Articles | Volume 15, issue 4
https://doi.org/10.5194/tc-15-2001-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/tc-15-2001-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
23 Apr 2021
Research article |
| 23 Apr 2021
| 23 Apr 2021
Interfacial supercooling and the precipitation of hydrohalite in frozen NaCl solutions as seen by X-ray absorption spectroscopy
Thorsten Bartels-Rausch
CORRESPONDING AUTHOR
Laboratory of Environmental Chemistry, Paul Scherrer Institut,
Villigen PSI, Switzerland
Xiangrui Kong
Laboratory of Environmental Chemistry, Paul Scherrer Institut,
Villigen PSI, Switzerland
now at: Department of Chemistry and Molecular Biology, Atmospheric
Science, University of Gothenburg, Gothenburg, Sweden
Fabrizio Orlando
Laboratory of Environmental Chemistry, Paul Scherrer Institut,
Villigen PSI, Switzerland
now at: Omya International AG, Oftringen, Switzerland
Luca Artiglia
Laboratory of Environmental Chemistry, Paul Scherrer Institut,
Villigen PSI, Switzerland
Astrid Waldner
Laboratory of Environmental Chemistry, Paul Scherrer Institut,
Villigen PSI, Switzerland
Thomas Huthwelker
Swiss Light Source (SLS), Paul Scherrer Institut, Villigen PSI,
Switzerland
Markus Ammann
Laboratory of Environmental Chemistry, Paul Scherrer Institut,
Villigen PSI, Switzerland
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Cited
14 citations as recorded by crossref.
- Environment Effects on X-Ray Absorption Spectra With Quantum Embedded Real-Time Time-Dependent Density Functional Theory Approaches M. De Santis et al. 10.3389/fchem.2022.823246
- Formation of NaCl eutectics in water-in-oil emulsion N. Kimizuka 10.1039/D2CP03061F
- Low-temperature ice nucleation of sea spray and secondary marine aerosols under cirrus cloud conditions R. Patnaude et al. 10.5194/acp-24-911-2024
- Ten crucial unknowns in atmospheric chemistry in the cold T. Bartels-Rausch et al. 10.1039/D5FD00056D
- A study on D2O/H2O-hydrohalite from Raman spectroscopy Q. Hu et al. 10.1016/j.molstruc.2024.138397
- Freezing-induced acidification of sea ice brine L. Veselý et al. 10.1016/j.scitotenv.2024.174194
- A temperature‐dependent hydrating structure around SO42− investigated from Raman spectroscopy Q. Hu et al. 10.1002/jrs.6348
- Salt Enrichment and Dynamics in the Interface of Supercooled Aqueous Droplets V. Kwan et al. 10.1021/jacs.2c01159
- Methane pumping by rapidly refreezing lead ice in the ice-covered Arctic Ocean E. Damm et al. 10.3389/feart.2024.1338246
- Phase diagram of NaCl–water by computer simulations: performance of non-polarizable force-fields G. Cassinello et al. 10.1080/00268976.2024.2398133
- Energy absorbancy and freezing-temperature tunability of NaCl solutions during ice formation Y. Shen et al. 10.1016/j.molliq.2021.117928
- Removing gas-phase features in near ambient pressure partial Auger-Meitner electron yield oxygen K-edge NEXAFS spectra T. Bartels-Rausch et al. 10.1016/j.elspec.2023.147320
- Adsorbed Water Promotes Chemically Active Environments on the Surface of Sodium Chloride X. Kong et al. 10.1021/acs.jpclett.3c00980
- Interfacial supercooling and the precipitation of hydrohalite in frozen NaCl solutions as seen by X-ray absorption spectroscopy T. Bartels-Rausch et al. 10.5194/tc-15-2001-2021
13 citations as recorded by crossref.
- Environment Effects on X-Ray Absorption Spectra With Quantum Embedded Real-Time Time-Dependent Density Functional Theory Approaches M. De Santis et al. 10.3389/fchem.2022.823246
- Formation of NaCl eutectics in water-in-oil emulsion N. Kimizuka 10.1039/D2CP03061F
- Low-temperature ice nucleation of sea spray and secondary marine aerosols under cirrus cloud conditions R. Patnaude et al. 10.5194/acp-24-911-2024
- Ten crucial unknowns in atmospheric chemistry in the cold T. Bartels-Rausch et al. 10.1039/D5FD00056D
- A study on D2O/H2O-hydrohalite from Raman spectroscopy Q. Hu et al. 10.1016/j.molstruc.2024.138397
- Freezing-induced acidification of sea ice brine L. Veselý et al. 10.1016/j.scitotenv.2024.174194
- A temperature‐dependent hydrating structure around SO42− investigated from Raman spectroscopy Q. Hu et al. 10.1002/jrs.6348
- Salt Enrichment and Dynamics in the Interface of Supercooled Aqueous Droplets V. Kwan et al. 10.1021/jacs.2c01159
- Methane pumping by rapidly refreezing lead ice in the ice-covered Arctic Ocean E. Damm et al. 10.3389/feart.2024.1338246
- Phase diagram of NaCl–water by computer simulations: performance of non-polarizable force-fields G. Cassinello et al. 10.1080/00268976.2024.2398133
- Energy absorbancy and freezing-temperature tunability of NaCl solutions during ice formation Y. Shen et al. 10.1016/j.molliq.2021.117928
- Removing gas-phase features in near ambient pressure partial Auger-Meitner electron yield oxygen K-edge NEXAFS spectra T. Bartels-Rausch et al. 10.1016/j.elspec.2023.147320
- Adsorbed Water Promotes Chemically Active Environments on the Surface of Sodium Chloride X. Kong et al. 10.1021/acs.jpclett.3c00980
Latest update: 08 Jul 2025
Short summary
Chemical reactions in sea salt embedded in coastal polar snow impact the composition and air quality of the atmosphere. Here, we investigate the phase changes of sodium chloride. This is of importance as chemical reactions proceed faster in liquid solutions compared to in solid salt and the precise precipitation temperature of sodium chloride is still under debate. We focus on the upper nanometres of sodium chloride–ice samples because of their role as a reactive interface in the environment.
Chemical reactions in sea salt embedded in coastal polar snow impact the composition and air...
