Articles | Volume 18, issue 11
https://doi.org/10.5194/tc-18-5153-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/tc-18-5153-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Massive mobilization of toxic elements from an intact rock glacier in the central Eastern Alps
Institute of Geological Sciences, Department of Earth Sciences, University of Bern, Baltzerstrasse 3, 3012 Bern, Switzerland
Gerhard Furrer
Institute of Biochemistry and Pollutant Dynamics (IBP), Department of Environmental Systems Science, ETH Zurich, 8092 Zurich, Switzerland
Michael Margreth
Swiss Federal Institute for Forest, Snow and Landscape Research WSL, Mountain Hydrology and Mass Movements, Zürichstrasse 111, 8903 Birmensdorf, Switzerland
David Mair
Institute of Geological Sciences, Department of Earth Sciences, University of Bern, Baltzerstrasse 3, 3012 Bern, Switzerland
Christoph Wanner
Institute of Geological Sciences, Department of Earth Sciences, University of Bern, Baltzerstrasse 3, 3012 Bern, Switzerland
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Michael Margreth, Florian Lustenberger, Dorothea Hug Peter, Fritz Schlunegger, and Massimiliano Zappa
Nat. Hazards Earth Syst. Sci. Discuss., https://doi.org/10.5194/nhess-2024-78, https://doi.org/10.5194/nhess-2024-78, 2024
Preprint under review for NHESS
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Recession models (RM) are crucial for observing the low flow behavior of a catchment. We developed two novel RM, which are designed to represent slowly draining catchment conditions. With a newly designed low flow prediction procedure we tested the prediction capability of these two models and three others from literature. One of our novel products delivered the best results, because it best represents the slowly draining catchment conditions.
Fritz Schlunegger, Edi Kissling, Dimitri Tibo Bandou, Guilhem Amin Douillet, David Mair, Urs Marti, Regina Reber, Patrick Fabian Schläfli, and Michael Alfred Schwenk
EGUsphere, https://doi.org/10.5194/egusphere-2024-683, https://doi.org/10.5194/egusphere-2024-683, 2024
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Overdeepenings are bedrock depressions filled with sediment. We combine the results of a gravity survey with drilling data to explore the morphology of such a depression beneath the city of Bern. We find that the target overdeepening comprises two basins >200 m deep. They are separated by a bedrock riegel that itself is cut by narrow canyons up to 150 m deep. We postulate that these structures formed underneath a glacier, where erosion by subglacial meltwater caused the formation of the canyons.
Ariel Henrique do Prado, David Mair, Philippos Garefalakis, Chantal Schmidt, Alexander Whittaker, Sebastien Castelltort, and Fritz Schlunegger
Hydrol. Earth Syst. Sci., 28, 1173–1190, https://doi.org/10.5194/hess-28-1173-2024, https://doi.org/10.5194/hess-28-1173-2024, 2024
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Engineering structures known as check dams are built with the intention of managing streams. The effectiveness of such structures can be expressed by quantifying the reduction of the sediment flux after their implementation. In this contribution, we estimate and compare the volumes of sediment transported in a mountain stream for engineered and non-engineered conditions. We found that without check dams the mean sediment flux would be ca. 10 times larger in comparison with the current situation.
Thomas Baer, Gerhard Furrer, Stephan Zimmermann, and Patrick Schleppi
Biogeosciences, 20, 4577–4589, https://doi.org/10.5194/bg-20-4577-2023, https://doi.org/10.5194/bg-20-4577-2023, 2023
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Nitrogen (N) deposition to forest ecosystems is a matter of concern because it affects their nutrient status and makes their soil acidic. We observed an ongoing acidification in a montane forest in central Switzerland even if the subsoil of this site contains carbonates and is thus well buffered. We experimentally added N to simulate a higher pollution, and this increased the acidification. After 25 years of study, however, we can see the first signs of recovery, also under higher N deposition.
Related subject area
Discipline: Frozen ground | Subject: Frozen ground hydrology
Short-term cooling, drying, and deceleration of an ice-rich rock glacier
Future permafrost degradation under climate change in a headwater catchment of Central Siberia: quantitative assessment with a mechanistic modelling approach
Brief communication: Mountain permafrost acts as an aquitard during an infiltration experiment monitored with electrical resistivity tomography time-lapse measurements
Towards accurate quantification of ice content in permafrost of the Central Andes – Part 1: Geophysics-based estimates from three different regions
Impact of lateral groundwater flow on hydrothermal conditions of the active layer in a high-Arctic hillslope setting
New insights into the drainage of inundated ice-wedge polygons using fundamental hydrologic principles
Soil infiltration characteristics and pore distribution under freezing–thawing conditions
Invited perspective: What lies beneath a changing Arctic?
Sub-permafrost methane seepage from open-system pingos in Svalbard
Soil moisture and hydrology projections of the permafrost region – a model intercomparison
Alexander Bast, Robert Kenner, and Marcia Phillips
The Cryosphere, 18, 3141–3158, https://doi.org/10.5194/tc-18-3141-2024, https://doi.org/10.5194/tc-18-3141-2024, 2024
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We monitor ground temperature, water pressure, and relative ice/water contents in a creeping ice-rich rock glacier in mountain permafrost to study its characteristics during a deceleration period with dry conditions and a summer heat wave. The snowpack has an important role as a provider of water and as a thermal insulator. Snow-poor winters, followed by dry summers, induce cooling and drying of the permafrost, leading to rock glacier deceleration.
Thibault Xavier, Laurent Orgogozo, Anatoly S. Prokushkin, Esteban Alonso-González, Simon Gascoin, and Oleg S. Pokrovsky
EGUsphere, https://doi.org/10.5194/egusphere-2023-3074, https://doi.org/10.5194/egusphere-2023-3074, 2024
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Permafrost (permanently frozen soil at depth) is thawing as a result of climate change. However, estimating its future degradation is particularly challenging due to the complex multi-physical processes involved. In this work, we designed and ran numerical simulations for months on a supercomputer to quantify the impact of climate change in a forested valley of Central Siberia. There, climate change could increase the thickness of the seasonally thawed soil layer in summer by up to 45 % by 2100.
Mirko Pavoni, Jacopo Boaga, Alberto Carrera, Giulia Zuecco, Luca Carturan, and Matteo Zumiani
The Cryosphere, 17, 1601–1607, https://doi.org/10.5194/tc-17-1601-2023, https://doi.org/10.5194/tc-17-1601-2023, 2023
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In the last decades, geochemical investigations at the springs of rock glaciers have been used to estimate their drainage processes, and the frozen layer is typically considered to act as an aquiclude or aquitard. In this work, we evaluated the hydraulic behavior of a mountain permafrost site by executing a geophysical monitoring experiment. Several hundred liters of salt water have been injected into the subsurface, and geoelectrical measurements have been performed to define the water flow.
Christin Hilbich, Christian Hauck, Coline Mollaret, Pablo Wainstein, and Lukas U. Arenson
The Cryosphere, 16, 1845–1872, https://doi.org/10.5194/tc-16-1845-2022, https://doi.org/10.5194/tc-16-1845-2022, 2022
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In view of water scarcity in the Andes, the significance of permafrost as a future water resource is often debated focusing on satellite-detected features such as rock glaciers. We present data from > 50 geophysical surveys in Chile and Argentina to quantify the ground ice volume stored in various permafrost landforms, showing that not only rock glacier but also non-rock-glacier permafrost contains significant ground ice volumes and is relevant when assessing the hydrological role of permafrost.
Alexandra Hamm and Andrew Frampton
The Cryosphere, 15, 4853–4871, https://doi.org/10.5194/tc-15-4853-2021, https://doi.org/10.5194/tc-15-4853-2021, 2021
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To investigate the effect of groundwater flow on the active layer on slopes in permafrost landscapes, we conducted several modeling experiments. We find that groundwater moving downslope in the subsurface causes areas uphill to be warmer than downhill. This effect is explained by differences in heat capacity, conductivity, and infiltration. Therefore, in a changing climate, higher soil moisture could have a cooling effect on the active layer and attenuate warming from higher air temperatures.
Dylan R. Harp, Vitaly Zlotnik, Charles J. Abolt, Bob Busey, Sofia T. Avendaño, Brent D. Newman, Adam L. Atchley, Elchin Jafarov, Cathy J. Wilson, and Katrina E. Bennett
The Cryosphere, 15, 4005–4029, https://doi.org/10.5194/tc-15-4005-2021, https://doi.org/10.5194/tc-15-4005-2021, 2021
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Polygon-shaped landforms present in relatively flat Arctic tundra result in complex landscape-scale water drainage. The drainage pathways and the time to transition from inundated conditions to drained have important implications for heat and carbon transport. Using fundamental hydrologic principles, we investigate the drainage pathways and timing of individual polygons, providing insights into the effects of polygon geometry and preferential flow direction on drainage pathways and timing.
Ruiqi Jiang, Tianxiao Li, Dong Liu, Qiang Fu, Renjie Hou, Qinglin Li, Song Cui, and Mo Li
The Cryosphere, 15, 2133–2146, https://doi.org/10.5194/tc-15-2133-2021, https://doi.org/10.5194/tc-15-2133-2021, 2021
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This paper outlines the results from laboratory tests of soil freezing impacts on infiltration rates, hydraulic conductivity, and soil pore distribution characteristics. The results indicated that macropores (> 5 mm) accounted for < 1 % of the pore-volume-contributed half of the flow in unfrozen conditions and that the freezing of macropores resulted in considerable decreases in hydraulic conductivity. The results should be of interest for cold region hydrology in general.
Jeffrey M. McKenzie, Barret L. Kurylyk, Michelle A. Walvoord, Victor F. Bense, Daniel Fortier, Christopher Spence, and Christophe Grenier
The Cryosphere, 15, 479–484, https://doi.org/10.5194/tc-15-479-2021, https://doi.org/10.5194/tc-15-479-2021, 2021
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Groundwater is an underappreciated catalyst of environmental change in a warming Arctic. We provide evidence of how changing groundwater systems underpin surface changes in the north, and we argue for research and inclusion of cryohydrogeology, the study of groundwater in cold regions.
Andrew J. Hodson, Aga Nowak, Mikkel T. Hornum, Kim Senger, Kelly Redeker, Hanne H. Christiansen, Søren Jessen, Peter Betlem, Steve F. Thornton, Alexandra V. Turchyn, Snorre Olaussen, and Alina Marca
The Cryosphere, 14, 3829–3842, https://doi.org/10.5194/tc-14-3829-2020, https://doi.org/10.5194/tc-14-3829-2020, 2020
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Methane stored below permafrost is an unknown quantity in the Arctic greenhouse gas budget. In coastal areas with rising sea levels, much of the methane seeps into the sea and is removed before it reaches the atmosphere. However, where land uplift outpaces rising sea levels, the former seabed freezes, pressurising methane-rich groundwater beneath, which then escapes via permafrost seepages called pingos. We describe this mechanism and the origins of the methane discharging from Svalbard pingos.
Christian G. Andresen, David M. Lawrence, Cathy J. Wilson, A. David McGuire, Charles Koven, Kevin Schaefer, Elchin Jafarov, Shushi Peng, Xiaodong Chen, Isabelle Gouttevin, Eleanor Burke, Sarah Chadburn, Duoying Ji, Guangsheng Chen, Daniel Hayes, and Wenxin Zhang
The Cryosphere, 14, 445–459, https://doi.org/10.5194/tc-14-445-2020, https://doi.org/10.5194/tc-14-445-2020, 2020
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Widely-used land models project near-surface drying of the terrestrial Arctic despite increases in the net water balance driven by climate change. Drying was generally associated with increases of active-layer depth and permafrost thaw in a warming climate. However, models lack important mechanisms such as thermokarst and soil subsidence that will change the hydrological regime and add to the large uncertainty in the future Arctic hydrological state and the associated permafrost carbon feedback.
Cited articles
ANU: Hydrodaten, Office for Nature and Environment, Canton of Grabünden, https://www.gr.ch/DE/institutionen/verwaltung/ekud/anu/aktuelles/umweltbeobachtung/hydrodaten/Seiten/Hydrodaten.aspx#/device/UMBRAIL_20/pegel_m, last access: 11 January 2024.
Ballantyne, C. K.: Periglacial Geomorphology, John Wiley & Sons Ltd, ISBN 9781405100069, 2018.
Barsch, D.: Rockglaciers, Springer Berlin Heidelberg, Berlin, Heidelberg, 331 pp., https://doi.org/10.1007/978-3-642-80093-1, 1996.
Brighenti, S., Tolotti, M., Bruno, M. C., Wharton, G., Pusch, M. T., and Bertoldi, W.: Ecosystem shifts in Alpine streams under glacier retreat and rock glacier thaw: A review, Sci. Total Environ., 675, 542–559, https://doi.org/10.1016/j.scitotenv.2019.04.221, 2019.
Brighenti, S., Engel, M., Tolotti, M., Bruno, M. C., Wharton, G., Comiti, F., Tirler, W., Cerasino, L., and Bertoldi, W.: Contrasting physical and chemical conditions of two rock glacier springs, Hydrol. Process., 35, 1–18, https://doi.org/10.1002/hyp.14159, 2021.
Calkins, D. and Dunne, T.: A salt tracing method for measuring channel velocities in small mountain streams, J. Hydrol., 11, 379–392, https://doi.org/10.1016/0022-1694(70)90003-X, 1970.
Colombo, N., Gruber, S., Martin, M., Malandrino, M., Magnani, A., Godone, D., Freppaz, M., Fratianni, S., and Salerno, F.: Rainfall as primary driver of discharge and solute export from rock glaciers: The Col d'Olen Rock Glacier in the NW Italian Alps, Sci. Total Environ., 639, 316–330, https://doi.org/10.1016/j.scitotenv.2018.05.098, 2018.
Day, T. J.: Observed mixing lengths in mountain streams, J. Hydrol., 35, 125–136, https://doi.org/10.1016/0022-1694(77)90081-6, 1977.
Del Siro, C., Scapozza, C., Perga, M. E., and Lambiel, C.: Investigating the origin of solutes in rock glacier springs in the Swiss Alps: A conceptual model, Front. Earth Sci., 11, 1–20, https://doi.org/10.3389/feart.2023.1056305, 2023.
Diem, D. and Stumm, W.: Is dissolved Mn2+ being oxidized by O2 in absence of Mn-bacteria or surface catalysts?, Geochim. Cosmochim. Ac., 48, 1571–1573, https://doi.org/10.1016/0016-7037(84)90413-7, 1984.
Dold, B., Aguilera, A., Cisternas, M. E., Bucchi, F., and Amils, R.: Sources for Iron Cycling in the Southern Ocean, Environ. Sci. Technol., 47, 6129–6136, 2013.
Dos Santos Vergilio, C., Lacerda, D., da Silva Souza, T., de Oliveira, B. C. V., Fioresi, V. S., de Souza, V. V., da Rocha Rodrigues, G., de Araujo Moreira Barbosa, M. K., Sartori, E., Rangel, T. P., de Almeida, D. Q. R., de Almeida, M. G., Thompson, F., and de Rezende, C. E.: Immediate and long-term impacts of one of the worst mining tailing dam failure worldwide (Bento Rodrigues, Minas Gerais, Brazil), Sci. Total Environ., 756, 143697, https://doi.org/10.1016/j.scitotenv.2020.143697, 2021.
ECV inventory: Essential Climate Variable (ECV), Climate Monitoring from Space, https://climatemonitoring.info/ecvinventory/, last access: 8 November 2024.
Exley, C.: The toxicity of aluminium in humans, Morphologie, 100, 51–55, https://doi.org/10.1016/j.morpho.2015.12.003, 2016.
Fortner, S. K., Mark, B. G., McKenzie, J. M., Bury, J., Trierweiler, A., Baraer, M., Burns, P. J., and Munk, L. A.: Elevated stream trace and minor element concentrations in the foreland of receding tropical glaciers, Appl. Geochem., 26, 1792–1801, https://doi.org/10.1016/j.apgeochem.2011.06.003, 2011.
Giardino, J. R. and Vitek, J. D.: The significance of rock glaciers in the glacial-periglacial landscape continuum, J. Quaternary Sci., 3, 97–103, https://doi.org/10.1002/jqs.3390030111, 1988.
Giardino, J. R., Vitek, J. D., and DeMorett, J. L.: A Model of Water Movement in Rock Glaciers and Associated Water Characteristics, in: Periglacial Geomorphology, Binghamton Geomorphology Symposium 22, edited by: Abrahams, A. D. and Dixon, J. C., Taylor & Francis, 26 pp., https://doi.org/10.4324/9781003028901, 1992.
Haeberli, W.: Creep of mountain permafrost: internal structure and flow of alpine rock glaciers, Mitteilungen der Versuchsanstalt fur Wasserbau, Hydrol. und Glaziologie an der Eidgenoss. Tech. Hochschule Zurich, 1985.
Harrington, J. S., Mozil, A., Hayashi, M., and Bentley, L. R.: Groundwater flow and storage processes in an inactive rock glacier, Hydrol. Process., 32, 3070–3088, https://doi.org/10.1002/hyp.13248, 2018.
Hayashi, M.: Alpine Hydrogeology: The Critical Role of Groundwater in Sourcing the Headwaters of the World, Groundwater, 58, 498–510, https://doi.org/10.1111/gwat.12965, 2020.
Humlum, O.: Active layer thermal regime at three rock glaciers in Greenland, Permafrost Periglac., 8, 383–408, https://doi.org/10.1002/(SICI)1099-1530(199710/12)8:4<383::AID-PPP265>3.0.CO;2-V, 1997.
Ikeda, A., Matsuoka, N., and Kääb, A.: Fast deformation of perennially frozen debris in a warm rock glacier in the Swiss Alps: An effect of liquid water, J. Geophys. Res.-Earth, 113, 1–12, https://doi.org/10.1029/2007JF000859, 2008.
Ilyashuk, B. P., Ilyashuk, E. A., Psenner, R., Tessadri, R., and Koinig, K. A.: Rock glacier outflows may adversely affect lakes: Lessons from the past and present of two neighboring water bodies in a crystalline-rock watershed, Environ. Sci. Technol., 48, 6192–6200, https://doi.org/10.1021/es500180c, 2014.
Ilyashuk, B. P., Ilyashuk, E. A., Psenner, R., Tessadri, R., and Koinig, K. A.: Rock glaciers in crystalline catchments: Hidden permafrost-related threats to alpine headwater lakes, Global Change Biol., 24, 1548–1562, https://doi.org/10.1111/gcb.13985, 2018.
Jones, D. B., Harrison, S., Anderson, K., and Betts, R. A.: Mountain rock glaciers contain globally significant water stores, Sci. Rep.-UK, 8, 1–10, https://doi.org/10.1038/s41598-018-21244-w, 2018.
Jones, D. B., Harrison, S., Anderson, K., and Whalley, W. B.: Rock glaciers and mountain hydrology: A review, Earth-Sci. Rev., 193, 66–90, https://doi.org/10.1016/j.earscirev.2019.04.001, 2019.
Kenner, R., Noetzli, J., Hoelzle, M., Raetzo, H., and Phillips, M.: Distinguishing ice-rich and ice-poor permafrost to map ground temperatures and ground ice occurrence in the Swiss Alps, The Cryosphere, 13, 1925–1941, https://doi.org/10.5194/tc-13-1925-2019, 2019.
Krainer, K. and Mostler, W.: Hydrology of Active Rock Glaciers: Examples from the Austrian Alps, Arct. Antarct. Alp. Res., 34, 142–149, https://doi.org/10.1080/15230430.2002.12003478, 2002.
Krainer, K. and Mostler, W.: Flow velocities of active rock glaciers in the Austrian Alps, Geogr. Ann. A, 88, 267–280, https://doi.org/10.1111/j.0435-3676.2006.00300.x, 2006.
Krainer, K., Mostler, W., and Spötl, C.: Discharge from active rock glaciers, Austrian Alps: A stable isotope approach, Austrian J. Earth Sci., 100, 102–112, 2007.
Krainer, K., Bressan, D., Dietre, B., Haas, J. N., Hajdas, I., Lang, K., Mair, V., Nickus, U., Reidl, D., Thies, H., and Tonidandel, D.: A 10 300 year-old permafrost core from the active rock glacier Lazaun, southern Ötztal Alps (South Tyrol, northern Italy), Quaternary Res., 83, 324–335, https://doi.org/10.1016/j.yqres.2014.12.005, 2015.
Leibundgut, C., Maloszewski, P., and Külls, C.: Tracers in Hydrology, John Wiley & Sons, Ltd, 415 pp., https://doi.org/10.1002/9780470747148, 2009.
Li, M., Yang, Y., Peng, Z., and Liu, G.: Assessment of rock glaciers and their water storage in Guokalariju, Tibetan Plateau, The Cryosphere, 18, 1–16, https://doi.org/10.5194/tc-18-1-2024, 2024.
MeteoSwiss: Federal Office for Meteorology and Climatology, MeteoSwiss, https://www.meteoschweiz.admin.ch/service-und-
publikationen/applikationen/messwerte-und-messnetze.html#
lang=de&swisstopoApiKey=cpZJOL3HuO5yENksi97q¶m
=messwerte-niederschlag-10min&station=SMM&chart=month, last access: 11 January 2024.
Moradi, H., Furrer, G., Michael, M., David, M., and Wanner, C.: Massive mobilization of toxic elements from an intact rock glacier in the Central Eastern Alps: insights on ice melt dynamics, Zenodo [data set], https://doi.org/10.5281/zenodo.10558549, 2024.
Muniz, I. P.: Freshwater acidification: its effects on species and communities of freshwater microbes, plants and animals, Proc. R. Soc. Ser. B-Bio., 97, 227–254, 1990.
Munroe, J. S. and Handwerger, A. L.: Contribution of rock glacier discharge to late summer and fall streamflow in the Uinta Mountains, Utah, USA, Hydrol. Earth Syst. Sci., 27, 543–557, https://doi.org/10.5194/hess-27-543-2023, 2023.
Nickus, U., Thies, H., Krainer, K., Lang, K., Mair, V., and Tonidandel, D.: A multi-millennial record of rock glacier ice chemistry (Lazaun, Italy), Front. Earth Sci., 11, 1141379, https://doi.org/10.3389/feart.2023.1141379, 2023.
Noetzli, J. and Pellet, C. (Eds.): Swiss Permafrost Bulletin 2022, PERMOS, 23 pp., https://www.permos.ch/publications (last access: 11 January 2024), 2023.
O'Donnell, J. A., Carey, M. P., Koch, J. C., Baughman, C., Hill, K., Zimmerman, C. E., Sullivan, P. F., Dial, R., Lyons, T., Cooper, D. J., and Poulin, B. A.: Metal mobilization from thawing permafrost to aquatic ecosystems is driving rusting of Arctic streams, Commun. Earth Environ., 5, 268, https://doi.org/10.1038/s43247-024-01446-z, 2024.
Parbhakar-Fox, A. and Lottermoser, B.: Principles of Sulfide Oxidation and Acid Rock Drainage BT – Environmental Indicators in Metal Mining, edited by: Lottermoser, B., Springer International Publishing, Cham, 15–34, https://doi.org/10.1007/978-3-319-42731-7_2, 2017.
Perruchoud, E. and Delaloye, R.: Short-Term Changes in Surface Velocities on the Becs-de-Bosson Rock Glacier (Western Swiss Alps), Grazer Schriften der Geogr. und Raumforsch., 43, 131–136, 2007.
Rist, A. and Phillips, M.: First results of investigations on hydrothermal processes within the active layer above alpine permafrost in steep terrain, Norsk Geogr. Tidsskr., 59, 177–183, https://doi.org/10.1080/00291950510020574, 2005.
Sannino, C., Qi, W., Rüthi, J., Stierli, B., and Frey, B.: Distinct taxonomic and functional profiles of high Arctic and alpine permafrost-affected soil microbiomes, Environ. Microbiome, 18, 1–22, https://doi.org/10.1186/s40793-023-00509-6, 2023.
Schmid, S. M., Fügenschuh, B., Kissling, E., and Schuster, R.: Tectonic map and overall architecture of the Alpine orogen, Eclogae Geol. Helv., 97, 93–117, https://doi.org/10.1007/s00015-004-1113-x, 2004.
Schmid, S. V.: Geologie des Umbrailgebiets, E–Periodica, 66, 101–210, https://doi.org/10.5169/seals-164185, 1973.
Shaw, C. A. and Tomljenovic, L.: Aluminum in the central nervous system (CNS): toxicity in humans and animals, vaccine adjuvants, and autoimmunity, Immunol. Res., 56, 304–316, https://doi.org/10.1007/s12026-013-8403-1, 2013.
SLF: Beschreibung automatische Stationen, Institute for Snow and Avalanche Research, https://www.slf.ch/de/lawinenbulletin-und-schneesituation/messwerte/beschreibung-automatische-stationen/, last access: 11 January 2024.
Steingruber, S. M., Bernasconi, S. M., and Valenti, G.: Climate Change-Induced Changes in the Chemistry of a High-Altitude Mountain Lake in the Central Alps, Aquat. Geochem., 27, 105–126, https://doi.org/10.1007/s10498-020-09388-6, 2021.
Swisstopo: Explanatory booklet of the Geological Atlas of Switzerland 1:25,000, Federal Office of Topography, https://shop.swisstopo.admin.ch/en/maps/geological-maps/explanatory-booklet-geological-atlas-switzerland-25000, last access: 11 January 2024a.
Swisstopo: GeoCover, Federal Office of Topography, https://www.swisstopo.admin.ch/en/geodata/geology/
maps/geocover.html, last access: 11 January 2024b.
Tenthorey, G.: Perennial névés and the hydrology of rock glaciers, Permafrost Periglac., 3, 247–252, https://doi.org/10.1002/ppp.3430030313, 1992.
Thies, H., Nickus, U., Mair, V., Tessadri, R., Tait, D., Thaler, B., and Psenner, R.: Unexpected response of high alpine lake waters to climate warming, Environ. Sci. Technol., 41, 7424–7429, https://doi.org/10.1021/es0708060, 2007.
Thies, H., Nickus, U., Tolotti, M., Tessadri, R., and Krainer, K.: Evidence of rock glacier melt impacts on water chemistry and diatoms in high mountain streams, Cold Reg. Sci. Technol., 96, 77–85, https://doi.org/10.1016/j.coldregions.2013.06.006, 2013.
Thies, H., Nickus, U., Tessadri, R., Tropper, P., and Krainer, K.: Peculiar arsenic, copper, nickel, uranium, and yttrium-rich stone coatings in a high mountain stream in the Austrian alps, Austrian J. Earth Sci., 110, 7, https://doi.org/10.17738/ajes.2017.0012, 2017.
Todd, A. S., Manning, A. H., Verplanck, P. L., Crouch, C., McKnight, D. M., and Dunham, R.: Climate-change-driven deterioration of water quality in a mineralized watershed, Environ. Sci. Technol., 46, 9324–9332, https://doi.org/10.1021/es3020056, 2012.
Tolotti, M., Cerasino, L., Donati, C., Pindo, M., Rogora, M., Seppi, R., and Albanese, D.: Alpine headwaters emerging from glaciers and rock glaciers host different bacterial communities: Ecological implications for the future, Sci. Total Environ., 717, 137101, https://doi.org/10.1016/j.scitotenv.2020.137101, 2020.
Tolotti, M., Brighenti, S., Bruno, M. C., Cerasino, L., Pindo, M., Tirler, W., and Albanese, D.: Ecological “Windows of opportunity” influence biofilm prokaryotic diversity differently in glacial and non-glacial Alpine streams, Sci. Total Environ., 944, 173826, https://doi.org/10.1016/j.scitotenv.2024.173826, 2024.
Wagner, T., Kainz, S., Wedenig, M., Pleschberger, R., Krainer, K., Kellerer-Pirklbauer, A., Ribis, M., Hergarten, S., and Winkler, G.: Wasserwirtschaftliche Aspekte von Blockgletschern in Kristallingebieten der Ostalpen, RGHeavyMetal, BBK No. 101093, The University of Graz, 2019.
Wagner, T., Brodacz, A., Krainer, K., and Winkler, G.: Active rock glaciers as shallow groundwater reservoirs, Austrian Alps, Grundwasser, 25, 215–230, https://doi.org/10.1007/s00767-020-00455-x, 2020.
Wagner, T., Kainz, S., Krainer, K., and Winkler, G.: Storage-discharge characteristics of an active rock glacier catchment in the Innere Ölgrube, Austrian Alps, Hydrol. Process., 35, 1–16, https://doi.org/10.1002/hyp.14210, 2021a.
Wagner, T., Seelig, S., Helfricht, K., Fischer, A., Avian, M., Krainer, K., and Winkler, G.: Assessment of liquid and solid water storage in rock glaciers versus glacier ice in the Austrian Alps, Sci. Total Environ., 800, 149593, https://doi.org/10.1016/j.scitotenv.2021.149593, 2021b.
Wanner, C., Pöthig, R., Carrero, S., Fernandez-Martinez, A., Jäger, C., and Furrer, G.: Natural occurrence of nanocrystalline Al-hydroxysulfates: Insights on formation, Al solubility control and As retention, Geochim. Cosmochim. Ac., 238, 252–269, https://doi.org/10.1016/j.gca.2018.06.031, 2018.
Wanner, C., Moradi, H., Ingold, P., Cardenas Bocanegra, M. A., Mercurio, R., and Furrer, G.: Rock glaciers in the Central Eastern Alps – How permafrost degradation can cause acid rock drainage, mobilization of toxic elements and formation of basaluminite, Global Planet. Change, 227, 104180, https://doi.org/10.1016/j.gloplacha.2023.104180, 2023.
Williams, M. W., Knauf, M., Caine, N., Liu, F., and Verplanck, P. L.: Geochemistry and source waters of rock glacier outflow, Colorado Front Range, Permafrost Periglac., 17, 13–33, https://doi.org/10.1002/ppp.535, 2006.
Williamson, M. A. and Rimstidt, J. D.: The kinetics and electrochemical rate-determining step of aqueous pyrite oxidation, Geochim. Cosmochim. Ac., 58, 5443–5454, https://doi.org/10.1016/0016-7037(94)90241-0, 1994.
Zarroca, M., Roqué, C., Linares, R., Salminci, J. G., and Gutiérrez, F.: Natural acid rock drainage in alpine catchments: A side effect of climate warming, Sci. Total Environ., 778, 146070, https://doi.org/10.1016/j.scitotenv.2021.146070, 2021.
Short summary
Detailed monitoring of a rock glacier spring in the Eastern Alps showed that more than 1 tonne of toxic solutes, such as aluminum, nickel, and manganese, is mobilized each year from a small permafrost area. The strong mobilization is caused by rock weathering and long-term accumulation of toxic solutes in permafrost ice. Today, climate-change-induced permafrost degradation leads to a quick and focused export in summer. This forms an unexpected, novel hazard for alpine and high-latitude areas.
Detailed monitoring of a rock glacier spring in the Eastern Alps showed that more than 1 tonne...