Articles | Volume 15, issue 12
https://doi.org/10.5194/tc-15-5529-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/tc-15-5529-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
10 Dec 2021
Research article |
| 10 Dec 2021
| 10 Dec 2021
Fractionation of O2∕N2 and Ar∕N2 in the Antarctic ice sheet during bubble formation and bubble–clathrate hydrate transition from precise gas measurements of the Dome Fuji ice core
National Institute of Polar Research, Tokyo 190-8518, Japan
Kenji Kawamura
National Institute of Polar Research, Tokyo 190-8518, Japan
Department of Polar Science, The Graduate University of Advanced
Studies (SOKENDAI), Tokyo 190-8518, Japan
Japan Agency for Marine Science and Technology (JAMSTEC), Yokosuka
237-0061, Japan
Tsutomu Uchida
Division of Applied Physics, Faculty of Engineering, Hokkaido
University, Sapporo 060-8628, Japan
Shuji Fujita
National Institute of Polar Research, Tokyo 190-8518, Japan
Department of Polar Science, The Graduate University of Advanced
Studies (SOKENDAI), Tokyo 190-8518, Japan
Kyotaro Kitamura
National Institute of Polar Research, Tokyo 190-8518, Japan
Motohiro Hirabayashi
National Institute of Polar Research, Tokyo 190-8518, Japan
Shuji Aoki
Center for Atmospheric and Oceanic Studies, Graduate School of
Science, Tohoku University, Sendai 980-8578, Japan
Shinji Morimoto
Center for Atmospheric and Oceanic Studies, Graduate School of
Science, Tohoku University, Sendai 980-8578, Japan
Takakiyo Nakazawa
Center for Atmospheric and Oceanic Studies, Graduate School of
Science, Tohoku University, Sendai 980-8578, Japan
Jeffrey P. Severinghaus
Scripps Institution of Oceanography, University of California San
Diego, La Jolla, CA 92093, USA
Jacob D. Morgan
Scripps Institution of Oceanography, University of California San
Diego, La Jolla, CA 92093, USA
Related authors
Frédéric Parrenin, Marie Bouchet, Christo Buizert, Emilie Capron, Ellen Corrick, Russell Drysdale, Kenji Kawamura, Amaëlle Landais, Robert Mulvaney, Ikumi Oyabu, and Sune Rasmussen
EGUsphere, https://doi.org/10.5194/egusphere-2023-2911, https://doi.org/10.5194/egusphere-2023-2911, 2024
Short summary
Short summary
The Paleochrono1 probablistic dating model allows to derive a common and optimized chronology for several paleoclimatic sites from various archives (ice cores, speleothems, marine cores, lake cores, etc.). It combines prior sedimentation scenarios with chronological information such as dated horizons, dated intervals, stratigraphic links and (for ice cores) Delta-depth observations. Paleochrono1 is available under the MIT open-source license.
Ryo Inoue, Shuji Fujita, Kenji Kawamura, Ikumi Oyabu, Fumio Nakazawa, Hideaki Motoyama, and Teruo Aoki
The Cryosphere, 18, 425–449, https://doi.org/10.5194/tc-18-425-2024, https://doi.org/10.5194/tc-18-425-2024, 2024
Short summary
Short summary
We measured the density, microstructural anisotropy, and specific surface area (SSA) of six firn cores collected within 60 km of Dome Fuji, Antarctica. We found a lack of significant density increase, development of vertically elongated microstructures, and a rapid decrease in SSA in the top few meters due to the metamorphism driven by water vapor transport under a temperature gradient. We highlight the significant spatial variability in the properties, which depends on the accumulation rate.
Christo Buizert, Sarah Shackleton, Jeffrey P. Severinghaus, William H. G. Roberts, Alan Seltzer, Bernhard Bereiter, Kenji Kawamura, Daniel Baggenstos, Anaïs J. Orsi, Ikumi Oyabu, Benjamin Birner, Jacob D. Morgan, Edward J. Brook, David M. Etheridge, David Thornton, Nancy Bertler, Rebecca L. Pyne, Robert Mulvaney, Ellen Mosley-Thompson, Peter D. Neff, and Vasilii V. Petrenko
Clim. Past, 19, 579–606, https://doi.org/10.5194/cp-19-579-2023, https://doi.org/10.5194/cp-19-579-2023, 2023
Short summary
Short summary
It is unclear how different components of the global atmospheric circulation, such as the El Niño effect, respond to large-scale climate change. We present a new ice core gas proxy, called krypton-86 excess, that reflects past storminess in Antarctica. We present data from 11 ice cores that suggest the new proxy works. We present a reconstruction of changes in West Antarctic storminess over the last 24 000 years and suggest these are caused by north–south movement of the tropical rain belt.
Ikumi Oyabu, Kenji Kawamura, Shuji Fujita, Ryo Inoue, Hideaki Motoyama, Kotaro Fukui, Motohiro Hirabayashi, Yu Hoshina, Naoyuki Kurita, Fumio Nakazawa, Hiroshi Ohno, Konosuke Sugiura, Toshitaka Suzuki, Shun Tsutaki, Ayako Abe-Ouchi, Masashi Niwano, Frédéric Parrenin, Fuyuki Saito, and Masakazu Yoshimori
Clim. Past, 19, 293–321, https://doi.org/10.5194/cp-19-293-2023, https://doi.org/10.5194/cp-19-293-2023, 2023
Short summary
Short summary
We reconstructed accumulation rate around Dome Fuji, Antarctica, over the last 5000 years from 15 shallow ice cores and seven snow pits. We found a long-term decreasing trend in the preindustrial period, which may be associated with secular surface cooling and sea ice expansion. Centennial-scale variations were also found, which may partly be related to combinations of volcanic, solar and greenhouse gas forcings. The most rapid and intense increases of accumulation rate occurred since 1850 CE.
Shun Tsutaki, Shuji Fujita, Kenji Kawamura, Ayako Abe-Ouchi, Kotaro Fukui, Hideaki Motoyama, Yu Hoshina, Fumio Nakazawa, Takashi Obase, Hiroshi Ohno, Ikumi Oyabu, Fuyuki Saito, Konosuke Sugiura, and Toshitaka Suzuki
The Cryosphere, 16, 2967–2983, https://doi.org/10.5194/tc-16-2967-2022, https://doi.org/10.5194/tc-16-2967-2022, 2022
Short summary
Short summary
We constructed an ice thickness map across the Dome Fuji region, East Antarctica, from improved radar data and previous data that had been collected since the late 1980s. The data acquired using the improved radar systems allowed basal topography to be identified with higher accuracy. The new ice thickness data show the bedrock topography, particularly the complex terrain of subglacial valleys and highlands south of Dome Fuji, with substantially high detail.
Giyoon Lee, Jinho Ahn, Hyeontae Ju, Florian Ritterbusch, Ikumi Oyabu, Christo Buizert, Songyi Kim, Jangil Moon, Sambit Ghosh, Kenji Kawamura, Zheng-Tian Lu, Sangbum Hong, Chang Hee Han, Soon Do Hur, Wei Jiang, and Guo-Min Yang
The Cryosphere, 16, 2301–2324, https://doi.org/10.5194/tc-16-2301-2022, https://doi.org/10.5194/tc-16-2301-2022, 2022
Short summary
Short summary
Blue-ice areas (BIAs) have several advantages for reconstructing past climate. However, the complicated ice flow in the area hinders constraining the age. We applied state-of-the-art techniques and found that the ages cover the last deglaciation period. Our study demonstrates that the BIA in northern Victoria Land may help reconstruct the past climate during the termination of the last glacial period.
Taku Umezawa, Satoshi Sugawara, Kenji Kawamura, Ikumi Oyabu, Stephen J. Andrews, Takuya Saito, Shuji Aoki, and Takakiyo Nakazawa
Atmos. Chem. Phys., 22, 6899–6917, https://doi.org/10.5194/acp-22-6899-2022, https://doi.org/10.5194/acp-22-6899-2022, 2022
Short summary
Short summary
Greenhouse gas methane in the Arctic atmosphere has not been accurately reported for 1900–1980 from either direct observations or ice core reconstructions. By using trace gas data from firn (compacted snow layers above ice sheet), air samples at two Greenland sites, and a firn air transport model, this study suggests a likely range of the Arctic methane reconstruction for the 20th century. Atmospheric scenarios from two previous studies are also evaluated for consistency with the firn data sets.
Ikumi Oyabu, Kenji Kawamura, Kyotaro Kitamura, Remi Dallmayr, Akihiro Kitamura, Chikako Sawada, Jeffrey P. Severinghaus, Ross Beaudette, Anaïs Orsi, Satoshi Sugawara, Shigeyuki Ishidoya, Dorthe Dahl-Jensen, Kumiko Goto-Azuma, Shuji Aoki, and Takakiyo Nakazawa
Atmos. Meas. Tech., 13, 6703–6731, https://doi.org/10.5194/amt-13-6703-2020, https://doi.org/10.5194/amt-13-6703-2020, 2020
Short summary
Short summary
Air in polar ice cores provides information on past atmosphere and climate. We present a new method for simultaneously measuring eight gases (CH4, N2O and CO2 concentrations; isotopic ratios of N2 and O2; elemental ratios between N2, O2 and Ar; and total air content) from single ice-core samples with high precision.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell N. Drysdale, Philip L. Gibbard, Lauren Gregoire, Feng He, Ruza F. Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis C. Tzedakis, Eric Wolff, and Xu Zhang
Geosci. Model Dev., 12, 3649–3685, https://doi.org/10.5194/gmd-12-3649-2019, https://doi.org/10.5194/gmd-12-3649-2019, 2019
Short summary
Short summary
As part of the Past Global Changes (PAGES) working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation for the Paleoclimate Modelling Intercomparison Project (PMIP4). This design includes time-varying changes in orbital forcing, greenhouse gas concentrations, continental ice sheets as well as freshwater input from the disintegration of continental ice sheets. Key paleo-records for model-data comparison are also included.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell Drysdale, Philip Gibbard, Lauren Gregoire, Feng He, Ruza Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis Tzedakis, Eric Wolff, and Xu Zhang
Clim. Past Discuss., https://doi.org/10.5194/cp-2018-106, https://doi.org/10.5194/cp-2018-106, 2018
Preprint withdrawn
Short summary
Short summary
The penultimate deglaciation (~ 138–128 ka), which represents the transition into the Last Interglacial period, provides a framework to investigate the climate and environmental response to large changes in boundary conditions. Here, as part of the PAGES-PMIP working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation as well as a selection of paleo records for upcoming model-data comparisons.
Ikumi Oyabu, Yoshinori Iizuka, Eric Wolff, and Margareta Hansson
Clim. Past Discuss., https://doi.org/10.5194/cp-2016-42, https://doi.org/10.5194/cp-2016-42, 2016
Manuscript not accepted for further review
Short summary
Short summary
This study presented the chemical compositions of non-volatile particles around the last termination in the Dome C ice core by using the sublimation-EDS method. The major soluble salt particles are CaSO4, Na2SO4, and NaCl, and time-series changes in the composition of these salts are similar to those for the Dome Fuji ice core. However, some differences occurred. The sulfatization rate of NaCl at Dome C is higher than that at Dome Fuji.
Romilly Harris Stuart, Amaëlle Landais, Laurent Arnaud, Christo Buizert, Emilie Capron, Marie Dumont, Quentin Libois, Robert Mulvaney, Anaïs Orsi, Ghislain Picard, Frédéric Prié, Jeffrey Severinghaus, Barbara Stenni, and Patricia Martinerie
The Cryosphere, 18, 3741–3763, https://doi.org/10.5194/tc-18-3741-2024, https://doi.org/10.5194/tc-18-3741-2024, 2024
Short summary
Short summary
Ice core δO2/N2 records are useful dating tools due to their local insolation pacing. A precise understanding of the physical mechanism driving this relationship, however, remain ambiguous. By compiling data from 15 polar sites, we find a strong dependence of mean δO2/N2 on accumulation rate and temperature in addition to the well-documented insolation dependence. Snowpack modelling is used to investigate which physical properties drive the mechanistic dependence on these local parameters.
Ryo Inoue, Teruo Aoki, Shuji Fujita, Shun Tsutaki, Hideaki Motoyama, Fumio Nakazawa, and Kenji Kawamura
The Cryosphere, 18, 3513–3531, https://doi.org/10.5194/tc-18-3513-2024, https://doi.org/10.5194/tc-18-3513-2024, 2024
Short summary
Short summary
We measured the snow specific surface area (SSA) at ~2150 surfaces between the coast near Syowa Station and Dome Fuji, East Antarctica, in summer 2021–2022. The observed SSA shows no elevation dependence between 15 and 500 km from the coast and increases toward the dome area beyond the range. SSA varies depending on surface morphologies and meteorological events. The spatial variation of SSA can be explained by snow metamorphism, snowfall frequency, and wind-driven inhibition of snow deposition.
Benjamin Hmiel, Vasilii V. Petrenko, Christo Buizert, Andrew M. Smith, Michael N. Dyonisius, Philip Place, Bin Yang, Quan Hua, Ross Beaudette, Jeffrey P. Severinghaus, Christina Harth, Ray F. Weiss, Lindsey Davidge, Melisa Diaz, Matthew Pacicco, James A. Menking, Michael Kalk, Xavier Faïn, Alden Adolph, Isaac Vimont, and Lee T. Murray
The Cryosphere, 18, 3363–3382, https://doi.org/10.5194/tc-18-3363-2024, https://doi.org/10.5194/tc-18-3363-2024, 2024
Short summary
Short summary
The main aim of this research is to improve understanding of carbon-14 that is produced by cosmic rays in ice sheets. Measurements of carbon-14 in ice cores can provide a range of useful information (age of ice, past atmospheric chemistry, past cosmic ray intensity). Our results show that almost all (>99 %) of carbon-14 that is produced in the upper layer of ice sheets is rapidly lost to the atmosphere. Our results also provide better estimates of carbon-14 production rates in deeper ice.
Jessica Ng, Jeffrey Severinghaus, Ryan Bay, and Delia Tosi
Clim. Past, 20, 1437–1449, https://doi.org/10.5194/cp-20-1437-2024, https://doi.org/10.5194/cp-20-1437-2024, 2024
Short summary
Short summary
The pattern of Earth’s ice age cycles shifted around a million years ago, becoming more extreme and longer in duration. Multiple projects are underway to obtain an Antarctic ice core that covers this time period, as ice cores contain important clues to why the transition happened. To make sure the ice is old enough at the bottom, we demonstrate how to use new technology to quickly measure dust patterns in the ice and compare them to dust in deep-ocean sediments whose ages are known.
Kumiko Goto-Azuma, Remi Dallmayr, Yoshimi Ogawa-Tsukagawa, Nobuhiro Moteki, Tatsuhiro Mori, Sho Ohata, Yutaka Kondo, Makoto Koike, Motohiro Hirabayashi, Jun Ogata, Kyotaro Kitamura, Kenji Kawamura, Koji Fujita, Sumito Matoba, Naoko Nagatsuka, Akane Tsushima, Kaori Fukuda, and Teruo Aoki
EGUsphere, https://doi.org/10.5194/egusphere-2024-1496, https://doi.org/10.5194/egusphere-2024-1496, 2024
Short summary
Short summary
We developed a continuous flow analysis system to analyse an ice core from northwest Greenland, and coupled it with an improved BC measurement technique. This coupling allowed accurate high-resolution analyses of BC particles' size distributions and concentrations with diameters between 70 nm and 4 μm for the past 350 years. Our results provide crucial insights into BC's climatic effects. We also found that previous ice core studies substantially underestimated the BC mass concentrations.
Kumiko Goto-Azuma, Yoshimi Ogawa-Tsukagawa, Kaori Fukuda, Koji Fujita, Motohiro Hirabayashi, Remi Dallmayr, Jun Ogata, Nobuhiro Moteki, Tatsuhiro Mori, Sho Ohata, Yutaka Kondo, Makoto Koike, Sumito Matoba, and Teruo Aoki
EGUsphere, https://doi.org/10.5194/egusphere-2024-1498, https://doi.org/10.5194/egusphere-2024-1498, 2024
Short summary
Short summary
Monthly records spanning 350 years from a Greenland ice core reveal trends in black carbon (BC) concentrations and sizes. BC concentrations have risen since the late 19th century due to the inflow of anthropogenic BC, with these particles being larger than those from biomass burning (BB). High BB BC concentration peaks in summer originating from BB could reduce albedo. However, BB BC showed no upward trend until the early 2000s. Our findings are crucial for validating aerosol and climate models.
Frédéric Parrenin, Marie Bouchet, Christo Buizert, Emilie Capron, Ellen Corrick, Russell Drysdale, Kenji Kawamura, Amaëlle Landais, Robert Mulvaney, Ikumi Oyabu, and Sune Rasmussen
EGUsphere, https://doi.org/10.5194/egusphere-2023-2911, https://doi.org/10.5194/egusphere-2023-2911, 2024
Short summary
Short summary
The Paleochrono1 probablistic dating model allows to derive a common and optimized chronology for several paleoclimatic sites from various archives (ice cores, speleothems, marine cores, lake cores, etc.). It combines prior sedimentation scenarios with chronological information such as dated horizons, dated intervals, stratigraphic links and (for ice cores) Delta-depth observations. Paleochrono1 is available under the MIT open-source license.
Ryo Inoue, Shuji Fujita, Kenji Kawamura, Ikumi Oyabu, Fumio Nakazawa, Hideaki Motoyama, and Teruo Aoki
The Cryosphere, 18, 425–449, https://doi.org/10.5194/tc-18-425-2024, https://doi.org/10.5194/tc-18-425-2024, 2024
Short summary
Short summary
We measured the density, microstructural anisotropy, and specific surface area (SSA) of six firn cores collected within 60 km of Dome Fuji, Antarctica. We found a lack of significant density increase, development of vertically elongated microstructures, and a rapid decrease in SSA in the top few meters due to the metamorphism driven by water vapor transport under a temperature gradient. We highlight the significant spatial variability in the properties, which depends on the accumulation rate.
Tomotaka Saruya, Atsushi Miyamoto, Shuji Fujita, Kumiko Goto-Azuma, Motohiro Hirabayashi, Akira Hori, Makoto Igarashi, Yoshinori Iizuka, Takao Kameda, Hiroshi Ohno, Wataru Shigeyama, and Shun Tsutaki
EGUsphere, https://doi.org/10.5194/egusphere-2023-3146, https://doi.org/10.5194/egusphere-2023-3146, 2024
Short summary
Short summary
Crystal orientation fabrics (COF) and microstructures in the deep sections of the Dome Fuji ice core were investigated using innovative methods with unprecedentedly high statistical significance and dense depth coverage. Together with our previous studies, we have obtained a whole layer profile of the COF and physical properties of the Dome Fuji ice core. COF profile and its fluctuation were found to be highly dependent on impurities concentrations and recrystallization processes.
John D. Patterson, Murat Aydin, Andrew M. Crotwell, Gabrielle Pétron, Jeffery P. Severinghaus, Paul B. Krummel, Ray L. Langenfelds, Vasilii V. Petrenko, and Eric S. Saltzman
Clim. Past, 19, 2535–2550, https://doi.org/10.5194/cp-19-2535-2023, https://doi.org/10.5194/cp-19-2535-2023, 2023
Short summary
Short summary
Atmospheric levels of molecular hydrogen (H2) can impact climate and air quality. Constraining past changes to atmospheric H2 is useful for understanding how H2 cycles through the Earth system and predicting the impacts of increasing anthropogenic emissions under the
hydrogen economy. Here, we use the aging air found in the polar snowpack to reconstruct H2 levels over the past 100 years. We find that H2 levels increased by 30 % over Greenland and 60 % over Antarctica during the 20th century.
Tobias Erhardt, Camilla Marie Jensen, Florian Adolphi, Helle Astrid Kjær, Remi Dallmayr, Birthe Twarloh, Melanie Behrens, Motohiro Hirabayashi, Kaori Fukuda, Jun Ogata, François Burgay, Federico Scoto, Ilaria Crotti, Azzurra Spagnesi, Niccoló Maffezzoli, Delia Segato, Chiara Paleari, Florian Mekhaldi, Raimund Muscheler, Sophie Darfeuil, and Hubertus Fischer
Earth Syst. Sci. Data, 15, 5079–5091, https://doi.org/10.5194/essd-15-5079-2023, https://doi.org/10.5194/essd-15-5079-2023, 2023
Short summary
Short summary
The presented paper provides a 3.8 kyr long dataset of aerosol concentrations from the East Greenland Ice coring Project (EGRIP) ice core. The data consists of 1 mm depth-resolution profiles of calcium, sodium, ammonium, nitrate, and electrolytic conductivity as well as decadal averages of these profiles. Alongside the data a detailed description of the measurement setup as well as a discussion of the uncertainties are given.
Jenna A. Epifanio, Edward J. Brook, Christo Buizert, Erin C. Pettit, Jon S. Edwards, John M. Fegyveresi, Todd A. Sowers, Jeffrey P. Severinghaus, and Emma C. Kahle
The Cryosphere, 17, 4837–4851, https://doi.org/10.5194/tc-17-4837-2023, https://doi.org/10.5194/tc-17-4837-2023, 2023
Short summary
Short summary
The total air content (TAC) of polar ice cores has long been considered a potential proxy for past ice sheet elevation. This study presents a high-resolution record of TAC from the South Pole ice core. The record reveals orbital- and millennial-scale variability that cannot be explained by elevation changes. The orbital- and millennial-scale changes are likely a product of firn grain metamorphism near the surface of the ice sheet, due to summer insolation changes or local accumulation changes.
Naoko Nagatsuka, Kumiko Goto-Azuma, Koji Fujita, Yuki Komuro, Motohiro Hirabayashi, Jun Ogata, Kaori Fukuda, Yoshimi Ogawa-Tsukagawa, Kyotaro Kitamura, Ayaka Yonekura, Fumio Nakazawa, Yukihiko Onuma, Naoyuki Kurita, Sune Olander Rasmussen, Giulia Sinnl, Trevor James Popp, and Dorthe Dahl-Jensen
EGUsphere, https://doi.org/10.5194/egusphere-2023-1666, https://doi.org/10.5194/egusphere-2023-1666, 2023
Preprint archived
Short summary
Short summary
We present a new high-temporal-resolution record of mineral composition in a northeastern Greenland ice-core (EGRIP) over the past 100 years. The ice core dust composition and its variation differed significantly from a northwestern Greenland ice core, which is likely due to differences in the geological sources of the dust. Our results suggest that the EGRIP ice core dust was constantly supplied from Northern Eurasia, North America, and Asia with minor contribution from Greenland coast.
Alice C. Frémand, Peter Fretwell, Julien A. Bodart, Hamish D. Pritchard, Alan Aitken, Jonathan L. Bamber, Robin Bell, Cesidio Bianchi, Robert G. Bingham, Donald D. Blankenship, Gino Casassa, Ginny Catania, Knut Christianson, Howard Conway, Hugh F. J. Corr, Xiangbin Cui, Detlef Damaske, Volkmar Damm, Reinhard Drews, Graeme Eagles, Olaf Eisen, Hannes Eisermann, Fausto Ferraccioli, Elena Field, René Forsberg, Steven Franke, Shuji Fujita, Yonggyu Gim, Vikram Goel, Siva Prasad Gogineni, Jamin Greenbaum, Benjamin Hills, Richard C. A. Hindmarsh, Andrew O. Hoffman, Per Holmlund, Nicholas Holschuh, John W. Holt, Annika N. Horlings, Angelika Humbert, Robert W. Jacobel, Daniela Jansen, Adrian Jenkins, Wilfried Jokat, Tom Jordan, Edward King, Jack Kohler, William Krabill, Mette Kusk Gillespie, Kirsty Langley, Joohan Lee, German Leitchenkov, Carlton Leuschen, Bruce Luyendyk, Joseph MacGregor, Emma MacKie, Kenichi Matsuoka, Mathieu Morlighem, Jérémie Mouginot, Frank O. Nitsche, Yoshifumi Nogi, Ole A. Nost, John Paden, Frank Pattyn, Sergey V. Popov, Eric Rignot, David M. Rippin, Andrés Rivera, Jason Roberts, Neil Ross, Anotonia Ruppel, Dustin M. Schroeder, Martin J. Siegert, Andrew M. Smith, Daniel Steinhage, Michael Studinger, Bo Sun, Ignazio Tabacco, Kirsty Tinto, Stefano Urbini, David Vaughan, Brian C. Welch, Douglas S. Wilson, Duncan A. Young, and Achille Zirizzotti
Earth Syst. Sci. Data, 15, 2695–2710, https://doi.org/10.5194/essd-15-2695-2023, https://doi.org/10.5194/essd-15-2695-2023, 2023
Short summary
Short summary
This paper presents the release of over 60 years of ice thickness, bed elevation, and surface elevation data acquired over Antarctica by the international community. These data are a crucial component of the Antarctic Bedmap initiative which aims to produce a new map and datasets of Antarctic ice thickness and bed topography for the international glaciology and geophysical community.
Takashi Obase, Ayako Abe-Ouchi, Fuyuki Saito, Shun Tsutaki, Shuji Fujita, Kenji Kawamura, and Hideaki Motoyama
The Cryosphere, 17, 2543–2562, https://doi.org/10.5194/tc-17-2543-2023, https://doi.org/10.5194/tc-17-2543-2023, 2023
Short summary
Short summary
We use a one-dimensional ice-flow model to examine the most suitable core location near Dome Fuji (DF), Antarctica. This model computes the temporal evolution of age and temperature from past to present. We investigate the influence of different parameters of climate and ice sheet on the ice's basal age and compare the results with ground radar surveys. We find that the local ice thickness primarily controls the age because it is critical to the basal melting, which can eliminate the old ice.
Christo Buizert, Sarah Shackleton, Jeffrey P. Severinghaus, William H. G. Roberts, Alan Seltzer, Bernhard Bereiter, Kenji Kawamura, Daniel Baggenstos, Anaïs J. Orsi, Ikumi Oyabu, Benjamin Birner, Jacob D. Morgan, Edward J. Brook, David M. Etheridge, David Thornton, Nancy Bertler, Rebecca L. Pyne, Robert Mulvaney, Ellen Mosley-Thompson, Peter D. Neff, and Vasilii V. Petrenko
Clim. Past, 19, 579–606, https://doi.org/10.5194/cp-19-579-2023, https://doi.org/10.5194/cp-19-579-2023, 2023
Short summary
Short summary
It is unclear how different components of the global atmospheric circulation, such as the El Niño effect, respond to large-scale climate change. We present a new ice core gas proxy, called krypton-86 excess, that reflects past storminess in Antarctica. We present data from 11 ice cores that suggest the new proxy works. We present a reconstruction of changes in West Antarctic storminess over the last 24 000 years and suggest these are caused by north–south movement of the tropical rain belt.
Michael N. Dyonisius, Vasilii V. Petrenko, Andrew M. Smith, Benjamin Hmiel, Peter D. Neff, Bin Yang, Quan Hua, Jochen Schmitt, Sarah A. Shackleton, Christo Buizert, Philip F. Place, James A. Menking, Ross Beaudette, Christina Harth, Michael Kalk, Heidi A. Roop, Bernhard Bereiter, Casey Armanetti, Isaac Vimont, Sylvia Englund Michel, Edward J. Brook, Jeffrey P. Severinghaus, Ray F. Weiss, and Joseph R. McConnell
The Cryosphere, 17, 843–863, https://doi.org/10.5194/tc-17-843-2023, https://doi.org/10.5194/tc-17-843-2023, 2023
Short summary
Short summary
Cosmic rays that enter the atmosphere produce secondary particles which react with surface minerals to produce radioactive nuclides. These nuclides are often used to constrain Earth's surface processes. However, the production rates from muons are not well constrained. We measured 14C in ice with a well-known exposure history to constrain the production rates from muons. 14C production in ice is analogous to quartz, but we obtain different production rates compared to commonly used estimates.
Ikumi Oyabu, Kenji Kawamura, Shuji Fujita, Ryo Inoue, Hideaki Motoyama, Kotaro Fukui, Motohiro Hirabayashi, Yu Hoshina, Naoyuki Kurita, Fumio Nakazawa, Hiroshi Ohno, Konosuke Sugiura, Toshitaka Suzuki, Shun Tsutaki, Ayako Abe-Ouchi, Masashi Niwano, Frédéric Parrenin, Fuyuki Saito, and Masakazu Yoshimori
Clim. Past, 19, 293–321, https://doi.org/10.5194/cp-19-293-2023, https://doi.org/10.5194/cp-19-293-2023, 2023
Short summary
Short summary
We reconstructed accumulation rate around Dome Fuji, Antarctica, over the last 5000 years from 15 shallow ice cores and seven snow pits. We found a long-term decreasing trend in the preindustrial period, which may be associated with secular surface cooling and sea ice expansion. Centennial-scale variations were also found, which may partly be related to combinations of volcanic, solar and greenhouse gas forcings. The most rapid and intense increases of accumulation rate occurred since 1850 CE.
Shun Tsutaki, Shuji Fujita, Kenji Kawamura, Ayako Abe-Ouchi, Kotaro Fukui, Hideaki Motoyama, Yu Hoshina, Fumio Nakazawa, Takashi Obase, Hiroshi Ohno, Ikumi Oyabu, Fuyuki Saito, Konosuke Sugiura, and Toshitaka Suzuki
The Cryosphere, 16, 2967–2983, https://doi.org/10.5194/tc-16-2967-2022, https://doi.org/10.5194/tc-16-2967-2022, 2022
Short summary
Short summary
We constructed an ice thickness map across the Dome Fuji region, East Antarctica, from improved radar data and previous data that had been collected since the late 1980s. The data acquired using the improved radar systems allowed basal topography to be identified with higher accuracy. The new ice thickness data show the bedrock topography, particularly the complex terrain of subglacial valleys and highlands south of Dome Fuji, with substantially high detail.
Tomotaka Saruya, Shuji Fujita, Yoshinori Iizuka, Atsushi Miyamoto, Hiroshi Ohno, Akira Hori, Wataru Shigeyama, Motohiro Hirabayashi, and Kumiko Goto-Azuma
The Cryosphere, 16, 2985–3003, https://doi.org/10.5194/tc-16-2985-2022, https://doi.org/10.5194/tc-16-2985-2022, 2022
Short summary
Short summary
Crystal orientation fabrics (COF) of the Dome Fuji ice core were investigated with an innovative method with unprecedentedly high statistical significance and dense depth coverage. The COF profile and its fluctuation were found to be highly dependent on concentrations of chloride ion and dust. The data suggest deformation of ice at the deepest zone is highly influenced by COF fluctuations that progressively develop from the near-surface firn toward the deepest zone within ice sheets.
Jacob D. Morgan, Christo Buizert, Tyler J. Fudge, Kenji Kawamura, Jeffrey P. Severinghaus, and Cathy M. Trudinger
The Cryosphere, 16, 2947–2966, https://doi.org/10.5194/tc-16-2947-2022, https://doi.org/10.5194/tc-16-2947-2022, 2022
Short summary
Short summary
The composition of air bubbles in Antarctic ice cores records information about past changes in properties of the snowpack. We find that, near the South Pole, thinner snowpack in the past is often due to steeper surface topography, in which faster winds erode the snow and deposit it in flatter areas. The slope and wind seem to also cause a seasonal bias in the composition of air bubbles in the ice core. These findings will improve interpretation of other ice cores from places with steep slopes.
Naveen Chandra, Prabir K. Patra, Yousuke Niwa, Akihiko Ito, Yosuke Iida, Daisuke Goto, Shinji Morimoto, Masayuki Kondo, Masayuki Takigawa, Tomohiro Hajima, and Michio Watanabe
Atmos. Chem. Phys., 22, 9215–9243, https://doi.org/10.5194/acp-22-9215-2022, https://doi.org/10.5194/acp-22-9215-2022, 2022
Short summary
Short summary
This paper is intended to accomplish two goals: (1) quantify mean and uncertainty in non-fossil-fuel CO2 fluxes estimated by inverse modeling and (2) provide in-depth analyses of regional CO2 fluxes in support of emission mitigation policymaking. CO2 flux variability and trends are discussed concerning natural climate variability and human disturbances using multiple lines of evidence.
Giyoon Lee, Jinho Ahn, Hyeontae Ju, Florian Ritterbusch, Ikumi Oyabu, Christo Buizert, Songyi Kim, Jangil Moon, Sambit Ghosh, Kenji Kawamura, Zheng-Tian Lu, Sangbum Hong, Chang Hee Han, Soon Do Hur, Wei Jiang, and Guo-Min Yang
The Cryosphere, 16, 2301–2324, https://doi.org/10.5194/tc-16-2301-2022, https://doi.org/10.5194/tc-16-2301-2022, 2022
Short summary
Short summary
Blue-ice areas (BIAs) have several advantages for reconstructing past climate. However, the complicated ice flow in the area hinders constraining the age. We applied state-of-the-art techniques and found that the ages cover the last deglaciation period. Our study demonstrates that the BIA in northern Victoria Land may help reconstruct the past climate during the termination of the last glacial period.
Taku Umezawa, Satoshi Sugawara, Kenji Kawamura, Ikumi Oyabu, Stephen J. Andrews, Takuya Saito, Shuji Aoki, and Takakiyo Nakazawa
Atmos. Chem. Phys., 22, 6899–6917, https://doi.org/10.5194/acp-22-6899-2022, https://doi.org/10.5194/acp-22-6899-2022, 2022
Short summary
Short summary
Greenhouse gas methane in the Arctic atmosphere has not been accurately reported for 1900–1980 from either direct observations or ice core reconstructions. By using trace gas data from firn (compacted snow layers above ice sheet), air samples at two Greenland sites, and a firn air transport model, this study suggests a likely range of the Arctic methane reconstruction for the 20th century. Atmospheric scenarios from two previous studies are also evaluated for consistency with the firn data sets.
Sarah Shackleton, James A. Menking, Edward Brook, Christo Buizert, Michael N. Dyonisius, Vasilii V. Petrenko, Daniel Baggenstos, and Jeffrey P. Severinghaus
Clim. Past, 17, 2273–2289, https://doi.org/10.5194/cp-17-2273-2021, https://doi.org/10.5194/cp-17-2273-2021, 2021
Short summary
Short summary
In this study, we measure atmospheric noble gases trapped in ice cores to reconstruct ocean temperature during the last glaciation. Comparing the new reconstruction to other climate records, we show that the ocean reached its coldest temperatures before ice sheets reached maximum volumes and atmospheric CO2 reached its lowest concentrations. Ocean cooling played a major role in lowering atmospheric CO2 early in the glaciation, but it only played a minor role later.
Naoko Nagatsuka, Kumiko Goto-Azuma, Akane Tsushima, Koji Fujita, Sumito Matoba, Yukihiko Onuma, Remi Dallmayr, Moe Kadota, Motohiro Hirabayashi, Jun Ogata, Yoshimi Ogawa-Tsukagawa, Kyotaro Kitamura, Masahiro Minowa, Yuki Komuro, Hideaki Motoyama, and Teruo Aoki
Clim. Past, 17, 1341–1362, https://doi.org/10.5194/cp-17-1341-2021, https://doi.org/10.5194/cp-17-1341-2021, 2021
Short summary
Short summary
Here we present a first high-temporal-resolution record of mineral composition in a Greenland ice core (SIGMA-D) over the past 100 years using SEM–EDS analysis. Our results show that the ice core dust composition varied on multi-decadal scales, which was likely affected by local temperature changes. We suggest that the ice core dust was constantly supplied from distant sources (mainly northern Canada) as well as local ice-free areas in warm periods (1915 to 1949 and 2005 to 2013).
Benjamin Birner, William Paplawsky, Jeffrey Severinghaus, and Ralph F. Keeling
Atmos. Meas. Tech., 14, 2515–2527, https://doi.org/10.5194/amt-14-2515-2021, https://doi.org/10.5194/amt-14-2515-2021, 2021
Short summary
Short summary
The atmospheric helium-to-nitrogen ratio is a promising indicator for circulation changes in the upper atmosphere and fossil fuel burning by humans. We present a very precise analysis method to determine changes in the helium-to-nitrogen ratio of air samples. The method relies on stabilizing the gas flow to a mass spectrometer and continuous removal of reactive gases. These advances enable new insights and monitoring possibilities for anthropogenic and natural processes.
Ikumi Oyabu, Kenji Kawamura, Kyotaro Kitamura, Remi Dallmayr, Akihiro Kitamura, Chikako Sawada, Jeffrey P. Severinghaus, Ross Beaudette, Anaïs Orsi, Satoshi Sugawara, Shigeyuki Ishidoya, Dorthe Dahl-Jensen, Kumiko Goto-Azuma, Shuji Aoki, and Takakiyo Nakazawa
Atmos. Meas. Tech., 13, 6703–6731, https://doi.org/10.5194/amt-13-6703-2020, https://doi.org/10.5194/amt-13-6703-2020, 2020
Short summary
Short summary
Air in polar ice cores provides information on past atmosphere and climate. We present a new method for simultaneously measuring eight gases (CH4, N2O and CO2 concentrations; isotopic ratios of N2 and O2; elemental ratios between N2, O2 and Ar; and total air content) from single ice-core samples with high precision.
Jenna A. Epifanio, Edward J. Brook, Christo Buizert, Jon S. Edwards, Todd A. Sowers, Emma C. Kahle, Jeffrey P. Severinghaus, Eric J. Steig, Dominic A. Winski, Erich C. Osterberg, Tyler J. Fudge, Murat Aydin, Ekaterina Hood, Michael Kalk, Karl J. Kreutz, David G. Ferris, and Joshua A. Kennedy
Clim. Past, 16, 2431–2444, https://doi.org/10.5194/cp-16-2431-2020, https://doi.org/10.5194/cp-16-2431-2020, 2020
Short summary
Short summary
A new ice core drilled at the South Pole provides a 54 000-year paleo-environmental record including the composition of the past atmosphere. This paper describes the gas chronology for the South Pole ice core, based on a high-resolution methane record. The new gas chronology, in combination with the existing ice age scale from Winski et al. (2019), allows a model-independent reconstruction of the delta age record.
Benjamin Birner, Martyn P. Chipperfield, Eric J. Morgan, Britton B. Stephens, Marianna Linz, Wuhu Feng, Chris Wilson, Jonathan D. Bent, Steven C. Wofsy, Jeffrey Severinghaus, and Ralph F. Keeling
Atmos. Chem. Phys., 20, 12391–12408, https://doi.org/10.5194/acp-20-12391-2020, https://doi.org/10.5194/acp-20-12391-2020, 2020
Short summary
Short summary
With new high-precision observations from nine aircraft campaigns and 3-D chemical transport modeling, we show that the argon-to-nitrogen ratio (Ar / N2) in the lowermost stratosphere provides a useful constraint on the “age of air” (the time elapsed since entry of an air parcel into the stratosphere). Therefore, Ar / N2 in combination with traditional age-of-air indicators, such as CO2 and N2O, could provide new insights into atmospheric mixing and transport.
James E. Lee, Edward J. Brook, Nancy A. N. Bertler, Christo Buizert, Troy Baisden, Thomas Blunier, V. Gabriela Ciobanu, Howard Conway, Dorthe Dahl-Jensen, Tyler J. Fudge, Richard Hindmarsh, Elizabeth D. Keller, Frédéric Parrenin, Jeffrey P. Severinghaus, Paul Vallelonga, Edwin D. Waddington, and Mai Winstrup
Clim. Past, 16, 1691–1713, https://doi.org/10.5194/cp-16-1691-2020, https://doi.org/10.5194/cp-16-1691-2020, 2020
Short summary
Short summary
The Roosevelt Island ice core was drilled to investigate climate from the eastern Ross Sea, West Antarctica. We describe the ice age-scale and gas age-scale of the ice core for 0–763 m (83 000 years BP). Old ice near the bottom of the core implies the ice dome existed throughout the last glacial period and that ice streaming was active in the region. Variations in methane, similar to those used as evidence of early human influence on climate, were observed prior to significant human populations.
Dominic A. Winski, Tyler J. Fudge, David G. Ferris, Erich C. Osterberg, John M. Fegyveresi, Jihong Cole-Dai, Zayta Thundercloud, Thomas S. Cox, Karl J. Kreutz, Nikolas Ortman, Christo Buizert, Jenna Epifanio, Edward J. Brook, Ross Beaudette, Jeffrey Severinghaus, Todd Sowers, Eric J. Steig, Emma C. Kahle, Tyler R. Jones, Valerie Morris, Murat Aydin, Melinda R. Nicewonger, Kimberly A. Casey, Richard B. Alley, Edwin D. Waddington, Nels A. Iverson, Nelia W. Dunbar, Ryan C. Bay, Joseph M. Souney, Michael Sigl, and Joseph R. McConnell
Clim. Past, 15, 1793–1808, https://doi.org/10.5194/cp-15-1793-2019, https://doi.org/10.5194/cp-15-1793-2019, 2019
Short summary
Short summary
A deep ice core was recently drilled at the South Pole to understand past variations in the Earth's climate. To understand the information contained within the ice, we present the relationship between the depth and age of the ice in the South Pole Ice Core. We found that the oldest ice in our record is from 54 302 ± 519 years ago. Our results show that, on average, 7.4 cm of snow falls at the South Pole each year.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell N. Drysdale, Philip L. Gibbard, Lauren Gregoire, Feng He, Ruza F. Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis C. Tzedakis, Eric Wolff, and Xu Zhang
Geosci. Model Dev., 12, 3649–3685, https://doi.org/10.5194/gmd-12-3649-2019, https://doi.org/10.5194/gmd-12-3649-2019, 2019
Short summary
Short summary
As part of the Past Global Changes (PAGES) working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation for the Paleoclimate Modelling Intercomparison Project (PMIP4). This design includes time-varying changes in orbital forcing, greenhouse gas concentrations, continental ice sheets as well as freshwater input from the disintegration of continental ice sheets. Key paleo-records for model-data comparison are also included.
Jens Mühle, Cathy M. Trudinger, Luke M. Western, Matthew Rigby, Martin K. Vollmer, Sunyoung Park, Alistair J. Manning, Daniel Say, Anita Ganesan, L. Paul Steele, Diane J. Ivy, Tim Arnold, Shanlan Li, Andreas Stohl, Christina M. Harth, Peter K. Salameh, Archie McCulloch, Simon O'Doherty, Mi-Kyung Park, Chun Ok Jo, Dickon Young, Kieran M. Stanley, Paul B. Krummel, Blagoj Mitrevski, Ove Hermansen, Chris Lunder, Nikolaos Evangeliou, Bo Yao, Jooil Kim, Benjamin Hmiel, Christo Buizert, Vasilii V. Petrenko, Jgor Arduini, Michela Maione, David M. Etheridge, Eleni Michalopoulou, Mike Czerniak, Jeffrey P. Severinghaus, Stefan Reimann, Peter G. Simmonds, Paul J. Fraser, Ronald G. Prinn, and Ray F. Weiss
Atmos. Chem. Phys., 19, 10335–10359, https://doi.org/10.5194/acp-19-10335-2019, https://doi.org/10.5194/acp-19-10335-2019, 2019
Short summary
Short summary
We discuss atmospheric concentrations and emissions of the strong greenhouse gas perfluorocyclobutane. A large fraction of recent emissions stem from China, India, and Russia, probably as a by-product from the production of fluoropolymers and fluorochemicals. Most historic emissions likely stem from developed countries. Total emissions are higher than what is being reported. Clearly, more measurements and better reporting are needed to understand emissions of this and other greenhouse gases.
James A. Menking, Edward J. Brook, Sarah A. Shackleton, Jeffrey P. Severinghaus, Michael N. Dyonisius, Vasilii Petrenko, Joseph R. McConnell, Rachael H. Rhodes, Thomas K. Bauska, Daniel Baggenstos, Shaun Marcott, and Stephen Barker
Clim. Past, 15, 1537–1556, https://doi.org/10.5194/cp-15-1537-2019, https://doi.org/10.5194/cp-15-1537-2019, 2019
Short summary
Short summary
An ice core from Taylor Glacier, Antarctica, spans a period ~ 70 000 years ago when Earth entered the last ice age. Chemical analyses of the ice and air bubbles allow for an independent determination of the ages of the ice and gas bubbles. The difference between the age of the ice and the bubbles at any given depth, called ∆age, is unusually high in the Taylor Glacier core compared to the Taylor Dome ice core situated to the south. This implies a dramatic accumulation gradient between the sites.
Yoichi Inai, Ryo Fujita, Toshinobu Machida, Hidekazu Matsueda, Yousuke Sawa, Kazuhiro Tsuboi, Keiichi Katsumata, Shinji Morimoto, Shuji Aoki, and Takakiyo Nakazawa
Atmos. Chem. Phys., 19, 7073–7103, https://doi.org/10.5194/acp-19-7073-2019, https://doi.org/10.5194/acp-19-7073-2019, 2019
Dmitry Belikov, Satoshi Sugawara, Shigeyuki Ishidoya, Fumio Hasebe, Shamil Maksyutov, Shuji Aoki, Shinji Morimoto, and Takakiyo Nakazawa
Atmos. Chem. Phys., 19, 5349–5361, https://doi.org/10.5194/acp-19-5349-2019, https://doi.org/10.5194/acp-19-5349-2019, 2019
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell Drysdale, Philip Gibbard, Lauren Gregoire, Feng He, Ruza Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis Tzedakis, Eric Wolff, and Xu Zhang
Clim. Past Discuss., https://doi.org/10.5194/cp-2018-106, https://doi.org/10.5194/cp-2018-106, 2018
Preprint withdrawn
Short summary
Short summary
The penultimate deglaciation (~ 138–128 ka), which represents the transition into the Last Interglacial period, provides a framework to investigate the climate and environmental response to large changes in boundary conditions. Here, as part of the PAGES-PMIP working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation as well as a selection of paleo records for upcoming model-data comparisons.
Benjamin Birner, Christo Buizert, Till J. W. Wagner, and Jeffrey P. Severinghaus
The Cryosphere, 12, 2021–2037, https://doi.org/10.5194/tc-12-2021-2018, https://doi.org/10.5194/tc-12-2021-2018, 2018
Short summary
Short summary
Ancient air enclosed in bubbles of the Antarctic ice sheet is a key source of information about the Earth's past climate. However, a range of physical processes in the snow layer atop an ice sheet may change the trapped air's chemical composition before it is occluded in the ice. We developed the first detailed 2-D computer simulation of these processes and found a new method to improve the reconstruction of past climate from air in ice cores bubbles.
Taku Umezawa, Carl A. M. Brenninkmeijer, Thomas Röckmann, Carina van der Veen, Stanley C. Tyler, Ryo Fujita, Shinji Morimoto, Shuji Aoki, Todd Sowers, Jochen Schmitt, Michael Bock, Jonas Beck, Hubertus Fischer, Sylvia E. Michel, Bruce H. Vaughn, John B. Miller, James W. C. White, Gordon Brailsford, Hinrich Schaefer, Peter Sperlich, Willi A. Brand, Michael Rothe, Thomas Blunier, David Lowry, Rebecca E. Fisher, Euan G. Nisbet, Andrew L. Rice, Peter Bergamaschi, Cordelia Veidt, and Ingeborg Levin
Atmos. Meas. Tech., 11, 1207–1231, https://doi.org/10.5194/amt-11-1207-2018, https://doi.org/10.5194/amt-11-1207-2018, 2018
Short summary
Short summary
Isotope measurements are useful for separating different methane sources. However, the lack of widely accepted standards and calibration methods for stable carbon and hydrogen isotopic ratios of methane in air has caused significant measurement offsets among laboratories. We conducted worldwide interlaboratory comparisons, surveyed the literature and assessed them systematically. This study may be of help in future attempts to harmonize data sets of isotopic composition of atmospheric methane.
Nancy A. N. Bertler, Howard Conway, Dorthe Dahl-Jensen, Daniel B. Emanuelsson, Mai Winstrup, Paul T. Vallelonga, James E. Lee, Ed J. Brook, Jeffrey P. Severinghaus, Taylor J. Fudge, Elizabeth D. Keller, W. Troy Baisden, Richard C. A. Hindmarsh, Peter D. Neff, Thomas Blunier, Ross Edwards, Paul A. Mayewski, Sepp Kipfstuhl, Christo Buizert, Silvia Canessa, Ruzica Dadic, Helle A. Kjær, Andrei Kurbatov, Dongqi Zhang, Edwin D. Waddington, Giovanni Baccolo, Thomas Beers, Hannah J. Brightley, Lionel Carter, David Clemens-Sewall, Viorela G. Ciobanu, Barbara Delmonte, Lukas Eling, Aja Ellis, Shruthi Ganesh, Nicholas R. Golledge, Skylar Haines, Michael Handley, Robert L. Hawley, Chad M. Hogan, Katelyn M. Johnson, Elena Korotkikh, Daniel P. Lowry, Darcy Mandeno, Robert M. McKay, James A. Menking, Timothy R. Naish, Caroline Noerling, Agathe Ollive, Anaïs Orsi, Bernadette C. Proemse, Alexander R. Pyne, Rebecca L. Pyne, James Renwick, Reed P. Scherer, Stefanie Semper, Marius Simonsen, Sharon B. Sneed, Eric J. Steig, Andrea Tuohy, Abhijith Ulayottil Venugopal, Fernando Valero-Delgado, Janani Venkatesh, Feitang Wang, Shimeng Wang, Dominic A. Winski, V. Holly L. Winton, Arran Whiteford, Cunde Xiao, Jiao Yang, and Xin Zhang
Clim. Past, 14, 193–214, https://doi.org/10.5194/cp-14-193-2018, https://doi.org/10.5194/cp-14-193-2018, 2018
Short summary
Short summary
Temperature and snow accumulation records from the annually dated Roosevelt Island Climate Evolution (RICE) ice core show that for the past 2 700 years, the eastern Ross Sea warmed, while the western Ross Sea showed no trend and West Antarctica cooled. From the 17th century onwards, this dipole relationship changed. Now all three regions show concurrent warming, with snow accumulation declining in West Antarctica and the eastern Ross Sea.
Satoshi Sugawara, Shigeyuki Ishidoya, Shuji Aoki, Shinji Morimoto, Takakiyo Nakazawa, Sakae Toyoda, Yoichi Inai, Fumio Hasebe, Chusaku Ikeda, Hideyuki Honda, Daisuke Goto, and Fanny A. Putri
Atmos. Chem. Phys., 18, 1819–1833, https://doi.org/10.5194/acp-18-1819-2018, https://doi.org/10.5194/acp-18-1819-2018, 2018
Short summary
Short summary
This is the first research that shows concrete evidence of gravitational separation in the tropical stratosphere. This implies that gravitational separation occurs within the entire stratosphere, which gives us new insight into atmospheric dynamics.
Sakae Toyoda, Naohiro Yoshida, Shinji Morimoto, Shuji Aoki, Takakiyo Nakazawa, Satoshi Sugawara, Shigeyuki Ishidoya, Mitsuo Uematsu, Yoichi Inai, Fumio Hasebe, Chusaku Ikeda, Hideyuki Honda, and Kentaro Ishijima
Atmos. Chem. Phys., 18, 833–844, https://doi.org/10.5194/acp-18-833-2018, https://doi.org/10.5194/acp-18-833-2018, 2018
Short summary
Short summary
By analysis of whole air samples collected by balloon-borne compact cryogenic samplers, we found that apparent isotope effect for stratospheric N2O between 25 and 30 km over the Equator is larger than that observed in other latitudes and that it is almost equal to the effect predicted by laboratory simulation experiments. These results suggest that equatorial middle stratosphere can be treated as an isolated region when we consider the decomposition of N2O by photochemical processes.
Alan M. Seltzer, Christo Buizert, Daniel Baggenstos, Edward J. Brook, Jinho Ahn, Ji-Woong Yang, and Jeffrey P. Severinghaus
Clim. Past, 13, 1323–1338, https://doi.org/10.5194/cp-13-1323-2017, https://doi.org/10.5194/cp-13-1323-2017, 2017
Short summary
Short summary
To explore whether the oxygen-18 to oxygen-16 ratio of atmospheric O2 is sensitive to the position of the tropical rain belts, we (1) present a record of ice core bubble oxygen isotope measurements from two Antarctic ice cores, and (2) examine the sensitivity of oxygen isotopes in precipitation, weighted by photosynthesis, to the location of oxygen production over the modern-day seasonal cycle. We find a strong modern relationship and discuss implications for past shifts in tropical rainfall.
Daniel Baggenstos, Thomas K. Bauska, Jeffrey P. Severinghaus, James E. Lee, Hinrich Schaefer, Christo Buizert, Edward J. Brook, Sarah Shackleton, and Vasilii V. Petrenko
Clim. Past, 13, 943–958, https://doi.org/10.5194/cp-13-943-2017, https://doi.org/10.5194/cp-13-943-2017, 2017
Short summary
Short summary
We present measurements of the gas composition in trapped air bubbles in ice samples taken from Taylor Glacier, Antarctica. We can show that ice from the entire last glacial cycle (125 000 years ago to the present) is exposed at the surface of this glacier and that the atmospheric record contained in the air bubbles is well preserved. Taylor Glacier therefore provides an easily accessible archive of ancient ice that allows for studies of trace components that require large ice volumes.
Keiichiro Hara, Sumito Matoba, Motohiro Hirabayashi, and Tetsuhide Yamasaki
Atmos. Chem. Phys., 17, 8577–8598, https://doi.org/10.5194/acp-17-8577-2017, https://doi.org/10.5194/acp-17-8577-2017, 2017
Short summary
Short summary
To obtain knowledge about sea-salt chemistry in polar regions, we made simultaneous measurements and sampling of aerosols, frost flowers, and brine around northwestern Greenland during winter–spring. Our results show sea-salt enrichment in frost flowers and snow. Also, the fractionated sea-salt particles were suspended in the atmosphere over sea-ice areas. From the field evidence and results from earlier studies, we propose and describe sea-salt cycles in seasonal sea-ice areas.
Dennis L. Nielson, Chris Delahunty, John W. Goodge, and Jeffery P. Severinghaus
Sci. Dril., 22, 29–33, https://doi.org/10.5194/sd-22-29-2017, https://doi.org/10.5194/sd-22-29-2017, 2017
Short summary
Short summary
The North American Testing (NAT) was designed to test critical functions of a Rapid Access Ice Drill (RAID) at a site in northern Utah. The RAID was designed to rapidly drill in Antarctica through over 2500 m of ice and then take a core sample of the bedrock. The system has many innovative features that required field testing before the system was shipped to Antarcitca. The NAT facility consisted of a borehole where we froze a column of ice to test drilling and fluid circulation functions.
Dmitry A. Belikov, Shamil Maksyutov, Alexander Ganshin, Ruslan Zhuravlev, Nicholas M. Deutscher, Debra Wunch, Dietrich G. Feist, Isamu Morino, Robert J. Parker, Kimberly Strong, Yukio Yoshida, Andrey Bril, Sergey Oshchepkov, Hartmut Boesch, Manvendra K. Dubey, David Griffith, Will Hewson, Rigel Kivi, Joseph Mendonca, Justus Notholt, Matthias Schneider, Ralf Sussmann, Voltaire A. Velazco, and Shuji Aoki
Atmos. Chem. Phys., 17, 143–157, https://doi.org/10.5194/acp-17-143-2017, https://doi.org/10.5194/acp-17-143-2017, 2017
Christo Buizert and Jeffrey P. Severinghaus
The Cryosphere, 10, 2099–2111, https://doi.org/10.5194/tc-10-2099-2016, https://doi.org/10.5194/tc-10-2099-2016, 2016
Short summary
Short summary
The upper 50–100 m of the world's ice sheets consists of the firn layer, a porous layer of snow that is slowly compacted by overlying snow. Understanding air movement inside the firn is critical for ice core climate reconstructions. Buizert and Severinghaus identify and describe a new mechanism of firn air movement. High- and low-pressure systems force air movement in the firn that drives strong mixing, called dispersion. Dispersion is the main mechanism for air mixing in the deep firn.
Alexandra Touzeau, Amaëlle Landais, Barbara Stenni, Ryu Uemura, Kotaro Fukui, Shuji Fujita, Sarah Guilbaud, Alexey Ekaykin, Mathieu Casado, Eugeni Barkan, Boaz Luz, Olivier Magand, Grégory Teste, Emmanuel Le Meur, Mélanie Baroni, Joël Savarino, Ilann Bourgeois, and Camille Risi
The Cryosphere, 10, 837–852, https://doi.org/10.5194/tc-10-837-2016, https://doi.org/10.5194/tc-10-837-2016, 2016
Short summary
Short summary
The relationship between water isotope ratios and temperature is investigated in precipitation snow at Vostok and Dome C, as well as in surface snow along traverses. The temporal slope of the linear regression for the precipitation is smaller than the geographical slope. Thus, using the latter could lead to an underestimation of past temperature changes. The processes active at remote sites (best glacial analogs) are explored through a combination of water isotopes in short snow pits.
Ikumi Oyabu, Yoshinori Iizuka, Eric Wolff, and Margareta Hansson
Clim. Past Discuss., https://doi.org/10.5194/cp-2016-42, https://doi.org/10.5194/cp-2016-42, 2016
Manuscript not accepted for further review
Short summary
Short summary
This study presented the chemical compositions of non-volatile particles around the last termination in the Dome C ice core by using the sublimation-EDS method. The major soluble salt particles are CaSO4, Na2SO4, and NaCl, and time-series changes in the composition of these salts are similar to those for the Dome Fuji ice core. However, some differences occurred. The sulfatization rate of NaCl at Dome C is higher than that at Dome Fuji.
Shin'ya Nakano, Kazue Suzuki, Kenji Kawamura, Frédéric Parrenin, and Tomoyuki Higuchi
Nonlin. Processes Geophys., 23, 31–44, https://doi.org/10.5194/npg-23-31-2016, https://doi.org/10.5194/npg-23-31-2016, 2016
Short summary
Short summary
This paper proposes a technique for dating an ice core. The proposed technique employs a hybrid method combining the sequential Monte Carlo method and the Markov chain Monte Carlo method, which is referred to as the particle Markov chain Monte Carlo method. The sequential Monte Carlo method, which is also known as the particle filter, is widely used for nonlinear time-series analysis. This paper demonstrates the usefulness of the approach in time-series analysis for dating an ice core.
S. Fujita, F. Parrenin, M. Severi, H. Motoyama, and E. W. Wolff
Clim. Past, 11, 1395–1416, https://doi.org/10.5194/cp-11-1395-2015, https://doi.org/10.5194/cp-11-1395-2015, 2015
A. Svensson, S. Fujita, M. Bigler, M. Braun, R. Dallmayr, V. Gkinis, K. Goto-Azuma, M. Hirabayashi, K. Kawamura, S. Kipfstuhl, H. A. Kjær, T. Popp, M. Simonsen, J. P. Steffensen, P. Vallelonga, and B. M. Vinther
Clim. Past, 11, 1127–1137, https://doi.org/10.5194/cp-11-1127-2015, https://doi.org/10.5194/cp-11-1127-2015, 2015
K. Ishijima, M. Takigawa, K. Sudo, S. Toyoda, N. Yoshida, T. Röckmann, J. Kaiser, S. Aoki, S. Morimoto, S. Sugawara, and T. Nakazawa
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-15-19947-2015, https://doi.org/10.5194/acpd-15-19947-2015, 2015
Revised manuscript not accepted
Short summary
Short summary
We developed an atmospheric N2O isotopocule model based on a chemistry-coupled atmospheric general circulation model and a simple method to optimize the model, and estimated the isotopic signatures of surface sources at the hemispheric scale. Data obtained from ground-based observations, measurements of firn air, and balloon and aircraft flights were used to optimize the long-term trends, interhemispheric gradients, and photolytic fractionation, respectively, in the model.
A. Ghosh, P. K. Patra, K. Ishijima, T. Umezawa, A. Ito, D. M. Etheridge, S. Sugawara, K. Kawamura, J. B. Miller, E. J. Dlugokencky, P. B. Krummel, P. J. Fraser, L. P. Steele, R. L. Langenfelds, C. M. Trudinger, J. W. C. White, B. Vaughn, T. Saeki, S. Aoki, and T. Nakazawa
Atmos. Chem. Phys., 15, 2595–2612, https://doi.org/10.5194/acp-15-2595-2015, https://doi.org/10.5194/acp-15-2595-2015, 2015
Short summary
Short summary
Atmospheric CH4 increased from 900ppb to 1800ppb during the period 1900–2010 at a rate unprecedented in any observational records. We use bottom-up emissions and a chemistry-transport model to simulate CH4. The optimized global total CH4 emission, estimated from the model–observation differences, increased at fastest rate during 1940–1990. Using δ13C of CH4 measurements we attribute this emission increase to biomass burning. Total CH4 lifetime is shortened by 4% over the simulation period.
F. Parrenin, S. Fujita, A. Abe-Ouchi, K. Kawamura, V. Masson-Delmotte, H. Motoyama, F. Saito, M. Severi, B. Stenni, R. Uemura, and E. Wolff
Clim. Past Discuss., https://doi.org/10.5194/cpd-11-377-2015, https://doi.org/10.5194/cpd-11-377-2015, 2015
Revised manuscript has not been submitted
C. Buizert, K. M. Cuffey, J. P. Severinghaus, D. Baggenstos, T. J. Fudge, E. J. Steig, B. R. Markle, M. Winstrup, R. H. Rhodes, E. J. Brook, T. A. Sowers, G. D. Clow, H. Cheng, R. L. Edwards, M. Sigl, J. R. McConnell, and K. C. Taylor
Clim. Past, 11, 153–173, https://doi.org/10.5194/cp-11-153-2015, https://doi.org/10.5194/cp-11-153-2015, 2015
K. Hara, F. Nakazawa, S. Fujita, K. Fukui, H. Enomoto, and S. Sugiyama
Atmos. Chem. Phys., 14, 10211–10230, https://doi.org/10.5194/acp-14-10211-2014, https://doi.org/10.5194/acp-14-10211-2014, 2014
M. Montagnat, N. Azuma, D. Dahl-Jensen, J. Eichler, S. Fujita, F. Gillet-Chaulet, S. Kipfstuhl, D. Samyn, A. Svensson, and I. Weikusat
The Cryosphere, 8, 1129–1138, https://doi.org/10.5194/tc-8-1129-2014, https://doi.org/10.5194/tc-8-1129-2014, 2014
E. Saikawa, R. G. Prinn, E. Dlugokencky, K. Ishijima, G. S. Dutton, B. D. Hall, R. Langenfelds, Y. Tohjima, T. Machida, M. Manizza, M. Rigby, S. O'Doherty, P. K. Patra, C. M. Harth, R. F. Weiss, P. B. Krummel, M. van der Schoot, P. J. Fraser, L. P. Steele, S. Aoki, T. Nakazawa, and J. W. Elkins
Atmos. Chem. Phys., 14, 4617–4641, https://doi.org/10.5194/acp-14-4617-2014, https://doi.org/10.5194/acp-14-4617-2014, 2014
S. O. Rasmussen, P. M. Abbott, T. Blunier, A. J. Bourne, E. Brook, S. L. Buchardt, C. Buizert, J. Chappellaz, H. B. Clausen, E. Cook, D. Dahl-Jensen, S. M. Davies, M. Guillevic, S. Kipfstuhl, T. Laepple, I. K. Seierstad, J. P. Severinghaus, J. P. Steffensen, C. Stowasser, A. Svensson, P. Vallelonga, B. M. Vinther, F. Wilhelms, and M. Winstrup
Clim. Past, 9, 2713–2730, https://doi.org/10.5194/cp-9-2713-2013, https://doi.org/10.5194/cp-9-2713-2013, 2013
K. Kawamura, J. P. Severinghaus, M. R. Albert, Z. R. Courville, M. A. Fahnestock, T. Scambos, E. Shields, and C. A. Shuman
Atmos. Chem. Phys., 13, 11141–11155, https://doi.org/10.5194/acp-13-11141-2013, https://doi.org/10.5194/acp-13-11141-2013, 2013
H. Fischer, J. Severinghaus, E. Brook, E. Wolff, M. Albert, O. Alemany, R. Arthern, C. Bentley, D. Blankenship, J. Chappellaz, T. Creyts, D. Dahl-Jensen, M. Dinn, M. Frezzotti, S. Fujita, H. Gallee, R. Hindmarsh, D. Hudspeth, G. Jugie, K. Kawamura, V. Lipenkov, H. Miller, R. Mulvaney, F. Parrenin, F. Pattyn, C. Ritz, J. Schwander, D. Steinhage, T. van Ommen, and F. Wilhelms
Clim. Past, 9, 2489–2505, https://doi.org/10.5194/cp-9-2489-2013, https://doi.org/10.5194/cp-9-2489-2013, 2013
S. Ishidoya, S. Sugawara, S. Morimoto, S. Aoki, T. Nakazawa, H. Honda, and S. Murayama
Atmos. Chem. Phys., 13, 8787–8796, https://doi.org/10.5194/acp-13-8787-2013, https://doi.org/10.5194/acp-13-8787-2013, 2013
V. V. Petrenko, P. Martinerie, P. Novelli, D. M. Etheridge, I. Levin, Z. Wang, T. Blunier, J. Chappellaz, J. Kaiser, P. Lang, L. P. Steele, S. Hammer, J. Mak, R. L. Langenfelds, J. Schwander, J. P. Severinghaus, E. Witrant, G. Petron, M. O. Battle, G. Forster, W. T. Sturges, J.-F. Lamarque, K. Steffen, and J. W. C. White
Atmos. Chem. Phys., 13, 7567–7585, https://doi.org/10.5194/acp-13-7567-2013, https://doi.org/10.5194/acp-13-7567-2013, 2013
A. Svensson, M. Bigler, T. Blunier, H. B. Clausen, D. Dahl-Jensen, H. Fischer, S. Fujita, K. Goto-Azuma, S. J. Johnsen, K. Kawamura, S. Kipfstuhl, M. Kohno, F. Parrenin, T. Popp, S. O. Rasmussen, J. Schwander, I. Seierstad, M. Severi, J. P. Steffensen, R. Udisti, R. Uemura, P. Vallelonga, B. M. Vinther, A. Wegner, F. Wilhelms, and M. Winstrup
Clim. Past, 9, 749–766, https://doi.org/10.5194/cp-9-749-2013, https://doi.org/10.5194/cp-9-749-2013, 2013
T. Kobashi, D. T. Shindell, K. Kodera, J. E. Box, T. Nakaegawa, and K. Kawamura
Clim. Past, 9, 583–596, https://doi.org/10.5194/cp-9-583-2013, https://doi.org/10.5194/cp-9-583-2013, 2013
P. Fretwell, H. D. Pritchard, D. G. Vaughan, J. L. Bamber, N. E. Barrand, R. Bell, C. Bianchi, R. G. Bingham, D. D. Blankenship, G. Casassa, G. Catania, D. Callens, H. Conway, A. J. Cook, H. F. J. Corr, D. Damaske, V. Damm, F. Ferraccioli, R. Forsberg, S. Fujita, Y. Gim, P. Gogineni, J. A. Griggs, R. C. A. Hindmarsh, P. Holmlund, J. W. Holt, R. W. Jacobel, A. Jenkins, W. Jokat, T. Jordan, E. C. King, J. Kohler, W. Krabill, M. Riger-Kusk, K. A. Langley, G. Leitchenkov, C. Leuschen, B. P. Luyendyk, K. Matsuoka, J. Mouginot, F. O. Nitsche, Y. Nogi, O. A. Nost, S. V. Popov, E. Rignot, D. M. Rippin, A. Rivera, J. Roberts, N. Ross, M. J. Siegert, A. M. Smith, D. Steinhage, M. Studinger, B. Sun, B. K. Tinto, B. C. Welch, D. Wilson, D. A. Young, C. Xiangbin, and A. Zirizzotti
The Cryosphere, 7, 375–393, https://doi.org/10.5194/tc-7-375-2013, https://doi.org/10.5194/tc-7-375-2013, 2013
Related subject area
Discipline: Ice sheets | Subject: Ice Cores
The grain-scale signature of isotopic diffusion in ice
Combining traditional and novel techniques to increase our understanding of the lock-in depth of atmospheric gases in polar ice cores – results from the EastGRIP region
Scientific history, sampling approach, and physical characterization of the Camp Century subglacial material, a rare archive from beneath the Greenland Ice Sheet
Novel approach to estimate the water isotope diffusion length in deep ice cores with an application to Marine Isotope Stage 19 in the Dome C ice core
The potential of in situ cosmogenic 14CO in ice cores as a proxy for galactic cosmic ray flux variations
Characterization of in situ cosmogenic 14CO production, retention and loss in firn and shallow ice at Summit, Greenland
Research into mechanical modeling based on characteristics of the fracture mechanics of ice cutting for scientific drilling in polar regions
Laser Ablation – ICP-MS measurements for high resolution chemical ice core analyses with a first application to an ice core from Skytrain Ice Rise (Antarctica)
Millennial and orbital-scale variability in a 54 000-year record of total air content from the South Pole ice core
Investigating the spatial representativeness of East Antarctic ice cores: a comparison of ice core and radar-derived surface mass balance over coastal ice rises and Dome Fuji
Greenland and Canadian Arctic ice temperature profiles database
Isotopic diffusion in ice enhanced by vein-water flow
A one-dimensional temperature and age modeling study for selecting the drill site of the oldest ice core near Dome Fuji, Antarctica
Chemical and visual characterisation of EGRIP glacial ice and cloudy bands within
Detection of ice core particles via deep neural networks
Development of crystal orientation fabric in the Dome Fuji ice core in East Antarctica: implications for the deformation regime in ice sheets
Gas isotope thermometry in the South Pole and Dome Fuji ice cores provides evidence for seasonal rectification of ice core gas records
Microstructure, micro-inclusions, and mineralogy along the EGRIP (East Greenland Ice Core Project) ice core – Part 2: Implications for palaeo-mineralogy
Microstructure, micro-inclusions, and mineralogy along the EGRIP ice core – Part 1: Localisation of inclusions and deformation patterns
Two-dimensional impurity imaging in deep Antarctic ice cores: snapshots of three climatic periods and implications for high-resolution signal interpretation
Brief communication: New radar constraints support presence of ice older than 1.5 Myr at Little Dome C
Pervasive diffusion of climate signals recorded in ice-vein ionic impurities
Multi-tracer study of gas trapping in an East Antarctic ice core
Very old firn air linked to strong density layering at Styx Glacier, coastal Victoria Land, East Antarctica
Glaciological characteristics in the Dome Fuji region and new assessment for “Oldest Ice”
Felix S. L. Ng
The Cryosphere, 18, 4645–4669, https://doi.org/10.5194/tc-18-4645-2024, https://doi.org/10.5194/tc-18-4645-2024, 2024
Short summary
Short summary
Liquid veins and grain boundaries in ice can accelerate the decay of climate signals in δ18O and δD by short-circuiting the slow isotopic diffusion in crystal grains. This theory for "excess diffusion" has not been confirmed experimentally. We show that, if the mechanism occurs, then distinct isotopic patterns must form near grain junctions, offering a testable prediction of the theory. We calculate the patterns and describe an experimental scheme for testing ice-core samples for the mechanism.
Julien Westhoff, Johannes Freitag, Anaïs Orsi, Patricia Martinerie, Ilka Weikusat, Michael Dyonisius, Xavier Faïn, Kevin Fourteau, and Thomas Blunier
The Cryosphere, 18, 4379–4397, https://doi.org/10.5194/tc-18-4379-2024, https://doi.org/10.5194/tc-18-4379-2024, 2024
Short summary
Short summary
We study the EastGRIP area, Greenland, in detail with traditional and novel techniques. Due to the compaction of the ice, at a certain depth, atmospheric gases can no longer exchange, and the atmosphere is trapped in air bubbles in the ice. We find this depth by pumping air from a borehole, modeling, and using a new technique based on the optical appearance of the ice. Our results suggest that the close-off depth lies at around 58–61 m depth and more precisely at 58.3 m depth.
Paul R. Bierman, Andrew J. Christ, Catherine M. Collins, Halley M. Mastro, Juliana Souza, Pierre-Henri Blard, Stefanie Brachfeld, Zoe R. Courville, Tammy M. Rittenour, Elizabeth K. Thomas, Jean-Louis Tison, and François Fripiat
The Cryosphere, 18, 4029–4052, https://doi.org/10.5194/tc-18-4029-2024, https://doi.org/10.5194/tc-18-4029-2024, 2024
Short summary
Short summary
In 1966, the U.S. Army drilled through the Greenland Ice Sheet at Camp Century, Greenland; they recovered 3.44 m of frozen material. Here, we decipher the material’s history. Water, flowing during a warm interglacial when the ice sheet melted from northwest Greenland, deposited the upper material which contains fossil plant and insect parts. The lower material, separated by more than a meter of ice with some sediment, is till, deposited by the ice sheet during a prior cold period.
Fyntan Shaw, Andrew M. Dolman, Torben Kunz, Vasileios Gkinis, and Thomas Laepple
The Cryosphere, 18, 3685–3698, https://doi.org/10.5194/tc-18-3685-2024, https://doi.org/10.5194/tc-18-3685-2024, 2024
Short summary
Short summary
Fast variability of water isotopes in ice cores is attenuated by diffusion but can be restored if the diffusion length is accurately estimated. Current estimation methods are inadequate for deep ice, mischaracterising millennial-scale climate variability. We address this using variability estimates from shallower ice. The estimated diffusion length of 31 cm for the bottom of the Dome C ice core is 20 cm less than the old method, enabling signal recovery on timescales previously considered lost.
Vasilii V. Petrenko, Segev BenZvi, Michael Dyonisius, Benjamin Hmiel, Andrew M. Smith, and Christo Buizert
The Cryosphere, 18, 3439–3451, https://doi.org/10.5194/tc-18-3439-2024, https://doi.org/10.5194/tc-18-3439-2024, 2024
Short summary
Short summary
This manuscript presents the concept for a new proxy for past variations in the galactic cosmic ray flux (GCR). Past variations in GCR flux are important to understand for interpretation of records of isotopes produced by cosmic rays; these records are used for reconstructing solar variations and past land ice extent. The proxy involves using measurements of 14CO in ice cores, which should provide an uncomplicated and precise estimate of past GCR flux variations for the past few thousand years.
Benjamin Hmiel, Vasilii V. Petrenko, Christo Buizert, Andrew M. Smith, Michael N. Dyonisius, Philip Place, Bin Yang, Quan Hua, Ross Beaudette, Jeffrey P. Severinghaus, Christina Harth, Ray F. Weiss, Lindsey Davidge, Melisa Diaz, Matthew Pacicco, James A. Menking, Michael Kalk, Xavier Faïn, Alden Adolph, Isaac Vimont, and Lee T. Murray
The Cryosphere, 18, 3363–3382, https://doi.org/10.5194/tc-18-3363-2024, https://doi.org/10.5194/tc-18-3363-2024, 2024
Short summary
Short summary
The main aim of this research is to improve understanding of carbon-14 that is produced by cosmic rays in ice sheets. Measurements of carbon-14 in ice cores can provide a range of useful information (age of ice, past atmospheric chemistry, past cosmic ray intensity). Our results show that almost all (>99 %) of carbon-14 that is produced in the upper layer of ice sheets is rapidly lost to the atmosphere. Our results also provide better estimates of carbon-14 production rates in deeper ice.
Xinyu Lv, Zhihao Cui, Ting Wang, Yumin Wen, An Liu, and Rusheng Wang
The Cryosphere, 18, 3351–3362, https://doi.org/10.5194/tc-18-3351-2024, https://doi.org/10.5194/tc-18-3351-2024, 2024
Short summary
Short summary
In this study, the formation process of ice chips was observed and the fracture mechanics characteristics of the ice during the cutting process were analyzed. Additionally, a mechanical model for the cutting force was established based on the observation and analysis results. Finally, influencing factors and laws of the cutting force were verified by cutting force test results generated under various experimental conditions.
Helene Hoffmann, Jason Day, Rachael Rhodes, Mackenzie Grieman, Jack Humby, Isobel Rowell, Christoph Nehrbass-Ahles, Robert Mulvaney, Sally Gibson, and Eric Wolff
EGUsphere, https://doi.org/10.5194/egusphere-2023-3071, https://doi.org/10.5194/egusphere-2023-3071, 2024
Short summary
Short summary
Ice cores are archives of past atmospheric conditions. In deep, old ice the layers containing this information get thinned to the millimetre scale or below. We installed a setup for high resolution (80 μm) chemical impurity measurements in ice cores using the laser ablation technique at the University of Cambridge. In a first application to Skytrain Ice Core from Antarctica we discuss the potential to detect fine layered structures in ice from Skytrain Ice Core up to an age of ~ 126 000 years.
Jenna A. Epifanio, Edward J. Brook, Christo Buizert, Erin C. Pettit, Jon S. Edwards, John M. Fegyveresi, Todd A. Sowers, Jeffrey P. Severinghaus, and Emma C. Kahle
The Cryosphere, 17, 4837–4851, https://doi.org/10.5194/tc-17-4837-2023, https://doi.org/10.5194/tc-17-4837-2023, 2023
Short summary
Short summary
The total air content (TAC) of polar ice cores has long been considered a potential proxy for past ice sheet elevation. This study presents a high-resolution record of TAC from the South Pole ice core. The record reveals orbital- and millennial-scale variability that cannot be explained by elevation changes. The orbital- and millennial-scale changes are likely a product of firn grain metamorphism near the surface of the ice sheet, due to summer insolation changes or local accumulation changes.
Marie G. P. Cavitte, Hugues Goosse, Kenichi Matsuoka, Sarah Wauthy, Vikram Goel, Rahul Dey, Bhanu Pratap, Brice Van Liefferinge, Thamban Meloth, and Jean-Louis Tison
The Cryosphere, 17, 4779–4795, https://doi.org/10.5194/tc-17-4779-2023, https://doi.org/10.5194/tc-17-4779-2023, 2023
Short summary
Short summary
The net accumulation of snow over Antarctica is key for assessing current and future sea-level rise. Ice cores record a noisy snowfall signal to verify model simulations. We find that ice core net snowfall is biased to lower values for ice rises and the Dome Fuji site (Antarctica), while the relative uncertainty in measuring snowfall increases rapidly with distance away from the ice core sites at the ice rises but not at Dome Fuji. Spatial variation in snowfall must therefore be considered.
Anja Løkkegaard, Kenneth D. Mankoff, Christian Zdanowicz, Gary D. Clow, Martin P. Lüthi, Samuel H. Doyle, Henrik H. Thomsen, David Fisher, Joel Harper, Andy Aschwanden, Bo M. Vinther, Dorthe Dahl-Jensen, Harry Zekollari, Toby Meierbachtol, Ian McDowell, Neil Humphrey, Anne Solgaard, Nanna B. Karlsson, Shfaqat A. Khan, Benjamin Hills, Robert Law, Bryn Hubbard, Poul Christoffersen, Mylène Jacquemart, Julien Seguinot, Robert S. Fausto, and William T. Colgan
The Cryosphere, 17, 3829–3845, https://doi.org/10.5194/tc-17-3829-2023, https://doi.org/10.5194/tc-17-3829-2023, 2023
Short summary
Short summary
This study presents a database compiling 95 ice temperature profiles from the Greenland ice sheet and peripheral ice caps. Ice viscosity and hence ice flow are highly sensitive to ice temperature. To highlight the value of the database in evaluating ice flow simulations, profiles from the Greenland ice sheet are compared to a modeled temperature field. Reoccurring discrepancies between modeled and observed temperatures provide insight on the difficulties faced when simulating ice temperatures.
Felix S. L. Ng
The Cryosphere, 17, 3063–3082, https://doi.org/10.5194/tc-17-3063-2023, https://doi.org/10.5194/tc-17-3063-2023, 2023
Short summary
Short summary
The stable isotopes of oxygen and hydrogen in ice cores are routinely analysed for the climate signals which they carry. It has long been known that the system of water veins in ice facilitates isotopic diffusion. Here, mathematical modelling shows that water flow in the veins strongly accelerates the diffusion and the decay of climate signals. The process hampers methods using the variations in signal decay with depth to reconstruct past climatic temperature.
Takashi Obase, Ayako Abe-Ouchi, Fuyuki Saito, Shun Tsutaki, Shuji Fujita, Kenji Kawamura, and Hideaki Motoyama
The Cryosphere, 17, 2543–2562, https://doi.org/10.5194/tc-17-2543-2023, https://doi.org/10.5194/tc-17-2543-2023, 2023
Short summary
Short summary
We use a one-dimensional ice-flow model to examine the most suitable core location near Dome Fuji (DF), Antarctica. This model computes the temporal evolution of age and temperature from past to present. We investigate the influence of different parameters of climate and ice sheet on the ice's basal age and compare the results with ground radar surveys. We find that the local ice thickness primarily controls the age because it is critical to the basal melting, which can eliminate the old ice.
Nicolas Stoll, Julien Westhoff, Pascal Bohleber, Anders Svensson, Dorthe Dahl-Jensen, Carlo Barbante, and Ilka Weikusat
The Cryosphere, 17, 2021–2043, https://doi.org/10.5194/tc-17-2021-2023, https://doi.org/10.5194/tc-17-2021-2023, 2023
Short summary
Short summary
Impurities in polar ice play a role regarding its climate signal and internal deformation. We bridge different scales using different methods to investigate ice from the Last Glacial Period derived from the EGRIP ice core in Greenland. We characterise different types of cloudy bands, i.e. frequently occurring milky layers in the ice, and analyse their chemistry with Raman spectroscopy and 2D imaging. We derive new insights into impurity localisation and deposition conditions.
Niccolò Maffezzoli, Eliza Cook, Willem G. M. van der Bilt, Eivind N. Støren, Daniela Festi, Florian Muthreich, Alistair W. R. Seddon, François Burgay, Giovanni Baccolo, Amalie R. F. Mygind, Troels Petersen, Andrea Spolaor, Sebastiano Vascon, Marcello Pelillo, Patrizia Ferretti, Rafael S. dos Reis, Jefferson C. Simões, Yuval Ronen, Barbara Delmonte, Marco Viccaro, Jørgen Peder Steffensen, Dorthe Dahl-Jensen, Kerim H. Nisancioglu, and Carlo Barbante
The Cryosphere, 17, 539–565, https://doi.org/10.5194/tc-17-539-2023, https://doi.org/10.5194/tc-17-539-2023, 2023
Short summary
Short summary
Multiple lines of research in ice core science are limited by manually intensive and time-consuming optical microscopy investigations for the detection of insoluble particles, from pollen grains to volcanic shards. To help overcome these limitations and support researchers, we present a novel methodology for the identification and autonomous classification of ice core insoluble particles based on flow image microscopy and neural networks.
Tomotaka Saruya, Shuji Fujita, Yoshinori Iizuka, Atsushi Miyamoto, Hiroshi Ohno, Akira Hori, Wataru Shigeyama, Motohiro Hirabayashi, and Kumiko Goto-Azuma
The Cryosphere, 16, 2985–3003, https://doi.org/10.5194/tc-16-2985-2022, https://doi.org/10.5194/tc-16-2985-2022, 2022
Short summary
Short summary
Crystal orientation fabrics (COF) of the Dome Fuji ice core were investigated with an innovative method with unprecedentedly high statistical significance and dense depth coverage. The COF profile and its fluctuation were found to be highly dependent on concentrations of chloride ion and dust. The data suggest deformation of ice at the deepest zone is highly influenced by COF fluctuations that progressively develop from the near-surface firn toward the deepest zone within ice sheets.
Jacob D. Morgan, Christo Buizert, Tyler J. Fudge, Kenji Kawamura, Jeffrey P. Severinghaus, and Cathy M. Trudinger
The Cryosphere, 16, 2947–2966, https://doi.org/10.5194/tc-16-2947-2022, https://doi.org/10.5194/tc-16-2947-2022, 2022
Short summary
Short summary
The composition of air bubbles in Antarctic ice cores records information about past changes in properties of the snowpack. We find that, near the South Pole, thinner snowpack in the past is often due to steeper surface topography, in which faster winds erode the snow and deposit it in flatter areas. The slope and wind seem to also cause a seasonal bias in the composition of air bubbles in the ice core. These findings will improve interpretation of other ice cores from places with steep slopes.
Nicolas Stoll, Maria Hörhold, Tobias Erhardt, Jan Eichler, Camilla Jensen, and Ilka Weikusat
The Cryosphere, 16, 667–688, https://doi.org/10.5194/tc-16-667-2022, https://doi.org/10.5194/tc-16-667-2022, 2022
Short summary
Short summary
We mapped and analysed solid inclusion in the upper 1340 m of the EGRIP ice core with Raman spectroscopy and microstructure mapping, based on bulk dust content derived via continuous flow analysis. We observe a large variety in mineralogy throughout the core and samples. The main minerals are sulfates, especially gypsum, and terrestrial dust minerals, such as quartz, mica, and feldspar. A change in mineralogy occurs around 900 m depth indicating a climate-related imprint.
Nicolas Stoll, Jan Eichler, Maria Hörhold, Tobias Erhardt, Camilla Jensen, and Ilka Weikusat
The Cryosphere, 15, 5717–5737, https://doi.org/10.5194/tc-15-5717-2021, https://doi.org/10.5194/tc-15-5717-2021, 2021
Short summary
Short summary
We did a systematic analysis of the location of inclusions in the EGRIP ice core, the first ice core from an ice stream. We combine this with crystal orientation and grain size data, enabling the first overview about the microstructure of this unique ice core. Micro-inclusions show a strong spatial variability and patterns (clusters or horizontal layers); roughly one-third is located at grain boundaries. More holistic approaches are needed to understand deformation processes in the ice better.
Pascal Bohleber, Marco Roman, Martin Šala, Barbara Delmonte, Barbara Stenni, and Carlo Barbante
The Cryosphere, 15, 3523–3538, https://doi.org/10.5194/tc-15-3523-2021, https://doi.org/10.5194/tc-15-3523-2021, 2021
Short summary
Short summary
Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) offers micro-destructive, micrometer-scale impurity analysis of ice cores. For improved understanding of the LA-ICP-MS signals, novel 2D impurity imaging is applied to selected glacial and interglacial samples of Antarctic deep ice cores. This allows evaluating the 2D impurity distribution in relation to ice crystal features and assessing implications for investigating highly thinned climate proxy signals in deep polar ice.
David A. Lilien, Daniel Steinhage, Drew Taylor, Frédéric Parrenin, Catherine Ritz, Robert Mulvaney, Carlos Martín, Jie-Bang Yan, Charles O'Neill, Massimo Frezzotti, Heinrich Miller, Prasad Gogineni, Dorthe Dahl-Jensen, and Olaf Eisen
The Cryosphere, 15, 1881–1888, https://doi.org/10.5194/tc-15-1881-2021, https://doi.org/10.5194/tc-15-1881-2021, 2021
Short summary
Short summary
We collected radar data between EDC, an ice core spanning ~800 000 years, and BELDC, the site chosen for a new
oldest icecore at nearby Little Dome C. These data allow us to identify 50 % older internal horizons than previously traced in the area. We fit a model to the ages of those horizons at BELDC to determine the age of deep ice there. We find that there is likely to be 1.5 Myr old ice ~265 m above the bed, with sufficient resolution to preserve desired climatic information.
Felix S. L. Ng
The Cryosphere, 15, 1787–1810, https://doi.org/10.5194/tc-15-1787-2021, https://doi.org/10.5194/tc-15-1787-2021, 2021
Short summary
Short summary
Current theory predicts climate signals in the vein chemistry of ice cores to migrate, hampering their dating. I show that the Gibbs–Thomson effect, which has been overlooked, causes fast diffusion that prevents signals from surviving into deep ice. Hence the deep climatic peaks in Antarctic and Greenlandic ice must be due to impurities in the ice matrix (outside veins) and safe from migration. These findings reset our understanding of postdepositional changes of ice-core climate signals.
Kévin Fourteau, Patricia Martinerie, Xavier Faïn, Christoph F. Schaller, Rebecca J. Tuckwell, Henning Löwe, Laurent Arnaud, Olivier Magand, Elizabeth R. Thomas, Johannes Freitag, Robert Mulvaney, Martin Schneebeli, and Vladimir Ya. Lipenkov
The Cryosphere, 13, 3383–3403, https://doi.org/10.5194/tc-13-3383-2019, https://doi.org/10.5194/tc-13-3383-2019, 2019
Short summary
Short summary
Understanding gas trapping in polar ice is essential to study the relationship between greenhouse gases and past climates. New data of bubble closure, used in a simple gas-trapping model, show inconsistency with the final air content in ice. This suggests gas trapping is not fully understood. We also use a combination of high-resolution measurements to investigate the effect of polar snow stratification on gas trapping and find that all strata have similar pores, but that some close in advance.
Youngjoon Jang, Sang Bum Hong, Christo Buizert, Hun-Gyu Lee, Sang-Young Han, Ji-Woong Yang, Yoshinori Iizuka, Akira Hori, Yeongcheol Han, Seong Joon Jun, Pieter Tans, Taejin Choi, Seong-Joong Kim, Soon Do Hur, and Jinho Ahn
The Cryosphere, 13, 2407–2419, https://doi.org/10.5194/tc-13-2407-2019, https://doi.org/10.5194/tc-13-2407-2019, 2019
Short summary
Short summary
We can learn how human activity altered atmospheric air from the interstitial air in the porous snow layer (firn) on top of glaciers. However, old firn air (> 55 years) was observed only at sites where surface temperatures and snow accumulation rates are very low, such as the South Pole. In this study, we report an unusually old firn air with CO2 age of 93 years from Styx Glacier, near the Ross Sea coast in Antarctica. We hypothesize that the large snow density variations increase firn air ages.
Nanna B. Karlsson, Tobias Binder, Graeme Eagles, Veit Helm, Frank Pattyn, Brice Van Liefferinge, and Olaf Eisen
The Cryosphere, 12, 2413–2424, https://doi.org/10.5194/tc-12-2413-2018, https://doi.org/10.5194/tc-12-2413-2018, 2018
Short summary
Short summary
In this study, we investigate the probability that the Dome Fuji region in East Antarctica contains ice more than 1.5 Ma old. The retrieval of a continuous ice-core record extending beyond 1 Ma is imperative to understand why the frequency of ice ages changed from 40 to 100 ka approximately 1 Ma ago.
We use a new radar dataset to improve the ice thickness maps, and apply a thermokinematic model to predict basal temperature and age of the ice. Our results indicate several areas of interest.
Cited articles
Azuma, N., Wang, Y., Yoshida, Y., and Narita, H.: Crystallographic analysis
of the Dome Fuji ice core, Physics of Ice Core Records, 45–61, available at: http://hdl.handle.net/2115/32461 (last access: 7 December 2021), 2000.
Battle, M., Bender, M., Sowers, T., Tans, P. P., Butler, J. H., Elkins, J. W., Ellis, J. T., Conway, T., Zhang, N., Lang, P., and Clarke, A. D.: Atmospheric gas concentrations over the past century measured in air from
firn at the South Pole, Nature, 383, 231-235, https://doi.org/10.1038/383231a0, 1996.
Battle, M. O., Severinghaus, J. P., Sofen, E. D., Plotkin, D., Orsi, A. J.,
Aydin, M., Montzka, S. A., Sowers, T., and Tans, P. P.: Controls on the
movement and composition of firn air at the West Antarctic Ice Sheet Divide,
Atmos. Chem. Phys., 11, 11007–11021, https://doi.org/10.5194/acp-11-11007-2011, 2011.
Bazin, L., Landais, A., Capron, E., Masson-Delmotte, V., Ritz, C., Picard,
G., Jouzel, J., Dumont, M., Leuenberger, M., and Prié, F.: Phase
relationships between orbital forcing and the composition of air trapped in
Antarctic ice cores, Clim. Past, 12, 729–748, https://doi.org/10.5194/cp-12-729-2016, 2016.
Bender, M. L.: Orbital tuning chronology for the Vostok climate record
supported by trapped gas composition, Earth Planet. Sc. Lett., 204, 275–289,
https://doi.org/10.1016/S0012-821X(02)00980-9, 2002.
Bender, M., Sowers, T., Barnola, J.-M., and Chappellaz, J.: Changes in the
Bender, M. L., Tans, P. P., Ellis, J. T., Orchardo, J., and Habfast, K.: A
high precision isotope ratio mass spectrometry method for measuring the
Bender, M., Sowers, T., and Lipenkov, V.: On the concentrations of O2, N2, and Ar in trapped gases from ice cores, J. Geophys. Res., 100, 18651–18660, https://doi.org/10.1029/94JD02212, 1995.
Bereiter, B., Schwander, J., Luthi, D., and Stocker, T. F.: Change in CO2 concentration and
Bereiter, B., Fischer, H., Schwander, J., and Stocker, T. F.: Diffusive
equilibration of N2, O2 and CO2 mixing ratios in a 1.5-million-years-old ice core, The Cryosphere, 8, 245–256, https://doi.org/10.5194/tc-8-245-2014, 2014.
Buizert, C., Fudge, T. J., Roberts, W. H. G., Steig, E. J., Sherriff-Tadano,
S., Ritz, C., Lefebvre, E., Edwards, J., Kawamura, K., Oyabu, I., Motoyama,
H., Kahle, E. C., Jones, T. R., Abe-Ouchi, A., Obase, T., Martin, C., Corr, H., Severinghaus, J. P., Beaudette, R., Epifanio, J. A., Brook, E. J., Martin, K., Chappellaz, J., Aoki, S., Nakazawa, T., Sowers, T., Alley, R.,
Ahn, J., Sigl, M., Severi, M., Dunbar, N. W., Svensson, A., Fegyveresi, J.,
He, C., Liu, Z., Zhu, J., Otto-Bliesner, B., Lipenkov, V., Kageyama, M., and
Schwander, J.: Antarctic-wide surface temperature and elevation during the
Last Glacial Maximum, Science, 372, 1097–1101, https://doi.org/10.1126/science.abd2897, 2021.
Chazallon, B., Champagnon, B., Panczer, G., Pauer, F., Klapproth, A., and
Kuhs, W. F.: Micro-Raman analysis of synthetic air clathrates, Eur. J. Mineral., 10, 1125–1134, 1998.
Craig, H. and Scarsi, P.: Helium isotope stratigraphy in the GISP2 ice core,
Eos Trans. Am. Geophys. Union, 78, F7, 1997.
Craig, H., Horibe, Y., and Sowers, T.: Gravitational separation of gases and
isotopes in polar ice caps, Science, 23, 1675–1678, https://doi.org/10.1126/science.242.4886.1675, 1988.
Extier, T., Landais, A., Bréant, C., Prié, F., Bazin, L., Dreyfus, G., Roche, D. M., and Leuenberger, M.: On the use of δ18Oatm for ice core dating, Quaternary Sci. Rev., 185, 244–257, https://doi.org/10.1016/j.quascirev.2018.02.008, 2018.
Fischer, H., Severinghaus, J., Brook, E., Wolff, E., Albert, M., Alemany, O., Arthern, R., Bentley, C., Blankenship, D., Chappellaz, J., Creyts, T., Dahl-Jensen, D., Dinn, M., Frezzotti, M., Fujita, S., Gallee, H., Hindmarsh,
R., Hudspeth, D., Jugie, G., Kawamura, K., Lipenkov, V., Miller, H., Mulvaney, R., Parrenin, F., Pattyn, F., Ritz, C., Schwander, J., Steinhage,
D., van Ommen, T., and Wilhelms, F.: Where to find 1.5 million yr old ice
for the IPICS “Oldest-Ice” ice core, Clim. Past, 9, 2489–2505,
https://doi.org/10.5194/cp-9-2489-2013, 2013.
Fujita, S., Okuyama, J., Hori, A., and Hondoh, T.: Metamorphism of stratified firn at Dome Fuji, Antarctica: A mechanism for local insolation modulation of gas transport conditions during bubble close off, J. Geophys. Res., 114, F03023, https://doi.org/10.1029/2008JF001143, 2009.
Fujita, S., Goto-Azuma, K., Hirabayashi, M., Hori, A., Iizuka, Y., Motizuki,
Y., Motoyama, H., and Takahashi, K.: Densification of layered firn in the
ice sheet at Dome Fuji, Antarctica, J. Glaciol., 62, 103–123, https://doi.org/10.1017/jog.2016.16, 2016.
Goto-Azuma, K., Hirabayashi, M., Motoyama, H., Miyake, T., Kuramoto, T., Uemura, R., Igarashi, M., Iizuka, Y., Sakurai, T., Horikawa, S., Suzuki, K.,
Suzuki, T., Fujita, K., Kondo, Y., Hattori, S., and Fujii, Y.: Reduced
marine phytoplankton sulphur emissions in the Southern Ocean during the past
seven glacials, Nat. Commun, 10, 3247, https://doi.org/10.1038/s41467-019-11128-6, 2019.
Hondoh, T. (Ed.): An Overview of Microphysical Processes in Ice Sheets: Toward Nanoglaciology, Low Temperature Science, Physics of Ice Core Records II, Institute of Low Temperature Science, Hokkaido University,
Japan, available at: http://hdl.handle.net/2115/45404 (last access: 7 December 2021), 2009.
Hoshina, Y., Fujita, K., Nakazawa, F., Iizuka, Y., Miyake, T., Hirabayashi,
M., Kuramoto, T., Fujita, S., and Motoyama, H.: Effect of accumulation rate
on water stable isotopes of near-surface snow in inland Antarctica, J. Geophys. Res.-Atmos., 119, 274–283, https://doi.org/10.1002/2013JD020771, 2014.
Huber, C. and Leuenberger, M.: Measurements of isotope and elemental ratios
of air from polar ice with a new on-line extraction method, Geochem. Geophy. Geosy., 5, 1–13, https://doi.org/10.1029/2004GC000766, 2004.
Huber, C., Beyerle, U., Leuenberger, M., Schwander, J., Kipfer, R., Spahni, R., Severinghaus, J. P., and Weiler, K.: Evidence for molecular size dependent gas fractionation in firn air derived from noble gases, oxygen,
and nitrogen measurements, Earth Planet. Sc. Lett., 243, 61–73, https://doi.org/10.1016/j.epsl.2005.12.036, 2006.
Ikeda-Fukazawa, T., Hondoh, T., Fukumura, T., Fukazawa, H., and Mae, S.:
Variation in
Ikeda-Fukazawa, T., Kawamura, K., and Hondoh, T.: Diffusion of nitrogen gas in ice Ih, Chem. Phys. Lett., 385, 467–471, https://doi.org/10.1016/j.cplett.2004.01.021, 2004.
Ikeda-Fukazawa, T., Fukumizu, K., Kawamura, K., Aoki, S., Nakazawa, T., and
Hondoh, T.: Effects of molecular diffusion on trapped gas composition in
polar ice cores, Earth Planet. Sc. Lett., 229, 183–192, https://doi.org/10.1016/j.epsl.2004.11.011, 2005.
Kawamura, K.: Variations of atmospheric components over the past 340 000 years from Dome Fuji deep ice core, Antarctica, PhD thesis, Tohoku University, Japan, available at: http://hdl.handle.net/10097/38833 (last access: 7 December 2021), 2001.
Kawamura, K., Parrenin, F., Lisiecki, L., Uemura, R., Vimeux, F., Severinghaus, J. P., Hutterli, M. A., Nakazawa, T., Aoki, S., Jouzel, J.,
Raymo, M. E., Matsumoto, K., Nakata, H., Motoyama, H., Fujita, S., Goto-Azuma, K., Fujii, Y., and Watanabe, O.: Northern Hemisphere forcing of
climatic cycles in Antarctica over the past 360,000 years, Nature, 448,
912–916, https://doi.org/10.1038/nature06015, 2007.
Kobashi, T., Severinghaus, J. P., and Kawamura, K.: Argon and nitrogen
isotopes of trapped air in the GISP2 ice core during the Holocene epoch
(0–1, 500 B.P.): Methodology and implications for gas loss processes, Geochim. Cosmochim. Ac., 72, 4675–4686, https://doi.org/10.1016/j.gca.2008.07.006, 2008.
Kobashi, T., Ikeda-Fukazawa, T., Suwa, M., Schwander, J., Kameda, T., Lundin, J., Hori, A., Motoyama, H., Döring, M., and Leuenberger, M.: Post-bubble close-off fractionation of gases in polar firn and ice cores: effects of accumulation rate on permeation through overloading pressure, Atmos. Chem. Phys., 15, 13895–13914, https://doi.org/10.5194/acp-15-13895-2015, 2015.
Kuhs, W. F., Klapproth, A., and Chazallon, B.: Chemical physics of air
clathrate hydrates, in: Physics of Ice Cores Records, edited by: Hondoh, T., Hokkaido University Press, Sapporo, 373–392, 2000.
Laskar, J., Robutel, P., Joutel, F., Gastineau, M., Correia, A. C. M., and Levrard, B.: A long-term numerical solution for the insolation quantities of the Earth, Astron. Astrophys., 428, 261–285, https://doi.org/10.1051/0004-6361:20041335, 2004.
Lipenkov, V. Y.: Air bubbles and air-hydrate crystals in the Vostok ice
core, Physics of Ice Core Records, Hokkaido University Press, Hokkaido, Japan, 327–358, available at: http://hdl.handle.net/2115/32474 (last access: 7 December 2021), 2000.
Lüthi, D., Bereiter, B., Stauffer, B., Winkler, R., Schwander, J., Kindler, P., Leuenberger, M., Kipfstuhl, J., Capron, E., Landais, A.,
Fischer, H., and Stocker, T. F.: CO2 and
Miller, S. L.: Clathrate hydrates of air in Antarctic ice, Science, 165,
489–490, https://doi.org/10.1126/science.165.3892.489, 1969.
Nagashima, H. D., Nemoto, K., and Ohmura, R.: Phase equilibrium for argon
clathrate hydrate at the temperatures from 197.6 K to 274.1 K, J. Chem.
Thermodynam., 127, 86–91, https://doi.org/10.1016/j.jct.2018.07.019, 2018.
Nakano, S., Suzuki, K., Kawamura, K., Parrenin, F., and Higuchi, T.: A
sequential Bayesian approach for the estimation of the age–depth relationship of the Dome Fuji ice core, Nonlin. Processes Geophys., 23, 31–44,
https://doi.org/10.5194/npg-23-31-2016, 2016.
Narita, H., Azuma, N., Hondoh, T., Fujii, M., Kawaguchi, M., Mae, S. J., Shoji, H., Kameda, T., and Watanabe, O.: Characteristics of air bubbles and
hydrates in the Dome Fuji ice core, Antarctica, Ann. Glaciol., 29, 207–210,
https://doi.org/10.3189/172756499781821300, 1999.
Ohno, H., Lipenkov, V., and Hondoh, T.: Air bubble to clathrate hydrate
transformation in polar ice sheets: A reconsideration based on the new data
from Dome Fuji ice core, Geophys. Res. Lett., 31, L21401, https://doi.org/10.1029/2004GL021151, 2004.
Ohno, H., Lipenkov, V. Y., and Hondoh, T.: Formation of air clathrate hydrates in polar ice sheets: heterogeneous nucleation induced by micro-inclusions, J. Glaciol., 56, 917–921 https://doi.org/10.3189/002214310794457317, 2010.
Ohno, H., Iizuka, Y., and Fujita, S.: Pure rotational Raman spectroscopy
applied to N2/O2 analysis of air bubbles in polar firn, J. Glaciol., 67, 903–908, https://doi.org/10.1017/jog.2021.40, 2021.
Oyabu, I., Iizuka, Y., Uemura, R., Miyake, T., Hirabayashi, M., Motoyama, H., Sakurai, T., Suzuki, T., and Hondoh, T.: Chemical compositions of sulfate and chloride salts over the last termination reconstructed from the Dome Fuji ice core, inland Antarctica, J. Geophys. Res.-Atmos., 119, 14045–14058, https://doi.org/10.1002/2014JD022030, 2014.
Oyabu, I., Kawamura, K., Kitamura, K., Dallmayr, R., Kitamura, A., Sawada, C., Severinghaus, J. P., Beaudette, R., Orsi, A., Sugawara, S., Ishidoya, S., Dahl-Jensen, D., Goto-Azuma, K., Aoki, S., and Nakazawa, T.: New technique for high-precision, simultaneous measurements of CH4, N2O and CO2 concentrations, isotopic and elemental ratios of N2, O2 and Ar, and total air content in ice cores by wet
extraction, Atmos. Meas. Tech., 13, 6703–6731, https://doi.org/10.5194/amt-13-6703-2020, 2020.
Oyabu, I., Kawamura, K., Kitamura, K., Hirabayashi, M., Aoki, S., Morimoto,
S., and Nakazawa, T.: Dome Fuji ice core gas data (112–2001 m, 15N,
Salamatin, A. N., Lipenkov, V., Ikeda-Fukazawa, T., and Hondoh, T.: Kinetics of air-hydrate nucleation in polar ice sheets, J. Cryst. Growth, 223, 285–305, https://doi.org/10.1016/S0022-0248(00)01002-2, 2001.
Seltzer, A. M., Buizert, C., Baggenstos, D., Brook, E. J., Ahn, J., Yang,
J.-W., and Severinghaus, J. P.: Does δ18O of O2 record meridional shifts in tropical rainfall?, Clim. Past, 13, 1323–1338,
https://doi.org/10.5194/cp-13-1323-2017, 2017.
Severinghaus, J. P.: South Pole (SPICECORE) 15N, 18O,
Severinghaus, J. P. and Battle, M. O.: Fractionation of gases in polar ice
during bubble close-off: New constraints from firn air Ne, Kr and Xe observations, Earth Planet. Sc. Lett., 244, 474–500, https://doi.org/10.1016/j.epsl.2006.01.032, 2006.
Severinghaus, J. P., Beaudette, R., Headly, M. A., Taylor, K., and Brook, E.
J.: Oxygen-18 of O2 Records the Impact of Abrupt Climate Change on the Terrestrial Biosphere, Science, 324, 1431–1434, https://doi.org/10.1126/science.1169473, 2009.
Shackleton, S., Bereiter, B., Baggenstos, D., Bauska, T. K., Brook, E. J.,
Marcott, S. A., and Severinghaus, J. P.: Is the Noble Gas-Based Rate of
Ocean Warming During the Younger Dryas Overestimated?, Geophys. Res. Lett.,
46, 5928–5936, https://doi.org/10.1029/2019GL082971, 2019.
Sowers, T., Bender, M., and Raynaud, D.: Elemental and isotopic composition
of occluded O2 and N2 in polar ice, J. Geophys. Res., 94,
5137–5150, https://doi.org/10.1029/JD094iD04p05137, 1989.
Suwa, M. and Bender, M. L.: Chronology of the Vostok ice core constrained by
Suwa, M. and Bender, M. L.:
Tsutaki, S., Fujita, S., Kawamura, K., Abe-Ouchi, A., Fukui, K., Motoyama, H., Hoshina, Y., Nakazawa, F., Obase, T., Ohno, H., Oyabu, I., Saito, F., Sugiura, K., and Suzuki, T.: High-resolution subglacial topography around Dome Fuji, Antarctica, based on ground-based radar surveys conducted over 30 years, The Cryosphere Discuss. [preprint], https://doi.org/10.5194/tc-2021-266, in review, 2021.
Uchida, T., Hondoh, T., Mae, S., Shoji, H., and Azuma, N.: Optimized Storage
Condition of Deep Ice Core Samples from a View Point of Air-Hydrate Analysis, Mem. Nat. Inst. Polar Res., 49, 320–327, 1994.
Uemura, R., Motoyama, H., Masson-Delmotte, V., Jouzel, J., Kawamura, K., Goto-Azuma, K., Fujita, S., Kuramoto, T., Hirabayashi, M., Miyake, T., Ohno, H., Fujita, K., Abe-Ouchi, A., Iizuka, Y., Horikawa, S., Igarashi, M., Suzuki, K., Suzuki, T., and Fujii, Y.: Asynchrony between Antarctic temperature and CO2 associated with obliquity over the past 720,000 years, Nat. Commun. 9, 961, https://doi.org/10.1038/s41467-018-03328-3, 2018.
Watanabe, O., Jouzel, J., Johnsen, S., Parrenin, F., Shoji, H., and Yoshida,
N.: Homogeneous climate variability across East Antarctica over the past
three glacial cycles, Nature, 422, 509–512, https://doi.org/10.1038/nature01525, 2003.
Short summary
We present O2/N2 and Ar/N2 records from the Dome Fuji ice core through the bubbly ice, bubble–clathrate transition, and clathrate ice zones without gas-loss fractionation. The insolation signal is preserved through the clathrate formation. The relationship between Ar/Ν2 and Ο2/Ν2 suggests that the fractionation for the bubble–clathrate transition is mass independent, while the bubble close-off process involves a combination of mass-independent and mass-dependent fractionation for O2 and Ar.
We present O2/N2 and Ar/N2 records from the Dome Fuji ice core through the bubbly ice,...
