Articles | Volume 18, issue 9
https://doi.org/10.5194/tc-18-4493-2024
© Author(s) 2024. This work is distributed under the Creative Commons Attribution 4.0 License.
Identifying airborne snow metamorphism with stable water isotopes
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- Final revised paper (published on 26 Sep 2024)
- Supplement to the final revised paper
- Preprint (discussion started on 08 Apr 2024)
- Supplement to the preprint
Interactive discussion
Status: closed
Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor
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RC1: 'Comment on egusphere-2024-745', Anonymous Referee #1, 24 May 2024
- AC1: 'Reply on RC1', Sonja Wahl, 28 Jun 2024
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RC2: 'Comment on egusphere-2024-745', Anonymous Referee #2, 28 May 2024
- AC2: 'Reply on RC2', Sonja Wahl, 28 Jun 2024
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RC3: 'Comment on egusphere-2024-745', Anonymous Referee #3, 03 Jun 2024
- AC3: 'Reply on RC3', Sonja Wahl, 28 Jun 2024
Peer review completion
AR – Author's response | RR – Referee report | ED – Editor decision | EF – Editorial file upload
ED: Publish subject to minor revisions (review by editor) (10 Jul 2024) by Lei Geng
AR by Sonja Wahl on behalf of the Authors (11 Jul 2024)
Author's response
Author's tracked changes
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ED: Publish as is (30 Jul 2024) by Lei Geng
AR by Sonja Wahl on behalf of the Authors (08 Aug 2024)
Manuscript
This novel study employs ring wind tunnel experiments combined with stable water isotope analysis to investigate airborne snow particle metamorphism. A main finding is that vapour deposition drives snow particle growth and rounding supported by the observed isotopic fractionation and concurrent SSA decrease. It is inferred that particles and air inside the saltation layer are not in thermal equilibrium as is commonly assumed in blowing snow models. Any mechanical particle fragmentation or coalescence likely play a smaller role in the observed particle size changes as they would not induce isotope fractionation. In turn, the water stable isotopic fractionation induced by airborne snow metamorphism needs to be taken into account when extracting climate information from ice cores, especially at dry and windy locations.
General Comments
This is a carefully designed laboratory experiment, with sound methods and data analysis, and with some interesting conclusions, and should published after addressing minor comments listed below.
While this may be common knowledge a very brief description of isothermal versus temperature gradient snow metamorphism as relevant to this study is warranted in the introduction. In particular to clarify the statement that a particle-air temperature gradient must exist to explain depositional particle growth and isotopic fractionation. The alternative would be vapour fluxes (sublimation/deposition) across an individual particle but also between particles driven by the curvature (Kelvin) effect resulting in local water vapour pressure gradients and super(or sub)-saturation.
These fluxes occur at thermal equilibrium and may also induce isotopic fractionation between solid and the remaining vapour phase. I may be convinced that the bulk isotopic composition of snow remains constant but some further discussion is warranted. To do this I'd suggest to better illustrate the temporal co-evolution of the stable H2O isotopes in both snow and also water vapour. E.g. add a similar figure as Fig.3 showing d18O, d2H and d-exx in the vapour phase. Some of the behaviour seen in experiment No.9 (Fig.4) is puzzling, e.g. O18 in vapour and snow shows correlation, whereas 2H shows anti-correlation (significant?). Was this behaviour observed also in other experiments and is this related to the mentioned non-equilibrium conditions?
Detailed Comments
L145 - Mention here what temp was the wind tunnel set to?
Table 1: Clarify in the caption that DELTA T means change in mean wind tunnel T over the duration of the experiment
L182 - cm3
L337 - Be specific: significant enrichment by how many permil?
L395 - In order to illustrate the concurrent vapour isotopic composition change across all experiments I suggest a similar figure as Fig3. (see above)
L431 - Shouldn't mechanic fragmentation lead to a SSA increase if it was the dominating process?
L441 - Please explain "higher SSA decay rates for isothermal snowpack metamorphism", how much higher? Higher than T-gradient metamorphism? reference?
L448 - Are particles in the saltation layer subject to a different metamorphism regime than those in the suspension layer? Please expand & add any relevant reference
L465 - What about the vapour flux between particles, i.e. sublimation of small snow particles, which may eventually disappear, followed by deposition to larger particles. See comment above.
L528 - Except that particle-to-particle vapour flux can occur also at T-gradient = 0 and RH_ice = 1 due to Kelvin effect (equivalent to isothermal metamorphism I think)
Fig.6 - yes, this is related to the curvature (Kelvin) effect
Conclusions - list here and possibly in the abstract the order of magnitude of the observed isotope fractionation attributed to airborne snow metamorphism in permil, a result relevant for the interpretation of field data.