kunlun Mountains
On the similarity and apparent cycles of isotopic variations in East Antarctic snow pits
The first luminescence dating of Tibetan glacier basal sediment
Methanesulfonic acid (MSA) migration in polar ice: data synthesis and theory
Felix S. L. Ng
The Cryosphere, 18, 4645–4669, https://doi.org/10.5194/tc-18-4645-2024, https://doi.org/10.5194/tc-18-4645-2024, 2024
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Liquid veins and grain boundaries in ice can accelerate the decay of climate signals in δ18O and δD by short-circuiting the slow isotopic diffusion in crystal grains. This theory for "excess diffusion" has not been confirmed experimentally. We show that, if the mechanism occurs, then distinct isotopic patterns must form near grain junctions, offering a testable prediction of the theory. We calculate the patterns and describe an experimental scheme for testing ice-core samples for the mechanism.
Julien Westhoff, Johannes Freitag, Anaïs Orsi, Patricia Martinerie, Ilka Weikusat, Michael Dyonisius, Xavier Faïn, Kevin Fourteau, and Thomas Blunier
The Cryosphere, 18, 4379–4397, https://doi.org/10.5194/tc-18-4379-2024, https://doi.org/10.5194/tc-18-4379-2024, 2024
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We study the EastGRIP area, Greenland, in detail with traditional and novel techniques. Due to the compaction of the ice, at a certain depth, atmospheric gases can no longer exchange, and the atmosphere is trapped in air bubbles in the ice. We find this depth by pumping air from a borehole, modeling, and using a new technique based on the optical appearance of the ice. Our results suggest that the close-off depth lies at around 58–61 m depth and more precisely at 58.3 m depth.
Paul R. Bierman, Andrew J. Christ, Catherine M. Collins, Halley M. Mastro, Juliana Souza, Pierre-Henri Blard, Stefanie Brachfeld, Zoe R. Courville, Tammy M. Rittenour, Elizabeth K. Thomas, Jean-Louis Tison, and François Fripiat
The Cryosphere, 18, 4029–4052, https://doi.org/10.5194/tc-18-4029-2024, https://doi.org/10.5194/tc-18-4029-2024, 2024
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In 1966, the U.S. Army drilled through the Greenland Ice Sheet at Camp Century, Greenland; they recovered 3.44 m of frozen material. Here, we decipher the material’s history. Water, flowing during a warm interglacial when the ice sheet melted from northwest Greenland, deposited the upper material which contains fossil plant and insect parts. The lower material, separated by more than a meter of ice with some sediment, is till, deposited by the ice sheet during a prior cold period.
Fyntan Shaw, Andrew M. Dolman, Torben Kunz, Vasileios Gkinis, and Thomas Laepple
The Cryosphere, 18, 3685–3698, https://doi.org/10.5194/tc-18-3685-2024, https://doi.org/10.5194/tc-18-3685-2024, 2024
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Fast variability of water isotopes in ice cores is attenuated by diffusion but can be restored if the diffusion length is accurately estimated. Current estimation methods are inadequate for deep ice, mischaracterising millennial-scale climate variability. We address this using variability estimates from shallower ice. The estimated diffusion length of 31 cm for the bottom of the Dome C ice core is 20 cm less than the old method, enabling signal recovery on timescales previously considered lost.
Vasilii V. Petrenko, Segev BenZvi, Michael Dyonisius, Benjamin Hmiel, Andrew M. Smith, and Christo Buizert
The Cryosphere, 18, 3439–3451, https://doi.org/10.5194/tc-18-3439-2024, https://doi.org/10.5194/tc-18-3439-2024, 2024
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This manuscript presents the concept for a new proxy for past variations in the galactic cosmic ray flux (GCR). Past variations in GCR flux are important to understand for interpretation of records of isotopes produced by cosmic rays; these records are used for reconstructing solar variations and past land ice extent. The proxy involves using measurements of 14CO in ice cores, which should provide an uncomplicated and precise estimate of past GCR flux variations for the past few thousand years.
Benjamin Hmiel, Vasilii V. Petrenko, Christo Buizert, Andrew M. Smith, Michael N. Dyonisius, Philip Place, Bin Yang, Quan Hua, Ross Beaudette, Jeffrey P. Severinghaus, Christina Harth, Ray F. Weiss, Lindsey Davidge, Melisa Diaz, Matthew Pacicco, James A. Menking, Michael Kalk, Xavier Faïn, Alden Adolph, Isaac Vimont, and Lee T. Murray
The Cryosphere, 18, 3363–3382, https://doi.org/10.5194/tc-18-3363-2024, https://doi.org/10.5194/tc-18-3363-2024, 2024
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The main aim of this research is to improve understanding of carbon-14 that is produced by cosmic rays in ice sheets. Measurements of carbon-14 in ice cores can provide a range of useful information (age of ice, past atmospheric chemistry, past cosmic ray intensity). Our results show that almost all (>99 %) of carbon-14 that is produced in the upper layer of ice sheets is rapidly lost to the atmosphere. Our results also provide better estimates of carbon-14 production rates in deeper ice.
Xinyu Lv, Zhihao Cui, Ting Wang, Yumin Wen, An Liu, and Rusheng Wang
The Cryosphere, 18, 3351–3362, https://doi.org/10.5194/tc-18-3351-2024, https://doi.org/10.5194/tc-18-3351-2024, 2024
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In this study, the formation process of ice chips was observed and the fracture mechanics characteristics of the ice during the cutting process were analyzed. Additionally, a mechanical model for the cutting force was established based on the observation and analysis results. Finally, influencing factors and laws of the cutting force were verified by cutting force test results generated under various experimental conditions.
Elena Di Stefano, Giovanni Baccolo, Massimiliano Clemenza, Barbara Delmonte, Deborah Fiorini, Roberto Garzonio, Margit Schwikowski, and Valter Maggi
The Cryosphere, 18, 2865–2874, https://doi.org/10.5194/tc-18-2865-2024, https://doi.org/10.5194/tc-18-2865-2024, 2024
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Rising temperatures are impacting the reliability of glaciers as environmental archives. This study reports how meltwater percolation affects the distribution of tritium and cesium, which are commonly used as temporal markers in dating ice cores, in a temperate glacier. Our findings challenge the established application of radionuclides for dating mountain ice cores and indicate tritium as the best choice.
Dorothea Elisabeth Moser, Elizabeth R. Thomas, Christoph Nehrbass-Ahles, Anja Eichler, and Eric Wolff
The Cryosphere, 18, 2691–2718, https://doi.org/10.5194/tc-18-2691-2024, https://doi.org/10.5194/tc-18-2691-2024, 2024
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Increasing temperatures worldwide lead to more melting of glaciers and ice caps, even in the polar regions. This is why ice-core scientists need to prepare to analyse records affected by melting and refreezing. In this paper, we present a summary of how near-surface melt forms, what structural imprints it leaves in snow, how various signatures used for ice-core climate reconstruction are altered, and how we can still extract valuable insights from melt-affected ice cores.
Susanne Preunkert, Pascal Bohleber, Michel Legrand, Adrien Gilbert, Tobias Erhardt, Roland Purtschert, Lars Zipf, Astrid Waldner, Joseph R. McConnell, and Hubertus Fischer
The Cryosphere, 18, 2177–2194, https://doi.org/10.5194/tc-18-2177-2024, https://doi.org/10.5194/tc-18-2177-2024, 2024
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Ice cores from high-elevation Alpine glaciers are an important tool to reconstruct the past atmosphere. However, since crevasses are common at these glacier sites, rigorous investigations of glaciological conditions upstream of drill sites are needed before interpreting such ice cores. On the basis of three ice cores extracted at Col du Dôme (4250 m a.s.l; French Alps), an overall picture of a dynamic crevasse formation is drawn, which disturbs the depth–age relation of two of the three cores.
Horst Machguth, Anja Eichler, Margit Schwikowski, Sabina Brütsch, Enrico Mattea, Stanislav Kutuzov, Martin Heule, Ryskul Usubaliev, Sultan Belekov, Vladimir N. Mikhalenko, Martin Hoelzle, and Marlene Kronenberg
The Cryosphere, 18, 1633–1646, https://doi.org/10.5194/tc-18-1633-2024, https://doi.org/10.5194/tc-18-1633-2024, 2024
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In 2018 we drilled an 18 m ice core on the summit of Grigoriev ice cap, located in the Tien Shan mountains of Kyrgyzstan. The core analysis reveals strong melting since the early 2000s. Regardless of this, we find that the structure and temperature of the ice have changed little since the 1980s. The probable cause of this apparent stability is (i) an increase in snowfall and (ii) the fact that meltwater nowadays leaves the glacier and thereby removes so-called latent heat.
Andrea Spolaor, Federico Scoto, Catherine Larose, Elena Barbaro, Francois Burgay, Mats P. Bjorkman, David Cappelletti, Federico Dallo, Fabrizio de Blasi, Dmitry Divine, Giuliano Dreossi, Jacopo Gabrieli, Elisabeth Isaksson, Jack Kohler, Tonu Martma, Louise S. Schmidt, Thomas V. Schuler, Barbara Stenni, Clara Turetta, Bartłomiej Luks, Mathieu Casado, and Jean-Charles Gallet
The Cryosphere, 18, 307–320, https://doi.org/10.5194/tc-18-307-2024, https://doi.org/10.5194/tc-18-307-2024, 2024
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We evaluate the impact of the increased snowmelt on the preservation of the oxygen isotope (δ18O) signal in firn records recovered from the top of the Holtedahlfonna ice field located in the Svalbard archipelago. Thanks to a multidisciplinary approach we demonstrate a progressive deterioration of the isotope signal in the firn core. We link the degradation of the δ18O signal to the increased occurrence and intensity of melt events associated with the rapid warming occurring in the archipelago.
Helene Hoffmann, Jason Day, Rachael Rhodes, Mackenzie Grieman, Jack Humby, Isobel Rowell, Christoph Nehrbass-Ahles, Robert Mulvaney, Sally Gibson, and Eric Wolff
EGUsphere, https://doi.org/10.5194/egusphere-2023-3071, https://doi.org/10.5194/egusphere-2023-3071, 2024
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Ice cores are archives of past atmospheric conditions. In deep, old ice the layers containing this information get thinned to the millimetre scale or below. We installed a setup for high resolution (80 μm) chemical impurity measurements in ice cores using the laser ablation technique at the University of Cambridge. In a first application to Skytrain Ice Core from Antarctica we discuss the potential to detect fine layered structures in ice from Skytrain Ice Core up to an age of ~ 126 000 years.
Lingwei Zhang, Tessa R. Vance, Alexander D. Fraser, Lenneke M. Jong, Sarah S. Thompson, Alison S. Criscitiello, and Nerilie J. Abram
The Cryosphere, 17, 5155–5173, https://doi.org/10.5194/tc-17-5155-2023, https://doi.org/10.5194/tc-17-5155-2023, 2023
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Physical features in ice cores provide unique records of past variability. We identified 1–2 mm ice layers without bubbles in surface ice cores from Law Dome, East Antarctica, occurring on average five times per year. The origin of these bubble-free layers is unknown. In this study, we investigate whether they have the potential to record past atmospheric processes and circulation. We find that the bubble-free layers are linked to accumulation hiatus events and meridional moisture transport.
Jenna A. Epifanio, Edward J. Brook, Christo Buizert, Erin C. Pettit, Jon S. Edwards, John M. Fegyveresi, Todd A. Sowers, Jeffrey P. Severinghaus, and Emma C. Kahle
The Cryosphere, 17, 4837–4851, https://doi.org/10.5194/tc-17-4837-2023, https://doi.org/10.5194/tc-17-4837-2023, 2023
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The total air content (TAC) of polar ice cores has long been considered a potential proxy for past ice sheet elevation. This study presents a high-resolution record of TAC from the South Pole ice core. The record reveals orbital- and millennial-scale variability that cannot be explained by elevation changes. The orbital- and millennial-scale changes are likely a product of firn grain metamorphism near the surface of the ice sheet, due to summer insolation changes or local accumulation changes.
Marie G. P. Cavitte, Hugues Goosse, Kenichi Matsuoka, Sarah Wauthy, Vikram Goel, Rahul Dey, Bhanu Pratap, Brice Van Liefferinge, Thamban Meloth, and Jean-Louis Tison
The Cryosphere, 17, 4779–4795, https://doi.org/10.5194/tc-17-4779-2023, https://doi.org/10.5194/tc-17-4779-2023, 2023
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The net accumulation of snow over Antarctica is key for assessing current and future sea-level rise. Ice cores record a noisy snowfall signal to verify model simulations. We find that ice core net snowfall is biased to lower values for ice rises and the Dome Fuji site (Antarctica), while the relative uncertainty in measuring snowfall increases rapidly with distance away from the ice core sites at the ice rises but not at Dome Fuji. Spatial variation in snowfall must therefore be considered.
Ling Fang, Theo M. Jenk, Dominic Winski, Karl Kreutz, Hanna L. Brooks, Emma Erwin, Erich Osterberg, Seth Campbell, Cameron Wake, and Margit Schwikowski
The Cryosphere, 17, 4007–4020, https://doi.org/10.5194/tc-17-4007-2023, https://doi.org/10.5194/tc-17-4007-2023, 2023
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Understanding the behavior of ocean–atmosphere teleconnections in the North Pacific during warm intervals can aid in predicting future warming scenarios. However, majority ice core records from Alaska–Yukon region only provide data for the last few centuries. This study introduces a continuous chronology for Denali ice core from Begguya, Alaska, using multiple dating methods. The early-Holocene-origin Denali ice core will facilitate future investigations of hydroclimate in the North Pacific.
Anja Løkkegaard, Kenneth D. Mankoff, Christian Zdanowicz, Gary D. Clow, Martin P. Lüthi, Samuel H. Doyle, Henrik H. Thomsen, David Fisher, Joel Harper, Andy Aschwanden, Bo M. Vinther, Dorthe Dahl-Jensen, Harry Zekollari, Toby Meierbachtol, Ian McDowell, Neil Humphrey, Anne Solgaard, Nanna B. Karlsson, Shfaqat A. Khan, Benjamin Hills, Robert Law, Bryn Hubbard, Poul Christoffersen, Mylène Jacquemart, Julien Seguinot, Robert S. Fausto, and William T. Colgan
The Cryosphere, 17, 3829–3845, https://doi.org/10.5194/tc-17-3829-2023, https://doi.org/10.5194/tc-17-3829-2023, 2023
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This study presents a database compiling 95 ice temperature profiles from the Greenland ice sheet and peripheral ice caps. Ice viscosity and hence ice flow are highly sensitive to ice temperature. To highlight the value of the database in evaluating ice flow simulations, profiles from the Greenland ice sheet are compared to a modeled temperature field. Reoccurring discrepancies between modeled and observed temperatures provide insight on the difficulties faced when simulating ice temperatures.
Felix S. L. Ng
The Cryosphere, 17, 3063–3082, https://doi.org/10.5194/tc-17-3063-2023, https://doi.org/10.5194/tc-17-3063-2023, 2023
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The stable isotopes of oxygen and hydrogen in ice cores are routinely analysed for the climate signals which they carry. It has long been known that the system of water veins in ice facilitates isotopic diffusion. Here, mathematical modelling shows that water flow in the veins strongly accelerates the diffusion and the decay of climate signals. The process hampers methods using the variations in signal decay with depth to reconstruct past climatic temperature.
Takashi Obase, Ayako Abe-Ouchi, Fuyuki Saito, Shun Tsutaki, Shuji Fujita, Kenji Kawamura, and Hideaki Motoyama
The Cryosphere, 17, 2543–2562, https://doi.org/10.5194/tc-17-2543-2023, https://doi.org/10.5194/tc-17-2543-2023, 2023
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We use a one-dimensional ice-flow model to examine the most suitable core location near Dome Fuji (DF), Antarctica. This model computes the temporal evolution of age and temperature from past to present. We investigate the influence of different parameters of climate and ice sheet on the ice's basal age and compare the results with ground radar surveys. We find that the local ice thickness primarily controls the age because it is critical to the basal melting, which can eliminate the old ice.
Nicolas Stoll, Julien Westhoff, Pascal Bohleber, Anders Svensson, Dorthe Dahl-Jensen, Carlo Barbante, and Ilka Weikusat
The Cryosphere, 17, 2021–2043, https://doi.org/10.5194/tc-17-2021-2023, https://doi.org/10.5194/tc-17-2021-2023, 2023
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Impurities in polar ice play a role regarding its climate signal and internal deformation. We bridge different scales using different methods to investigate ice from the Last Glacial Period derived from the EGRIP ice core in Greenland. We characterise different types of cloudy bands, i.e. frequently occurring milky layers in the ice, and analyse their chemistry with Raman spectroscopy and 2D imaging. We derive new insights into impurity localisation and deposition conditions.
Michael N. Dyonisius, Vasilii V. Petrenko, Andrew M. Smith, Benjamin Hmiel, Peter D. Neff, Bin Yang, Quan Hua, Jochen Schmitt, Sarah A. Shackleton, Christo Buizert, Philip F. Place, James A. Menking, Ross Beaudette, Christina Harth, Michael Kalk, Heidi A. Roop, Bernhard Bereiter, Casey Armanetti, Isaac Vimont, Sylvia Englund Michel, Edward J. Brook, Jeffrey P. Severinghaus, Ray F. Weiss, and Joseph R. McConnell
The Cryosphere, 17, 843–863, https://doi.org/10.5194/tc-17-843-2023, https://doi.org/10.5194/tc-17-843-2023, 2023
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Cosmic rays that enter the atmosphere produce secondary particles which react with surface minerals to produce radioactive nuclides. These nuclides are often used to constrain Earth's surface processes. However, the production rates from muons are not well constrained. We measured 14C in ice with a well-known exposure history to constrain the production rates from muons. 14C production in ice is analogous to quartz, but we obtain different production rates compared to commonly used estimates.
Niccolò Maffezzoli, Eliza Cook, Willem G. M. van der Bilt, Eivind N. Støren, Daniela Festi, Florian Muthreich, Alistair W. R. Seddon, François Burgay, Giovanni Baccolo, Amalie R. F. Mygind, Troels Petersen, Andrea Spolaor, Sebastiano Vascon, Marcello Pelillo, Patrizia Ferretti, Rafael S. dos Reis, Jefferson C. Simões, Yuval Ronen, Barbara Delmonte, Marco Viccaro, Jørgen Peder Steffensen, Dorthe Dahl-Jensen, Kerim H. Nisancioglu, and Carlo Barbante
The Cryosphere, 17, 539–565, https://doi.org/10.5194/tc-17-539-2023, https://doi.org/10.5194/tc-17-539-2023, 2023
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Multiple lines of research in ice core science are limited by manually intensive and time-consuming optical microscopy investigations for the detection of insoluble particles, from pollen grains to volcanic shards. To help overcome these limitations and support researchers, we present a novel methodology for the identification and autonomous classification of ice core insoluble particles based on flow image microscopy and neural networks.
Tomotaka Saruya, Shuji Fujita, Yoshinori Iizuka, Atsushi Miyamoto, Hiroshi Ohno, Akira Hori, Wataru Shigeyama, Motohiro Hirabayashi, and Kumiko Goto-Azuma
The Cryosphere, 16, 2985–3003, https://doi.org/10.5194/tc-16-2985-2022, https://doi.org/10.5194/tc-16-2985-2022, 2022
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Crystal orientation fabrics (COF) of the Dome Fuji ice core were investigated with an innovative method with unprecedentedly high statistical significance and dense depth coverage. The COF profile and its fluctuation were found to be highly dependent on concentrations of chloride ion and dust. The data suggest deformation of ice at the deepest zone is highly influenced by COF fluctuations that progressively develop from the near-surface firn toward the deepest zone within ice sheets.
Jacob D. Morgan, Christo Buizert, Tyler J. Fudge, Kenji Kawamura, Jeffrey P. Severinghaus, and Cathy M. Trudinger
The Cryosphere, 16, 2947–2966, https://doi.org/10.5194/tc-16-2947-2022, https://doi.org/10.5194/tc-16-2947-2022, 2022
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The composition of air bubbles in Antarctic ice cores records information about past changes in properties of the snowpack. We find that, near the South Pole, thinner snowpack in the past is often due to steeper surface topography, in which faster winds erode the snow and deposit it in flatter areas. The slope and wind seem to also cause a seasonal bias in the composition of air bubbles in the ice core. These findings will improve interpretation of other ice cores from places with steep slopes.
Giyoon Lee, Jinho Ahn, Hyeontae Ju, Florian Ritterbusch, Ikumi Oyabu, Christo Buizert, Songyi Kim, Jangil Moon, Sambit Ghosh, Kenji Kawamura, Zheng-Tian Lu, Sangbum Hong, Chang Hee Han, Soon Do Hur, Wei Jiang, and Guo-Min Yang
The Cryosphere, 16, 2301–2324, https://doi.org/10.5194/tc-16-2301-2022, https://doi.org/10.5194/tc-16-2301-2022, 2022
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Blue-ice areas (BIAs) have several advantages for reconstructing past climate. However, the complicated ice flow in the area hinders constraining the age. We applied state-of-the-art techniques and found that the ages cover the last deglaciation period. Our study demonstrates that the BIA in northern Victoria Land may help reconstruct the past climate during the termination of the last glacial period.
Wangbin Zhang, Shugui Hou, Shuang-Ye Wu, Hongxi Pang, Sharon B. Sneed, Elena V. Korotkikh, Paul A. Mayewski, Theo M. Jenk, and Margit Schwikowski
The Cryosphere, 16, 1997–2008, https://doi.org/10.5194/tc-16-1997-2022, https://doi.org/10.5194/tc-16-1997-2022, 2022
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This study proposes a quantitative method to reconstruct annual precipitation records at the millennial timescale from the Tibetan ice cores through combining annual layer identification based on LA-ICP-MS measurement with an ice flow model. The reliability of this method is assessed by comparing our results with other reconstructed and modeled precipitation series for the Tibetan Plateau. The assessment shows that the method has a promising performance.
Dieter R. Tetzner, Claire S. Allen, and Elizabeth R. Thomas
The Cryosphere, 16, 779–798, https://doi.org/10.5194/tc-16-779-2022, https://doi.org/10.5194/tc-16-779-2022, 2022
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The presence of diatoms in Antarctic ice cores has been scarcely documented and poorly understood. Here we present a detailed analysis of the spatial and temporal distribution of the diatom record preserved in a set of Antarctic ice cores. Our results reveal that the timing and amount of diatoms deposited present a strong geographical division. This study highlights the potential of the diatom record preserved in Antarctic ice cores to provide useful information about past environmental changes.
Nicolas Stoll, Maria Hörhold, Tobias Erhardt, Jan Eichler, Camilla Jensen, and Ilka Weikusat
The Cryosphere, 16, 667–688, https://doi.org/10.5194/tc-16-667-2022, https://doi.org/10.5194/tc-16-667-2022, 2022
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We mapped and analysed solid inclusion in the upper 1340 m of the EGRIP ice core with Raman spectroscopy and microstructure mapping, based on bulk dust content derived via continuous flow analysis. We observe a large variety in mineralogy throughout the core and samples. The main minerals are sulfates, especially gypsum, and terrestrial dust minerals, such as quartz, mica, and feldspar. A change in mineralogy occurs around 900 m depth indicating a climate-related imprint.
Nicolas Stoll, Jan Eichler, Maria Hörhold, Tobias Erhardt, Camilla Jensen, and Ilka Weikusat
The Cryosphere, 15, 5717–5737, https://doi.org/10.5194/tc-15-5717-2021, https://doi.org/10.5194/tc-15-5717-2021, 2021
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We did a systematic analysis of the location of inclusions in the EGRIP ice core, the first ice core from an ice stream. We combine this with crystal orientation and grain size data, enabling the first overview about the microstructure of this unique ice core. Micro-inclusions show a strong spatial variability and patterns (clusters or horizontal layers); roughly one-third is located at grain boundaries. More holistic approaches are needed to understand deformation processes in the ice better.
Ikumi Oyabu, Kenji Kawamura, Tsutomu Uchida, Shuji Fujita, Kyotaro Kitamura, Motohiro Hirabayashi, Shuji Aoki, Shinji Morimoto, Takakiyo Nakazawa, Jeffrey P. Severinghaus, and Jacob D. Morgan
The Cryosphere, 15, 5529–5555, https://doi.org/10.5194/tc-15-5529-2021, https://doi.org/10.5194/tc-15-5529-2021, 2021
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We present O2/N2 and Ar/N2 records from the Dome Fuji ice core through the bubbly ice, bubble–clathrate transition, and clathrate ice zones without gas-loss fractionation. The insolation signal is preserved through the clathrate formation. The relationship between Ar/Ν2 and Ο2/Ν2 suggests that the fractionation for the bubble–clathrate transition is mass independent, while the bubble close-off process involves a combination of mass-independent and mass-dependent fractionation for O2 and Ar.
Giovanni Baccolo, Barbara Delmonte, Elena Di Stefano, Giannantonio Cibin, Ilaria Crotti, Massimo Frezzotti, Dariush Hampai, Yoshinori Iizuka, Augusto Marcelli, and Valter Maggi
The Cryosphere, 15, 4807–4822, https://doi.org/10.5194/tc-15-4807-2021, https://doi.org/10.5194/tc-15-4807-2021, 2021
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As scientists are pushing efforts to recover deep ice cores to extend paleoclimatic reconstructions, it is now essential to explore deep ice. The latter was considered a relatively stable environment, but this view is changing. This study shows that the conditions of deep ice promote the interaction between soluble and insoluble impurities, favoring complex geochemical reactions that lead to the englacial dissolution and precipitation of specific minerals present in atmospheric mineral dust.
Pascal Bohleber, Marco Roman, Martin Šala, Barbara Delmonte, Barbara Stenni, and Carlo Barbante
The Cryosphere, 15, 3523–3538, https://doi.org/10.5194/tc-15-3523-2021, https://doi.org/10.5194/tc-15-3523-2021, 2021
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Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) offers micro-destructive, micrometer-scale impurity analysis of ice cores. For improved understanding of the LA-ICP-MS signals, novel 2D impurity imaging is applied to selected glacial and interglacial samples of Antarctic deep ice cores. This allows evaluating the 2D impurity distribution in relation to ice crystal features and assessing implications for investigating highly thinned climate proxy signals in deep polar ice.
Sebastian Hellmann, Melchior Grab, Johanna Kerch, Henning Löwe, Andreas Bauder, Ilka Weikusat, and Hansruedi Maurer
The Cryosphere, 15, 3507–3521, https://doi.org/10.5194/tc-15-3507-2021, https://doi.org/10.5194/tc-15-3507-2021, 2021
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In this study, we analyse whether ultrasonic measurements on ice core samples could be employed to derive information about the particular ice crystal orientation in these samples. We discuss if such ultrasonic scans of ice core samples could provide similarly detailed results as the established methods, which usually destroy the ice samples. Our geophysical approach is minimally invasive and could support the existing methods with additional and (semi-)continuous data points along the ice core.
Shugui Hou, Wangbin Zhang, Ling Fang, Theo M. Jenk, Shuangye Wu, Hongxi Pang, and Margit Schwikowski
The Cryosphere, 15, 2109–2114, https://doi.org/10.5194/tc-15-2109-2021, https://doi.org/10.5194/tc-15-2109-2021, 2021
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We present ages for two new ice cores reaching bedrock, from the Zangser Kangri (ZK) glacier in the northwestern Tibetan Plateau and the Shulenanshan (SLNS) glacier in the western Qilian Mountains. We estimated bottom ages of 8.90±0.57/0.56 ka and 7.46±1.46/1.79 ka for the ZK and SLNS ice core respectively, constraining the time range accessible by Tibetan ice cores to the Holocene.
David A. Lilien, Daniel Steinhage, Drew Taylor, Frédéric Parrenin, Catherine Ritz, Robert Mulvaney, Carlos Martín, Jie-Bang Yan, Charles O'Neill, Massimo Frezzotti, Heinrich Miller, Prasad Gogineni, Dorthe Dahl-Jensen, and Olaf Eisen
The Cryosphere, 15, 1881–1888, https://doi.org/10.5194/tc-15-1881-2021, https://doi.org/10.5194/tc-15-1881-2021, 2021
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We collected radar data between EDC, an ice core spanning ~800 000 years, and BELDC, the site chosen for a new
oldest icecore at nearby Little Dome C. These data allow us to identify 50 % older internal horizons than previously traced in the area. We fit a model to the ages of those horizons at BELDC to determine the age of deep ice there. We find that there is likely to be 1.5 Myr old ice ~265 m above the bed, with sufficient resolution to preserve desired climatic information.
Felix S. L. Ng
The Cryosphere, 15, 1787–1810, https://doi.org/10.5194/tc-15-1787-2021, https://doi.org/10.5194/tc-15-1787-2021, 2021
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Current theory predicts climate signals in the vein chemistry of ice cores to migrate, hampering their dating. I show that the Gibbs–Thomson effect, which has been overlooked, causes fast diffusion that prevents signals from surviving into deep ice. Hence the deep climatic peaks in Antarctic and Greenlandic ice must be due to impurities in the ice matrix (outside veins) and safe from migration. These findings reset our understanding of postdepositional changes of ice-core climate signals.
Ling Fang, Theo M. Jenk, Thomas Singer, Shugui Hou, and Margit Schwikowski
The Cryosphere, 15, 1537–1550, https://doi.org/10.5194/tc-15-1537-2021, https://doi.org/10.5194/tc-15-1537-2021, 2021
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The interpretation of the ice-core-preserved signal requires a precise chronology. Radiocarbon (14C) dating of the water-insoluble organic carbon (WIOC) fraction has become an important dating tool. However, this method is restricted by the low concentration in the ice. In this work, we report first 14C dating results using the dissolved organic carbon (DOC) fraction. The resulting ages are comparable in both fractions, but by using the DOC fraction the required ice mass can be reduced.
Filipe G. L. Lindau, Jefferson C. Simões, Barbara Delmonte, Patrick Ginot, Giovanni Baccolo, Chiara I. Paleari, Elena Di Stefano, Elena Korotkikh, Douglas S. Introne, Valter Maggi, Eduardo Garzanti, and Sergio Andò
The Cryosphere, 15, 1383–1397, https://doi.org/10.5194/tc-15-1383-2021, https://doi.org/10.5194/tc-15-1383-2021, 2021
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Information about the past climate variability in tropical South America is stored in the snow layers of the tropical Andean glaciers. Here we show evidence that the presence of very large aeolian mineral dust particles at Nevado Illimani (Bolivia) is strictly controlled by the occurrence of summer storms in the Bolivian Altiplano. Therefore, based on the snow dust content and its composition of stable water isotopes, we propose a new proxy for information on previous summer storms.
Elizabeth Ruth Thomas, Guisella Gacitúa, Joel B. Pedro, Amy Constance Faith King, Bradley Markle, Mariusz Potocki, and Dorothea Elisabeth Moser
The Cryosphere, 15, 1173–1186, https://doi.org/10.5194/tc-15-1173-2021, https://doi.org/10.5194/tc-15-1173-2021, 2021
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Here we present the first-ever radar and ice core data from the sub-Antarctic islands of Bouvet Island, Peter I Island, and Young Island. These islands have the potential to record past climate in one of the most data-sparse regions on earth. Despite their northerly location, surface melting is generally low, and the upper layer of the ice at most sites is undisturbed. We estimate that a 100 m ice core drilled on these islands could capture climate over the past 100–200 years.
Kirstin Hoffmann, Francisco Fernandoy, Hanno Meyer, Elizabeth R. Thomas, Marcelo Aliaga, Dieter Tetzner, Johannes Freitag, Thomas Opel, Jorge Arigony-Neto, Christian Florian Göbel, Ricardo Jaña, Delia Rodríguez Oroz, Rebecca Tuckwell, Emily Ludlow, Joseph R. McConnell, and Christoph Schneider
The Cryosphere, 14, 881–904, https://doi.org/10.5194/tc-14-881-2020, https://doi.org/10.5194/tc-14-881-2020, 2020
Kévin Fourteau, Patricia Martinerie, Xavier Faïn, Christoph F. Schaller, Rebecca J. Tuckwell, Henning Löwe, Laurent Arnaud, Olivier Magand, Elizabeth R. Thomas, Johannes Freitag, Robert Mulvaney, Martin Schneebeli, and Vladimir Ya. Lipenkov
The Cryosphere, 13, 3383–3403, https://doi.org/10.5194/tc-13-3383-2019, https://doi.org/10.5194/tc-13-3383-2019, 2019
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Understanding gas trapping in polar ice is essential to study the relationship between greenhouse gases and past climates. New data of bubble closure, used in a simple gas-trapping model, show inconsistency with the final air content in ice. This suggests gas trapping is not fully understood. We also use a combination of high-resolution measurements to investigate the effect of polar snow stratification on gas trapping and find that all strata have similar pores, but that some close in advance.
Youngjoon Jang, Sang Bum Hong, Christo Buizert, Hun-Gyu Lee, Sang-Young Han, Ji-Woong Yang, Yoshinori Iizuka, Akira Hori, Yeongcheol Han, Seong Joon Jun, Pieter Tans, Taejin Choi, Seong-Joong Kim, Soon Do Hur, and Jinho Ahn
The Cryosphere, 13, 2407–2419, https://doi.org/10.5194/tc-13-2407-2019, https://doi.org/10.5194/tc-13-2407-2019, 2019
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We can learn how human activity altered atmospheric air from the interstitial air in the porous snow layer (firn) on top of glaciers. However, old firn air (> 55 years) was observed only at sites where surface temperatures and snow accumulation rates are very low, such as the South Pole. In this study, we report an unusually old firn air with CO2 age of 93 years from Styx Glacier, near the Ross Sea coast in Antarctica. We hypothesize that the large snow density variations increase firn air ages.
Shugui Hou, Wangbin Zhang, Hongxi Pang, Shuang-Ye Wu, Theo M. Jenk, Margit Schwikowski, and Yetang Wang
The Cryosphere, 13, 1743–1752, https://doi.org/10.5194/tc-13-1743-2019, https://doi.org/10.5194/tc-13-1743-2019, 2019
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The apparent discrepancy between the Holocene δ18O records of the Guliya and the Chongce ice cores may be attributed to a possible misinterpretation of the Guliya ice core chronology.
Sentia Goursaud, Valérie Masson-Delmotte, Vincent Favier, Suzanne Preunkert, Michel Legrand, Bénédicte Minster, and Martin Werner
The Cryosphere, 13, 1297–1324, https://doi.org/10.5194/tc-13-1297-2019, https://doi.org/10.5194/tc-13-1297-2019, 2019
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We report new water stable isotope records from the first highly resolved firn core drilled in Adélie Land and covering 1998–2014. Using an updated database, we show that mean values are in line with the range of coastal values. Statistical analyses show no relationship between our record and local surface air temperature. Atmospheric back trajectories and isotopic simulations suggest that water stable isotopes in Adélie provide a fingerprint of the variability of atmospheric dynamics.
Nanna B. Karlsson, Tobias Binder, Graeme Eagles, Veit Helm, Frank Pattyn, Brice Van Liefferinge, and Olaf Eisen
The Cryosphere, 12, 2413–2424, https://doi.org/10.5194/tc-12-2413-2018, https://doi.org/10.5194/tc-12-2413-2018, 2018
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In this study, we investigate the probability that the Dome Fuji region in East Antarctica contains ice more than 1.5 Ma old. The retrieval of a continuous ice-core record extending beyond 1 Ma is imperative to understand why the frequency of ice ages changed from 40 to 100 ka approximately 1 Ma ago.
We use a new radar dataset to improve the ice thickness maps, and apply a thermokinematic model to predict basal temperature and age of the ice. Our results indicate several areas of interest.
Shugui Hou, Theo M. Jenk, Wangbin Zhang, Chaomin Wang, Shuangye Wu, Yetang Wang, Hongxi Pang, and Margit Schwikowski
The Cryosphere, 12, 2341–2348, https://doi.org/10.5194/tc-12-2341-2018, https://doi.org/10.5194/tc-12-2341-2018, 2018
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We present multiple lines of evidence indicating that the Chongce ice cores drilled from the northwestern Tibetan Plateau reaches back only to the early Holocene. This result is at least, 1 order of magnitude younger than the nearby Guliya ice core (~30 km away from the Chongce ice core drilling site) but similar to other Tibetan ice cores. Thus it is necessary to explore multiple dating techniques to confirm the age ranges of the Tibetan ice cores.
Thomas Laepple, Thomas Münch, Mathieu Casado, Maria Hoerhold, Amaelle Landais, and Sepp Kipfstuhl
The Cryosphere, 12, 169–187, https://doi.org/10.5194/tc-12-169-2018, https://doi.org/10.5194/tc-12-169-2018, 2018
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We explain why snow pits across different sites in East Antarctica show visually similar isotopic variations. We argue that the similarity and the apparent cycles of around 20 cm in the δD and δ18O variations are the result of a seasonal cycle in isotopes, noise, for example from precipitation intermittency, and diffusion. The near constancy of the diffusion length across many ice-coring sites explains why the structure and cycle length is largely independent of the accumulation conditions.
Zhu Zhang, Shugui Hou, and Shuangwen Yi
The Cryosphere, 12, 163–168, https://doi.org/10.5194/tc-12-163-2018, https://doi.org/10.5194/tc-12-163-2018, 2018
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We provide the first luminescence dating of the basal sediment of the Chongce ice cap in the western Kunlun Mountains on the north-western Tibetan Plateau (TP), which gives an upper constraint for the age of the bottom ice at the drilling site. The age is more than 1 order of magnitude younger than the previously suggested age of the basal ice of the nearby Guliya ice cap (~ 40 km away from the Chongce ice cap). This work provides an important step towards better understanding the TP ice cores.
Matthew Osman, Sarah B. Das, Olivier Marchal, and Matthew J. Evans
The Cryosphere, 11, 2439–2462, https://doi.org/10.5194/tc-11-2439-2017, https://doi.org/10.5194/tc-11-2439-2017, 2017
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We combine a synthesis of 22 ice core records and a model of soluble impurity transport to investigate the enigmatic, post-depositional migration of methanesulfonic acid in polar ice. Our findings suggest that migration may be universal across coastal regions of Greenland and Antarctica, though it is mitigated at sites with higher accumulation and (or) lower impurity content. Records exhibiting severe migration may still be useful for inferring decadal and lower-frequency climate variability.
Cited articles
Ahn, J., Headly, M., Wahlen, M., Brook, E. J., Mayewski, P. A., and Taylor, K. C.: CO2 diffusion in polar ice: observations from naturally formed CO2 spikes in the Siple Dome (Antarctica) ice core, J. Glaciol., 54, 685–695, 2008.
Bender, M. L.: Orbital tuning chronology for the Vostok climate record supported by trapped gas composition, Earth Planet. Sci. Lett., 204, 275–289, 2002.
Bereiter, B., Schwander, J., Lüthi, D., and Stocker, T. F.: Change in CO2 concentration and O2 / N2 ratio in ice cores due to molecular diffusion, Geophys. Res. Lett., 36, L05703, https://doi.org/10.1029/2008GL036737, 2009.
Bereiter, B., Lüthi, D., Siegrist, M., Schüpbach, S., Stocker, T. F., and Fischer, H.: Mode change of millennial CO2 variability during the last glacial cycle associated with a bipolar marine carbon seesaw, P. Natl. Acad. Sci., 109, 9755–9760, 2012.
Durand, G., Svensson, A., Persson, A., Gagliardini, O., Gillet-Chaulet, F., Sjolte, J., Montagnat, M., and Dahl-Jensen, D.: Evolution of the texture along the EPICA Dome C ice core, Physics of ice core records II, 68, 91–105, 2009.
Elderfield, H., Ferretti, P., Greaves, M., Crowhurst, S., McCave, I. N., Hodell, D., and Piotrowski, A. M.: Evolution of Ocean Temperature and Ice Volume Through the Mid-Pleistocene Climate Transition, Science, 337, 704–709, 2012.
Enting, I. G.: On the use of smoothing splines to filter CO2 data, J. Geophys. Res., 92, 10977–10984, 1987.
EPICA community members: One-to-one coupling of glacial climate variability in Greenland and Antarctica, Nature, 444, 195–198, 2006.
Fischer, H., Severinghaus, J., Brook, E., Wolff, E., Albert, M., Alemany, O., Arthern, R., Bentley, C., Blankenship, D., Chappellaz, J., Creyts, T., Dahl-Jensen, D., Dinn, M., Frezzotti, M., Fujita, S., Gallee, H., Hindmarsh, R., Hudspeth, D., Jugie, G., Kawamura, K., Lipenkov, V., Miller, H., Mulvaney, R., Parrenin, F., Pattyn, F., Ritz, C., Schwander, J., Steinhage, D., van Ommen, T., and Wilhelms, F.: Where to find 1.5 million yr old ice for the IPICS "Oldest-Ice" ice core, Clim. Past, 9, 2489–2505, https://doi.org/10.5194/cp-9-2489-2013, 2013.
Huber, C., Leuenberger, M., and Zumbrunnen, O.: Continuous Extraction of Trapped Air from Bubble Ice or Water for On-Line Determination of Isotope Ratios, Anal. Chem., 75, 2324–2332, 2003.
Ikeda-Fukazawa, T., Kawamura, K., and Hondoh, T.: Mechanism of Molecular Diffusion in Ice Crystals, Molecular Simulation, 30, 973–979, 2004.
Ikeda-Fukazawa, T., Fukumizu, K., Kawamura, K., Aoki, S., Nakazawa, T., and Hondoh, T.: Effects of molecular diffusion on trapped gas composition in polar ice cores, EPSL, 229, 183–192, 2005.
Jouzel, J., Masson-Delmotte, V., Cattani, O., Dreyfus, G., Falourd, S., Hoffmann, G., Minster, B., Nouet, J., Barnola, J., Chappellaz, J., Fischer, H., Gallet, J. C., Johnsen, S., Leuenberger, M., Loulergue, L., Lüthi, D., Oerter, H., Parrenin, F., Raisbeck, G., Raynaud, D., Schilt, A., Schwander, J., Selmo, E., Souchez, R., Spahni, R., Stauffer, B., Steffensen, J. P., Stenni, B., Stocker, T. F., Tison, J., Werner, M., and Wolff, E. W.: Orbital and millennial Antarctic climate variability over the last 800,000 years, Science, 317, 793–796, 2007.
Kawamura, K., Parrenin, F., Lisiecki, L., Uemura, R., Vimeux, F., Severinghaus, J. P., Hutterli, M. A., Nakazawa, T., Aoki, S., Jouzel, J., Raymo, M. E., Matsumoto, K., Nakata, H., Motoyama, H., Fujita, S., Goto-Azuma, K., Fujii, Y., and Watanabe, O.: Northern Hemisphere forcing of climatic cycles in Antarctica over the past 360,000 years, Nature, 448, 912–917, 2007.
Lliboutry, L.: A critical review of analytical approximate solutions for steady state velocities and temperature in cold ice sheets, Z. Gletscherkd. Glacialgeol, 15, 135–148, 1979.
Lüthi, D., Le Floch, M., Bereiter, B., Blunier, T., Barnola, J., Siegenthaler, U., Raynaud, D., Jouzel, J., Fischer, H., Kawamura, K., and Stocker, T. F.: High-resolution carbon dioxide concentration record 650,000–800,000 years before present, Nature, 453, 379–382, 2008.
Lüthi, D., Bereiter, B., Stauffer, B., Winkler, R., Schwander, J., Kindler, P., Leuenberger, M., Kipfstuhl, S., Capron, E., Landais, A., Fischer, H., and Stocker, T. F.: CO2 and O2 / N2 variations in and just below the bubble–clathrate transformation zone of Antarctic ice cores, Earth Planet. Sci. Lett., 297, 226–233, 2010.
NEEM community members: Eemian interglacial reconstructed from a Greenland folded ice core, Nature, 493, 489–494, 2013.
Parrenin, F., Barnola, J.-M., Beer, J., Blunier, T., Castellano, E., Chappellaz, J., Dreyfus, G., Fischer, H., Fujita, S., Jouzel, J., Kawamura, K., Lemieux-Dudon, B., Loulergue, L., Masson-Delmotte, V., Narcisi, B., Petit, J.-R., Raisbeck, G., Raynaud, D., Ruth, U., Schwander, J., Severi, M., Spahni, R., Steffensen, J. P., Svensson, A., Udisti, R., Waelbroeck, C., and Wolff, E.: The EDC3 chronology for the EPICA Dome C ice core, Clim. Past, 3, 485–497, https://doi.org/10.5194/cp-3-485-2007, 2007a.
Parrenin, F., Dreyfus, G., Durand, G., Fujita, S., Gagliardini, O., Gillet, F., Jouzel, J., Kawamura, K., Lhomme, N., Masson-Delmotte, V., Ritz, C., Schwander, J., Shoji, H., Uemura, R., Watanabe, O., and Yoshida, N.: 1-D-ice flow modelling at EPICA Dome C and Dome Fuji, East Antarctica, Clim. Past, 3, 243–259, https://doi.org/10.5194/cp-3-243-2007, 2007b.
Petit, J. R., Jouzel, J., Raynaud, D., Barkov, N. I., Barnola, J., Basile, I., Bender, M., Chappellaz, J., Davis, M., Delaygue, G., Delmotte, M., Kotlyakov, V. M., Legrand, M., Lipenkov, V. Y., Lorius, C., Pépin, L., Ritz, C., Saltzman, E., and Stievenard, M.: Climate and atmospheric history of the past 420,000 years from the Vostok ice core, Antarctica, Nature, 399, 429–436, 1999.
Pol, K., Masson-Delmotte, V., Johnsen, S., Bigler, M., Cattani, O., Durand, G., Falourd, S., Jouzel, J., Minster, B., Parrenin, F., Ritz, C., Steen-Larsen, H. C., and Stenni, B.: New MIS 19 EPICA Dome C high resolution deuterium data: Hints for a problematic preservation of climate variability at sub-millennial scale in the "oldest ice", Earth Planet. Sci. Lett., 298, 95–103, 2010.
Salamatin, A. N., Lipenkov, V. Y., and Blinov, K. V.: Vostok (Antarctica) climate record time-scale deduced from the analysis of a borehole-temperature profile, Ann. Glaciol., 20, 207–214, 1994.
Salamatin, A. N., Lipenkov, V. Y., Barkov, N., Jouzel, J., Petit, J. R., and Raynaud, D.: Ice core age dating and paleothermometer calibration based on isotope and temperature profiles from deep boreholes at Vostok Station (East Antarctica), J. Geophys. Res., 103, 8963–8977, 1998.
Salamatin, A. N., Lipenkov, V. Y., Ikeda-Fukazawa, T., and Hondoh, T.: Kinetics of air-hydrate nucleation in polar ice sheets, Journal of Crystal Growth, 223, 285–305, 2001.
Schwander, J., Sowers, T., Barnola, J., Blunier, T., Fuchs, A., and Malaizé, B.: Age scale of the air in the Summit ice: Implication for glacial-interglacial temperature change, J. Geophys. Res., 102, 19483–19493, 1997.
Spahni, R., Schwander, J., Flückiger, J., Stauffer, B., Chappellaz, J., and Raynaud, D.: The attenuation of fast atmospheric CH4 variations recorded in polar ice cores, Geophys. Res. Lett., 30, 1571, https://doi.org/10.1029/2003GL017093, 2003.
Uchida, T., Miyamoto, A., Shin'Yama, A., and Hondoh, T.: Crystal growth of air hydrates over 720 ka in Dome Fuji (Antarctica) ice cores: microscopic observations of morphological changes below 2000 m depth, J. Glaciol., 57, 1017–1026, 2011.
