Articles | Volume 13, issue 9
https://doi.org/10.5194/tc-13-2385-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/tc-13-2385-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
12 Sep 2019
Research article |
| 12 Sep 2019
| 12 Sep 2019
The morphology of ice and liquid brine in an environmental scanning electron microscope: a study of the freezing methods
Environmental Electron Microscopy Group, Institute of Scientific
Instruments of the Czech Academy of Sciences, Brno, Czech Republic
Vilém Neděla
Environmental Electron Microscopy Group, Institute of Scientific
Instruments of the Czech Academy of Sciences, Brno, Czech Republic
Jiří Runštuk
Environmental Electron Microscopy Group, Institute of Scientific
Instruments of the Czech Academy of Sciences, Brno, Czech Republic
Department of Chemistry, Faculty of Science, Masaryk University, Brno, Czech Republic
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Cited
21 citations as recorded by crossref.
- Structural Effects of Gas Hydrate Antiagglomerant Molecules on Interfacial Interparticle Force Interactions S. Hu et al. 10.1021/acs.langmuir.0c02503
- Technical note: Sublimation of frozen CsCl solutions in an environmental scanning electron microscope (ESEM) – determining the number and size of salt particles relevant to sea salt aerosols L. Vetráková et al. 10.5194/acp-23-4463-2023
- CFD Analyses of Density Gradients under Conditions of Supersonic Flow at Low Pressures R. Bayer et al. 10.3390/s24185968
- Using Excimeric Fluorescence to Study How the Cooling Rate Determines the Behavior of Naphthalenes in Freeze-Concentrated Solutions: Vitrification and Crystallization G. Ondrušková et al. 10.1021/acs.jpcb.0c07817
- Physical Characterization of Frozen Aqueous Solutions Containing Sodium Chloride and Humic Acid at Environmentally Relevant Temperatures S. Chakraborty & T. Kahan 10.1021/acsearthspacechem.9b00319
- Partitioning of Crystalline and Amorphous Phases During Freezing of Simulated Enceladus Ocean Fluids M. Fox‐Powell & C. Cousins 10.1029/2020JE006628
- The ice–vapour interface during growth and sublimation M. Cascajo-Castresana et al. 10.5194/acp-21-18629-2021
- Determination of solid-state acidity of lyophilized trehalose containing citrate, phosphate, and histidine buffers using UV/VIS diffuse reflectance and solid-state NMR spectroscopy A. Lay-Fortenbery et al. 10.1016/j.xphs.2024.09.019
- ESEM Methodology for the Study of Ice Samples at Environmentally Relevant Subzero Temperatures: “Subzero ESEM” K. Závacká et al. 10.1017/S1431927621013854
- Photochlorination of Anthracene in Saline Ice under Simulated Solar Light Y. Li et al. 10.3390/w16091237
- Advanced environmental scanning electron microscopy reveals natural surface nano-morphology of condensed mitotic chromosomes in their native state V. Neděla et al. 10.1038/s41598-024-63515-9
- Dynamical in-situ observation of the lyophilization and vacuum-drying processes of a model biopharmaceutical system by an environmental scanning electron microscope Ľ. Vetráková et al. 10.1016/j.ijpharm.2020.119448
- Incorporation of a Morphologically Controlled Ice Grain Boundary into a Microfluidic Device for Size-Selective Separation of Micro/Nanospheres J. Kimijima et al. 10.1021/acs.analchem.3c02330
- Investigating freezing-induced acidity changes in citrate buffers B. Susrisweta et al. 10.1016/j.ijpharm.2023.123211
- Making good’s buffers good for freezing: The acidity changes and their elimination via mixing with sodium phosphate L. Veselý et al. 10.1016/j.ijpharm.2020.120128
- Freezing-induced acidification of sea ice brine L. Veselý et al. 10.1016/j.scitotenv.2024.174194
- Impact of secondary ice in a frozen NaCl freeze-concentrated solution on the extent of methylene blue aggregation L. Veselý et al. 10.1016/j.ijpharm.2023.123691
- Temperature and Concentration Affect Particle Size Upon Sublimation of Saline Ice: Implications for Sea Salt Aerosol Production in Polar Regions K. Závacká et al. 10.1029/2021GL097098
- Acidity and Phase Behavior of Frozen Hydrochloric Acid during Thawing R. Štůsek et al. 10.1021/acs.jpcc.4c04540
- The morphology of ice and liquid brine in an environmental scanning electron microscope: a study of the freezing methods Ľ. Vetráková et al. 10.5194/tc-13-2385-2019
- Vitrification and increase of basicity in between ice Ih crystals in rapidly frozen dilute NaCl aqueous solutions K. Imrichová et al. 10.1063/1.5100852
19 citations as recorded by crossref.
- Structural Effects of Gas Hydrate Antiagglomerant Molecules on Interfacial Interparticle Force Interactions S. Hu et al. 10.1021/acs.langmuir.0c02503
- Technical note: Sublimation of frozen CsCl solutions in an environmental scanning electron microscope (ESEM) – determining the number and size of salt particles relevant to sea salt aerosols L. Vetráková et al. 10.5194/acp-23-4463-2023
- CFD Analyses of Density Gradients under Conditions of Supersonic Flow at Low Pressures R. Bayer et al. 10.3390/s24185968
- Using Excimeric Fluorescence to Study How the Cooling Rate Determines the Behavior of Naphthalenes in Freeze-Concentrated Solutions: Vitrification and Crystallization G. Ondrušková et al. 10.1021/acs.jpcb.0c07817
- Physical Characterization of Frozen Aqueous Solutions Containing Sodium Chloride and Humic Acid at Environmentally Relevant Temperatures S. Chakraborty & T. Kahan 10.1021/acsearthspacechem.9b00319
- Partitioning of Crystalline and Amorphous Phases During Freezing of Simulated Enceladus Ocean Fluids M. Fox‐Powell & C. Cousins 10.1029/2020JE006628
- The ice–vapour interface during growth and sublimation M. Cascajo-Castresana et al. 10.5194/acp-21-18629-2021
- Determination of solid-state acidity of lyophilized trehalose containing citrate, phosphate, and histidine buffers using UV/VIS diffuse reflectance and solid-state NMR spectroscopy A. Lay-Fortenbery et al. 10.1016/j.xphs.2024.09.019
- ESEM Methodology for the Study of Ice Samples at Environmentally Relevant Subzero Temperatures: “Subzero ESEM” K. Závacká et al. 10.1017/S1431927621013854
- Photochlorination of Anthracene in Saline Ice under Simulated Solar Light Y. Li et al. 10.3390/w16091237
- Advanced environmental scanning electron microscopy reveals natural surface nano-morphology of condensed mitotic chromosomes in their native state V. Neděla et al. 10.1038/s41598-024-63515-9
- Dynamical in-situ observation of the lyophilization and vacuum-drying processes of a model biopharmaceutical system by an environmental scanning electron microscope Ľ. Vetráková et al. 10.1016/j.ijpharm.2020.119448
- Incorporation of a Morphologically Controlled Ice Grain Boundary into a Microfluidic Device for Size-Selective Separation of Micro/Nanospheres J. Kimijima et al. 10.1021/acs.analchem.3c02330
- Investigating freezing-induced acidity changes in citrate buffers B. Susrisweta et al. 10.1016/j.ijpharm.2023.123211
- Making good’s buffers good for freezing: The acidity changes and their elimination via mixing with sodium phosphate L. Veselý et al. 10.1016/j.ijpharm.2020.120128
- Freezing-induced acidification of sea ice brine L. Veselý et al. 10.1016/j.scitotenv.2024.174194
- Impact of secondary ice in a frozen NaCl freeze-concentrated solution on the extent of methylene blue aggregation L. Veselý et al. 10.1016/j.ijpharm.2023.123691
- Temperature and Concentration Affect Particle Size Upon Sublimation of Saline Ice: Implications for Sea Salt Aerosol Production in Polar Regions K. Závacká et al. 10.1029/2021GL097098
- Acidity and Phase Behavior of Frozen Hydrochloric Acid during Thawing R. Štůsek et al. 10.1021/acs.jpcc.4c04540
2 citations as recorded by crossref.
- The morphology of ice and liquid brine in an environmental scanning electron microscope: a study of the freezing methods Ľ. Vetráková et al. 10.5194/tc-13-2385-2019
- Vitrification and increase of basicity in between ice Ih crystals in rapidly frozen dilute NaCl aqueous solutions K. Imrichová et al. 10.1063/1.5100852
Latest update: 23 Dec 2024
Short summary
We froze salty solutions to examine where and how the brine is distributed within the ice by using an environmental scanning electron microscope. The structures are highly heterogeneous, consisting of almost pure ice intertwined with brine, which can form lamellae, veins, or pools on the surface. Considering various concentrations and methods for laboratory ice preparation, we determined how the freezing technique influences the microstructure of the brine on and in the ice.
We froze salty solutions to examine where and how the brine is distributed within the ice by...
