the Creative Commons Attribution 4.0 License.

the Creative Commons Attribution 4.0 License.

# On the reflectance spectroscopy of snow

### Alexander Kokhanovsky

### Maxim Lamare

### Biagio Di Mauro

### Ghislain Picard

### Laurent Arnaud

### Marie Dumont

### François Tuzet

### Carsten Brockmann

### Jason E. Box

We propose a system of analytical equations to retrieve snow grain size and absorption coefficient of pollutants from snow reflectance or snow albedo measurements in the visible and near-infrared regions of the electromagnetic spectrum, where snow single-scattering albedo is close to 1.0. It is assumed that ice grains and impurities (e.g., dust, black and brown carbon) are externally mixed, and that the snow layer is semi-infinite and vertically and horizontally homogeneous. The influence of close-packing effects on reflected light intensity are assumed to be small and ignored. The system of nonlinear equations is solved analytically under the assumption that impurities have the spectral absorption coefficient, which obey the Ångström power law, and the impurities influence the registered spectra only in the visible and not in the near infrared (and vice versa for ice grains). The theory is validated using spectral reflectance measurements and albedo of clean and polluted snow at various locations (Antarctica Dome C, European Alps). A technique to derive the snow albedo (plane and spherical) from reflectance measurements at a fixed observation geometry is proposed. The technique also enables the simulation of hyperspectral snow reflectance measurements in the broad spectral range from ultraviolet to the near infrared for a given snow surface if the actual measurements are performed at a restricted number of wavelengths (two to four, depending on the type of snow and the measurement system).

The reflective properties of clean and polluted snow are of importance for various applications, including climate (Hansen and Nazarenko, 2007) and environmental pollution (Nazarenko et al., 2017) studies. The spectral snow reflectance is usually studied in the framework of the radiative transfer theory. The application of the numerical methods for the solution of the radiative transfer equation for snow layers has been performed by, among others, Mishchenko et al. (1999), Stamnes et al. (2011) and He et al. (2018). The approximate solutions of the radiative transfer equation useful for snow optics and spectroscopy applications have been developed by Warren and Wiscombe (1980), Wiscombe and Warren (1980) and Kokhanovsky and Zege (2004). In this work, we propose an analytical snow albedo and reflectance model which can be used to derive near-surface snow optical and microphysical properties using measurements at just two to four wavelengths in the visible and near infrared depending on the measurement system and type of snow. In particular, we present the method for the determination of snow grain size, absorption Ångström coefficient and spectral absorption coefficient of impurities embedded in the snow matrix assuming an external mixture of snow grains and impurities. The technique to derive the snow albedo from reflectance measurements is also presented. The absorption and extinction of light by snow grains is treated in the framework of a geometrical optical approximation. The absorption coefficient of impurities is modeled using the Ångström power law. All derivations are performed in the framework of the asymptotic radiative transfer theory (see, e.g., Kokhanovsky and Zege, 2004; Zege et al., 2011). It is assumed that the snow layer is vertically and horizontally homogeneous and semi-infinite. Therefore, the effects of the finite layer thickness are ignored.

## 2.1 The snow reflectance

The snow reflectance *R* (equal to unity for ideal white Lambertian
reflectors; see Appendix A) can be presented in the following way using
approximate asymptotic radiative transfer theory (Kokhanovsky and Zege,
2004):

where $x=u\left({\mathit{\mu}}_{\mathrm{0}}\right)u\left(\mathit{\mu}\right)/{R}_{\mathrm{0}},{R}_{\mathrm{0}}$ is the
reflectance of a semi-infinite non-absorbing snow layer; $u\left({\mathit{\mu}}_{\mathrm{0}}\right)=\frac{\mathrm{3}}{\mathrm{7}}\left(\mathrm{1}+\mathrm{2}{\mathit{\mu}}_{\mathrm{0}}\right)$; *μ*_{0} is the cosine of
the solar zenith angle; *μ* is the cosine of the viewing zenith angle; and
*r*_{s} is the snow spherical albedo:

where

*g* is the asymmetry parameter and *ω*_{0} is the single-scattering
albedo. Let us introduce the probability of photon absorption $\mathit{\beta}\equiv \mathrm{1}-{\mathit{\omega}}_{\mathrm{0}}$. It is equal as the ratio of absorption *κ*_{abs}
and extinction *κ*_{ext} coefficients:

where

The first and second terms in Eq. (5) correspond to the ice grains and pollutants, respectively. We assume that scattering and extinction of light by impurities are much smaller than by ice grains and, therefore (Kokhanovsky and Zege, 2004),

Here, $d=\mathrm{1.5}\overline{V}/\overline{S}$ is the effective diameter of ice grains, $\overline{V}$ is the average volume of grains and $\overline{S}$ is their average
projected area averaged over all directions (equal to $\sum /\mathrm{4}$ for convex
particles in random orientation, where ∑ is the average surface area and
*c* is the volumetric concentration of the snow grains). The value of *c* is
equal to the volume of grains in unit volume of snow ($c=N\overline{V}$, where
*N* is the number of snow grains in unit volume of snow (cm^{−3})). It is
related to the dry-snow density *ρ*_{s} by the following relation:
*ρ*_{s}=*c**ρ*_{i}, where *ρ*_{i} is the bulk ice
density.

The product of the effective diameter *d* and the bulk ice absorption
coefficient *α* is a small number in the visible and near infrared. Then
it follows (Kokhanovsky and Zege, 2004; see their Eq. 37 for the absorption
path length inversely proportional to the absorption coefficient) that

where *B* is the grain-shape-dependent parameter (absorption enhancement
parameter) and $\mathit{\alpha}=\frac{\mathrm{4}\mathit{\pi}\mathit{\chi}}{\mathit{\lambda}}$, where *χ* is the
imaginary part of the ice refractive index at the wavelength *λ*.

We present the absorption coefficient of pollutants in snow as

where ${\mathit{\kappa}}_{\mathrm{0}}\equiv {\mathit{\kappa}}_{\mathrm{abs}}^{\mathrm{pol}}\left({\mathit{\lambda}}_{\mathrm{0}}\right),\stackrel{\mathrm{\u0303}}{\mathit{\lambda}}=\mathit{\lambda}/{\mathit{\lambda}}_{\mathrm{0}},{\mathit{\lambda}}_{\mathrm{0}}=\mathrm{1}$ µm and
*m* is the absorption Angstrom coefficient.

It follows from Eqs. (4)–(8) that

where

and therefore

Let the parameter *z*=*y*^{2}, from which it follows that

where

${\mathit{\kappa}}_{\mathrm{0}}^{\ast}={\mathit{\kappa}}_{\mathrm{0}}/c$ and

is the effective absorption length (EAL) and

is a grain-shape-dependent (but not grain-size-dependent) parameter.

The parameter *l* can be determined directly from reflectance or albedo
measurements, enabling also the determination of the grain diameter $d=l/\mathit{\xi}$ assuming a particular shape of grains. It has been found that the asymmetry
parameter of crystalline clouds is usually in the range 0.74–0.76 in the
visible (Garret, 2008). The asymmetry parameter *g* for snow has not been
measured so far in situ, but we shall assume that it is close to that in
crystalline clouds and adopt the value 0.75. It follows from experimental
studies of Libois et al. (2014) that *B*=1.6 on average. Therefore, it
follows (see Eq. 15) that *ξ*≈11.38.

Using the EAL, the equations for the snow reflectance and spherical albedo may be simplified.

Namely, it follows that

The plane albedo can be derived as well (Kokhanovsky and Zege, 2004):

The relationship between the albedo and the reflectance *R* is given in
Appendix A. It follows from Eq. (16) that the spectral reflectance of
polluted snow is determined by four a priori unknown parameters: *l*,
*R*_{0}, *f* and *m*. They can be estimated from the measurements of reflectance at four
wavelengths. This also enables the determination of the spectral reflectance
(and albedo; see Eq. 18) at the visible and near-infrared wavelengths at
an arbitrary *λ*. It follows that

where the numbers 1, 2, 3 and 4 signify the wavelengths used.
Equations (19)–(22) can be used to compute four unknown parameters given
above and, therefore, to determine reflectance and albedo at any wavelength in
the visible and the near infrared using Eqs. (16)–(18). Let us assume that
the spectral channels are selected in a way that the effects of ice
absorption can be neglected in the first two channels (*λ*_{1},*λ*_{2}) and effects of absorption by pollutants are negligible in the
second pair of channels (*λ*_{3},*λ*_{4}). This situation is
typical of not heavily polluted snow. Then it follows, instead of
Eqs. (19)–(22), that

Equations (25) and (26) can be used to find the pair (*l*,*R*_{0}):

where ${\mathit{\epsilon}}_{\mathrm{1}}=\mathrm{1}/(\mathrm{1}-b),{\mathit{\epsilon}}_{\mathrm{2}}=\mathrm{1}/(\mathrm{1}-{b}^{-\mathrm{1}})$ and $b=\sqrt{{\mathit{\alpha}}_{\mathrm{3}}/{\mathit{\alpha}}_{\mathrm{4}}}$. Then it follows from Eqs. (23) and (24) that

where ${p}_{k}={\mathrm{ln}}^{\mathrm{2}}\left({R}_{k}/{R}_{\mathrm{0}}\right)$. In the absence
of pollutants, Eq. (27) remains valid. However, the parameters *m* and *f* are
undefined, and $R={R}_{\mathrm{0}}\mathrm{exp}(-x\sqrt{\mathit{\alpha}l})$.

One may also derive the impurity absorption coefficient at the wavelength *λ*_{0} normalized to the concentration of ice grains *c* (see Eq. 1):

where *f* is given by Eq. (29). The normalized absorption coefficient at each
wavelength can also be found using Eqs. (8), (28) and (30).

To determine the concentration of pollutants (*c*_{p}), one must either
know in advance or determine the impurity volumetric absorption coefficient,
defined as

where ${\overline{C}}_{\mathrm{abs}}$ is the average absorption cross section of impurities and $\overline{V}$ is the average volume of absorbing impurities. Namely, it follows by definition that

and

where $\mathbb{C}={c}_{\mathrm{p}}/c$.

The value of *K*(*λ*_{0}) can be found if one knows the
type of pollutants and their microphysical properties. In particular, it
follows for the impurities much smaller than the wavelength *λ*_{0}
(van de Hulst, 1981) that

where

is the pollutant bulk absorption coefficient, *χ*_{pol}(*λ*_{0}) is the imaginary part of pollutant refractive index
and *n*_{pol} is the real part of the pollutant refractive index,

It follows that *F*=0.9 for soot (assuming that *n*=1.75, *χ*_{pol}=0.47 in the visible). One can see that ℂ can be found if one
knows the refractive index of absorbing Rayleigh particles in advance.

In particular, it follows for soot impurities that

In the case of non-Rayleigh scatterers, one needs to know not only the refractive
index but also the particle size distribution and shape of particles,
enabling the determination of the impurity volumetric absorption coefficient
*K*(*λ*_{0}) and, therefore, the normalized
concentration of impurities:

## 2.2 The snow albedo

### 2.2.1 Theory

If the plane albedo is the measured physical quantity, one needs to find only
three constants: *l*, *f* and *m*.

The respective analytical equations can be presented as

We shall assume that the last channel is not influenced by impurities and the first two channels are not influenced by the absorption of light by grains. Then it follows that

The EAL can be found from Eq. (44):

It follows from Eqs. (42) and (43) that

where *ψ*_{k}=ln^{2}*r*_{k}.

In the case of unpolluted snow, one derives

Equation (45) can be used to find the effective absorption length and,
therefore, the spectral albedo of unpolluted snow at any wavelength using
Eq. (47). If not plane but rather spherical albedo is measured, then all
equations presented in this section are valid, except one should assume that
*u*=1 and substitute *r* with *r*_{s} (Kokhanovsky and Zege, 2004).

## 3.1 The measurements of the plane albedo

We have applied the technique developed above to the measured spectral plane albedo both for polluted and pure snow. Therefore, in situ spectral albedo measurements were obtained from two different field sites located in the French Alps (polluted snow) and in Antarctica (clean snow).

The spectral albedo of a spring alpine snowpack was measured at the Col du
Lautaret field site ($\mathrm{45}{}^{\circ}{\mathrm{2}}^{\prime}$ N, $\mathrm{6}{}^{\circ}{\mathrm{2}}^{\prime}$ E;
2100 m a.s.l.) in the French Alps. The measurements were performed using a
non-automated version of the spectrometer system described above. The
handheld instrument has a single light collector, located at the end of a 3 m
boom placed 1.5 m above the surface. The boom is rotated by the operator to
successively acquire the downward and upward solar radiation. The spectral
albedo data (each spectral albedo measurement at a given point is an average
of five measurements) at several locations close to the Col du
Lautaret field site were obtained on 12 April 2017 across a 100 m transect,
in an attempt to account for spatial variability. The measurements were acquired
in clear-sky conditions, with a solar zenith angle varying between 47.9 and
52.2^{∘}.

The results of comparison of measurements and the theory presented above are
illustrated in Fig. 1 at the Col du Lautaret field site. The parameters
*l*, *f* and *m* have been found from Eqs. (42)–(44) and the measurements at the
wavelengths *λ*_{1}=400 nm, *λ*_{2}=560 nm and *λ*_{3}=1020 nm. At other measurement sites across a transect the results of the
intercomparison are excellent and similar to those presented in Fig. 1.
Therefore, the theory can be used to derive snow optical and microphysical
properties even for polluted snowpack. The derived spectral probability of
photon absorption for the case shown in Fig. 1 is presented in Fig. 2. The
derived absorption coefficient (assuming $c=\mathrm{1}/\mathrm{3}$), the grain diameter *d* and
the absorption Ångström parameter *m* for five sites across the transect
are listed in Table 1 (lines 1–5). It follows that the value of *m* is in
the range 2.4–4.1, consistent with the identified presence of dust particles
in snow (Doherty et al., 2010). The pure black carbon impurities have
values of *m* close to 1. The grain diameter is in the range 1.7–2.2 mm,
consistent with low values of snow albedo at 1020 nm (see Fig. 1). Wiscombe
and Warren (1981) calculated the dependence of the clean-snow spectral
albedo at the solar zenith angle 60^{∘} and several grain radii and
presented it in their Fig. 8. It follows from their calculations that the
albedo decreases from 0.8 to 0.4 mm, while the diameter of grains changes from
0.1 to 2 mm. It follows from our Fig. 1 that the measured plane albedo is
close to 0.45, signifying the dominance of large grains in the snowpack as
reported in Table 1.

The spectral albedo of pure snow (very low amount of impurities) was measured
at Dome C ($\mathrm{75}{}^{\circ}{\mathrm{5}}^{\prime}$ S, $\mathrm{123}{}^{\circ}{\mathrm{17}}^{\prime}$ E) in Antarctica using
an automated spectral radiometer (Libois et al., 2015; Picard et al., 2016;
Dumont et al., 2017). The instrument is composed of two individual heads
located approximately 1.5 m above the surface. Each head contains two cosine
receptors facing upward and downward, which receive the incident solar
radiation and the reflected radiation. The collectors are connected to an
Ocean Optics Maya2000 Pro spectrometer with fiber optics through an optical
switch. Radiation is measured over the 350–1100 nm spectral range with an
effective spectral resolution of 3 nm. Albedo was calculated as the ratio of
the upward and downward spectral irradiance. A full description of the
instrument and the processing steps to calculate the spectral albedo are
given by Picard et al. (2016). The spectral albedo measurements used here
were made on 10 January 2017, with a solar zenith angle of 63.2^{∘},
during clear-sky conditions assessed by ground observations.

The results of the application of the proposed technique to the pure snow (no
pollution) albedo measured in Antarctica are illustrated in Fig. 3.
Application of our technique results in excellent agreement with measured
albedo over pure snow (no pollution) in Antarctica. Because the snow at Dome
C is clean/pristine, the value of *f* is negligible, resulting in snow albedo
depending only on the effective absorption length/grain size, which has been
derived at a single wavelength (1020 nm). The derived grain diameter for the
case presented in Fig. 3 is equal to 0.5 mm. The retrieval error estimation
is presented in Appendix B.

## 3.2 The measurements of the spectral reflectance

The application of the developed theory to the measurements of the spectral
reflectance is presented in Fig. 4 for two locations with different dust
loads (39.6 and 107.4 ppm). The spectral reflectance of snow was measured in
the European Alps (Artavaggio plains; 1650 m a.s.l.; $\mathrm{45}{}^{\circ}{\mathrm{55}}^{\prime}{\mathrm{56.70}}^{\prime \prime}$ N, $\mathrm{9}{}^{\circ}{\mathrm{31}}^{\prime}{\mathrm{33.28}}^{\prime \prime}$ E) at the solar zenith angle equal
to 52^{∘}. The measurements were made on 14 March 2014, after a major
transport and deposition of mineral dust from the Sahara. The event
was very intense, and it was reported in the recent scientific literature
regarding snow optical properties (Di Mauro et al., 2015; Dumont et al.,
2017), atmospheric chemistry and physics (Belosi et al., 2017), and
microbiology (Weil et al., 2017). The dust transport event deposited fine
mineral dust particles from the atmosphere via wet deposition, according to
the BSC-DREAM8b model (Basart et al., 2012). Spectral measurements of snow
were made using a field spectrometer (Analytical Spectral
Devices (ASD) FieldSpec Pro). This instrument features a spectral range of 350–2500 nm, a
full width at half maximum of 5–10 nm and a spectral resolution of 1 nm.
Data presented here were collected under clear-sky conditions at noon.
Incident radiation was estimated using a Lambertian Spectralon panel.
Reflected radiance was divided by incident radiance, and the hemispherical
conical reflectance factor was calculated for two plots containing 39.6 and
107.4 ppm of dust. Dust concentration was measured with a Coulter counter by
integrating particles with a diameter smaller than 18 µm. Spectral
measurements were performed at nadir using a bare optical fiber (field of
view of 25^{∘}) at 80 cm from the snow sample. Both the optical fiber
and the spectralon panel were equipped with an optical level. Further details
on this dataset can be found in Di Mauro et al. (2015).

One can see that the theory works well not only for the albedo measurements
(see the previous section) but also for the reflectance measurements for
polluted snow layers. In particular, our results are closer to the
measurements than the theoretical model described by Flanner et
al. (2007) (see Fig. 4b in Di Mauro et al., 2015). The derived parameters are
given in Table 1 (lines 6–7). The value of *m* is 4.1 for the case with
the 39.6 ppm dust concentration and 6.4 for the case with 107.4 dust
concentration. Because the difference is quite large for the close locations,
we conclude that snow also contained other pollutants (say, soot), and the
determined value of *m* represents the combined effect with larger values of
*m* for larger concentrations of dust, which is consistent with other
observations of this parameter in snow (Doherty et al., 2010). The retrieved
absorption coefficient of snow pollutants (at the wavelength ${\mathit{\lambda}}^{\ast}=\mathrm{560}$ nm) is 0.1191 m^{−1} for the dust concentration 39.6 ppm and
0.3123 m^{−1} for the dust concentration of 107.4 ppm. Assuming that
the dust chemical composition and also the dust particle size distribution
are the same at both locations, we can assume that the ratio of absorption
coefficients at two locations should be equal to the ratio of dust
concentrations. The difference between the two ratios is <3 %, which is
within the measurement uncertainty (10 % for dust load measurements),
suggesting that the retrieved absorption coefficients at the two sites are
consistent with each other.

The mass absorption coefficient (MAC) can be estimated using

where *ρ* is the density of the substance of impurities. Assuming that

one can derive that

which is consistent with the
values of MAC given by Utry et al. (2015) (e.g.,
0.0023 m^{2} g^{−1} for quartz and
0.0051 m^{2} g^{−1} for illite; see their Table 1).

In this work, we have presented a sequence of analytical equations, which can be used to determine the snow grain size, the absorption coefficient of impurities and the absorption Ångström coefficient of surface snow impurities from the snow reflectance measured at four wavelengths: two in the visible and two in the near infrared, as suggested by Warren (2013). In the case of albedo measurements just three wavelengths can be used to find main snow properties. For unpolluted snow, it is enough to perform the measurements at two wavelengths (for reflectance measurements) or just at a single wavelength (for albedo measurements) in the near infrared to determine the snow grain size.

In principle, the refractive index of dust and dust size distribution can also be determined using derived the spectral absorption coefficient of dust and assuming the shape of dust particles. However, we did not make an attempt at such retrievals in this work. A method for the retrieval of the complex refractive index and single-scattering optical properties of dust deposited in mountain snow based on exact radiative transfer calculations was proposed by McKenzie Siles et al. (2017) under the assumption that local optical properties of dust grains can be simulated assuming the spherical shape of particles. Their method is based on the extraction of dust grains from snowpack. Our technique does not require such a complicated procedure.

We have demonstrated how snow albedo can be derived from spectral reflectance
measurements avoiding complicated integration with respect to the observation
geometry (azimuth, viewing angle). The last point is useful for the
determination of the snow *albedo* from spectral *reflectance*
measurements (say, from aircraft or satellite) at a fixed observation
geometry. Although the comprehensive validation of the retrievals has not
been attempted, we have found that the ratio of derived absorption
coefficients of pollutants at two concentrations is close to the ratio of
pollutant concentrations derived independently, which indeed should be the
case taking the proximity of two measurement sites with different dust loads.
The general validity of the approach is proven using field measurements
(Alps, Antarctica) of both spectral reflectance and plane albedo.

The determination of the EAL *l* (unlike the effective grain diameter *d*)
both from reflectance and albedo measurements is practically insensitive to
the a priori unknown shape of ice crystals. Therefore, this length may be
useful for the characterization of snowpack microstructure (in addition to
the grain size *d*). The results presented in this work are useful for the
interpretation of snow properties using both reflectance spectroscopy (Hapke,
2005) and imaging spectrometry (Dozier et al., 2009). It is assumed that the
semi-infinite snow layer is vertically and horizontally homogeneous. The
effects of the snow layer finite thickness, close-packing effects, snow
vertical inhomogeneity, possible internal mixture of pollutants in snow
grains and underlying surface albedo (ice, soil, grass) are ignored.

The data are available from the first author upon request.

## B1 The effective absorption length and diameter of grains

Let us consider the error budget for the retrieved snow parameters. To simplify, we assume that the snow parameters are derived using albedo measurements.

The value of *l* is determined from measurements just at a single wavelength
in the framework of the theory given above. It follows from Eq. (45) that

where

Therefore, the relative effective absorption length retrieval error is
directly proportional to the relative measurement error in the measured
albedo. Larger values of *l* correspond to the smaller albedo. So one would
conclude that the error of retrieval of larger values of EAL is
generally smaller (see Eq. B2). For the cases presented in Figs. 1 and 2, the
wavelength 1020 nm has been used in the retrieval process, and one finds that
*K* is equal to −2.5 and −5.8, respectively. Assuming the measurement
error of 3 %, one derives that EAL is determined with accuracies of −7.5
and −17.4 %, respectively, with better accuracy for the observations in
Alps, because the albedo is lower there. Also we see that the overestimation
of the albedo in the experiment leads to the underestimation of the EAL, and
the other way around in the of case measurements which underestimate the snow albedo
because *K* is negative. Because *K* generally decreases with the wavelength,
one must use the largest wavelengths to have better accuracy (say, 1020 nm
instead of 865 nm). The wavelength should not be above 1200 nm or so
(depending on the snow grain size) because the underlying theory is valid for
weakly absorbing media only. So strong ice absorption bands must be avoided.
The value of the snow grain size is proportional to the value of *l*.
Therefore, our conclusions are also valid for the derived snow grain size
assuming that one knows the parameter *ξ* (see Eq. 15) exactly. However,
this parameter is known with some error.

The uncertainty in the parameter $\mathit{\xi}=\mathrm{16}B/\mathrm{3}(\mathrm{1}-g)$ is difficult to access
because we rely on a priori values for the snow asymmetry parameter and the
absorption enhancement parameter *B*. We use the following values: *B*=1.6 and
*g*=0.75. The reported values of *g* for crystalline clouds do not go above
0.8. Therefore, the modulus of the absolute error in the parameter 1−*g* is
smaller than 0.05 (and the relative error is below 20 %). The value of *B*
is usually in the range 1.4–1.8, and therefore the absolute error in the
parameter *B* is equal approximately to ±0.2 and the
relative error is ±12.5 %. It follows that the absolute value of the
maximal relative error in the parameter *ξ* is close to 24 %. The error
could be smaller if the assumptions used in the derivations are closer
to the actual snow conditions. We find that the maximal relative error in the
derived grain diameter for the cases shown in Figs. 1 and 2 is 25–30 %
depending on the snow type, which is substantially larger than the
error in the estimation of EAL.

Let us consider the error budget for the retrieved spectral absorption
coefficient of pollutants. The absolute error of the retrieved parameter Δ*x* is defined as

This error depends on *j* measurement errors of reflectance/albedo at
*j*-channel Δ*y*_{j}; *J* is the number of channels used to
retrieve the corresponding parameter assuming that there are no forward-model
errors. It a difficult task to estimate the forward-model error
theoretically. It depends on the specific type of snowpack.

It follows from Eqs. (46) and (B3) that

where

We conclude that the errors of the pair (*f*,*m*) determination increase
if the selected wavelengths at two channels in the visible are too close and
if the logarithm of albedo at selected channels is close to unity (say, weak
concentration of pollutants for the channels in the visible). The albedo
decreases for the cases with illumination closer to nadir. Therefore, to
reduce errors, one needs to use measurements with larger deviations of Sun
from the horizon direction.

The absorption coefficient of pollutants is given by the following equation (see Eqs. 8, 13, 30):

Therefore, one derives

One concludes that the errors in the estimated snow volumetric concentration
*c* (snow density; see Appendix A), the absorption enhancement coefficient
*B* and the pair (*f*,*m*) must be combined to estimate the total error in
the retrieved spectral absorption coefficient of impurities in snow. The
errors are lower if one is interested in the spectral absorption coefficient
of impurities normalized to its value at a specific wavelength defined as

where *λ*_{∗} is the selected wavelength (say, 550 nm).

One derives for this coefficient

and, therefore, only the accuracy of the determination of absorption Angström exponent influences the result:

An important point is the determination of the concentration of pollutants in
snow from optical remote-sensing data. In principle the concentration of
pollutants can be found if the absorption coefficient of pollutants at a
given wavelength is known. For instance, it follows by definition (see Eq. 31
for the definition of the volumetric absorption coefficient of impurities
*K*) that

Therefore, uncertainty in the derived or assumed value of *K* (or mass
extinction coefficient ${K}_{\mathrm{m}}=K/{\mathit{\rho}}_{\mathrm{p}}$, where *ρ*_{p} is
the density of the substance of a pollutant) influences the retrieval error
in addition to uncertainty of the derived absorption coefficient of
pollutants ${\mathit{\kappa}}_{\mathrm{abs}}^{\mathrm{pol}}\left(\mathit{\lambda}\right)$. One
can see that the determination of the concentration of pollutants from
optical remote sensing of snowpack is a very challenging task.

In particular, one finds that the positive bias in the measured albedo in the visible will lead to the underestimation of the concentration of pollutants (assuming that the grain size is exactly known). It should be pointed out that in most cases the concentration of pollutants is so small that it can not be assessed using optical instruments (change in reflectance is inside experimental measurement error). This issue has been discussed by Zege et al. (2011) and Warren (2013). Similar conclusions hold also if the reflectance (and not albedo) is the measured quantity.

AK prepared the first draft of the paper and also derived all equations presented in the paper. The measurements were performed by ML, BDM, GP, LA, MD, and FT. CB and JEB contributed to the discussion of the results and preparation of the final version of the paper.

The authors declare that they have no conflict of interest.

This work was mainly supported by the European Space Agency in the framework
of ESRIN contract no. 4000118926/16/I-NB, “Scientific Exploitation of
Operational Missions (SEOM) Sentinel-3 Snow (Sentinel-3 for Science, Land
Study 1: Snow)”. CNRM/CEN and IGE are part of LabEx OSUG@2020. Measurements
in the French Alps were funded by the ANRJCJ grant EBONI 16-CE01-0006 and at
Dome C by ANR JCJC MONISNOW 1-JS56-005-01.

Edited by: Benjamin Smith

Reviewed by: two anonymous referees

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