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  <front>
    <journal-meta><journal-id journal-id-type="publisher">TC</journal-id><journal-title-group>
    <journal-title>The Cryosphere</journal-title>
    <abbrev-journal-title abbrev-type="publisher">TC</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">The Cryosphere</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1994-0424</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/tc-16-1765-2022</article-id><title-group><article-title>Divergence of apparent and intrinsic snow albedo over a season at <?xmltex \hack{\break}?>a
sub-alpine site with implications for remote sensing</article-title><alt-title>Divergence of apparent and intrinsic snow albedo</alt-title>
      </title-group><?xmltex \runningtitle{Divergence of apparent and intrinsic snow albedo}?><?xmltex \runningauthor{E. H. Bair et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Bair</surname><given-names>Edward H.</given-names></name>
          <email>nbair@eri.ucsb.edu</email>
        <ext-link>https://orcid.org/0000-0002-6554-387X</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Dozier</surname><given-names>Jeff</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-8542-431X</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Stern</surname><given-names>Charles</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4">
          <name><surname>LeWinter</surname><given-names>Adam</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5 aff1">
          <name><surname>Rittger</surname><given-names>Karl</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-8733-434X</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff6">
          <name><surname>Savagian</surname><given-names>Alexandria</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Stillinger</surname><given-names>Timbo</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-5250-4495</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4">
          <name><surname>Davis</surname><given-names>Robert E.</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>Earth Research Institute, University of California, Santa Barbara, CA  93106,
USA</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Bren School of Environmental Science &amp; Management, University of
California, Santa Barbara, CA  93106, USA</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Lamont-Doherty Earth Observatory, Palisades, NY 10964, USA </institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>Cold Regions Research and Engineering Laboratory, Hanover, NH 03755, USA</institution>
        </aff>
        <aff id="aff5"><label>5</label><institution>Institute of Arctic and Alpine Research, University of Colorado,
Boulder, Boulder, CO  80309, USA</institution>
        </aff>
        <aff id="aff6"><label>6</label><institution>Bowdoin College, Brunswick, ME  04011, USA</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Edward H. Bair (nbair@eri.ucsb.edu)</corresp></author-notes><pub-date><day>6</day><month>May</month><year>2022</year></pub-date>
      
      <volume>16</volume>
      <issue>5</issue>
      <fpage>1765</fpage><lpage>1778</lpage>
      <history>
        <date date-type="received"><day>22</day><month>November</month><year>2021</year></date>
           <date date-type="rev-request"><day>30</day><month>November</month><year>2021</year></date>
           <date date-type="rev-recd"><day>6</day><month>April</month><year>2022</year></date>
           <date date-type="accepted"><day>13</day><month>April</month><year>2022</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2022 </copyright-statement>
        <copyright-year>2022</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://tc.copernicus.org/articles/.html">This article is available from https://tc.copernicus.org/articles/.html</self-uri><self-uri xlink:href="https://tc.copernicus.org/articles/.pdf">The full text article is available as a PDF file from https://tc.copernicus.org/articles/.pdf</self-uri>
      <abstract><title>Abstract</title>

      <p id="d1e182">Intrinsic albedo is the bihemispherical reflectance independent of effects
of topography or surface roughness. Conversely, the apparent albedo is the
reflected radiation divided by the incident and may be affected by
topography or roughness. For snow, the surface is often rough, and these two
optical quantities have different uses: intrinsic albedo is used in
scattering equations whereas apparent albedo should be used in energy
balance models. Complementing numerous studies devoted to surface roughness
and its effect on snow reflectance, this work analyzes a time series of
intrinsic and apparent snow albedos over a season at a sub-alpine site using
an automated terrestrial laser scanner to map the snow surface topography.
An updated albedo model accounts for shade, and in situ albedo measurements
from a field spectrometer are compared to those from a spaceborne
multispectral sensor. A spectral unmixing approach using a shade endmember
(to address the common problem of unknown surface topography) produces grain
size and impurity solutions; the modeled shade fraction is compared to the
intrinsic and apparent albedo difference. As expected and consistent with
other studies, the results show that intrinsic albedo is consistently
greater than apparent albedo. Both albedos decrease rapidly as ablation
hollows form during melt, combining effects of impurities on the surface and
increasing roughness. Intrinsic broadband albedos average 0.056 greater than
apparent albedos, with the difference being 0.052 in the near infrared or
0.022 if the average (planar) topography is known and corrected. Field
measurements of spectral surface reflectance confirm that multispectral
sensors see the apparent albedo but lack the spectral resolution to
distinguish between darkening from ablation hollows versus low
concentrations of impurities. In contrast, measurements from the field
spectrometer have sufficient resolution to discern darkening from the two
sources. Based on these results, conclusions are as follows: (1) impurity estimates
from multispectral sensors are only reliable for relatively dirty snow with
high snow fraction; (2) a shade endmember must be used in spectral mixture
models, even for in situ spectroscopic measurements; and (3) snow albedo
models should produce apparent albedos by accounting for the shade fraction.
The conclusion re-iterates that albedo is the most practical snow
reflectance quantity for remote sensing.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e194">Snow albedo plays an important role in Earth's climate and hydrology. For
example, a small (0.015 to 0.030) decrease in snow albedo over the Northern
Hemisphere is twice as effective as a doubling of CO<inline-formula><mml:math id="M1" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> at raising global
air temperature   (Hansen and Nazarenko, 2004). Likewise, during the
COVID-19 lockdowns, a cleaner snowpack, presumably from a reduction in
anthropogenic emissions, prevented 6.6 km<inline-formula><mml:math id="M2" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> of snow/ice from melting in
the Indus River basin   (Bair et al., 2021a), more water than is
stored in the largest reservoir in California. Yet, snow albedo is difficult
to measure   (Bair et al., 2018), especially in the mountains where
lighting conditions vary dramatically. To understand Earth's climate and the
effect humans have on it, an understanding of how snow surface topography
affects snow albedo is imperative. The concepts of intrinsic and apparent
albedos form the basis of this study. Intrinsic albedo is the
bihemispherical reflectance (Nicodemus et al., 1977; Schaepman-Strub et
al., 2006) of a substance independent of effects of roughness or topography.
Apparent albedo is the ratio of the reflected divided by the incident radiation
and may incorporate artifacts caused by roughness or topography. Here we use
the term albedo to refer to a broadband albedo, covering the solar spectrum.
Albedos covering a narrower spectral range are denoted with additional
descriptors such as near-infrared albedo. Since the snow surface is rarely
smooth, distinction between apparent and intrinsic albedo is an important
consideration that is often ignored. For example, MODIS measurements of snow
albedo that comprise the National Solar Radiation Database have been found
to be positively biased because they fail to account for surface roughness
(Gueymard et al., 2019). Both albedos should be studied, as
apparent and intrinsic albedos have different uses. An apparent albedo
should be used when modeling energy budgets  (Bair et al., 2016), as
it dictates how much shortwave radiation is absorbed by the surface.
Intrinsic albedos are needed to understand changes in snow properties that
affect albedo, such as changes in grain size and darkening from
light-absorbing particles like soot or dust (Clarke and Noone, 1985;
Jones, 1913; Warren, 2019).</p>
      <p id="d1e215">Most snow albedo models follow approaches developed 4 decades ago, based
on radiative transfer (Warren, 1982). These models provide intrinsic
albedos controlled by illumination angle, water equivalent when snow is
shallow, and grain-scale snow properties, which have included grain size
(Wiscombe and Warren, 1980), grain shape
(Libois et al., 2013), snow structure
(Kaempfer et al., 2007), direct and indirect effects of
light-absorbing particles (Picard et al., 2020; Skiles and Painter,
2019), and vertical heterogeneity  (Zhou et al., 2003). Other efforts
have focused on rapid calculation (Bair et al., 2019; Flanner et al.,
2021; Gardner and Sharp, 2010) and inversion from remotely sensed imagery
(Bair et al., 2021b; Nolin, 2010; Painter et al., 2012a).
Weiser et al. (2016) present a correction for albedometers over
snow where the underlying terrain is unknown, based on modeled or measured
irradiance from nearby well-leveled radiometers, but not accounting for
surface roughness. A shade endmember has been introduced to account for
lighting differences across surfaces    (Adams et al., 1986),
thereby enabling the use of an apparent albedo for quantitative
spectroscopy. These shade endmembers have proven successful when applied to
snow cover mapping (Bair et al., 2021b; Nolin et al., 1993; Painter et
al., 2003; Rosenthal and Dozier, 1996). Yet, the widely used albedo models
cited above do not account for varying illumination within the field of view,
meaning their results can be positively biased.</p>
      <p id="d1e218">Features that affect snow roughness include suncups (ablation hollows),
penitentes, and wind-formed features like ripples, sastrugi, and dunes
(Filhol and Sturm, 2015). Because of their topographic variation in
solar exposure, all of these roughness features can significantly affect
apparent albedo. Matthes (1934) described “suncups” as having
“a honeycombed appearance, the surface being pitted with deep cell-like
hollows”. However, Rhodes et al. (1987) use the term “ablation
hollows” to describe these features as they are not always caused by solar
radiation. Instead Rhodes et al. (1987) find that the presence of
impurities on the snow surface governs the formation of ablation hollows,
growing in direct sunlight for relatively clean snow and decaying in dirty
snow   (Lliboutry, 1964). This hypothesis was confirmed with a field
experiment where an ash-covered snowfield on Mount Olympus from the Mount
Saint Helens eruption was cleared. After 2 weeks, the ash-free area had
developed larger ablation hollows than the rest of the ash-covered snowfield
(Rhodes et al., 1987). Observations of penitentes go back to
Darwin (1845, Ch. XV). Penitentes are columns of snow that point
at the sun and are thought to be sublimation features
(Betterton, 2001). Penitentes can be much larger than ablation
hollows, with measured heights over 2 m   (Lhermitte et al., 2014).
Ripples, sastrugi, and dunes are formed by wind erosion whose orientation
varies with the direction of the prevailing winds    (Filhol and
Sturm, 2015; Seligman, 1936).  Warren et al. (1998) report that
sastrugi can reduce albedo by altering the angle of incidence for direct
solar radiation and by trapping photons through multiple reflections.</p>
      <p id="d1e221">Several studies have attempted to model the reflectance of roughness
features with simple shapes (Carroll, 1982; Leroux and Fily, 1998;
Zhuravleva and Kokhanovsky, 2011), with more recent studies employing ray
tracing of three-dimensional surface models (Larue et al., 2020; Manninen
et al., 2021). A few studies have focused on the surface roughness and the
implications for remote sensing by incorporating multiple viewing geometries
(Corbett and Su, 2015; Kuchiki et al., 2011; Lyapustin et al., 2010;
Nolin and Payne, 2007) or by measuring spatial variability within a
satellite sensor pixel  (Wright et al., 2014). These approaches are
well-suited toward expansive high-latitude snowpacks but ill-suited towards
dynamic midlatitude snowpacks with mixed pixels where the snow cover can
change between satellite overpasses. The consensus in the literature is that
roughness features can lower the snow albedo by up to 0.40, but decreases of
a few percent are more common. To our knowledge, none of these studies have
tracked the snow surface topography throughout a snow season, nor have they
examined the effects of snow surface topography on spectral mixture
analysis.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Approach</title>
<sec id="Ch1.S2.SS1">
  <label>2.1</label><title>Radiometric measurements</title>
      <p id="d1e239">Albedos were measured (Fig. 1) at CUES – Cold
Regions Research and Engineering Laboratory and University of California,
Santa Barbara Energy Site – on Mammoth Mountain, CA, USA
(Bair et al., 2015). To eliminate
darkening from the ground, shadowing from vegetation, and effects from high
zenith angles, only clear days with a deep, optically thick snowpack were
examined. Radiometer measurements were taken at the satellite overpass time
(Sect. 2.3). Uplooking and downlooking Eppley
precision spectral pyranometers (PSPs) with both clear (285–2800 nm) and
near-infrared (700–2800 nm) domes were located on both the fixed and
adjustable arms, providing redundant measurements of the incoming irradiance
in both wavelength regions, and providing measurements of reflected
radiation from both the fixed and adjustable arms. The adjustable arm keeps
its downlooking radiometers about 1 m above the snow surface, whereas the
fixed arm is mounted 8 m above the ground, so its distance from the snow
surface depends on the snow depth. In measuring the reflected radiation, two
artifacts must be minimized. If the downlooking radiometer is too far above
the snow, the field of view is too large, so other, darker objects like the
tower itself and trees, will cause the snow albedo to be too low.
Conversely, if the radiometer and its arm are too close to the snow, they
will cast a shadow that will also cause the albedo to be too low. By
experiment, we found that the combination of these two artifacts is
minimized when the radiometer is <inline-formula><mml:math id="M3" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 m above the snow, so as
the snow depth changes, we maintain the adjustable arm's height at about
that distance.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><?xmltex \currentcnt{1}?><?xmltex \def\figurename{Figure}?><label>Figure 1</label><caption><p id="d1e251">Fixed and adjustable albedo arms at the CRREL UCSB Energy Site (CUES) in the
summer <bold>(a)</bold> and winter <bold>(b)</bold>.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://tc.copernicus.org/articles/16/1765/2022/tc-16-1765-2022-f01.jpg"/>

        </fig>

      <p id="d1e266">The ratio of diffuse to direct irradiance was computed using a Delta-T SPN1
Sunshine pyranometer mounted on the fixed arm, which integrates over a
slightly different spectral band (400–2700 nm) than the PSP clear. Because
of the different response and biases (Habte et al., 2015;
Wilcox and Myers, 2008) arising from issues such as thermal offsets
(Haeffelin et al., 2001), only the diffuse ratio (used
in the terrain correction described in Sect. 2.2)
from the SPN1 was used. The irradiance measured by each PSP was split into
direct and diffuse components using this ratio. Calculations using SMARTS
v2.9.8   (Gueymard, 2019) provide an estimate of the spectral
distribution of irradiance not subject to instrument error. We use the
SMARTS simulations to adjust the measurements of the diffuse fraction from
the SPN1 (400–2700 nm) to account for the diffuse fraction in the irradiance
measurements from the PSPs with clear and near-infrared domes. The accuracy
of an atmospheric radiation model depends on the accuracy of the estimates
of the atmospheric properties, principally aerosols and water vapor. Errors
in field radiometer measurements stem from calibration inaccuracies and
siting of the instrument. The comparison between SMARTS and the measurements
yields <inline-formula><mml:math id="M4" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>≥</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula>.99 for both the PSP and the SPN1
(Fig. 2 and Table 1), suggesting sufficient relative accuracy to make both instruments
suitable for albedo measurement. However, the reflected radiation is
measured by downlooking PSPs – there is no downlooking SPN1 – so we used the
same type of radiometers (PSPs) to measure the irradiance and reflected
solar radiation.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2"><?xmltex \currentcnt{2}?><?xmltex \def\figurename{Figure}?><label>Figure 2</label><caption><p id="d1e287">Measured vs. modeled irradiance at CUES for three broadband sensors: an Eppley
precision spectral pyranometer (PSP) mounted on an adjustable albedometer
arm kept <inline-formula><mml:math id="M5" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 m above the snow surface (PSP clear, adjustable),
a PSP mounted <inline-formula><mml:math id="M6" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 8 m above bare ground (PSP clear, fixed), and
a Delta-K SPN1 Sunshine pyranometer also mounted <inline-formula><mml:math id="M7" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 8 m above
bare ground (SPN1 global, fixed). The differences between the instruments,
particularly at high radiation values, are likely caused by different
thermal responses  (Haeffelin et al., 2001).</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://tc.copernicus.org/articles/16/1765/2022/tc-16-1765-2022-f02.png"/>

        </fig>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1"><?xmltex \currentcnt{1}?><label>Table 1</label><caption><p id="d1e320">Radiometer measurement differences shown in Fig. 2.</p></caption><oasis:table frame="topbot"><?xmltex \begin{scaleboxenv}{.95}[.95]?><oasis:tgroup cols="4">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Name</oasis:entry>
         <oasis:entry colname="col2">RMSD,</oasis:entry>
         <oasis:entry colname="col3">Difference,</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M8" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">W m<inline-formula><mml:math id="M9" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">W m<inline-formula><mml:math id="M10" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">PSP clear, adjustable</oasis:entry>
         <oasis:entry colname="col2">76</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M11" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>56</oasis:entry>
         <oasis:entry colname="col4">0.956</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">PSP clear, fixed</oasis:entry>
         <oasis:entry colname="col2">64</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M12" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>55</oasis:entry>
         <oasis:entry colname="col4">0.988</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SPN1 global, fixed</oasis:entry>
         <oasis:entry colname="col2">35</oasis:entry>
         <oasis:entry colname="col3">22</oasis:entry>
         <oasis:entry colname="col4">0.984</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup><?xmltex \end{scaleboxenv}?></oasis:table></table-wrap>

      <p id="d1e459">Reflected radiation was measured using the downlooking PSPs, in both
broadband (285–2800 nm) and near-infrared (700–2800 nm) wavelengths. We
mounted one pair of PSPs on the adjustable computer-controlled and
self-leveling arm, kept <inline-formula><mml:math id="M13" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 m above the snow surface to
prevent non-snow objects from being seen, and the other pair on the fixed
arm 8 m above the bare ground. To illustrate the effect of non-snow objects
within the downlooking radiometers' fields of view,
Fig. 3 shows a comparison.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><?xmltex \currentcnt{3}?><?xmltex \def\figurename{Figure}?><label>Figure 3</label><caption><p id="d1e471">Reflected radiation, from downlooking radiometers, and snow depth measured
at CUES.</p></caption>
          <?xmltex \igopts{width=384.112205pt}?><graphic xlink:href="https://tc.copernicus.org/articles/16/1765/2022/tc-16-1765-2022-f03.png"/>

        </fig>

      <p id="d1e480">When the snowpack is deep and continuous spatially, the downlooking
radiometers on the adjustable boom have greater values than those on the
fixed arm (Fig. 3, 10–17 May 2021). This condition
occurs because darker non-snow objects are within the radiometers'
fields of view on the fixed arm. Contrast this to the snow-free condition at
the end of May where reflected radiation is the same for the radiometers on
both the fixed arm and adjustable arm. In patchy snow, the opposite occurs;
on 19–20  May 2021, the radiation measured by the nIR PSP on the fixed arm
exceeds that of the clear PSP. This condition occurs because the radiometers
on the fixed boom view additional emerging vegetation with a higher nIR
albedo than snow. Thus, to prevent non-snow objects from contaminating the
snow albedo measurements, only the downlooking radiometers on the adjustable
arm were used to measure reflected radiation.</p>
      <p id="d1e484">Although a radiometer views a hemisphere, the downlooking field of view is
restricted to about <inline-formula><mml:math id="M14" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 150<inline-formula><mml:math id="M15" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> due to
manufacturing constraints     (Wu et al., 2018).  Sailor
et al. (2006) showed that the size of a radiometer's field of view that
accounts for 95 % of the reflected radiation is <inline-formula><mml:math id="M16" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">8.7</mml:mn><mml:mi>h</mml:mi></mml:mrow></mml:math></inline-formula>, where <inline-formula><mml:math id="M17" display="inline"><mml:mi>h</mml:mi></mml:math></inline-formula> is the
height of the radiometer above the surface. The radiometer's height above
the snow surface of <inline-formula><mml:math id="M18" display="inline"><mml:mrow><mml:mi>h</mml:mi><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">1.0</mml:mn></mml:mrow></mml:math></inline-formula> m translates to a footprint
diameter <inline-formula><mml:math id="M19" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> of 8.7 m. In comparison, the downlooking radiometers on the
fixed arm 8 m above bare ground would see a footprint larger than 40 m over
snow with 1 m depth. To our knowledge, CUES is the only site where snow
albedo is measured using an adjustable albedo arm. Given such a large
footprint, an examination of published images of tower arms at other sites
where snow albedo is measured (Elder et al., 2009; Landry et al., 2014;
Lejeune et al., 2019; Lhermitte et al., 2014) shows non-snow objects within
the downlooking radiometer's field of view at every site.</p>
</sec>
<sec id="Ch1.S2.SS2">
  <label>2.2</label><title>Surface topography and corrections</title>
      <p id="d1e550">A Riegl VZ-400 laser scanner automatically scanned the snow surface every
hour during the 2021 water year. Point clouds were converted to surfaces as
follows. Noise was removed using a filter  (Rusu et al.,
2008), and additional days with blowing snow were manually removed because
the moving particles obscure the snow surface  (Bair et
al., 2012). The adjustable albedometer arm was removed from the point clouds
using a morphological filter  (Pingel et al., 2013). Point
clouds were converted to surfaces with 1 cm spatial resolution using
bilinear interpolation. A radial mask was applied to the surface to simulate
the footprint seen by the downlooking PSP. Slope and aspect were computed
for a plane fit to the surface. The rough surface combines with the local
illumination angle to affect the apparent snow albedo.</p>
      <p id="d1e553">Four broadband albedos were computed. An uncorrected apparent albedo is
computed as
            <disp-formula id="Ch1.E1" content-type="numbered"><label>1</label><mml:math id="M20" display="block"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">uncorrected</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mo>↑</mml:mo></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi>I</mml:mi><mml:mo>↓</mml:mo></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M21" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mo>↑</mml:mo></mml:msub></mml:mrow></mml:math></inline-formula> is the reflected radiation measured by the downlooking
PSP, and <inline-formula><mml:math id="M22" display="inline"><mml:mrow><mml:msub><mml:mi>I</mml:mi><mml:mo>↓</mml:mo></mml:msub></mml:mrow></mml:math></inline-formula> is the irradiance measured by the uplooking PSP.
An albedo with a plane fit to the surface built from the point cloud is
computed as
            <disp-formula id="Ch1.E2" content-type="numbered"><label>2</label><mml:math id="M23" display="block"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">planar</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mo>↑</mml:mo></mml:msub></mml:mrow><mml:mrow><mml:mi>c</mml:mi><mml:msub><mml:mi>B</mml:mi><mml:mo>↓</mml:mo></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mo>↓</mml:mo></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M24" display="inline"><mml:mrow><mml:mi>c</mml:mi><mml:mo>=</mml:mo><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub><mml:mo>/</mml:mo><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is a
correction factor of a sloped to a level surface. <inline-formula><mml:math id="M25" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the
illumination angle for the plane, <inline-formula><mml:math id="M26" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is the solar zenith angle
for a level surface, <inline-formula><mml:math id="M27" display="inline"><mml:mrow><mml:msub><mml:mi>B</mml:mi><mml:mo>↓</mml:mo></mml:msub></mml:mrow></mml:math></inline-formula> is the direct irradiance, and
<inline-formula><mml:math id="M28" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mo>↓</mml:mo></mml:msub></mml:mrow></mml:math></inline-formula> is the diffuse irradiance. This planar correction has been
applied in previous work (Bair et al., 2018; Painter et al., 2012b).
Because the ratio <inline-formula><mml:math id="M29" display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula> is in the denominator of Eq. (2),
<inline-formula><mml:math id="M30" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">planar</mml:mi></mml:msub><mml:mo>&gt;</mml:mo><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">uncorrected</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> when <inline-formula><mml:math id="M31" display="inline"><mml:mrow><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub><mml:mo>&lt;</mml:mo><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> and equal when the angles are equal, less otherwise.</p>
      <p id="d1e764">An albedo with a spatial correction to account for the rough surface is
computed by considering the effects for a generic point on the rough surface
and then averaging those effects over the downlooking radiometer's
field of view, i.e., a circle with 8.7 m diameter. Every point on the
surface has slope <inline-formula><mml:math id="M32" display="inline"><mml:mi>S</mml:mi></mml:math></inline-formula> and aspect <inline-formula><mml:math id="M33" display="inline"><mml:mi>A</mml:mi></mml:math></inline-formula>, and <inline-formula><mml:math id="M34" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ϕ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is the solar azimuth. The
cosine of the illumination angle at each point is
            <disp-formula id="Ch1.E3" content-type="numbered"><label>3</label><mml:math id="M35" display="block"><mml:mrow><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mi mathvariant="normal">max</mml:mi><mml:mfenced close="]" open="["><mml:mrow><mml:mn mathvariant="normal">0</mml:mn><mml:mo>,</mml:mo><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mi>cos⁡</mml:mi><mml:mi>S</mml:mi><mml:mo>+</mml:mo><mml:mi>sin⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mi>sin⁡</mml:mi><mml:mi>S</mml:mi><mml:mi>cos⁡</mml:mi><mml:mfenced close=")" open="("><mml:mrow><mml:msub><mml:mi mathvariant="italic">ϕ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>-</mml:mo><mml:mi>A</mml:mi></mml:mrow></mml:mfenced></mml:mrow></mml:mfenced><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula></p>
      <p id="d1e854">The use of the max function sets the value of <inline-formula><mml:math id="M36" display="inline"><mml:mrow><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> to zero on
self-shaded slopes, when otherwise the cosine would be negative. In addition
to the slope affecting the magnitude of the irradiance, local horizons
formed by neighboring points, in or out of the same ablation hollow, affect
the illumination in two ways: (1) a neighboring high point might shade a
slope that would otherwise be illuminated, and (2) the set of horizons in all
directions partly obstructs the overlying hemisphere. We define the view
factor <inline-formula><mml:math id="M37" display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">Ω</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> as the fraction of the hemisphere that is open
to the sky; a completely unobstructed surface has a view factor
<inline-formula><mml:math id="M38" display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">Ω</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula>. Dozier (2022) describes methods to rapidly
compute the horizons and the view factor.</p>
      <p id="d1e897">Considering the albedo of a rough snow surface involves multiple
reflections. Over a range of wavelengths, the spectral distribution changes
with each reflection. Therefore, the initial approach to model this effect
uses monochromatic radiation, with <inline-formula><mml:math id="M39" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula> to indicate a spectral albedo,
omitting a wavelength identifier unless necessary. Setting <inline-formula><mml:math id="M40" display="inline"><mml:mrow><mml:msub><mml:mi>F</mml:mi><mml:mi mathvariant="normal">dif</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> as the
fraction of the spectral irradiance that is diffuse and setting the value of
the initial irradiance on a horizontal surface to <inline-formula><mml:math id="M41" display="inline"><mml:mi>I</mml:mi></mml:math></inline-formula>, the “spatial” spectral
radiation that initially escapes into the overlying hemisphere without being
re-reflected is
            <disp-formula id="Ch1.E4" content-type="numbered"><label>4</label><mml:math id="M42" display="block"><mml:mrow><?xmltex \hack{\hbox\bgroup\fontsize{7.5}{7.5}\selectfont$\displaystyle}?><mml:mtable rowspacing="0.2ex" class="split" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">esc</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mn mathvariant="normal">0</mml:mn></mml:mfenced></mml:mrow></mml:msubsup><mml:mo>=</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mspace width="0.25em" linebreak="nobreak"/><mml:msub><mml:mi mathvariant="normal">IV</mml:mi><mml:mi mathvariant="normal">Ω</mml:mi></mml:msub><mml:mfenced open="[" close="]"><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mfenced open="(" close=")"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi>F</mml:mi><mml:mi mathvariant="normal">dif</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:msubsup><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi><mml:mrow><mml:mo>(</mml:mo><mml:mtext>direct</mml:mtext><mml:mo>)</mml:mo></mml:mrow></mml:msubsup><mml:mo>+</mml:mo><mml:msub><mml:mi>F</mml:mi><mml:mi mathvariant="normal">dif</mml:mi></mml:msub><mml:msubsup><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi><mml:mrow><mml:mo>(</mml:mo><mml:mtext>diffuse</mml:mtext><mml:mo>)</mml:mo></mml:mrow></mml:msubsup><mml:mo>+</mml:mo><mml:mfenced close=")" open="("><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">Ω</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:msup><mml:mfenced open="(" close=")"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi><mml:mrow><mml:mo>(</mml:mo><mml:mtext>diffuse</mml:mtext><mml:mo>)</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:mfenced><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:mfenced></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><?xmltex \hack{\hspace{1.5cm}}?><mml:mtext mathvariant="normal">directly reflected</mml:mtext><?xmltex \hack{\hspace{1.5cm}}?><mml:mtext mathvariant="normal">diffusely reflected</mml:mtext></mml:mtd></mml:mtr></mml:mtable><?xmltex \hack{$\egroup}?><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          with <inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> as the intrinsic spectral albedo on a level, smooth
surface unaffected by topography; the superscripts designate the albedo to
direct vs. diffuse irradiance. The right-hand term inside the brackets
accounts for reflected radiation within a point's field of view impinging on
the point. The direct and diffuse spectral albedos of snow differ slightly
(Wiscombe and Warren, 1980); the major difference in the
broadband values lies in the different spectral distributions of the direct
and diffuse irradiance. Generally, <inline-formula><mml:math id="M44" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi><mml:mtext>(diffuse)</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula> will be larger because the diffuse irradiance more heavily
concentrates in the wavelengths where snow is brightest.</p>
      <p id="d1e1087">Not all the initially reflected radiation escapes into the overlying
hemisphere. Instead, some of it re-reflects and eventually escapes or is
trapped (Warren et al., 1998) by the roughness. The re-reflected
radiation that does not escape is subject to possible internal reflection,
its initial value being
            <disp-formula id="Ch1.E5" content-type="numbered"><label>5</label><mml:math id="M45" display="block"><mml:mrow><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">internal</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mn mathvariant="normal">0</mml:mn></mml:mfenced></mml:mrow></mml:msubsup><mml:mo>=</mml:mo><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">esc</mml:mi><mml:mrow><mml:mfenced open="(" close=")"><mml:mn mathvariant="normal">0</mml:mn></mml:mfenced></mml:mrow></mml:msubsup><mml:mfenced open="(" close=")"><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">Ω</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">Ω</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle></mml:mfenced><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula></p>
      <p id="d1e1136">To account for multiple reflections, at each reflection the value of the
incident radiation is multiplied by the fraction <inline-formula><mml:math id="M46" display="inline"><mml:mrow><mml:mfenced open="(" close=")"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">Ω</mml:mi></mml:msub></mml:mrow></mml:mfenced></mml:mrow></mml:math></inline-formula> that accounts for the reflection remaining in the ablation
hollow, the fraction <inline-formula><mml:math id="M47" display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">Ω</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> that escapes, and the spectral
albedo. The albedo of the re-reflected radiation, <inline-formula><mml:math id="M48" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi><mml:mrow><mml:mfenced open="(" close=")"><mml:mtext>RR</mml:mtext></mml:mfenced></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula>, is biased toward the wavelengths where
snow is brightest. An order-of-scattering approach to the multiple
reflections lets some reflected radiation escape at each iteration <inline-formula><mml:math id="M49" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula>, and some
remains available for re-reflection:
            <disp-formula id="Ch1.E6" content-type="numbered"><label>6</label><mml:math id="M50" display="block"><mml:mtable class="split" rowspacing="0.2ex" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd><mml:mrow><mml:mi mathvariant="normal">escaped</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">esc</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mi>n</mml:mi></mml:mfenced></mml:mrow></mml:msubsup></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>=</mml:mo><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">internal</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mrow><mml:mi>n</mml:mi><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:mfenced></mml:mrow></mml:msubsup><mml:msubsup><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mtext>diffuse</mml:mtext></mml:mfenced></mml:mrow></mml:msubsup><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">Ω</mml:mi></mml:msub></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd><mml:mrow><mml:mi mathvariant="normal">remaining</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">internal</mml:mi><mml:mrow><mml:mfenced open="(" close=")"><mml:mi>n</mml:mi></mml:mfenced></mml:mrow></mml:msubsup></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>=</mml:mo><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">internal</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mrow><mml:mi>n</mml:mi><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:mfenced></mml:mrow></mml:msubsup><mml:msubsup><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mtext>diffuse</mml:mtext></mml:mfenced></mml:mrow></mml:msubsup><mml:mfenced close=")" open="("><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">Ω</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:mo>.</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:math></disp-formula></p>
      <p id="d1e1296">This series converges in a half dozen iterations because
<inline-formula><mml:math id="M51" display="inline"><mml:mrow><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">internal</mml:mi><mml:mrow><mml:mfenced open="(" close=")"><mml:mi>n</mml:mi></mml:mfenced></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> declines in proportion to <inline-formula><mml:math id="M52" display="inline"><mml:mrow><mml:msup><mml:mfenced open="(" close=")"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">Ω</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:mi>n</mml:mi></mml:msup></mml:mrow></mml:math></inline-formula>. The spatial spectral albedo <inline-formula><mml:math id="M53" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">spatial</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mo>∑</mml:mo><mml:msub><mml:mi>I</mml:mi><mml:mi mathvariant="normal">esc</mml:mi></mml:msub><mml:mo>/</mml:mo><mml:mi>I</mml:mi></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d1e1358">To adapt Eqs. (4) through (6) to compare modeled and measured albedo
integrated over a range of wavelengths – for example the broadband and
near-infrared albedos described in Sect. 2.1 – <inline-formula><mml:math id="M54" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> cannot simply be replaced
with <inline-formula><mml:math id="M55" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, because wavelength-integrated albedo depends on
the convolution of the spectral albedo with spectral distribution of the
irradiance. Including the spectral identifier <inline-formula><mml:math id="M56" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula>, the wavelength
integrated albedo is
            <disp-formula id="Ch1.E7" content-type="numbered"><label>7</label><mml:math id="M57" display="block"><mml:mrow><mml:mi mathvariant="italic">α</mml:mi><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:munderover><mml:mo movablelimits="false">∫</mml:mo><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:munderover><mml:mi mathvariant="italic">ρ</mml:mi><mml:mfenced close=")" open="("><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced><mml:mi>I</mml:mi><mml:mfenced open="(" close=")"><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced><mml:mi mathvariant="normal">d</mml:mi><mml:mi mathvariant="italic">λ</mml:mi></mml:mrow><mml:mrow><mml:munderover><mml:mo movablelimits="false">∫</mml:mo><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:munderover><mml:mi>I</mml:mi><mml:mfenced open="(" close=")"><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced><mml:mi mathvariant="normal">d</mml:mi><mml:mi mathvariant="italic">λ</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M58" display="inline"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mfenced close=")" open="("><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced></mml:mrow></mml:math></inline-formula> varies with wavelength, so <inline-formula><mml:math id="M59" display="inline"><mml:mrow><mml:mi mathvariant="italic">α</mml:mi><mml:mo>×</mml:mo><mml:mi>I</mml:mi></mml:mrow></mml:math></inline-formula> has a different spectral distribution than <inline-formula><mml:math id="M60" display="inline"><mml:mi>I</mml:mi></mml:math></inline-formula> itself. That
distribution is weighted toward the wavelengths where <inline-formula><mml:math id="M61" display="inline"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mfenced open="(" close=")"><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced></mml:mrow></mml:math></inline-formula> is larger, so each reflection causes <inline-formula><mml:math id="M62" display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula> to increase even
though <inline-formula><mml:math id="M63" display="inline"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mfenced open="(" close=")"><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced></mml:mrow></mml:math></inline-formula> does not change. To address this
problem, we derive an empirical function to estimate intrinsic broadband and
near-infrared albedos at step <inline-formula><mml:math id="M64" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula>. In Eqs. (4) through
(6), <inline-formula><mml:math id="M65" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is replaced with <inline-formula><mml:math id="M66" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi><mml:mrow><mml:mfenced open="(" close=")"><mml:mi>n</mml:mi></mml:mfenced></mml:mrow></mml:msubsup><mml:mo>=</mml:mo><mml:mi>f</mml:mi><mml:mfenced open="(" close=")"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mn mathvariant="normal">0</mml:mn></mml:mfenced></mml:mrow></mml:msubsup><mml:mo>,</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi>n</mml:mi></mml:mrow></mml:mfenced></mml:mrow></mml:math></inline-formula>. <inline-formula><mml:math id="M67" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">spatial</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is modeled at every point in
each day's topographic grid. For each day, the mean of those values,
<inline-formula><mml:math id="M68" display="inline"><mml:mover accent="true"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">spatial</mml:mi></mml:msub></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula>, over the field of view of the downlooking
radiometer is equivalent to the measured <inline-formula><mml:math id="M69" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">uncorrected</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, so
comparing the model to the measurement enables solving for the intrinsic
wavelength-integrated snow albedo <inline-formula><mml:math id="M70" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi><mml:mrow><mml:mfenced open="(" close=")"><mml:mn mathvariant="normal">0</mml:mn></mml:mfenced></mml:mrow></mml:msubsup><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d1e1631">To create <inline-formula><mml:math id="M71" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mfenced close=")" open="("><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi><mml:mrow><mml:mfenced open="(" close=")"><mml:mn mathvariant="normal">0</mml:mn></mml:mfenced></mml:mrow></mml:msubsup><mml:mo>,</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi>n</mml:mi></mml:mrow></mml:mfenced></mml:mrow></mml:math></inline-formula>, we generated solar irradiance spectra using SMARTS
(Gueymard, 2019) over observed solar zenith angles, 23
to 63<inline-formula><mml:math id="M72" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>. We modeled spectral snow albedo (Warren, 1982) over
the range of zenith angles, snow grain effective radii from 50 to
1000 <inline-formula><mml:math id="M73" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>, and mass concentrations of dust from <inline-formula><mml:math id="M74" display="inline"><mml:mrow><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">8</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> to
<inline-formula><mml:math id="M75" display="inline"><mml:mrow><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> (i.e., 10 ng g<inline-formula><mml:math id="M76" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> to 1 g kg<inline-formula><mml:math id="M77" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>), assuming an effective dust radius of
3 <inline-formula><mml:math id="M78" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>, comparable to measured values, and dust optical properties from
measurements by  Skiles et al. (2017) from the San Juan Mountains.
This simulation thus covered spectral albedo ranges of clean to dirty snow
with fine to coarse grains. The SMARTS calculations also enabled
transformation of the diffuse fraction measured by the SPN1 to the
wavelength ranges of the broadband and near-infrared PSP radiometers. Equation (4), without the <inline-formula><mml:math id="M79" display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">Ω</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> term, was
applied and spectral albedos were multiplied by the spectral irradiance.
Defining <inline-formula><mml:math id="M80" display="inline"><mml:mi>I</mml:mi></mml:math></inline-formula> as spectral radiation and <inline-formula><mml:math id="M81" display="inline"><mml:mi>E</mml:mi></mml:math></inline-formula> as wavelength-integrated radiation,
initial values are
            <disp-formula id="Ch1.E8" content-type="numbered"><label>8</label><mml:math id="M82" display="block"><mml:mtable rowspacing="0.2ex" class="split" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd><mml:mrow><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">reflected</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mn mathvariant="normal">0</mml:mn></mml:mfenced></mml:mrow></mml:msubsup><mml:mfenced open="(" close=")"><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>=</mml:mo><mml:msub><mml:mi>I</mml:mi><mml:mo>↓</mml:mo></mml:msub><mml:mfenced open="(" close=")"><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced><mml:mfenced close="" open="{"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">direct</mml:mi></mml:msub><mml:mfenced open="(" close=")"><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced><mml:mfenced open="[" close="]"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi>F</mml:mi><mml:mi mathvariant="normal">dif</mml:mi></mml:msub><mml:mfenced close=")" open="("><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced></mml:mrow></mml:mfenced></mml:mrow></mml:mfenced></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mfenced open="" close="}"><mml:mrow><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">diffuse</mml:mi></mml:msub><mml:mfenced close=")" open="("><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced><mml:msub><mml:mi>F</mml:mi><mml:mi mathvariant="normal">dif</mml:mi></mml:msub><mml:mfenced open="(" close=")"><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced></mml:mrow></mml:mfenced></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd><mml:mrow><mml:msubsup><mml:mi>E</mml:mi><mml:mi mathvariant="normal">reflected</mml:mi><mml:mrow><mml:mfenced open="(" close=")"><mml:mn mathvariant="normal">0</mml:mn></mml:mfenced></mml:mrow></mml:msubsup></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>=</mml:mo><mml:munderover><mml:mo movablelimits="false">∫</mml:mo><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:munderover><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">reflected</mml:mi><mml:mrow><mml:mfenced open="(" close=")"><mml:mn mathvariant="normal">0</mml:mn></mml:mfenced></mml:mrow></mml:msubsup><mml:mfenced close=")" open="("><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced><mml:mi mathvariant="normal">d</mml:mi><mml:mi mathvariant="italic">λ</mml:mi></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd><mml:mrow><mml:msup><mml:mi mathvariant="italic">α</mml:mi><mml:mrow><mml:mfenced open="(" close=")"><mml:mn mathvariant="normal">0</mml:mn></mml:mfenced></mml:mrow></mml:msup></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>=</mml:mo><mml:msubsup><mml:mi>E</mml:mi><mml:mi mathvariant="normal">reflected</mml:mi><mml:mrow><mml:mfenced open="(" close=")"><mml:mn mathvariant="normal">0</mml:mn></mml:mfenced></mml:mrow></mml:msubsup><mml:mo>/</mml:mo><mml:munderover><mml:mo movablelimits="false">∫</mml:mo><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:munderover><mml:msub><mml:mi>I</mml:mi><mml:mo>↓</mml:mo></mml:msub><mml:mfenced open="(" close=")"><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced><mml:mi mathvariant="normal">d</mml:mi><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:math></disp-formula>
          then at iteration, the value of <inline-formula><mml:math id="M83" display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula> increases in the following
way (Fig. 4). Note that <inline-formula><mml:math id="M84" display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">Ω</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is
omitted from these iterations, because the interest lies in the change in
wavelength-integrated albedo, not in the escaping radiation at each
reflection. Moreover, all the radiation in the subsequent reflections is
diffuse,<?xmltex \hack{\newpage}?>
            <disp-formula id="Ch1.E9" content-type="numbered"><label>9</label><mml:math id="M85" display="block"><mml:mtable rowspacing="0.2ex" class="split" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd><mml:mrow><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">reflected</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mi>n</mml:mi></mml:mfenced></mml:mrow></mml:msubsup><mml:mfenced open="(" close=")"><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>=</mml:mo><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">reflected</mml:mi><mml:mrow><mml:mfenced open="(" close=")"><mml:mrow><mml:mi>n</mml:mi><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:mfenced></mml:mrow></mml:msubsup><mml:mfenced close=")" open="("><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="normal">diffuse</mml:mi></mml:msub><mml:mfenced open="(" close=")"><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd><mml:mrow><mml:msubsup><mml:mi>E</mml:mi><mml:mi mathvariant="normal">reflected</mml:mi><mml:mrow><mml:mfenced open="(" close=")"><mml:mi>n</mml:mi></mml:mfenced></mml:mrow></mml:msubsup></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>=</mml:mo><mml:munderover><mml:mo movablelimits="false">∫</mml:mo><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:munderover><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">reflected</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mi>n</mml:mi></mml:mfenced></mml:mrow></mml:msubsup><mml:mfenced open="(" close=")"><mml:mi mathvariant="italic">λ</mml:mi></mml:mfenced><mml:mi mathvariant="normal">d</mml:mi><mml:mi mathvariant="italic">λ</mml:mi></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd><mml:mrow><mml:msup><mml:mi mathvariant="italic">α</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mi>n</mml:mi></mml:mfenced></mml:mrow></mml:msup></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>=</mml:mo><mml:msubsup><mml:mi>E</mml:mi><mml:mi mathvariant="normal">reflected</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mi>n</mml:mi></mml:mfenced></mml:mrow></mml:msubsup><mml:mo>/</mml:mo><mml:msubsup><mml:mi>E</mml:mi><mml:mi mathvariant="normal">reflected</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mrow><mml:mi>n</mml:mi><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:mfenced></mml:mrow></mml:msubsup><mml:mo>.</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:math></disp-formula></p>
      <p id="d1e2106">The assumption of a Lambertian surface versus the use of directional
quantities differs in the snow literature. In this study, a Lambertian
assumption is used, justified with the use of nadir-looking instruments with
measurements taken midday and with the lack of directional knowledge of the
re-reflected radiation. Further, as surface roughness increases, so does
backscattering      (Manninen et al., 2021), thereby
counteracting some of the forward scattering in snow. Finally, ablation
hollows, the largest surface roughness features observed, have no preferred
orientation, unlike sastrugi or penitentes. These factors reduce the
importance of angular effects    (Painter and Dozier, 2004; Warren
et al., 1998). Further, a goal of this study is to compare in situ with
remotely sensed snow measurements. At the remote sensing scale, the average
or sub-pixel-scale snow surface topography is usually unknown, thus the
directional factors cannot be accurately computed. Although the snow-free
topography may be known, the snow surface above can differ markedly,
especially at fine (e.g., meter) scales.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><?xmltex \currentcnt{4}?><?xmltex \def\figurename{Figure}?><label>Figure 4</label><caption><p id="d1e2111">Increase in broadband albedo caused by internal reflections within an
ablation hollow. The <inline-formula><mml:math id="M86" display="inline"><mml:mi>x</mml:mi></mml:math></inline-formula> axis shows the initial albedo from Eq. (8) covering a range of grain sizes and
concentration of light-absorbing particles, and the <inline-formula><mml:math id="M87" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> axis shows the number
of reflections from 1 to 10. The intensity shows the resulting increase in
albedo from Eq. (9).</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://tc.copernicus.org/articles/16/1765/2022/tc-16-1765-2022-f04.png"/>

        </fig>

</sec>
<sec id="Ch1.S2.SS3">
  <label>2.3</label><title>Remotely sensed measurements</title>
      <p id="d1e2142">Bottom-of-atmosphere (surface, Level 2A) reflectance estimates from the
Sentinel-2A/B (S2) multispectral instrument were obtained. Nine bands (bands
2–7, 8a, and 11–12) were used with a spatial resolution of 20 m. To convert
the narrow band surface reflectance estimates to broadband albedo,
coefficients for snow-free and snow-covered surfaces, derived from radiative
transfer simulations were used    (Table 2 in Li et al., 2018). This
surface reflectance product was processed using the Snow Property Inversion
from Remote Sensing model (SPIReS, Bair et al., 2021b) to
obtain fractional snow-covered area and surface properties. Broadband albedo
uncertainty from S2 (0.036) was estimated based on maximum differences
between acquisitions for a bare-ground target pixel, consisting of no trees,
bare soil, and small shrubs. This uncertainty is close to a validation
effort of S2 over dark and bright soils that showed band-wise errors up to
0.040 (Gascon et al., 2017).</p>
      <p id="d1e2145">The target pixel on Mammoth Mountain for comparison to the snow measured at
CUES was selected because it is near CUES (2.2 km away), is at a similar
elevation (CUES at 2916 m vs. target at 3041 m), has a slope of zero across
the 20 m pixel, and was nearly 100 % snow-covered for 6 months, from
mid-November through mid-May. It would have been preferable to select a
pixel immediately adjacent to CUES, but none met those criteria. Thus, it is
assumed that snow conditions and thus albedo were similar at the two sites,
at least within the uncertainty of the remotely sensed and in situ broadband
measurements. The mean local solar time for overpass from Sentinel-2 is
10:30, leading to times at CUES of 18:39 to 18:47 UTC. Thus, the
corresponding in situ albedo measurements described in Sect. 2.2 were taken within that window of time.</p>
</sec>
<sec id="Ch1.S2.SS4">
  <label>2.4</label><title>Shade endmember simulations</title>
      <p id="d1e2156">Intrinsic snow albedo was modeled using a two-stream radiative transfer
approximation coupled with Mie scattering as described in Sect. 2.2. Of note is that dust is assumed to be the
predominant pollutant, based on chemical analyses from CUES
(Sterle et al., 2013). Other endmembers used were an empirical
snow-free background (for the remotely sensed solutions) and an ideal shade
endmember with an albedo of zero across all bands    (Adams et al.,
1986).</p>
</sec>
<sec id="Ch1.S2.SS5">
  <label>2.5</label><title>In situ spectroscopy</title>
      <p id="d1e2168">A Spectra Vista HR-1024i was used with a Spectralon panel with 0.99 albedo
over the 250–2500 nm wavelength range for irradiance measurement. The lens
used has a 4<inline-formula><mml:math id="M88" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> field of view and was held about 1.5 m above
the snow surface, leading to a footprint of about 5 cm. Measurements were
made on days with clear skies, and the spectrometer was held plumb rather
than slope parallel. Noise was smoothed using an 11-point sliding window fit
with a local regression using a first-degree polynomial.</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Results and discussion</title>
      <p id="d1e2189">An example of ablation hollows mapped by the laser scanner is shown in
Fig. 5a, b. In situ albedos from CUES from the water year 2021 are shown in Fig. 6:
uncorrected <inline-formula><mml:math id="M89" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">uncorrected</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, planar-corrected <inline-formula><mml:math id="M90" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">planar</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>,
and intrinsic <inline-formula><mml:math id="M91" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> are based on the spatial calculations.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5" specific-use="star"><?xmltex \currentcnt{5}?><?xmltex \def\figurename{Figure}?><label>Figure 5</label><caption><p id="d1e2227">Snow with ablation hollows on 12 May 2021 at 10:45:00 PST. <bold>(a)</bold> Corresponding
apparent albedo seen by the radiometer. <bold>(b)</bold> The uncorrected albedo is 0.54
(mean of what is shown). The albedo with a planar correction is 0.55, and the
intrinsic albedo based on the spatial analysis is 0.61.</p></caption>
        <?xmltex \igopts{width=355.659449pt}?><graphic xlink:href="https://tc.copernicus.org/articles/16/1765/2022/tc-16-1765-2022-f05.png"/>

      </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6" specific-use="star"><?xmltex \currentcnt{6}?><?xmltex \def\figurename{Figure}?><label>Figure 6</label><caption><p id="d1e2244">In situ albedos on Mammoth Mountain in the water year 2021. Shown are
the uncorrected, planar-corrected, and intrinsic albedos for broadband <bold>(a)</bold>
and near-infrared <bold>(b)</bold> wavelengths. Planar correction involved fitting a
plane to the snow surface and using the solar illumination angle on that
plane compared to that on a flat surface. Intrinsic albedos are derived from
analyzing the view factors and illumination angles on the rough surface and
using Eqs. (4) through
(9) to solve for <inline-formula><mml:math id="M92" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. The
difference between the intrinsic and planar albedos is shown in <bold>(c)</bold>.</p></caption>
        <?xmltex \igopts{width=384.112205pt}?><graphic xlink:href="https://tc.copernicus.org/articles/16/1765/2022/tc-16-1765-2022-f06.png"/>

      </fig>

      <p id="d1e2274">In situ and remotely sensed albedos on Mammoth Mountain from the water year 2021
are shown in Fig. 7. An unadjusted (i.e., not
adjusted for shade or trees) fractional snow-covered area (<inline-formula><mml:math id="M93" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">sca</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), estimated
with SPIReS (Bair et al., 2021b), from a nearby target pixel is
also shown. The high <inline-formula><mml:math id="M94" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">sca</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> confirms that mixed (snow and non-snow) pixel
effects are minimal. An estimate of the broadband pixel albedo measured by
Sentinel 2A/B (S2) is also shown, as described in Sect. 2.3. Finally, the surface roughness (in degrees,
divided by 30 for scale) is plotted, also described in Sect. 2.2.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7" specific-use="star"><?xmltex \currentcnt{7}?><?xmltex \def\figurename{Figure}?><label>Figure 7</label><caption><p id="d1e2301">In situ and remotely sensed snow on Mammoth Mountain, water year 2021. Shown
are uncorrected albedos measured at CUES, with the error bars (0.020) based
on stated values from the manufacturer. The unadjusted (i.e., not adjusted
for shade or trees) fractional snow-covered area (<inline-formula><mml:math id="M95" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">sca</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) from the Snow
Property Inversion from Remote Sensing (SPIReS) model is shown. An estimate
of the broadband pixel albedo measured by Sentinel 2A/B (S2) is shown. The
error bar height (0.036) is the maximum difference in the bare-ground (no
snow) reflectance.</p></caption>
        <?xmltex \igopts{width=355.659449pt}?><graphic xlink:href="https://tc.copernicus.org/articles/16/1765/2022/tc-16-1765-2022-f07.png"/>

      </fig>

      <p id="d1e2321">In Fig. 6, the intrinsic albedo is usually greater
than the uncorrected or planar-corrected albedo, agreeing with previous work
over more limited timespans (e.g., Larue et al., 2020; Lhermitte et al.,
2014; Manninen et al., 2021). The largest planar corrections appear in
winter, when the planar sloped surface facing away from the sun receives
the lowest irradiance relative to a flat surface. The spatial corrections
are more nuanced because they involve the solar geometry and the roughness
of the surface. As the days get longer in the spring, the solar zenith angle
is smaller, but the rougher surface causes more variability in the view
factor and illumination on each slope.</p>
      <p id="d1e2324">Warren et al. (1998) posited two mechanisms for albedo reduction
caused by surface roughness: reduction of effective illumination angle and
photon trapping. The difference <inline-formula><mml:math id="M96" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">uncorrected</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> characterizes the combined contribution. In this study
covering 110 d of the water year 2021 snow season, the differences
amounted to <inline-formula><mml:math id="M97" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.056 in the broadband albedo and <inline-formula><mml:math id="M98" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.052 in the near infrared.
Larue et al. (2020) estimate a decrease in spectral albedo
at 1000 nm of <inline-formula><mml:math id="M99" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.02 to <inline-formula><mml:math id="M100" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.03 for low-SSA (specific surface area, i.e., large grain size) snow, but
in the snow studied here with extensive ablation hollows, the magnitudes are
greater. The difference <inline-formula><mml:math id="M101" display="inline"><mml:mrow><mml:mfenced open="[" close="]"><mml:mrow><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">internal</mml:mi><mml:mrow><mml:mfenced close=")" open="("><mml:mn mathvariant="normal">0</mml:mn></mml:mfenced></mml:mrow></mml:msubsup><mml:mo>-</mml:mo><mml:mfenced open="(" close=")"><mml:mrow><mml:mo>∑</mml:mo><mml:msub><mml:mi>I</mml:mi><mml:mi mathvariant="normal">esc</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:msubsup><mml:mi>I</mml:mi><mml:mi mathvariant="normal">esc</mml:mi><mml:mrow><mml:mfenced open="(" close=")"><mml:mn mathvariant="normal">0</mml:mn></mml:mfenced></mml:mrow></mml:msubsup></mml:mrow></mml:mfenced></mml:mrow></mml:mfenced></mml:mrow></mml:math></inline-formula> characterizes photon
trapping, which accounts for a mean of 4 % of the lost broadband radiation
and 5 % of the loss in the near infrared. In the late spring when the snow
surface was quite rough, these losses exceeded 20 %. These result follows
from   Warren et al. (1998), who state that intermediate snow albedos
will be most impacted by photon trapping.</p>
      <p id="d1e2413">The intrinsic albedo is generally greater than the planar-corrected albedo,
showing that the planar correction that has been performed in previous
research (Bair et al., 2018; Painter et al., 2012b) accounts for surface
slope but not for roughness. But the planar correction is useful as the
difference between the planar-corrected and the intrinsic albedo quantifies
the impact of sub-slope surface roughness at this location. This difference
implies that in areas where the average surface topography is accurately
quantified (e.g., over 0.5–1.0 km pixels), a terrain-corrected (adjusted to
level) surface reflectance can be used in a spectral mixture model in with a
shade endmember to decrease uncertainty in impurity estimates. However, for
sensors with finer resolution (e.g., <inline-formula><mml:math id="M102" display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> 30 m), caution is advised with
terrain corrections. If ground control points are not available, as in the
case of many remote parts of the world, vertical errors in high-resolution
elevation products approach the pixel size (Gottwald et al., 2017;
Rodríguez et al., 2006; Shean et al., 2016). These errors are
compounded when computing gradients (i.e., slope and aspect) needed for
terrain corrections. These errors are especially noticeable for sharp
features such as ridgelines. Thus, a shade endmember without any terrain
correction may produce the most accurate results for these locations.</p>
      <p id="d1e2424">Narrow-to-broadband albedo conversions confirm that the apparent albedo is
being seen from space. As surface roughness increases to its maximum during
melt, albedo falls rapidly. This period coincides with the time of year when
snow becomes dirtiest on the surface, as the albedo is no longer being
refreshed with new snowfall. Thus, the darkening effects of surface
roughness occur simultaneously with the build-up of impurities
(Betterton, 2001; Rhodes et al., 1987), which presents a challenge for
remote sensing. However, because impurities only affect visible through
near-infrared snow albedo, and snow grain size only affects albedo in the
nIR/SWIR, while shadowing affects the entire broadband spectrum, an
instrument with sufficient spectral resolution and accuracy should be able
to discriminate between the causes of darkening.</p>
      <p id="d1e2427">To test this hypothesis, SPIReS was run on S2 imagery with dirty snow
endmembers and with a clean snow assumption. The resulting grain size and
impurity concentration estimates were then used in the updated broadband
snow albedo that now accounts for shade. Because the pixel is close to
fully snow covered, this estimated albedo should be comparable to the
narrow-to-broadband conversions shown in Fig. 7.
The uncorrected albedo measured at CUES from Fig. 7 is plotted along with these two model runs (Fig. 8). With overlapping error bars for each scene, the resulting albedos are
indistinguishable within measured error (Bair et al., 2021b).
In the clean-snow run, the dust endmember is swapped for the shade endmember
(Table 2). In situ spectroscopic measurements (also
in Table 2) provide some validation but also
illustrate the wide spatial variability of the snow surface just across the
CUES study area.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8" specific-use="star"><?xmltex \currentcnt{8}?><?xmltex \def\figurename{Figure}?><label>Figure 8</label><caption><p id="d1e2432">Broadband snow albedo solutions from SPIReS compared to the uncorrected
albedo measured at CUES (same as in Fig. 7). In
the first set of SPIReS solutions, dirty snow endmembers are used, while in
the other the snow is assumed clean. Both sets use a shade endmember. Error
bars are <inline-formula><mml:math id="M103" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>0.025 (Bair et al., 2021b).</p></caption>
        <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://tc.copernicus.org/articles/16/1765/2022/tc-16-1765-2022-f08.png"/>

      </fig>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T2" specific-use="star"><?xmltex \currentcnt{2}?><label>Table 2</label><caption><p id="d1e2451">Model solutions from SPIReS using measurements from Mammoth Mountain taken
on 11 May 2021, the last two points with error bars shown in
Fig. 8. The instruments are Sentinel 2B MSI (S2)
and the Spectra Vista HR 1024i field spectrometer (SVC). One of the SPIReS
runs used a clean-snow assumption to illustrate the difficulty in separating
shade from dust endmembers (with low concentrations) with a multispectral
instrument. The fractional snow-covered area (<inline-formula><mml:math id="M104" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">sca</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) and shade (<inline-formula><mml:math id="M105" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">shade</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) as
well as the grain radius and dust concentration are unknowns that are solved
for.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="7">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Instrument</oasis:entry>
         <oasis:entry colname="col2">Dirty or clean</oasis:entry>
         <oasis:entry colname="col3">Albedo</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M106" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">sca</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M107" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">shade</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6">Grain radius,</oasis:entry>
         <oasis:entry colname="col7">Dust,</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">snow assumed?</oasis:entry>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M108" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7">ppm</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">S2</oasis:entry>
         <oasis:entry colname="col2">dirty</oasis:entry>
         <oasis:entry colname="col3">0.55–0.60</oasis:entry>
         <oasis:entry colname="col4">0.96</oasis:entry>
         <oasis:entry colname="col5">0.00</oasis:entry>
         <oasis:entry colname="col6">766</oasis:entry>
         <oasis:entry colname="col7">122</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">S2</oasis:entry>
         <oasis:entry colname="col2">clean</oasis:entry>
         <oasis:entry colname="col3">0.57–0.62</oasis:entry>
         <oasis:entry colname="col4">0.77</oasis:entry>
         <oasis:entry colname="col5">0.23</oasis:entry>
         <oasis:entry colname="col6">130</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SVC</oasis:entry>
         <oasis:entry colname="col2">dirty</oasis:entry>
         <oasis:entry colname="col3">0.41–0.63</oasis:entry>
         <oasis:entry colname="col4">0.63–0.94</oasis:entry>
         <oasis:entry colname="col5">0.06–0.37</oasis:entry>
         <oasis:entry colname="col6">453–538</oasis:entry>
         <oasis:entry colname="col7">48–282</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d1e2649">Importantly, the spectroscopic measurements show that, when used in a model,
there is a consistent ability to discriminate between darkening caused by
impurities and by shade. For example, despite the high spatial variability,
neither the shade endmember nor the dust concentration is zero in any of the
solutions. An example of dirty snow with a shaded solution is shown in
Fig. 9.</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F9"><?xmltex \currentcnt{9}?><?xmltex \def\figurename{Figure}?><label>Figure 9</label><caption><p id="d1e2655">Example of measured and modeled reflectance from field spectroscopy
measurements from 12 May 2021 (Table 2). The model
estimates (with an RMSE <inline-formula><mml:math id="M109" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.006) are <inline-formula><mml:math id="M110" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">shade</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M111" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.31, grain radius <inline-formula><mml:math id="M112" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula>
454 <inline-formula><mml:math id="M113" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>, dust concentration <inline-formula><mml:math id="M114" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 77 ppm, <inline-formula><mml:math id="M115" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">apparent</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula>.45
(measured/modeled), and <inline-formula><mml:math id="M116" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">intrinsic</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula>.66 (modeled without shade).</p></caption>
        <?xmltex \igopts{width=213.395669pt}?><graphic xlink:href="https://tc.copernicus.org/articles/16/1765/2022/tc-16-1765-2022-f09.png"/>

      </fig>

      <p id="d1e2744">Because the snow surface is rarely flat or level, shade needs to be
accounted for, even when using measurements taken from a field spectrometer.
Thus, shade needs to be included in snow albedo models, which often use lookup tables for rapid processing. Figure 10 shows the
results of radiative transfer simulations to illustrate the effect of shade
on the difference between intrinsic and apparent albedo.</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F10"><?xmltex \currentcnt{10}?><?xmltex \def\figurename{Figure}?><label>Figure 10</label><caption><p id="d1e2749">Difference between intrinsic and apparent albedo versus shade fraction. The
gray area represents the range of radiative transfer solutions using
different combinations of grain sizes, solar zenith angles, and impurities.</p></caption>
        <?xmltex \igopts{width=213.395669pt}?><graphic xlink:href="https://tc.copernicus.org/articles/16/1765/2022/tc-16-1765-2022-f10.png"/>

      </fig>

      <p id="d1e2758">There is a positive relationship: as <inline-formula><mml:math id="M117" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">shade</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> increases, the difference
between intrinsic and apparent albedo increases, but the scatter also
increases. A simple adjustment is not possible; instead the lookup tables
and albedo model presented in  Bair et al. (2019) have been
updated to include <inline-formula><mml:math id="M118" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">shade</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. The new albedo model estimates an apparent albedo
as
          <disp-formula id="Ch1.E10" content-type="numbered"><label>10</label><mml:math id="M119" display="block"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">apparent</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mi>f</mml:mi><mml:mfenced open="(" close=")"><mml:mrow><mml:msub><mml:mi>r</mml:mi><mml:mi mathvariant="normal">g</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">μ</mml:mi><mml:mo>,</mml:mo><mml:mi>Z</mml:mi><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="normal">LAP</mml:mi><mml:mi mathvariant="normal">name</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">δ</mml:mi><mml:mo>,</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">shade</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
        where <inline-formula><mml:math id="M120" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">apparent</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the apparent albedo over three wavelength
ranges (broadband, near-infrared, and visible), <inline-formula><mml:math id="M121" display="inline"><mml:mrow><mml:msub><mml:mi>r</mml:mi><mml:mi mathvariant="normal">g</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the grain radius
in micrometers, <inline-formula><mml:math id="M122" display="inline"><mml:mi mathvariant="italic">μ</mml:mi></mml:math></inline-formula> is the cosine of the solar zenith angle, <inline-formula><mml:math id="M123" display="inline"><mml:mi>Z</mml:mi></mml:math></inline-formula> is the
surface elevation in kilometers, <inline-formula><mml:math id="M124" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="normal">LAP</mml:mi><mml:mi mathvariant="normal">name</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the type of light-absorbing
particles (dust or soot), and <inline-formula><mml:math id="M125" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> is the LAP concentration. Other
properties such as an assumed midlatitude winter atmosphere are unchanged
from  Bair et al. (2019).</p>
</sec>
<sec id="Ch1.S4" sec-type="conclusions">
  <label>4</label><title>Conclusions</title>
      <p id="d1e2901">A time series of intrinsic and apparent snow albedos over a season at a
sub-alpine site were presented. In situ albedo measurements were compared to
those from a spaceborne multispectral sensor. The multispectral measurements
and those from a field spectrometer were used in a spectral mixture model.
As expected and consistent with other studies, the results show that
intrinsic albedo is consistently greater than apparent albedo. Both albedos
decrease rapidly as ablation hollows form during melt, combining effects of
build-up of impurities on the surface and increasing roughness.</p>
      <p id="d1e2904">There are several conclusions with implications for remote sensing, but also
in situ measurement of snow albedo. For multispectral sensors, darkening
effects from snow surface roughness are significant and can easily be
confused with those from impurities. In contrast, measurements from a field
spectrometer have sufficient spectral resolution and accuracy to distinguish
between the two effects. A spectral mixture model run on spectra obtained at
a study site confirms significant darkening at the snow surface,
simultaneously occurring from roughness and impurities, with wide variation
spatially. In turn, a spectral mixture model was used with Sentinel 2A/B
multispectral imagery assuming a clean snowpack and a dirty snowpack. Both
model runs were able to match measured snow albedo with plausible solutions,
but the clean snow model used the shade endmember in place of the dust
endmember.</p>
      <p id="d1e2907">The 0.056 difference between intrinsic and apparent albedo is equivalent to
the decrease in broadband albedo caused by 63 ppm dust for typical snow in
spring. If the surface topography is known to the point where a plane can be
fit, the difference between the intrinsic and planar-corrected albedo (mean
of 0.022) could be used instead, equivalent to darkening by around 22 ppm
dust. Thus, to improve uncertainty in impurity estimates, a terrain
correction used in conjunction with a shade endmember in a spectral mixture
model can be used for moderate resolution sensors (e.g., 0.4–1 km), but
caution is advised for terrain corrections at finer resolutions (<inline-formula><mml:math id="M126" display="inline"><mml:mo lspace="0mm">≤</mml:mo></mml:math></inline-formula> 30 m) owing to elevation model errors. Generally, impurity estimates from
multispectral sensors are only distinguishable from surface roughness
effects for relatively dirty snow. Likewise, for a multispectral sensor,
mixed pixels can be spectrally inseparable from pixels containing only dirty
snow. Thus, only pixels with high snow fraction should be used for impurity
estimates from a multispectral sensor (Bair et al., 2021b; Painter et
al., 2012a). These conclusions were also reached by Warren
(2013), but for black carbon on the snow surface in the Arctic.</p>
      <p id="d1e2917">This study emphasizes the difficulties in modeling lighting conditions on
the snow surface. Because of these difficulties, a recommendation is to
always use a shade endmember in unmixing models, even for in situ
spectroscopic measurements. Likewise, snow albedo models should produce
apparent albedos by accounting for the shade fraction. To this end, lookup
tables and code have been revised to account for shade. The apparent albedo
produced should be used in energy balance models where intrinsic albedos
have been previously used.</p>
      <p id="d1e2921">In this study, albedos were used rather than directional reflectance
quantities. The justifications are the use of nadir-looking instruments with
measurements taken midday; that as surface roughness increases, so does
backscattering, thereby counteracting the forward scattering in snow; and
that ablation hollows, the largest surface roughness features observed, have
no preferred orientation, unlike sastrugi or penitentes. These factors
reduce the importance of angular effects. But the most compelling
justification is that for snow, the average or sub-pixel-scale snow surface
topography is usually unknown, so the directional factors cannot be
accurately computed.</p>
      <p id="d1e2924">Future work could focus on testing these findings in other snow climates
with different surface roughness features, mainly formed by wind
(Filhol and Sturm, 2015). The findings about discrimination between
darkening from surface roughness and impurities as well as detection limits
for impurities from multispectral sensors require further testing. For
example, results from dirtier snowpacks should be examined, although the
size of the ablation hollows will be reduced  (Lliboutry, 1964;
Rhodes et al., 1987). These findings highlight the need for hyperspectral
measurements of snow from aerial and spaceborne sensors. The NASA Earth
Observing-1 Hyperion was promising in this regard, but lack of coverage,
repeat passes, or a surface reflectance product limited utility. The
upcoming NASA Surface Biology and Geology (SBG) and ESA Copernicus
Hyperspectral Imaging Mission for the Environment (CHIME) spaceborne
spectrometers may offer chances to test these findings using spectroscopic
measurements from space.</p>
</sec>

      
      </body>
    <back><notes notes-type="codeavailability"><title>Code availability</title>

      <p id="d1e2932">All the code used is available on GitHub at the first author's repository:
<uri>https://github.com/edwardbair</uri> (last access: 2 May 2022) and Zenodo (<ext-link xlink:href="https://doi.org/10.5281/zenodo.6513094" ext-link-type="DOI">10.5281/zenodo.6513094</ext-link>, Bair, 2022).</p>
  </notes><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d1e2944">Automated in situ measurements are available at <ext-link xlink:href="https://doi.org/10.21424/R4159Q" ext-link-type="DOI">10.21424/R4159Q</ext-link> (Bair, 2021).</p>

      <p id="d1e2950">Sentinel-2A/B MSI imagery can be found at the Copernicus Open Access Hub:
<uri>https://scihub.copernicus.eu/</uri> (Copernicus and European Space Agency, 2021)</p>

      <p id="d1e2956">Processed in situ measurements are on Zenodo:
<ext-link xlink:href="https://doi.org/10.5281/zenodo.6458451" ext-link-type="DOI">10.5281/zenodo.6458451</ext-link> (Dozier and Bair, 2022).</p>
  </notes><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e2965">Author contributions, according to CRediT taxonomy, are as follows.</p>

      <p id="d1e2968">EHB was responsible for conceptualization, data curation, formal analysis, funding, acquisition, investigation, methodology, and writing (original draft).</p>

      <p id="d1e2971">JD was responsible for conceptualization, software, formal analysis, investigation, methodology, and writing (review and editing).</p>

      <p id="d1e2974">CS was responsible for conceptualization and data curation.</p>

      <p id="d1e2977">AL was responsible for resources and funding acquisition.</p>

      <p id="d1e2981">KR was responsible for funding acquisition and writing (review and editing).</p>

      <p id="d1e2984">AS was responsible for conceptualization and writing (review and editing).</p>

      <p id="d1e2987">TS was responsible for investigation and writing (review and editing).</p>

      <p id="d1e2990">RED was responsible for resources and funding acquisition.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e2996">The contact author has declared that neither they nor their co-authors have any competing interests.</p>
  </notes><notes notes-type="disclaimer"><title>Disclaimer</title>

      <p id="d1e3002">Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e3008">We thank  Mark Flanner for editing and the two anonymous referees for their critiques.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d1e3013">This research was supported by NASA awards 80NSSC21K0997, 80NSSC20K1722,
80NSSC20K1349, 80NSSC18K1489, and 80NSSC21K0620. Other support is from
the Broad Agency Announcement Program and the Cold Regions Research and
Engineering Laboratory (ERDC-CRREL) under contract no. W913E520C0019 and the
Department of Defense (DOD) Research Participation Program administered by
the Oak Ridge Institute for Science and Education (ORISE).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d1e3019">This paper was edited by Mark Flanner and reviewed by two anonymous referees.</p>
  </notes><ref-list>
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