Articles | Volume 18, issue 3
https://doi.org/10.5194/tc-18-1053-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/tc-18-1053-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Grain growth of ice doped with soluble impurities
Qinyu Wang
Key Laboratory of Earth and Planetary Physics, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 101408, China
Sheng Fan
Department of Geology, University of Otago, Ōtepoti / Dunedin, Aotearoa / New Zealand
Department of Earth Sciences, University of Cambridge, Cambridge, UK
RSC, Te Whanganui-a-Tara / Wellington, Aotearoa / New Zealand
Key Laboratory of Earth and Planetary Physics, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 101408, China
Related authors
Qinyu Wang, Sheng Fan, Daniel H. Richards, Rachel Worthington, David J. Prior, and Chao Qi
The Cryosphere, 19, 827–848, https://doi.org/10.5194/tc-19-827-2025, https://doi.org/10.5194/tc-19-827-2025, 2025
Short summary
Short summary
Ice often exhibits a single-cluster fabric when deformed to high strains in glaciers and ice sheets. Using the equal-channel angular pressing technique, we achieved high shear strains in laboratory experiments and examined the fabrics. We investigated the evolutions of fabric and recrystallization mechanisms with strain. The results suggest that rotation recrystallization dominates fabric development when ice is deformed to high strains, explaining the fabrics found in natural ice.
Qinyu Wang, Sheng Fan, Daniel H. Richards, Rachel Worthington, David J. Prior, and Chao Qi
The Cryosphere, 19, 827–848, https://doi.org/10.5194/tc-19-827-2025, https://doi.org/10.5194/tc-19-827-2025, 2025
Short summary
Short summary
Ice often exhibits a single-cluster fabric when deformed to high strains in glaciers and ice sheets. Using the equal-channel angular pressing technique, we achieved high shear strains in laboratory experiments and examined the fabrics. We investigated the evolutions of fabric and recrystallization mechanisms with strain. The results suggest that rotation recrystallization dominates fabric development when ice is deformed to high strains, explaining the fabrics found in natural ice.
Sheng Fan, David J. Prior, Brent Pooley, Hamish Bowman, Lucy Davidson, David Wallis, Sandra Piazolo, Chao Qi, David L. Goldsby, and Travis F. Hager
The Cryosphere, 17, 3443–3459, https://doi.org/10.5194/tc-17-3443-2023, https://doi.org/10.5194/tc-17-3443-2023, 2023
Short summary
Short summary
The microstructure of ice controls the behaviour of polar ice flow. Grain growth can modify the microstructure of ice; however, its processes and kinetics are poorly understood. We conduct grain-growth experiments on synthetic and natural ice samples at 0 °C. Microstructural data show synthetic ice grows continuously with time. In contrast, natural ice does not grow within a month. The inhibition of grain growth in natural ice is largely contributed by bubble pinning at ice grain boundaries.
Franz Lutz, David J. Prior, Holly Still, M. Hamish Bowman, Bia Boucinhas, Lisa Craw, Sheng Fan, Daeyeong Kim, Robert Mulvaney, Rilee E. Thomas, and Christina L. Hulbe
The Cryosphere, 16, 3313–3329, https://doi.org/10.5194/tc-16-3313-2022, https://doi.org/10.5194/tc-16-3313-2022, 2022
Short summary
Short summary
Ice crystal alignment in the sheared margins of fast-flowing polar ice is important as it may control the ice sheet flow rate, from land to the ocean. Sampling shear margins is difficult because of logistical and safety considerations. We show that crystal alignments in a glacier shear margin in Antarctica can be measured using sound waves. Results from a seismic experiment on the 50 m scale and from ultrasonic experiments on the decimetre scale match ice crystal measurements from an ice core.
Cited articles
Arena, L., Nasello, O., and Levi, L.: Effect of bubbles on grain growth in ice, J. Phys. Chem. B, 101, 6109–6112, https://doi.org/10.1021/jp9632394, 1997. a
Atkinson, H.: Overview no. 65: Theories of normal grain growth in pure single phase systems, Acta Metall., 36, 469–491, https://doi.org/10.1016/0001-6160(88)90079-X, 1988. a
Barr, A. C. and McKinnon, W. B.: Convection in ice I shells and mantles with self-consistent grain size, J. Geophys. Res.-Planets, 112, E02012, https://doi.org/10.1029/2006JE002781, 2007. a
Baumgartner, M.: Analysis of salt-bearing aqueous solutions in synthetic fluid inclusions by microthermometry and cryogenic Raman spectroscopy, Ph.D. thesis, University of Leoben, 2009. a
Behn, M. D., Goldsby, D. L., and Hirth, G.: The role of grain size evolution in the rheology of ice: implications for reconciling laboratory creep data and the Glen flow law, The Cryosphere, 15, 4589–4605, https://doi.org/10.5194/tc-15-4589-2021, 2021. a, b, c
Blackford, J. R.: Sintering and microstructure of ice: a review, J. Phys. D, 40, R355, https://doi.org/10.1088/0022-3727/40/21/R02, 2007. a
Bons, P. D., Jessell, M. W., Evans, L., Barr, T., and Stüwe, K.: Modeling of anisotropic grain growth in minerals, Memoirs-Geol. Soc. Am., 193, 39–50, https://doi.org/10.1130/0-8137-1193-2.39, 2001. a
Bons, P. D., Kleiner, T., Llorens, M.-G., Prior, D. J., Sachau, T., Weikusat, I., and Jansen, D.: Greenland Ice Sheet: Higher nonlinearity of ice flow significantly reduces estimated basal motion, Geophys. Res. Lett., 45, 6542–6548, 2018. a
Brady, J. B.: Magma in a beaker: Analog experiments with water and various salts or sugar for teaching igneous petrology, Can. Mineral., 47, 457–471, 2009. a
Breton, D. J., Baker, I., and Cole, D. M.: Microstructural evolution of polycrystalline ice during confined creep testing, Cold Reg. Sci. Technol., 127, 25–36, 2016. a
Brook, R. J.: Controlled grain growth, in: Ceramic Fabrication Processes: Treatise on Materials Science and Technology, edited by: Wang, F. F. Y., Academic Press, New York, Vol. 9, 331–364, https://doi.org/10.1016/B978-0-12-341809-8.50024-3, 1976. a
Burke, J. E. and Turnbull, D.: Recrystallization and grain growth, Prog. Metal Phys., 3, 220–292, https://doi.org/10.1016/0502-8205(52)90009-9, 1952. a, b
Conde, M. M., Rovere, M., and Gallo, P.: Spontaneous NaCl-doped ice at seawater conditions: focus on the mechanisms of ion inclusion, Phys. Chem. Chem. Phys., 19, 9566–9574, 2017. a
Cuffey, K., Conway, H., Gades, A., Hallet, B., Raymond, C., and Whitlow, S.: Deformation properties of subfreezing glacier ice: role of crystal size, chemical impurities, and rock particles inferred from in situ measurements, J. Geophys. Res.-Sol. Ea., 105, 27895–27915, 2000. a
Durand, G., Weiss, J., Lipenkov, V., Barnola, J., Krinner, G., Parrenin,F., Delmonte, B., Ritz, C., Duval, P., Röthlisberger, R., and Bigler, M.: Effect of impurities on grain growth in cold ice sheets, J. Geophys. Res.-Earth, 111, F01015, https://doi.org/10.1029/2005JF000320, 2006. a, b
Duval, P.: Grain growth and mechanical behaviour of polar ice, Ann. Glaciol., 6, 79–82, 1985. a
Fan, S., Prior, D. J., Pooley, B., Bowman, H., Davidson, L., Wallis, D., Piazolo, S., Qi, C., Goldsby, D. L., and Hager, T. F.: Grain growth of natural and synthetic ice at 0 °C, The Cryosphere, 17, 3443–3459, https://doi.org/10.5194/tc-17-3443-2023, 2023. a, b, c
Farver, J. R., Yund, R. A., and Rubie, D. C.: Magnesium grain boundary diffusion in forsterite aggregates at 1000–1300°C and 0.1 MPa to 10 GPa, J. Geophys. Res.-Sol. Ea., 99, 19809–19819, 1994. a
Goldsby, D. L. and Kohlstedt, D. L.: Superplastic deformation of ice: Experimental observations, J. Geophys. Res.-Sol. Ea., 106, 11017–11030, 2001. a
Gow, A. J.: On the rates of growth of grains and crystals in South Polar firn, J. Glaciol., 8, 241–252, 1969. a
Gross, G. W., Wong, P. M., and Humes, K.: Concentration dependent solute redistribution at the ice–water phase boundary. III. Spontaneous convection. Chloride solutions, J. Chem. Phys., 67, 5264–5274, 1977. a
Hammonds, K. and Baker, I.: The effects of H2SO4 on the mechanical behavior and microstructural evolution of polycrystalline ice, J. Geophys. Res.-Earth, 123, 535–556, 2018. a
Hansen, L. N., Zimmerman, M. E., and Kohlstedt, D. L.: The influence of microstructure on deformation of olivine in the grain-boundary sliding regime, J. Geophys. Res.-Sol. Ea., 117, B09201, https://doi.org/10.1029/2012JB009305, 2012. a
Hartig, S. M.: Basic image analysis and manipulation in ImageJ, Current Protocols in Molecular Biology, 102, 14–15, 2013. a
Iliescu, D. and Baker, I.: Effects of impurities and their redistribution during recrystallization of ice crystals, J. Glaciol., 54, 362–370, 2008. a
Kipfstuhl, S., Hamann, I., Lambrecht, A., Freitag, J., Faria, S. H., Grigoriev, D., and Azuma, N.: Microstructure mapping: a new method for imaging deformation-induced microstructural features of ice on the grain scale, J. Glaciol., 52, 398–406, 2006. a
Kipfstuhl, S., Faria, S. H., Azuma, N., Freitag, J., Hamann, I., Kaufmann, P., Miller, H., Weiler, K., and Wilhelms, F.: Evidence of dynamic recrystallization in polar firn, J. Geophys. Res.-Sol. Ea., 114, B05204, https://doi.org/10.1029/2008JB005583, 2009. a
Koizumi, S., Hiraga, T., Tachibana, C., Tasaka, M., Miyazaki, T., Kobayashi, T., Takamasa, A., Ohashi, N., and Sano, S.: Synthesis of highly dense and fine-grained aggregates of mantle composites by vacuum sintering of nano-sized mineral powders, Phys. Chem. Miner., 37, 505–518, 2010. a
Krawczynska, A. T., Gierlotka, S., Suchecki, P., Setman, D., Adamczyk-Cieslak, B., Lewandowska, M., and Zehetbauer, M.: Recrystallization and grain growth of a nano/ultrafine structured austenitic stainless steel during annealing under high hydrostatic pressure, J. Mater. Sci., 53, 11823–11836, 2018. a
Langway, C., Shoji, H., and Azuma, N.: Crystal size and orientation patterns in the Wisconsin-age ice from Dye 3, Greenland, Ann. Glaciol., 10, 109–115, 1988. a
McCarthy, C., Cooper, R. F., Goldsby, D. L., Durham, W. B., and Kirby, S. H.: Transient and steady state creep response of ice I and magnesium sulfate hydrate eutectic aggregates, J. Geophys. Res.-Planets, 116, E04007, https://doi.org/10.1029/2010JE003689, 2011. a
McKinnon, W. B.: Convective instability in Europa's floating ice shell, Geophys. Res. Lett., 26, 951–954, 1999. a
Meyers, C. D.,: Experimental Deformation of Olivine Aggregates, Ph. D. thesis, University of Minnesota, 2023. a
Najafkhani, F., Mirzadeh, H., and Zamani, M.: Effect of intercritical annealing conditions on grain growth kinetics of dual phase steel, Met. Mater. Int., 25, 1039–1046, 2019. a
Nasello, O., Di Prinzio, C., and Guzmán, P.: Grain boundary properties of ice doped with small concentrations of potassium chloride (KCl), J. Phys., 19, 246218, https://doi.org/10.1088/0953-8984/19/24/246218, 2007. a
Noguchi, N., Kubo, T., Durham, W. B., Kagi, H., and Shimizu, I.: Self-diffusion of polycrystalline ice Ih under confining pressure: Hydrogen isotope analysis using 2-D Raman imaging, Physi. Earth Planet. Int., 257, 40–47, 2016. a
Obbard, R. and Baker, I.: The microstructure of meteoric ice from Vostok, Antarctica, J. Glaciol., 53, 41–62, 2007. a
Ohno, H., Igarashi, M., and Hondoh, T.: Salt inclusions in polar ice core: Location and chemical form of water-soluble impurities, Earth Planet. Sc. Lett., 232, 171–178, 2005. a
Ohno, H., Igarashi, M., and Hondoh, T.: Characteristics of salt inclusions in polar ice from Dome Fuji, East Antarctica, Geophys. Res. Lett., 33, L08501, https://doi.org/10.1029/2006GL025774, 2006. a
Ohuchi, T. and Nakamura, M.: Grain growth in the forsterite–diopside system, Phys. Earth Planet. Int., 160, 1–21, 2007. a
Pachitariu, M. and Stringer, C.: Cellpose 2.0: how to train your own model, Nature Meth., 19, 1634–1641, 2022. a
Paterson, W.: Why ice-age ice is sometimes “soft”, Cold Reg. Sci. Technol., 20, 75–98, 1991. a
Petrenko, V. F. and Whitworth, R. W.: Physics of ice, OUP Oxford, ISBN 9780198518952, 1999. a
Qi, C. and Goldsby, D. L.: An experimental investigation of the effect of grain size on “dislocation creep” of ice, J. Geophys. Res.-Sol. Ea., 126, e2021JB021824, https://doi.org/10.1029/2021JB021824, 2021. a
Rothery, D. A.: Satellites of the Outer Planets: Worlds in their own right, Oxford University Press, ISBN 9780195125559, 1999. a
Ruiz, J.: Equilibrium convection on a tidally heated and stressed icy shell of Europa for a composite water ice rheology, Earth Moon Planets, 107, 157–167, 2010. a
Sakurai, T., Ohno, H., Horikawa, S., Iizuka, Y., Uchida, T., Hirakawa, K., and Hondoh, T.: The chemical forms of water-soluble microparticles preserved in the Antarctic ice sheet during Termination I, J. Glaciol., 57, 1027–1032, 2011. a
Shewmon, P. G.: The movement of small inclusions in solids by a temperature gradient, AIME Trans., 230, 1134–1137, 1964. a
Stringer, C., Wang, T., Michaelos, M., and Pachitariu, M.: Cellpose: a generalist algorithm for cellular segmentation, Nature Meth., 18, 100–106, 2021. a
Wang, Q., Fan, S., and Qi, C.: Data of “Grain growth of ice doped with soluble impurities”, figshare [data set], https://doi.org/10.6084/m9.figshare.24212103.v2, 2023. a
Weiss, J., Vidot, J., Gay, M., Arnaud, L., Duval, P., and Petit, J. R.: Dome Concordia ice microstructure: impurities effect on grain growth, Ann. Glaciol., 35, 552–558, 2002. a
Wood, G. and Walton, A.: Homogeneous nucleation kinetics of ice from water, J. Appl. Phys., 41, 3027–3036, 1970. a
Short summary
We explored how the grain size of polycrystalline ice is affected by soluble impurities by conducting experiments on ice-containing salts. Results showed that above/below the eutectic point, impurities enhance/hinder grain growth, due to production of melts/precipitation of salt hydrates. Our findings offer insights into the dynamics of natural ice masses.
We explored how the grain size of polycrystalline ice is affected by soluble impurities by...