Articles | Volume 11, issue 6
https://doi.org/10.5194/tc-11-2439-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/tc-11-2439-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| Highlight paper
| 
03 Nov 2017
Research article | Highlight paper |
| 03 Nov 2017
Methanesulfonic acid (MSA) migration in polar ice: data synthesis and theory
Matthew Osman
CORRESPONDING AUTHOR
Massachusetts Institute of Technology/Woods Hole Oceanographic Institution Joint Program in Oceanography/
Applied Ocean Sciences and Engineering, Woods Hole, MA 02543, USA
Sarah B. Das
Dept. of Geology and Geophysics, Woods Hole Oceanographic Institution, Woods Hole, MA, USA
Olivier Marchal
Dept. of Geology and Geophysics, Woods Hole Oceanographic Institution, Woods Hole, MA, USA
Matthew J. Evans
Dept. of Chemistry, Wheaton College, Wheaton, MA, USA
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Cited
16 citations as recorded by crossref.
- Sea-ice reconstructions from bromine and iodine in ice cores P. Vallelonga et al. 10.1016/j.quascirev.2021.107133
- Effective diffusivity of sulfuric acid in Antarctic ice cores T. Fudge et al. 10.5194/cp-20-297-2024
- Spatial distribution and potential sources of methanesulfonic acid in High Asia glaciers Y. Li et al. 10.1016/j.atmosres.2020.105227
- Industrial-era decline in Arctic methanesulfonic acid is offset by increased biogenic sulfate aerosol U. Jongebloed et al. 10.1073/pnas.2307587120
- Variability of sea salt and methanesulfonate in firn cores from northern Victoria Land, Antarctica: Their links to oceanic and atmospheric condition variability in the Ross Sea S. Ro et al. 10.3389/feart.2022.896470
- An age scale for new climate records from Sherman Island, West Antarctica I. Rowell et al. 10.5194/cp-19-1699-2023
- Examining links between dust deposition and phytoplankton response using ice cores J. Hooper et al. 10.1016/j.aeolia.2018.11.001
- The ST22 chronology for the Skytrain Ice Rise ice core – Part 1: A stratigraphic chronology of the last 2000 years H. Hoffmann et al. 10.5194/cp-18-1831-2022
- Pervasive diffusion of climate signals recorded in ice-vein ionic impurities F. Ng 10.5194/tc-15-1787-2021
- Calibration of Arctic ice core bromine enrichment records for past sea ice reconstructions F. Scoto et al. 10.1016/j.scitotenv.2024.177063
- A Comparison of 36Cl Nuclear Bomb Inputs Deposited in Snow From Vostok and Talos Dome, Antarctica, Using the 36Cl/Cl− ratio S. Pivot et al. 10.1029/2018JD030200
- Investigating halogens and MSA in the Southern Hemisphere: A spatial analysis D. Segato et al. 10.1016/j.atmosenv.2023.120279
- Industrial-era decline in subarctic Atlantic productivity M. Osman et al. 10.1038/s41586-019-1181-8
- Sulfur aerosols in the Arctic, Antarctic, and Tibetan Plateau: Current knowledge and future perspectives Q. Pei et al. 10.1016/j.earscirev.2021.103753
- Spatial and temporal variability of environmental proxies from the top 120 m of two ice cores in Dronning Maud Land (East Antarctica) S. Wauthy et al. 10.5194/essd-16-35-2024
- Ion concentrations in ice wedges: An innovative approach to reconstruct past climate variability Y. Iizuka et al. 10.1016/j.epsl.2019.03.013
16 citations as recorded by crossref.
- Sea-ice reconstructions from bromine and iodine in ice cores P. Vallelonga et al. 10.1016/j.quascirev.2021.107133
- Effective diffusivity of sulfuric acid in Antarctic ice cores T. Fudge et al. 10.5194/cp-20-297-2024
- Spatial distribution and potential sources of methanesulfonic acid in High Asia glaciers Y. Li et al. 10.1016/j.atmosres.2020.105227
- Industrial-era decline in Arctic methanesulfonic acid is offset by increased biogenic sulfate aerosol U. Jongebloed et al. 10.1073/pnas.2307587120
- Variability of sea salt and methanesulfonate in firn cores from northern Victoria Land, Antarctica: Their links to oceanic and atmospheric condition variability in the Ross Sea S. Ro et al. 10.3389/feart.2022.896470
- An age scale for new climate records from Sherman Island, West Antarctica I. Rowell et al. 10.5194/cp-19-1699-2023
- Examining links between dust deposition and phytoplankton response using ice cores J. Hooper et al. 10.1016/j.aeolia.2018.11.001
- The ST22 chronology for the Skytrain Ice Rise ice core – Part 1: A stratigraphic chronology of the last 2000 years H. Hoffmann et al. 10.5194/cp-18-1831-2022
- Pervasive diffusion of climate signals recorded in ice-vein ionic impurities F. Ng 10.5194/tc-15-1787-2021
- Calibration of Arctic ice core bromine enrichment records for past sea ice reconstructions F. Scoto et al. 10.1016/j.scitotenv.2024.177063
- A Comparison of 36Cl Nuclear Bomb Inputs Deposited in Snow From Vostok and Talos Dome, Antarctica, Using the 36Cl/Cl− ratio S. Pivot et al. 10.1029/2018JD030200
- Investigating halogens and MSA in the Southern Hemisphere: A spatial analysis D. Segato et al. 10.1016/j.atmosenv.2023.120279
- Industrial-era decline in subarctic Atlantic productivity M. Osman et al. 10.1038/s41586-019-1181-8
- Sulfur aerosols in the Arctic, Antarctic, and Tibetan Plateau: Current knowledge and future perspectives Q. Pei et al. 10.1016/j.earscirev.2021.103753
- Spatial and temporal variability of environmental proxies from the top 120 m of two ice cores in Dronning Maud Land (East Antarctica) S. Wauthy et al. 10.5194/essd-16-35-2024
- Ion concentrations in ice wedges: An innovative approach to reconstruct past climate variability Y. Iizuka et al. 10.1016/j.epsl.2019.03.013
Latest update: 20 Nov 2024
Short summary
We combine a synthesis of 22 ice core records and a model of soluble impurity transport to investigate the enigmatic, post-depositional migration of methanesulfonic acid in polar ice. Our findings suggest that migration may be universal across coastal regions of Greenland and Antarctica, though it is mitigated at sites with higher accumulation and (or) lower impurity content. Records exhibiting severe migration may still be useful for inferring decadal and lower-frequency climate variability.
We combine a synthesis of 22 ice core records and a model of soluble impurity transport to...
