Articles | Volume 19, issue 11
https://doi.org/10.5194/tc-19-5693-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/tc-19-5693-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
14 Nov 2025
Research article |
| 14 Nov 2025
| 14 Nov 2025
Doomed descent? How fast sulphate signals diffuse in the EPICA Dome C ice column
School of Geography and Planning, University of Sheffield, Sheffield, UK
Rachael H. Rhodes
Department of Earth Sciences, University of Cambridge, Cambridge, UK
Tyler J. Fudge
Department of Earth and Space Sciences, University of Washington, Seattle, WA, USA
Eric W. Wolff
Department of Earth Sciences, University of Cambridge, Cambridge, UK
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The Cryosphere, 19, 4611–4655, https://doi.org/10.5194/tc-19-4611-2025, https://doi.org/10.5194/tc-19-4611-2025, 2025
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The ice sheets covering Antarctica have built up over millenia through successive snowfall events which become buried and preserved as internal surfaces of equal age detectable with ice-penetrating radar. This paper describes an international initiative working together on these archival data to build a comprehensive 3-D picture of how old the ice is everywhere across Antarctica and how this is being used to reconstruct past and to predict future ice and climate behaviour.
Felix S. L. Ng
The Cryosphere, 18, 4645–4669, https://doi.org/10.5194/tc-18-4645-2024, https://doi.org/10.5194/tc-18-4645-2024, 2024
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Liquid veins and grain boundaries in ice can accelerate the decay of climate signals in δ18O and δD by short-circuiting the slow isotopic diffusion in crystal grains. This theory for "excess diffusion" has not been confirmed experimentally. We show that, if the mechanism occurs, then distinct isotopic patterns must form near grain junctions, offering a testable prediction of the theory. We calculate the patterns and describe an experimental scheme for testing ice-core samples for the mechanism.
Felix S. L. Ng
The Cryosphere, 17, 3063–3082, https://doi.org/10.5194/tc-17-3063-2023, https://doi.org/10.5194/tc-17-3063-2023, 2023
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The stable isotopes of oxygen and hydrogen in ice cores are routinely analysed for the climate signals which they carry. It has long been known that the system of water veins in ice facilitates isotopic diffusion. Here, mathematical modelling shows that water flow in the veins strongly accelerates the diffusion and the decay of climate signals. The process hampers methods using the variations in signal decay with depth to reconstruct past climatic temperature.
Felix S. L. Ng
The Cryosphere, 15, 1787–1810, https://doi.org/10.5194/tc-15-1787-2021, https://doi.org/10.5194/tc-15-1787-2021, 2021
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Current theory predicts climate signals in the vein chemistry of ice cores to migrate, hampering their dating. I show that the Gibbs–Thomson effect, which has been overlooked, causes fast diffusion that prevents signals from surviving into deep ice. Hence the deep climatic peaks in Antarctic and Greenlandic ice must be due to impurities in the ice matrix (outside veins) and safe from migration. These findings reset our understanding of postdepositional changes of ice-core climate signals.
Pascal Bohleber, Nicolas Stoll, Piers Larkman, Rachael H. Rhodes, and David Clases
The Cryosphere, 19, 5485–5498, https://doi.org/10.5194/tc-19-5485-2025, https://doi.org/10.5194/tc-19-5485-2025, 2025
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To avoid misinterpretation of impurity signals in ice cores, post-depositional changes need to be identified. Peak broadening with depth observed especially for S was previously related to diffusion in ice veins, but the exact physical mechanisms remain unclear. Our two-dimensional impurity maps by laser ablation inductively coupled plasma mass spectrometry were extended for the first time to S and Cl and support a view on diffusion not only through veins but also along grain boundaries.
Robert G. Bingham, Julien A. Bodart, Marie G. P. Cavitte, Ailsa Chung, Rebecca J. Sanderson, Johannes C. R. Sutter, Olaf Eisen, Nanna B. Karlsson, Joseph A. MacGregor, Neil Ross, Duncan A. Young, David W. Ashmore, Andreas Born, Winnie Chu, Xiangbin Cui, Reinhard Drews, Steven Franke, Vikram Goel, John W. Goodge, A. Clara J. Henry, Antoine Hermant, Benjamin H. Hills, Nicholas Holschuh, Michelle R. Koutnik, Gwendolyn J.-M. C. Leysinger Vieli, Emma J. MacKie, Elisa Mantelli, Carlos Martín, Felix S. L. Ng, Falk M. Oraschewski, Felipe Napoleoni, Frédéric Parrenin, Sergey V. Popov, Therese Rieckh, Rebecca Schlegel, Dustin M. Schroeder, Martin J. Siegert, Xueyuan Tang, Thomas O. Teisberg, Kate Winter, Shuai Yan, Harry Davis, Christine F. Dow, Tyler J. Fudge, Tom A. Jordan, Bernd Kulessa, Kenichi Matsuoka, Clara J. Nyqvist, Maryam Rahnemoonfar, Matthew R. Siegfried, Shivangini Singh, Vjeran Višnjević, Rodrigo Zamora, and Alexandra Zuhr
The Cryosphere, 19, 4611–4655, https://doi.org/10.5194/tc-19-4611-2025, https://doi.org/10.5194/tc-19-4611-2025, 2025
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The ice sheets covering Antarctica have built up over millenia through successive snowfall events which become buried and preserved as internal surfaces of equal age detectable with ice-penetrating radar. This paper describes an international initiative working together on these archival data to build a comprehensive 3-D picture of how old the ice is everywhere across Antarctica and how this is being used to reconstruct past and to predict future ice and climate behaviour.
Shuai Yan, Duncan A. Young, Donald D. Blankenship, Tyler J. Fudge, Duyi Li, Laura Lindzey, Hunter Reeves, Alejandra Vega-Gonzalez, Shivangini Singh, Megan Kerr, Emily Wilbur, and Michelle Koutnik
EGUsphere, https://doi.org/10.5194/egusphere-2025-3944, https://doi.org/10.5194/egusphere-2025-3944, 2025
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This study examines the radar characteristics of the basal unit along Dome A’s southern flank. Through manual mapping and delay-Doppler analysis, we identifies two basal unit types and maps the spatial variation of incoherent scattering. The results suggest that basal unit radar appearance is influenced by englacial temperature variability and potentially by subglacial geological controls.
Niklas Kappelt, Eric Wolff, Marcus Christl, Christof Vockenhuber, Philip Gautschi, and Raimund Muscheler
Clim. Past, 21, 1585–1594, https://doi.org/10.5194/cp-21-1585-2025, https://doi.org/10.5194/cp-21-1585-2025, 2025
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By measuring the radioactive decay of atmospherically produced 36Cl and 10Be in an ice core drilled in West Antarctica, we were able to determine the age of the deepest sample close to bedrock to be about 550 thousand years old. This means that the ice in this location, known as Skytrain Ice Rise, has survived several warm periods in the past, at least since marine isotope stage 11.
Amy Constance Faith King, Thomas Keith Bauska, Amaelle Landais, Carlos Martin, and Eric William Wolff
EGUsphere, https://doi.org/10.5194/egusphere-2025-3305, https://doi.org/10.5194/egusphere-2025-3305, 2025
This preprint is open for discussion and under review for Climate of the Past (CP).
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We show how measurements of nitrogen isotopes in Antarctic ice core records can be used to show dramatic thinning of an ice sheet during ice mass changes in the Holocene. Combining such measurements with proxies for ice sheet elevation could be a powerful tool for constraining the history of ice dynamics at sites which are sensitive to rapid changes, and could contribute to constraining ice sheet models.
Marc J. Sailer, Tyler J. Fudge, John D. Patterson, Shuai Yan, Duncan A. Young, Shivangini Singh, Don Blankenship, and Megan Kerr
EGUsphere, https://doi.org/10.5194/egusphere-2025-2104, https://doi.org/10.5194/egusphere-2025-2104, 2025
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In this study, we model vertical atmospheric gas diffusion in ice older than 1 million years in the Antarctic ice sheet. We estimate climate signal preservation and help identify a potential region for a future deep ice core in East Antarctica. We find that regions with low accumulation rates and moderate ice thickness result in lower diffusion rates. In particular, the foothills of Dome A is a promising location for a deep ice core that extends the present ice core record.
Piers Larkman, Rachael H. Rhodes, Nicolas Stoll, Carlo Barbante, and Pascal Bohleber
The Cryosphere, 19, 1373–1390, https://doi.org/10.5194/tc-19-1373-2025, https://doi.org/10.5194/tc-19-1373-2025, 2025
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Impurities in ice cores can be preferentially located at the boundaries between crystals of ice, impacting the interpretation of high-resolution data collected from ice core samples. Through use of a modelling framework, we demonstrate that one-dimensional signals can be significantly affected by this association, meaning high-resolution measurements must be carefully designed. Accounting for this effect is important for interpreting ice core data, especially for deep ice samples.
Qinggang Gao, Emilie Capron, Louise C. Sime, Rachael H. Rhodes, Rahul Sivankutty, Xu Zhang, Bette L. Otto-Bliesner, and Martin Werner
Clim. Past, 21, 419–440, https://doi.org/10.5194/cp-21-419-2025, https://doi.org/10.5194/cp-21-419-2025, 2025
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Marine sediment and ice core records suggest a warmer Southern Ocean and Antarctica at the early last interglacial, ~127 000 years ago. However, when only forced by orbital parameters and greenhouse gas concentrations during that period, state-of-the-art climate models do not reproduce the magnitude of warming. Here we show that much of the warming at southern middle to high latitudes can be reproduced by a UK climate model, HadCM3, with a 3000-year freshwater forcing over the North Atlantic.
Xavier Faïn, Sophie Szopa, Vaishali Naïk, Patricia Martinerie, David M. Etheridge, Rachael H. Rhodes, Cathy M. Trudinger, Vasilii V. Petrenko, Kévin Fourteau, and Philip Place
Atmos. Chem. Phys., 25, 1105–1119, https://doi.org/10.5194/acp-25-1105-2025, https://doi.org/10.5194/acp-25-1105-2025, 2025
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Carbon monoxide (CO) plays a crucial role in the atmosphere's oxidizing capacity. In this study, we analyse how historical (1850–2014) [CO] outputs from state-of-the-art global chemistry–climate models over Greenland and Antarctica are able to capture both absolute values and trends recorded in multi-site ice archives. A disparity in [CO] growth rates emerges in the Northern Hemisphere between models and observations from 1920–1975 CE, possibly linked to uncertainties in CO emission factors.
Helene Hoffmann, Jason Day, Rachael H. Rhodes, Mackenzie Grieman, Jack Humby, Isobel Rowell, Christoph Nehrbass-Ahles, Robert Mulvaney, Sally Gibson, and Eric Wolff
The Cryosphere, 18, 4993–5013, https://doi.org/10.5194/tc-18-4993-2024, https://doi.org/10.5194/tc-18-4993-2024, 2024
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Ice cores are archives of past atmospheric conditions. In deep and old ice, the layers containing this information get thinned to the millimetre scale or below. We installed a setup for high-resolution (182 μm) chemical impurity measurements in ice cores using the laser ablation technique at the University of Cambridge. In a first application to the Skytrain ice core from Antarctica, we discuss the potential to detect fine-layered structures in ice up to an age of 26 000 years.
Felix S. L. Ng
The Cryosphere, 18, 4645–4669, https://doi.org/10.5194/tc-18-4645-2024, https://doi.org/10.5194/tc-18-4645-2024, 2024
Short summary
Short summary
Liquid veins and grain boundaries in ice can accelerate the decay of climate signals in δ18O and δD by short-circuiting the slow isotopic diffusion in crystal grains. This theory for "excess diffusion" has not been confirmed experimentally. We show that, if the mechanism occurs, then distinct isotopic patterns must form near grain junctions, offering a testable prediction of the theory. We calculate the patterns and describe an experimental scheme for testing ice-core samples for the mechanism.
Rachael H. Rhodes, Yvan Bollet-Quivogne, Piers Barnes, Mirko Severi, and Eric W. Wolff
Clim. Past, 20, 2031–2043, https://doi.org/10.5194/cp-20-2031-2024, https://doi.org/10.5194/cp-20-2031-2024, 2024
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Some ionic components slowly move through glacier ice by diffusion, but the rate of this diffusion, its exact mechanism(s), and the factors that might influence it are poorly understood. In this study, we model how peaks in sulfate, deposited at Dome C on the Antarctic ice sheet after volcanic eruptions, change with depth and time. We find that the sulfate diffusion rate in ice is relatively fast in young ice near the surface, but the rate is markedly reduced over time.
Dorothea Elisabeth Moser, Elizabeth R. Thomas, Christoph Nehrbass-Ahles, Anja Eichler, and Eric Wolff
The Cryosphere, 18, 2691–2718, https://doi.org/10.5194/tc-18-2691-2024, https://doi.org/10.5194/tc-18-2691-2024, 2024
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Increasing temperatures worldwide lead to more melting of glaciers and ice caps, even in the polar regions. This is why ice-core scientists need to prepare to analyse records affected by melting and refreezing. In this paper, we present a summary of how near-surface melt forms, what structural imprints it leaves in snow, how various signatures used for ice-core climate reconstruction are altered, and how we can still extract valuable insights from melt-affected ice cores.
Qinggang Gao, Louise C. Sime, Alison J. McLaren, Thomas J. Bracegirdle, Emilie Capron, Rachael H. Rhodes, Hans Christian Steen-Larsen, Xiaoxu Shi, and Martin Werner
The Cryosphere, 18, 683–703, https://doi.org/10.5194/tc-18-683-2024, https://doi.org/10.5194/tc-18-683-2024, 2024
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Antarctic precipitation is a crucial component of the climate system. Its spatio-temporal variability impacts sea level changes and the interpretation of water isotope measurements in ice cores. To better understand its climatic drivers, we developed water tracers in an atmospheric model to identify moisture source conditions from which precipitation originates. We find that mid-latitude surface winds exert an important control on moisture availability for Antarctic precipitation.
Tyler J. Fudge, Raphael Sauvage, Linh Vu, Benjamin H. Hills, Mirko Severi, and Edwin D. Waddington
Clim. Past, 20, 297–312, https://doi.org/10.5194/cp-20-297-2024, https://doi.org/10.5194/cp-20-297-2024, 2024
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We use the oldest Antarctic ice core to estimate the rate of diffusion of sulfuric acid. Sulfuric acid is a marker of past volcanic activity and is critical in developing ice core timescales. The rate of diffusion is uncertain and is important to know, both for selecting future ice core locations and interpreting ice core records. We find the effective diffusivity of sulfate is 10 times smaller than previously estimated, indicating that the sulfuric acid signals will persist for longer.
Xavier Faïn, David M. Etheridge, Kévin Fourteau, Patricia Martinerie, Cathy M. Trudinger, Rachael H. Rhodes, Nathan J. Chellman, Ray L. Langenfelds, Joseph R. McConnell, Mark A. J. Curran, Edward J. Brook, Thomas Blunier, Grégory Teste, Roberto Grilli, Anthony Lemoine, William T. Sturges, Boris Vannière, Johannes Freitag, and Jérôme Chappellaz
Clim. Past, 19, 2287–2311, https://doi.org/10.5194/cp-19-2287-2023, https://doi.org/10.5194/cp-19-2287-2023, 2023
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We report on a 3000-year record of carbon monoxide (CO) levels in the Southern Hemisphere's high latitudes by combining ice core and firn air measurements with modern direct atmospheric samples. Antarctica [CO] remained stable (–835 to 1500 CE), decreased during the Little Ice Age, and peaked around 1985 CE. Such evolution reflects stable biomass burning CO emissions before industrialization, followed by growth from CO anthropogenic sources, which decline after 1985 due to improved combustion.
Isobel Rowell, Carlos Martin, Robert Mulvaney, Helena Pryer, Dieter Tetzner, Emily Doyle, Hara Madhav Talasila, Jilu Li, and Eric Wolff
Clim. Past, 19, 1699–1714, https://doi.org/10.5194/cp-19-1699-2023, https://doi.org/10.5194/cp-19-1699-2023, 2023
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We present an age scale for a new type of ice core from a vulnerable region in West Antarctic, which is lacking in longer-term (greater than a few centuries) ice core records. The Sherman Island core extends to greater than 1 kyr. We provide modelling evidence for the potential of a 10 kyr long core. We show that this new type of ice core can be robustly dated and that climate records from this core will be a significant addition to existing regional climate records.
Felix S. L. Ng
The Cryosphere, 17, 3063–3082, https://doi.org/10.5194/tc-17-3063-2023, https://doi.org/10.5194/tc-17-3063-2023, 2023
Short summary
Short summary
The stable isotopes of oxygen and hydrogen in ice cores are routinely analysed for the climate signals which they carry. It has long been known that the system of water veins in ice facilitates isotopic diffusion. Here, mathematical modelling shows that water flow in the veins strongly accelerates the diffusion and the decay of climate signals. The process hampers methods using the variations in signal decay with depth to reconstruct past climatic temperature.
Robert Mulvaney, Eric W. Wolff, Mackenzie M. Grieman, Helene H. Hoffmann, Jack D. Humby, Christoph Nehrbass-Ahles, Rachael H. Rhodes, Isobel F. Rowell, Frédéric Parrenin, Loïc Schmidely, Hubertus Fischer, Thomas F. Stocker, Marcus Christl, Raimund Muscheler, Amaelle Landais, and Frédéric Prié
Clim. Past, 19, 851–864, https://doi.org/10.5194/cp-19-851-2023, https://doi.org/10.5194/cp-19-851-2023, 2023
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We present an age scale for a new ice core drilled at Skytrain Ice Rise, an ice rise facing the Ronne Ice Shelf in Antarctica. Various measurements in the ice and air phases are used to match the ice core to other Antarctic cores that have already been dated, and a new age scale is constructed. The 651 m ice core includes ice that is confidently dated to 117 000–126 000 years ago, in the last interglacial. Older ice is found deeper down, but there are flow disturbances in the deeper ice.
David A. Hodell, Simon J. Crowhurst, Lucas Lourens, Vasiliki Margari, John Nicolson, James E. Rolfe, Luke C. Skinner, Nicola C. Thomas, Polychronis C. Tzedakis, Maryline J. Mleneck-Vautravers, and Eric W. Wolff
Clim. Past, 19, 607–636, https://doi.org/10.5194/cp-19-607-2023, https://doi.org/10.5194/cp-19-607-2023, 2023
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We produced a 1.5-million-year-long history of climate change at International Ocean Discovery Program Site U1385 of the Iberian margin, a well-known location for rapidly accumulating sediments on the seafloor. Our record demonstrates that longer-term orbital changes in Earth's climate were persistently overprinted by abrupt millennial-to-centennial climate variability. The occurrence of abrupt climate change is modulated by the slower variations in Earth's orbit and climate background state.
François Burgay, Rafael Pedro Fernández, Delia Segato, Clara Turetta, Christopher S. Blaszczak-Boxe, Rachael H. Rhodes, Claudio Scarchilli, Virginia Ciardini, Carlo Barbante, Alfonso Saiz-Lopez, and Andrea Spolaor
The Cryosphere, 17, 391–405, https://doi.org/10.5194/tc-17-391-2023, https://doi.org/10.5194/tc-17-391-2023, 2023
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The paper presents the first ice-core record of bromine (Br) in the Antarctic plateau. By the observation of the ice core and the application of atmospheric chemical models, we investigate the behaviour of bromine after its deposition into the snowpack, with interest in the effect of UV radiation change connected to the formation of the ozone hole, the role of volcanic deposition, and the possible use of Br to reconstruct past sea ice changes from ice core collect in the inner Antarctic plateau.
Eric W. Wolff, Andrea Burke, Laura Crick, Emily A. Doyle, Helen M. Innes, Sue H. Mahony, James W. B. Rae, Mirko Severi, and R. Stephen J. Sparks
Clim. Past, 19, 23–33, https://doi.org/10.5194/cp-19-23-2023, https://doi.org/10.5194/cp-19-23-2023, 2023
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Large volcanic eruptions leave an imprint of a spike of sulfate deposition that can be measured in ice cores. Here we use a method that logs the number and size of large eruptions recorded in an Antarctic core in a consistent way through the last 200 000 years. The rate of recorded eruptions is variable but shows no trends. In particular, there is no increase in recorded eruptions during deglaciation periods. This is consistent with most recorded eruptions being from lower latitudes.
Takahito Mitsui, Polychronis C. Tzedakis, and Eric W. Wolff
Clim. Past, 18, 1983–1996, https://doi.org/10.5194/cp-18-1983-2022, https://doi.org/10.5194/cp-18-1983-2022, 2022
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We provide simple quantitative models for the interglacial and glacial intensities over the last 800 000 years. Our results suggest that the memory of previous climate states and the time course of the insolation in both hemispheres are crucial for understanding interglacial and glacial intensities. In our model, the shift in interglacial intensities at the Mid-Brunhes Event (~430 ka) is ultimately attributed to the amplitude modulation of obliquity.
Helene M. Hoffmann, Mackenzie M. Grieman, Amy C. F. King, Jenna A. Epifanio, Kaden Martin, Diana Vladimirova, Helena V. Pryer, Emily Doyle, Axel Schmidt, Jack D. Humby, Isobel F. Rowell, Christoph Nehrbass-Ahles, Elizabeth R. Thomas, Robert Mulvaney, and Eric W. Wolff
Clim. Past, 18, 1831–1847, https://doi.org/10.5194/cp-18-1831-2022, https://doi.org/10.5194/cp-18-1831-2022, 2022
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The WACSWAIN project (WArm Climate Stability of the West Antarctic ice sheet in the last INterglacial) investigates the fate of the West Antarctic Ice Sheet during the last warm period on Earth (115 000–130 000 years before present). Within this framework an ice core was recently drilled at Skytrain Ice Rise. In this study we present a stratigraphic chronology of that ice core based on absolute age markers and annual layer counting for the last 2000 years.
Xavier Crosta, Karen E. Kohfeld, Helen C. Bostock, Matthew Chadwick, Alice Du Vivier, Oliver Esper, Johan Etourneau, Jacob Jones, Amy Leventer, Juliane Müller, Rachael H. Rhodes, Claire S. Allen, Pooja Ghadi, Nele Lamping, Carina B. Lange, Kelly-Anne Lawler, David Lund, Alice Marzocchi, Katrin J. Meissner, Laurie Menviel, Abhilash Nair, Molly Patterson, Jennifer Pike, Joseph G. Prebble, Christina Riesselman, Henrik Sadatzki, Louise C. Sime, Sunil K. Shukla, Lena Thöle, Maria-Elena Vorrath, Wenshen Xiao, and Jiao Yang
Clim. Past, 18, 1729–1756, https://doi.org/10.5194/cp-18-1729-2022, https://doi.org/10.5194/cp-18-1729-2022, 2022
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Despite its importance in the global climate, our knowledge of Antarctic sea-ice changes throughout the last glacial–interglacial cycle is extremely limited. As part of the Cycles of Sea Ice Dynamics in the Earth system (C-SIDE) Working Group, we review marine- and ice-core-based sea-ice proxies to provide insights into their applicability and limitations. By compiling published records, we provide information on Antarctic sea-ice dynamics over the past 130 000 years.
Jacob D. Morgan, Christo Buizert, Tyler J. Fudge, Kenji Kawamura, Jeffrey P. Severinghaus, and Cathy M. Trudinger
The Cryosphere, 16, 2947–2966, https://doi.org/10.5194/tc-16-2947-2022, https://doi.org/10.5194/tc-16-2947-2022, 2022
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The composition of air bubbles in Antarctic ice cores records information about past changes in properties of the snowpack. We find that, near the South Pole, thinner snowpack in the past is often due to steeper surface topography, in which faster winds erode the snow and deposit it in flatter areas. The slope and wind seem to also cause a seasonal bias in the composition of air bubbles in the ice core. These findings will improve interpretation of other ice cores from places with steep slopes.
Eric W. Wolff, Hubertus Fischer, Tas van Ommen, and David A. Hodell
Clim. Past, 18, 1563–1577, https://doi.org/10.5194/cp-18-1563-2022, https://doi.org/10.5194/cp-18-1563-2022, 2022
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Projects are underway to drill ice cores in Antarctica reaching 1.5 Myr back in time. Dating such cores will be challenging. One method is to match records from the new core against datasets from existing marine sediment cores. Here we explore the options for doing this and assess how well the ice and marine records match over the existing 800 000-year time period. We are able to recommend a strategy for using marine data to place an age scale on the new ice cores.
Xavier Faïn, Rachael H. Rhodes, Philip Place, Vasilii V. Petrenko, Kévin Fourteau, Nathan Chellman, Edward Crosier, Joseph R. McConnell, Edward J. Brook, Thomas Blunier, Michel Legrand, and Jérôme Chappellaz
Clim. Past, 18, 631–647, https://doi.org/10.5194/cp-18-631-2022, https://doi.org/10.5194/cp-18-631-2022, 2022
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Carbon monoxide (CO) is a regulated pollutant and one of the key components determining the oxidizing capacity of the atmosphere. In this study, we analyzed five ice cores from Greenland at high resolution for CO concentrations by coupling laser spectrometry with continuous melting. By combining these new datasets, we produced an upper-bound estimate of past atmospheric CO abundance since preindustrial times for the Northern Hemisphere high latitudes, covering the period from 1700 to 1957 CE.
Laura Crick, Andrea Burke, William Hutchison, Mika Kohno, Kathryn A. Moore, Joel Savarino, Emily A. Doyle, Sue Mahony, Sepp Kipfstuhl, James W. B. Rae, Robert C. J. Steele, R. Stephen J. Sparks, and Eric W. Wolff
Clim. Past, 17, 2119–2137, https://doi.org/10.5194/cp-17-2119-2021, https://doi.org/10.5194/cp-17-2119-2021, 2021
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The ~ 74 ka eruption of Toba was one of the largest eruptions of the last 100 ka. We have measured the sulfur isotopic composition for 11 Toba eruption candidates in two Antarctic ice cores. Sulfur isotopes allow us to distinguish between large eruptions that have erupted material into the stratosphere and smaller ones that reach lower altitudes. Using this we have identified the events most likely to be Toba and place the eruption on the transition into a cold period in the Northern Hemisphere.
Felix S. L. Ng
The Cryosphere, 15, 1787–1810, https://doi.org/10.5194/tc-15-1787-2021, https://doi.org/10.5194/tc-15-1787-2021, 2021
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Current theory predicts climate signals in the vein chemistry of ice cores to migrate, hampering their dating. I show that the Gibbs–Thomson effect, which has been overlooked, causes fast diffusion that prevents signals from surviving into deep ice. Hence the deep climatic peaks in Antarctic and Greenlandic ice must be due to impurities in the ice matrix (outside veins) and safe from migration. These findings reset our understanding of postdepositional changes of ice-core climate signals.
Bette L. Otto-Bliesner, Esther C. Brady, Anni Zhao, Chris M. Brierley, Yarrow Axford, Emilie Capron, Aline Govin, Jeremy S. Hoffman, Elizabeth Isaacs, Masa Kageyama, Paolo Scussolini, Polychronis C. Tzedakis, Charles J. R. Williams, Eric Wolff, Ayako Abe-Ouchi, Pascale Braconnot, Silvana Ramos Buarque, Jian Cao, Anne de Vernal, Maria Vittoria Guarino, Chuncheng Guo, Allegra N. LeGrande, Gerrit Lohmann, Katrin J. Meissner, Laurie Menviel, Polina A. Morozova, Kerim H. Nisancioglu, Ryouta O'ishi, David Salas y Mélia, Xiaoxu Shi, Marie Sicard, Louise Sime, Christian Stepanek, Robert Tomas, Evgeny Volodin, Nicholas K. H. Yeung, Qiong Zhang, Zhongshi Zhang, and Weipeng Zheng
Clim. Past, 17, 63–94, https://doi.org/10.5194/cp-17-63-2021, https://doi.org/10.5194/cp-17-63-2021, 2021
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The CMIP6–PMIP4 Tier 1 lig127k experiment was designed to address the climate responses to strong orbital forcing. We present a multi-model ensemble of 17 climate models, most of which have also completed the CMIP6 DECK experiments and are thus important for assessing future projections. The lig127ksimulations show strong summer warming over the NH continents. More than half of the models simulate a retreat of the Arctic minimum summer ice edge similar to the average for 2000–2018.
Jenna A. Epifanio, Edward J. Brook, Christo Buizert, Jon S. Edwards, Todd A. Sowers, Emma C. Kahle, Jeffrey P. Severinghaus, Eric J. Steig, Dominic A. Winski, Erich C. Osterberg, Tyler J. Fudge, Murat Aydin, Ekaterina Hood, Michael Kalk, Karl J. Kreutz, David G. Ferris, and Joshua A. Kennedy
Clim. Past, 16, 2431–2444, https://doi.org/10.5194/cp-16-2431-2020, https://doi.org/10.5194/cp-16-2431-2020, 2020
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A new ice core drilled at the South Pole provides a 54 000-year paleo-environmental record including the composition of the past atmosphere. This paper describes the gas chronology for the South Pole ice core, based on a high-resolution methane record. The new gas chronology, in combination with the existing ice age scale from Winski et al. (2019), allows a model-independent reconstruction of the delta age record.
Cited articles
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Short summary
Impurity diffusion in ice destroys climate history. We give a new way to find the diffusion rate from ice-core records. Its use on sulphate of the European Project for Ice Coring in Antarctica Dome C core reveals rapid diffusion in snow (suggesting H2SO4 vapour diffusion in air pores) and slow diffusion in the ice below (involving signal relocation between crystal interfaces). We estimate a maximum sulphate diffusion length of 2 cm for the old ice sought by the coring projects on Little Dome C.
Impurity diffusion in ice destroys climate history. We give a new way to find the diffusion rate...
