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<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" xml:lang="en" dtd-version="3.0" article-type="research-article"><?xmltex \makeatother\@nolinetrue\makeatletter?>
  <front>
    <journal-meta><journal-id journal-id-type="publisher">TC</journal-id><journal-title-group>
    <journal-title>The Cryosphere</journal-title>
    <abbrev-journal-title abbrev-type="publisher">TC</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">The Cryosphere</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1994-0424</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/tc-15-4589-2021</article-id><title-group><article-title>The role of grain size evolution in  the rheology of ice: implications for reconciling laboratory creep data and the Glen flow law</article-title><alt-title>The role of grain size evolution in the rheology of ice</alt-title>
      </title-group><?xmltex \runningtitle{The role of grain size evolution in the rheology of ice}?><?xmltex \runningauthor{M. D. Behn et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Behn</surname><given-names>Mark D.</given-names></name>
          <email>mark.behn@bc.edu</email>
        <ext-link>https://orcid.org/0000-0002-2001-1335</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Goldsby</surname><given-names>David L.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Hirth</surname><given-names>Greg</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>Dept. Earth &amp; Environmental Sciences, Boston College, Chestnut
Hill, MA 02467, USA</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Dept. Earth &amp; Environmental Science, University of Pennsylvania,
Philadelphia, PA 19104, USA</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Dept. Earth, Environmental &amp; Planetary Sciences, Brown University, Providence, RI 02912, USA</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Mark D. Behn (mark.behn@bc.edu)</corresp></author-notes><pub-date><day>29</day><month>September</month><year>2021</year></pub-date>
      
      <volume>15</volume>
      <issue>9</issue>
      <fpage>4589</fpage><lpage>4605</lpage>
      <history>
        <date date-type="received"><day>6</day><month>October</month><year>2020</year></date>
           <date date-type="rev-request"><day>14</day><month>November</month><year>2020</year></date>
           <date date-type="rev-recd"><day>10</day><month>July</month><year>2021</year></date>
           <date date-type="accepted"><day>23</day><month>August</month><year>2021</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2021 </copyright-statement>
        <copyright-year>2021</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://tc.copernicus.org/articles/.html">This article is available from https://tc.copernicus.org/articles/.html</self-uri><self-uri xlink:href="https://tc.copernicus.org/articles/.pdf">The full text article is available as a PDF file from https://tc.copernicus.org/articles/.pdf</self-uri>
      <abstract><title>Abstract</title>
    <p id="d1e112">Viscous flow in ice is often described by the Glen flow law – a
non-Newtonian, power-law relationship between stress and strain rate with a
stress exponent <inline-formula><mml:math id="M1" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M2" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3. The Glen law is attributed to
grain-size-insensitive dislocation creep; however, laboratory and field
studies demonstrate that deformation in ice can be strongly dependent on
grain size. This has led to the hypothesis that at sufficiently low
stresses, ice flow is controlled by grain boundary sliding, which explicitly incorporates the grain size dependence of ice rheology. Experimental studies
find that neither dislocation creep (<inline-formula><mml:math id="M3" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M4" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 4) nor grain boundary
sliding (<inline-formula><mml:math id="M5" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M6" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.8) have stress exponents that match the value of
<inline-formula><mml:math id="M7" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M8" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3 in the Glen law. Thus, although the Glen law provides an
approximate description of ice flow in glaciers and ice sheets, its
functional form is not explained by a single deformation mechanism. Here we
seek to understand the origin of the <inline-formula><mml:math id="M9" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M10" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3 dependence of the
Glen law by using the “wattmeter” to model grain size evolution in ice.
The wattmeter posits that grain size is controlled by a balance between the
mechanical work required for grain growth and dynamic grain size reduction.
Using the wattmeter, we calculate grain size evolution in two end-member
cases: (1) a 1-D shear zone and (2) as a function of depth within an
ice sheet. Calculated grain sizes match both laboratory data  and ice core
observations for the interior of ice sheets. Finally, we show that
variations in grain size with deformation conditions result in an effective
stress exponent intermediate between grain boundary sliding and dislocation
creep, which is consistent with a value of <inline-formula><mml:math id="M11" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M12" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 3 <inline-formula><mml:math id="M13" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.5 over the range
of strain rates found in most natural systems.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e217">Glaciers and ice sheets deform via gravity-driven viscous flow. The most
widely employed constitutive description of ice flow is the grain-size-independent Glen law, a power-law expression between strain rate
(<inline-formula><mml:math id="M14" display="inline"><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover></mml:math></inline-formula>) and stress (<inline-formula><mml:math id="M15" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula>) of the form
<inline-formula><mml:math id="M16" display="inline"><mml:mrow><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mo>=</mml:mo><mml:mi>B</mml:mi><mml:msup><mml:mi mathvariant="italic">σ</mml:mi><mml:mi>n</mml:mi></mml:msup></mml:mrow></mml:math></inline-formula>, where <inline-formula><mml:math id="M17" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> is a temperature-dependent
constant that embodies the Arrhenius dependence of creep. The Glen law is
characterized by a stress exponent <inline-formula><mml:math id="M18" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> of <inline-formula><mml:math id="M19" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3 and is based on
the classic laboratory experiments of Glen (1952, 1955) and numerous
subsequent experiments on coarse-grained polycrystalline ice. Applications
of the Glen law to natural settings have found that it provides a reasonably
good description of flow in glaciers and ice sheets (e.g., Weertman, 1983).
For example, it has been shown that the flow-line morphology of the
Greenland and west Antarctic ice sheets (Cuffey, 2006), as well as smaller
Antarctic ice caps (Martin and Sanderson, 1980; Hamley et al., 1985; Young
et al., 1989), is consistent with a stress exponent of <inline-formula><mml:math id="M20" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3.
Further, the relationship between stress and strain rate in spreading ice
shelves (Thomas, 1973; Jezek et al., 1985), as well as borehole tilt
measurements in temperate glaciers (Raymond, 1973, 1980) and ice sheets
(Paterson, 1983), also supports the lab-derived value of <inline-formula><mml:math id="M21" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M22" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3.</p>
      <p id="d1e300">Yet despite Glen law's widespread adoption in ice-flow models, several
lines of evidence indicate that it is an oversimplification of the
rheological behavior of ice. Indeed, while reported <inline-formula><mml:math id="M23" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> values are typically
within an error of <inline-formula><mml:math id="M24" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3, there is considerable variability in the
observational constraints. For example, using data from Taylor Glacier,
Antarctica, Cuffey and Kavanaugh (2011)  found a range in <inline-formula><mml:math id="M25" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> from 2.6–5.1,
with a best fitting value of 3.5. Further, flow<?pagebreak page4590?> line observations from East
Antarctica compiled by Budd and Jacka (1989)  are consistent with <inline-formula><mml:math id="M26" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> values
between 3–4. Intriguingly, although many studies acknowledge this degree of
uncertainty in <inline-formula><mml:math id="M27" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula>, the canonical value of 3 is still used to infer variability
in other parameters that influence the creep behavior of ice, such as grain
size, fabric development, impurities, and water content (e.g., Cuffey and
Paterson, 2010). These effects are often parameterized with an enhancement
factor, which modifies the <inline-formula><mml:math id="M28" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> term in the Glen law, but not the stress
exponent. In particular, grain size variations have been shown to influence
creep rates in basal ice in cores from Greenland and Antarctica (e.g.,
Cuffey et al., 2000).</p>
      <p id="d1e346">From the laboratory perspective, the Glen law fails to describe ice rheology
over a wide range of stresses (Pimienta et al., 1987; Duval and Castelnau,
1995; Durham and Stern, 2001; Goldsby and Kohlstedt, 2001; Montagnat and
Duval, 2004), with an observed stress exponent <inline-formula><mml:math id="M29" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M30" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 3 at high stress
and <inline-formula><mml:math id="M31" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M32" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 3 at low stress (Fig. 1). Indeed, Glen (1952) originally
determined a value of <inline-formula><mml:math id="M33" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M34" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 4 based on early experimental data at stresses of
0.2–1 MPa. The low-<inline-formula><mml:math id="M35" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> regime suggested by more recent laboratory data for
samples of comparatively coarse grains sizes (<inline-formula><mml:math id="M36" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 0.1 mm) is of
particular importance for glaciology because it indicates a potential
transition to a low-<inline-formula><mml:math id="M37" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> creep mechanism at typical glacier stresses (<inline-formula><mml:math id="M38" display="inline"><mml:mo lspace="0mm">≤</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M39" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.1 MPa). Values of <inline-formula><mml:math id="M40" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M41" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2 are often associated
with creep mechanisms that involve dislocation-accommodated grain boundary
sliding (GBS), which are strongly dependent on grain size. Mechanisms
involving GBS are characterized by increasing strain rate with decreasing
grain size, i.e., <inline-formula><mml:math id="M42" display="inline"><mml:mrow><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mo>∝</mml:mo><mml:msup><mml:mi>d</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mi>m</mml:mi></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, where <inline-formula><mml:math id="M43" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> is grain size
and the grain size exponent <inline-formula><mml:math id="M44" display="inline"><mml:mi>m</mml:mi></mml:math></inline-formula> has a value of 1–3 depending on the mechanisms
that accommodate GBS creep (e.g., Poirier, 1985; Langdon, 1994).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1"><?xmltex \currentcnt{1}?><?xmltex \def\figurename{Figure}?><label>Figure 1</label><caption><p id="d1e480">Strain rate versus stress compiled from laboratory experiments on
coarse-grained ice revealing the existence of the dislocation creep regime
(<inline-formula><mml:math id="M45" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M46" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 4) and GBS-limited creep regime (<inline-formula><mml:math id="M47" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M48" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1.8) at high and low stress, respectively. The upper and lower solid lines show a grain boundary sliding flow law calculated for grain sizes of 0.2 and 2 mm, respectively;
the dashed–dotted line shows the dislocation creep flow law; the dotted line depicts the
Glen law. Data are from ambient pressure tests at 268 K: <inline-formula><mml:math id="M49" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M50" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.2 mm
(diamonds) (Goldsby and Kohlstedt, 2001); <inline-formula><mml:math id="M51" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M52" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 1 mm (squares)
(Steinemann, 1958); <inline-formula><mml:math id="M53" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M54" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 1 mm (circles) (Mellor and Smith, 1966); <inline-formula><mml:math id="M55" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M56" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 1 mm (triangles; Barnes et al., 1971). Note that the Glen law fails to adequately describe the flow of ice over a wide range of stresses. Figure adapted from Goldsby (2006).</p></caption>
        <?xmltex \igopts{width=170.716535pt}?><graphic xlink:href="https://tc.copernicus.org/articles/15/4589/2021/tc-15-4589-2021-f01.png"/>

      </fig>

      <p id="d1e575">Most early laboratory experiments on ice, such as those by Glen (1952,
1955), focused on polycrystalline samples with grain sizes typical of
natural settings (1–10 mm). However, these data are difficult to interpret
in terms of a GBS creep mechanism at low stresses because it is hard to
separate to steady state from transient creep (Weertman, 1983). Access to
low-stress (low-<inline-formula><mml:math id="M57" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula>) creep mechanisms on a practical timeframe requires
fabrication of specimens with grain sizes that are much smaller than
typically found in terrestrial ice (Goldsby and Kohlstedt, 2001; Durham et
al., 2001). Creep experiments on such samples reveal a stress exponent of <inline-formula><mml:math id="M58" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M59" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 4 at high stresses with no grain size dependence and are interpreted to
reflect a dislocation creep mechanism (Goldsby and Kohlstedt, 2001). By
contrast, with decreasing stress the data reveal the existence of a creep
regime characterized by <inline-formula><mml:math id="M60" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M61" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1.8 (Fig. 1) and a marked dependence on grain size with <inline-formula><mml:math id="M62" display="inline"><mml:mi>m</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M63" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1.4. These values of <inline-formula><mml:math id="M64" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M65" display="inline"><mml:mi>m</mml:mi></mml:math></inline-formula> are consistent with a GBS creep
mechanism in which GBS is accommodated by dislocation motion (Nieh et al.,
1997).</p>
      <p id="d1e642">These laboratory data lead to a paradox for interpreting the behavior of ice
flow in natural settings – namely, the laboratory-derived stress
exponents for neither dislocation creep (<inline-formula><mml:math id="M66" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M67" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 4) nor
dislocation-accommodated GBS (<inline-formula><mml:math id="M68" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M69" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.8) match the value of <inline-formula><mml:math id="M70" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M71" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3 in the Glen law. One possible explanation for this discrepancy is that
variations in ice grain size will influence the relative contributions of
GBS and dislocation creep, leading to a transitional regime between these
two creep mechanisms (Peltier et al., 2000; Goldsby, 2006). To evaluate this
hypothesis, it is necessary to quantify how grain size evolves spatially and
temporally within glaciers and ice sheets. A number of studies have
investigated the competing effects of grain growth and dynamic
recrystallization on grain size in ice (e.g., Alley, 1992; Alley et al.,
1995; Duval and Castelnau, 1995; De La Chapelle et al., 1998; Montagnat
and Duval, 2000; Durand et al., 2006; Roessiger et al., 2011; Ng and Jacka,
2017). Faria et al. (2014a) proposed a fully coupled model in which
steady-state grain size is described as a function of temperature and
strain rate, but in deriving an expression for steady-state grain size they
assumed the grain-size-independent Glen law. Here, we develop a unified
description of grain size and deformation that explicitly accounts for the
experimental constraints on grain-size-sensitive creep.</p>
      <p id="d1e688">We build on the framework for grain size evolution proposed by Faria et al. (2014a). We do so by adapting the<?pagebreak page4591?> “wattmeter” (Austin and Evans, 2007,
2009), originally developed to quantify grain size evolution in crustal and
mantle rocks, to calculate grain sizes in ice. The wattmeter is based on the
concept that grain size in any solid crystal aggregate is controlled by the
balance of the mechanical work required for grain growth and dynamic
recrystallization. Coupling the wattmeter with a composite flow law that
incorporates both GBS and dislocation creep, we (1) develop a model that
provides a self-consistent description of deformation and grain size
evolution in ice and (2) test our model using constraints from laboratory
data and natural settings. Lastly, we show that grain size evolution in
response to deformation leads to an effective stress exponent that is
intermediate between grain boundary sliding and dislocation creep,
consistent with the <inline-formula><mml:math id="M72" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M73" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3 value of the Glen law.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Grain size evolution model for ice</title>
      <p id="d1e713">Several models have been proposed to quantify the evolution of grain size in
pure ice. The simplest of these models is the piezometric relationship, in
which grain size is related directly to the inverse of stress (e.g., Azuma
and Higashi, 1983; Jacka and Li, 1994). However, while the piezometer
considers the competition between grain growth and grain size reduction due
to strain (Jacka and Li, 1994), it only considers grain size at steady
state and does not take into account how these two processes vary with the
evolving deformation conditions. Near the surface, ice core data show a
monotonic increase in grain size with depth, indicating that grain growth is
the dominant process controlling grain size (Gow et al., 1997). However, at
greater depths, grain sizes often stabilize, suggesting a steady state in
which the rate of recrystallization balances the rate of grain growth (e.g.,
Roessinger et al., 2011; Faria et al., 2014b). Similar processes are thought
to occur in crustal and mantle rocks and have led to models that assume
grain growth and recrystallization are balanced at the field boundary
between grain-size-sensitive (e.g., diffusion or GBS) creep and grain-size-insensitive (e.g., dislocation) creep (de Bresser et al., 2001). In crust
and mantle rocks, the force for grain boundary reduction becomes negligible
when diffusion creep dominates (Evans et al., 2001). However, this is not
applicable for the field boundary between GBS and dislocation creep in ice,
where easy slip on the basal plane of ice will produce intracrystalline
deformation, similar to observations in olivine (e.g., Hansen et al., 2012).</p>
      <p id="d1e716">Another class of models derived to study crustal and mantle rocks explicitly
calculate the rates of grain growth and grain size reduction (e.g., Hall
and Parmentier, 2003; Montési and Hirth, 2003; Bercovici and Ricard,
2014). A particularly successful model, which accurately predicts grain
sizes in a range of natural samples (e.g., calcite, quartz, olivine), is the
wattmeter (Austin and Evans, 2007, 2009). The wattmeter posits that the
mean grain size, <inline-formula><mml:math id="M74" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>, of a volume of rock or ice is controlled by the balance
of mechanical work required for grain growth and dynamic recrystallization.
Specifically, the wattmeter calculates the rate of grain size evolution from
the competing rates of grain growth and dynamic recrystallization:
          <disp-formula id="Ch1.E1" content-type="numbered"><label>1</label><mml:math id="M75" display="block"><mml:mrow><mml:mover accent="true"><mml:mi>d</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mo>=</mml:mo><mml:msub><mml:mover accent="true"><mml:mi>d</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">gg</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mover accent="true"><mml:mi>d</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">red</mml:mi></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
        where <inline-formula><mml:math id="M76" display="inline"><mml:mover accent="true"><mml:mi>d</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover></mml:math></inline-formula> is the change in mean grain size with respect to time,
<inline-formula><mml:math id="M77" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>d</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the rate of grain growth, and <inline-formula><mml:math id="M78" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>d</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">red</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the
rate of grain size reduction or “polygonization” (Alley et al., 1995).</p>
      <p id="d1e797">Below we describe our approach for calculating the rates of grain growth and
grain size reduction and how the grain size evolution law in Eq. (1) can be
coupled with a composite flow law that includes both GBS and dislocation
creep to predict the effective stress exponent for ice.</p>
<sec id="Ch1.S2.SS1">
  <label>2.1</label><title>Grain growth</title>
      <p id="d1e807">Following Alley et al. (1986), we assume that grain growth can be described
by a relationship of the form
            <disp-formula id="Ch1.E2" content-type="numbered"><label>2</label><mml:math id="M79" display="block"><mml:mrow><mml:msup><mml:mi>d</mml:mi><mml:mi>p</mml:mi></mml:msup><mml:mo>-</mml:mo><mml:msubsup><mml:mi>d</mml:mi><mml:mi mathvariant="normal">o</mml:mi><mml:mi>p</mml:mi></mml:msubsup><mml:mo>=</mml:mo><mml:mi>K</mml:mi><mml:mi>t</mml:mi><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M80" display="inline"><mml:mi>K</mml:mi></mml:math></inline-formula> follows an Arrhenius relation:
            <disp-formula id="Ch1.E3" content-type="numbered"><label>3</label><mml:math id="M81" display="block"><mml:mrow><mml:mi>K</mml:mi><mml:mo>=</mml:mo><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub><mml:mi>exp⁡</mml:mi><mml:mfenced open="(" close=")"><mml:mrow><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mi>R</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mfenced><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          In these equations <inline-formula><mml:math id="M82" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi mathvariant="normal">o</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is an initial grain size, <inline-formula><mml:math id="M83" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> is the grain growth
exponent, <inline-formula><mml:math id="M84" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> is time, <inline-formula><mml:math id="M85" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the grain growth constant, <inline-formula><mml:math id="M86" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the
activation enthalpy for grain growth, <inline-formula><mml:math id="M87" display="inline"><mml:mi>R</mml:mi></mml:math></inline-formula> is the universal gas constant, and
<inline-formula><mml:math id="M88" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> is temperature. Substituting Eq. (3) into Eq. (2) and differentiating with respect to time allows us to write an expression for the rate of grain
growth:
            <disp-formula id="Ch1.E4" content-type="numbered"><label>4</label><mml:math id="M89" display="block"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>d</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">gg</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msup><mml:mi>p</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:msup><mml:mi>d</mml:mi><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi>p</mml:mi></mml:mrow></mml:msup><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub><mml:mi>exp⁡</mml:mi><mml:mfenced open="(" close=")"><mml:mrow><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mi>R</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mfenced><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          Equation (4) provides a general expression for grain growth; however, the
values of the grain growth parameters <inline-formula><mml:math id="M90" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M91" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math id="M92" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> are not well
constrained in natural systems and depend on the presence of microparticles,
bubbles, and/or other impurities in the ice (e.g., Alley et al., 1986). In
Sect. 2.5 we will describe our approach for estimating these parameters
using a combination of laboratory and ice core data.</p>
</sec>
<sec id="Ch1.S2.SS2">
  <label>2.2</label><title>Grain size reduction</title>
      <p id="d1e1042">The wattmeter posits that the rate of grain size reduction <inline-formula><mml:math id="M93" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>d</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">red</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is controlled by the rate of mechanical work and the rate at which this
work is dissipated (Austin and Evans, 2007, 2009; Bercovici and Ricard,
2012). Specifically, the rate of mechanical work per unit volume,
<inline-formula><mml:math id="M94" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>W</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">tot</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, is defined as
            <disp-formula id="Ch1.E5" content-type="numbered"><label>5</label><mml:math id="M95" display="block"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>W</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">tot</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mi mathvariant="italic">σ</mml:mi><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M96" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula> is von Mises equivalent stress and <inline-formula><mml:math id="M97" display="inline"><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover></mml:math></inline-formula> is
strain rate (assuming that the rate of stress change is negligible over<?pagebreak page4592?> the
timescale of grain size evolution). This work rate must be balanced by the
rate at which the internal energy of the system, <inline-formula><mml:math id="M98" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>E</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">int</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>,
increases plus the rate at which energy is dissipated, <inline-formula><mml:math id="M99" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi mathvariant="italic">θ</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">irr</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>:
            <disp-formula id="Ch1.E6" content-type="numbered"><label>6</label><mml:math id="M100" display="block"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>W</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">tot</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mi mathvariant="italic">σ</mml:mi><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mo>=</mml:mo><mml:msub><mml:mover accent="true"><mml:mi>E</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">int</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mover accent="true"><mml:mi mathvariant="italic">θ</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">irr</mml:mi></mml:msub><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          The increase in internal energy can be related to the increase in grain
boundary area:
            <disp-formula id="Ch1.E7" content-type="numbered"><label>7</label><mml:math id="M101" display="block"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>E</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">int</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>-</mml:mo><mml:mi>c</mml:mi><mml:mi mathvariant="italic">γ</mml:mi></mml:mrow><mml:mrow><mml:msup><mml:mi>d</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mover accent="true"><mml:mi>d</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">red</mml:mi></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M102" display="inline"><mml:mi mathvariant="italic">γ</mml:mi></mml:math></inline-formula> is the grain boundary energy and <inline-formula><mml:math id="M103" display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula> is a geometrical factor
(<inline-formula><mml:math id="M104" display="inline"><mml:mi mathvariant="italic">π</mml:mi></mml:math></inline-formula> for spherical grains). The rate of dissipation in Eq. (6) is
related to the fraction, <inline-formula><mml:math id="M105" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula>, of the total work rate that is
responsible for increases in internal energy:
            <disp-formula id="Ch1.E8" content-type="numbered"><label>8</label><mml:math id="M106" display="block"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi mathvariant="italic">θ</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">irr</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mfenced close=")" open="("><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi mathvariant="italic">λ</mml:mi></mml:mrow></mml:mfenced><mml:mi mathvariant="italic">σ</mml:mi><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          Here we note a difference in the application of the wattmeter to ice
compared to crustal and mantle rocks. In most terrestrial minerals, the two
primary creep mechanisms are diffusion and dislocation creep. Because grain
growth during diffusion creep was shown to be the same as that during static
conditions (Karato et al., 1986), the work done by diffusion creep is
assumed to be completely dissipated (i.e., <inline-formula><mml:math id="M107" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">diff</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula>), and only
dislocation creep leads to grain size reduction. By contrast, under
Earth-like pressure and temperature conditions, ice deformation proceeds
primarily by a combination of GBS and dislocation creep (Goldsby and
Kohlstedt, 2001). Because some fraction of the work done by both GBS and
dislocation creep will lead to grain size reduction (i.e., <inline-formula><mml:math id="M108" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> &amp; <inline-formula><mml:math id="M109" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula>), the dissipation rate can be rewritten as
            <disp-formula id="Ch1.E9" content-type="numbered"><label>9</label><mml:math id="M110" display="block"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi mathvariant="italic">θ</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">irr</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mfenced close=")" open="("><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi mathvariant="italic">β</mml:mi></mml:mrow></mml:mfenced><mml:mfenced close=")" open="("><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:mi mathvariant="italic">σ</mml:mi><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mo>+</mml:mo><mml:mi mathvariant="italic">β</mml:mi><mml:mfenced close=")" open="("><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:mi mathvariant="italic">σ</mml:mi><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where
            <disp-formula id="Ch1.E10" content-type="numbered"><label>10</label><mml:math id="M111" display="block"><mml:mrow><mml:mi mathvariant="italic">β</mml:mi><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>W</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>W</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">tot</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          Here we assume that the total work rate can be expressed as the sum of the
contributions from the individual deformation mechanisms:
            <disp-formula id="Ch1.E11" content-type="numbered"><label>11</label><mml:math id="M112" display="block"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>W</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">tot</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mover accent="true"><mml:mi>W</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">disl</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mover accent="true"><mml:mi>W</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mi mathvariant="italic">σ</mml:mi><mml:msub><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">disl</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:mi mathvariant="italic">σ</mml:mi><mml:msub><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          Substituting Eqs. (7) and (9) into Eq. (6) we derive an expression relating
the rate of grain size reduction to the total work rate:
            <disp-formula id="Ch1.E12" content-type="numbered"><label>12</label><mml:math id="M113" display="block"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>d</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">red</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mfenced open="(" close=")"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:mi mathvariant="italic">β</mml:mi><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:mi mathvariant="italic">β</mml:mi><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:msup><mml:mi>d</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow><mml:mrow><mml:mo>-</mml:mo><mml:mi>c</mml:mi><mml:mi mathvariant="italic">γ</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mi mathvariant="italic">σ</mml:mi><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover></mml:mrow></mml:math></disp-formula>
          The final grain size evolution equation can then be assembled from Eqs. (1),
(4), and (12):
            <disp-formula id="Ch1.E13" content-type="numbered"><label>13</label><mml:math id="M114" display="block"><mml:mrow><mml:mtable class="split" rowspacing="0.2ex" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>d</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">tot</mml:mi></mml:msub></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>=</mml:mo><mml:msup><mml:mi>p</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:msup><mml:mi>d</mml:mi><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi>p</mml:mi></mml:mrow></mml:msup><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub><mml:mi>exp⁡</mml:mi><mml:mfenced close=")" open="("><mml:mrow><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mi>R</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mfenced></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mfenced close=")" open="("><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:mi mathvariant="italic">β</mml:mi><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:mi mathvariant="italic">β</mml:mi><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:msup><mml:mi>d</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow><mml:mrow><mml:mi>c</mml:mi><mml:mi mathvariant="italic">γ</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mi mathvariant="italic">σ</mml:mi><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover></mml:mrow></mml:mtd></mml:mtr></mml:mtable><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          It is often useful to define a steady-state grain size, <inline-formula><mml:math id="M115" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi mathvariant="normal">ss</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, which occurs when <inline-formula><mml:math id="M116" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>d</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">tot</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula>:
            <disp-formula id="Ch1.E14" content-type="numbered"><label>14</label><mml:math id="M117" display="block"><mml:mrow><mml:msubsup><mml:mi>d</mml:mi><mml:mi mathvariant="normal">ss</mml:mi><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>+</mml:mo><mml:mi>p</mml:mi></mml:mrow></mml:msubsup><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub><mml:mi>exp⁡</mml:mi><mml:mfenced close=")" open="("><mml:mrow><mml:mo>-</mml:mo><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mi>R</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mfenced><mml:msup><mml:mi>p</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mi>c</mml:mi><mml:mi mathvariant="italic">γ</mml:mi></mml:mrow><mml:mrow><mml:mfenced close=")" open="("><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:mi mathvariant="italic">β</mml:mi><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:mi mathvariant="italic">β</mml:mi><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:mi mathvariant="italic">σ</mml:mi><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          The concept of a steady-state grain size is analogous to that derived by
Faria et al. (2014a), with the exception that they assumed creep was
governed exclusively by the Glen law and grain size was related to
stress only (e.g., Jacka and Li, 1994) rather than to the work rate (Eq. 6). In practice the steady-state grain size may not be achieved if there is
insufficient time for grains to fully evolve to be in equilibrium with the
surrounding deformation conditions. In these situations, Eq. (13) must be
solved and coupled with the governing equations and constitutive
relationships.</p>
      <p id="d1e1798">The values of <inline-formula><mml:math id="M118" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M119" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>  are uncertain and have not been determined independently.
Therefore, for simplicity we assume that <inline-formula><mml:math id="M120" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, thereby lumping the effects of
grain boundary energy, grain geometry, and <inline-formula><mml:math id="M121" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula> into a single “scaling
factor” in Eq. (14) (Austin and Evans, 2009). In the following sections, we
vary <inline-formula><mml:math id="M122" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula> to elucidate the behavior of the model with respect to
variations in any of these three parameters. We emphasize that the wattmeter
models the rate of change in the internal energy and relates this to the
grain size reduction rate (and thus increase in internal energy owing to
increase in grain boundary area). A key assumption is that the rate of
change in grain size is greater than the rate of change in stress – thus
the dislocation density can be considered constant for a given stress
(Austin and Evans, 2007, 2009).</p>
      <p id="d1e1859">Finally, we note that the wattmeter approximates mean grain size, <inline-formula><mml:math id="M123" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>, as the
diameter of a circular grain of ice. Comparing these theoretical values to
grain sizes in natural systems can be challenging because grains are
irregular and are typically measured in a 2-D cross section (e.g., thin
section) through a 3-D sample. In our comparisons to data below, natural
grain sizes were estimated using the line intercept technique of Alley and
Woods (1996). In this approach, the average distance between grain
boundaries along a series of lines through a sample is measured and then
scaled by a correction factor of the order of 1 (1.5 for circular grains;
Gifkens, 1970) in order to account for the fact that when making a thin
section many grains are cut near their edge as opposed to near their center
(Gow, 1969). Further, because this approach is also used in the measurement
of grain sizes in the derivation of the flow laws (Goldsby and Kohlstedt,
2001), it allows us to compare our calculated grain sizes to ice core data in
a self-consistent manner.</p>
</sec>
<sec id="Ch1.S2.SS3">
  <label>2.3</label><title>Composite rheology for ice</title>
      <p id="d1e1877">To apply the grain size evolution model defined by Eq. (13) to natural
systems, we calculate the relative rates of deformation by GBS and
dislocation creep. To do so, we formulate<?pagebreak page4593?> a two-mechanism composite flow law
that contains additive contributions from each creep mechanism of the form
            <disp-formula id="Ch1.E15" content-type="numbered"><label>15</label><mml:math id="M124" display="block"><mml:mrow><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mo>=</mml:mo><mml:msub><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">disl</mml:mi></mml:msub><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          This composite law has been used to model the rheology of ice satellites
(Barr and McKinnon, 2007) and the relative contribution of GBS and
dislocation creep in ice sheets (Kuiper et al., 2020). Here the creep
mechanisms are assumed to be independent and each term on the
right-hand-side of Eq. (15) is expressed as a flow law of the general form
            <disp-formula id="Ch1.E16" content-type="numbered"><label>16</label><mml:math id="M125" display="block"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi mathvariant="italic">ε</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi>i</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>A</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:msup><mml:mi>d</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:msub><mml:mi>m</mml:mi><mml:mi>i</mml:mi></mml:msub></mml:mrow></mml:msup><mml:msup><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi>i</mml:mi></mml:msub></mml:mrow></mml:msup><mml:mi>exp⁡</mml:mi><mml:mfenced close=")" open="("><mml:mrow><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi>i</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mi>R</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mfenced><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M126" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mi>i</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is a material constant, <inline-formula><mml:math id="M127" display="inline"><mml:mrow><mml:msub><mml:mi>m</mml:mi><mml:mi>i</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the grain size exponent for
creep, <inline-formula><mml:math id="M128" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi>i</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the stress exponent, and <inline-formula><mml:math id="M129" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi>i</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the activation energy.
The subscript <inline-formula><mml:math id="M130" display="inline"><mml:mi>i</mml:mi></mml:math></inline-formula> denotes the parameters that depend on the deformation
mechanism (e.g., GBS or dislocation creep). We note that Goldsby and
Kohlstedt (2001) presented a more complicated composite law that includes a
term for creep limited by basal dislocation slip and also a theoretical flow
law for diffusion creep. However, extrapolations to grain sizes typical of
glaciers and ice sheets demonstrate that neither of these additional creep
mechanisms are likely to be important for the flow of terrestrial ice
bodies. A list of flow law parameters required to extrapolate Eq. (16) to
the full temperature range (up to the melting point) is given in Goldsby
and Kohlstedt (2001).</p>
</sec>
<sec id="Ch1.S2.SS4">
  <label>2.4</label><title>Model setup</title>
      <p id="d1e2035">To solve for grain size evolution in ice, we consider two scenarios: (1) deformation in a shear zone under an imposed velocity contrast <inline-formula><mml:math id="M131" display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">sz</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and
(2) deformation in a 1-D vertical column of ice with an assumed surface slope,
<inline-formula><mml:math id="M132" display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula>. For the case of a shear zone with no along-strike pressure and/or
viscosity gradients, the shear stress, <inline-formula><mml:math id="M133" display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula>, will be constant and a
function of only the viscosity and velocity contrast:
            <disp-formula id="Ch1.E17" content-type="numbered"><label>17</label><mml:math id="M134" display="block"><mml:mrow><mml:mi mathvariant="italic">τ</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="italic">η</mml:mi><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>∂</mml:mo><mml:mi>v</mml:mi></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>w</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M135" display="inline"><mml:mi mathvariant="italic">η</mml:mi></mml:math></inline-formula> is the viscosity, <inline-formula><mml:math id="M136" display="inline"><mml:mi>v</mml:mi></mml:math></inline-formula> is the velocity parallel to the shear zone, and <inline-formula><mml:math id="M137" display="inline"><mml:mi>w</mml:mi></mml:math></inline-formula> is the direction perpendicular to the strike of the shear zone.
Integrating Eq. (17) over the width of the shear zone, <inline-formula><mml:math id="M138" display="inline"><mml:mrow><mml:msub><mml:mi>w</mml:mi><mml:mi mathvariant="normal">o</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, allows us to write stress in terms of the imposed velocity:
            <disp-formula id="Ch1.E18" content-type="numbered"><label>18</label><mml:math id="M139" display="block"><mml:mrow><mml:mi mathvariant="italic">τ</mml:mi><mml:mo>=</mml:mo><mml:msub><mml:mi>V</mml:mi><mml:mi mathvariant="normal">sz</mml:mi></mml:msub><mml:msup><mml:mfenced close=")" open="("><mml:mrow><mml:munderover><mml:mo movablelimits="false">∫</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mrow><mml:msub><mml:mi>w</mml:mi><mml:mi mathvariant="normal">o</mml:mi></mml:msub></mml:mrow></mml:munderover><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mi mathvariant="italic">η</mml:mi></mml:mfrac></mml:mstyle><mml:mi mathvariant="normal">d</mml:mi><mml:mi>w</mml:mi></mml:mrow></mml:mfenced><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          The viscosity can be reformulated from the flow law (Eq. 16) in terms of the
stress:
            <disp-formula id="Ch1.E19" content-type="numbered"><label>19</label><mml:math id="M140" display="block"><mml:mrow><mml:mi mathvariant="italic">η</mml:mi><mml:mfenced close=")" open="("><mml:mi mathvariant="italic">σ</mml:mi></mml:mfenced><mml:mo>=</mml:mo><mml:msup><mml:mi>A</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:msup><mml:mi mathvariant="italic">σ</mml:mi><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi>n</mml:mi></mml:mrow></mml:msup><mml:msup><mml:mi>d</mml:mi><mml:mi>m</mml:mi></mml:msup><mml:mi>exp⁡</mml:mi><mml:mfenced open="(" close=")"><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mi>Q</mml:mi><mml:mrow><mml:mi>R</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:mfrac></mml:mstyle></mml:mfenced></mml:mrow></mml:math></disp-formula>
          In the case of deformation within a column of ice with a zero-slip basal
boundary condition, the shear stress is calculated from the surface slope
and increases linearly as a function of depth, <inline-formula><mml:math id="M141" display="inline"><mml:mi>z</mml:mi></mml:math></inline-formula>, in the ice sheet:
            <disp-formula id="Ch1.E20" content-type="numbered"><label>20</label><mml:math id="M142" display="block"><mml:mrow><mml:mi mathvariant="italic">τ</mml:mi><mml:mo>(</mml:mo><mml:mi>z</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi>g</mml:mi><mml:mfenced close=")" open="("><mml:mrow><mml:mi>H</mml:mi><mml:mo>-</mml:mo><mml:mi>z</mml:mi></mml:mrow></mml:mfenced><mml:mi>sin⁡</mml:mi><mml:mo>(</mml:mo><mml:mi mathvariant="italic">α</mml:mi><mml:mo>)</mml:mo><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          Here <inline-formula><mml:math id="M143" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula> is the density of ice, <inline-formula><mml:math id="M144" display="inline"><mml:mi>g</mml:mi></mml:math></inline-formula> is the gravitational acceleration, and
<inline-formula><mml:math id="M145" display="inline"><mml:mi>H</mml:mi></mml:math></inline-formula> is the thickness of the ice sheet. Note that in practice we relate the
shear stress to the von Mises equivalent stress in the wattmeter (Eq. 13)
and flow law (Eq. 16) through the square root of the second invariant of the
stress tensor, which in this geometry reduces to <inline-formula><mml:math id="M146" display="inline"><mml:mrow><mml:mi mathvariant="italic">τ</mml:mi><mml:mo>=</mml:mo><mml:msqrt><mml:mn mathvariant="normal">3</mml:mn></mml:msqrt><mml:mi mathvariant="italic">σ</mml:mi></mml:mrow></mml:math></inline-formula>.</p>
</sec>
<sec id="Ch1.S2.SS5">
  <label>2.5</label><title>Calibration of grain growth parameters</title>
      <p id="d1e2307">Before using the wattmeter to predict grain sizes in natural systems, we
must first constrain the grain growth parameters used in the model as they
will directly control the balance between grain growth and grain size
reduction. As noted above, grain growth rates in ice are highly sensitive to
the presence of impurities, both soluble (e.g., bubbles, ions) and insoluble
(e.g., dust/microparticles) (Alley et al., 1986). While the expressions for
grain size evolution derived above do not explicitly account for the effects
of impurities, we can parameterize their effects through their influence on
grain growth. To constrain the grain growth parameters (<inline-formula><mml:math id="M147" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M148" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, and
<inline-formula><mml:math id="M149" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) in Eq. (4), we turn to a combination of laboratory and ice core
data. Azuma et al. (2012) measured grain growth rates in laboratory samples
both with and without bubbles and found that the grain growth exponent for
bubble-free ice was relatively small (<inline-formula><mml:math id="M150" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M151" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2) but was
significantly larger (<inline-formula><mml:math id="M152" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M153" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 7–9) in ice containing bubbles (Fig. 2). The increase in the grain growth exponent in the presence of bubbles was
interpreted to reflect the role of “impurity drag”.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2"><?xmltex \currentcnt{2}?><?xmltex \def\figurename{Figure}?><label>Figure 2</label><caption><p id="d1e2370">Comparison of grain growth rates derived from laboratory and ice
core data. Data from individual laboratory experiments by Azuma et al. (2012) with and without bubbles are shown by red and blue symbols, respectively. Grain sizes for the GRIP (black circles; Thorsteinsson et al., 1997) and GISP2 (open triangles; Gow et al., 1997) ice cores are plotted
as a function of time based on the age models of Dansgaard et al. (1993) and
Ram et al. (2000), respectively. Only ice core data between 150–300 m depth
where grain growth dominates are used (see text). Red and blue curves show the
fit to individual experiments conducted at a temperature equivalent to the
ice core data (243 K); grain growth exponents (labeled) are calculated
following the methodology in Bons et al. (2001). The black curve shows the fit
calculated using all three laboratory experiments that contain bubbles and
the GRIP ice core data. Dotted black lines show the 1<inline-formula><mml:math id="M154" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula> error estimate on
fit to lab and ice core data.</p></caption>
          <?xmltex \igopts{width=227.622047pt}?><graphic xlink:href="https://tc.copernicus.org/articles/15/4589/2021/tc-15-4589-2021-f02.png"/>

        </fig>

      <p id="d1e2386">To investigate the applicability of these experimentally derived
grain growth rates to natural systems, we compared them to grain sizes in
the shallow portions of the GRIP and GISP2 ice cores where recrystallization
rates are expected to be small and the increase in grain size with depth
dominantly reflects the rate of grain growth (Gow et al., 1997). We use only
grain sizes from the depth range between 150 m (<inline-formula><mml:math id="M155" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 500 years;
taken to represent the depth at which the ice is fully compacted) and 300 m
(<inline-formula><mml:math id="M156" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 1500 years; below which grain sizes no longer increase at a
constant rate, indicative of the influence of recrystallization). For
comparison with the laboratory data, depth was converted to time for the
GRIP and GISP2 cores based on the age models of Dansgaard et al. (1993) and
Ram et al. (2000), respectively.</p>
      <p id="d1e2404">Using experiments conducted at the temperature conditions found between
150–300 m depth in the GRIP and GISP2 ice cores (243 K; Hvidberg et al.,
1997), we first refit the Azuma et al. (2012) experimental data for the
grain growth parameters <inline-formula><mml:math id="M157" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M158" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> using the approach of Bons et al. (2001).
We find grain growth exponents in the range of 7.1–8.4 for experiments with
bubbles and <inline-formula><mml:math id="M159" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M160" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1.8 for the<?pagebreak page4594?> single experiment without bubbles (red and blue
curves in Fig. 2). Extrapolating these parameters to timescales applicable
to glaciers and ice sheets (e.g., 10<inline-formula><mml:math id="M161" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula>–10<inline-formula><mml:math id="M162" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">5</mml:mn></mml:msup></mml:math></inline-formula> years), we show that (1) the grain growth parameters derived for ice with bubbles provide a
significantly better fit to the ice core data compared to the grain growth
rates for bubble-free ice (compare red vs. blue curves in Fig. 2), and (2) the parameters derived from experiment AL5 provide the best overall fit to
the ice core data. However, there is some variability in the experimental
data – possibly reflecting differences in bubble content and/or the
difficulty in extrapolating grain growth parameters determined on
timescales of hours to days in the laboratory to timescales of thousands
of years in natural systems. In an attempt to address these issues, we refit
the Azuma et al. (2012) data from all three experiments containing bubbles at
243 K (AL5, AM5, and AS5) jointly with the GRIP ice core data. We do not
include the GISP2 data in this fit, as we will calculate grain size as a
function of depth throughout the entire GISP2 core in Sect. 3.3 below. The
joint fit results in a grain growth exponent <inline-formula><mml:math id="M163" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> of 6.03 <inline-formula><mml:math id="M164" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.25 (solid
black line in Fig. 2), slightly less than the values derived from the
individual laboratory experiments.</p>
      <p id="d1e2472">Our goal in fitting the grain growth exponent in this way is to derive an
“empirical” <inline-formula><mml:math id="M165" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> value that, in conjunction with the corresponding values of
<inline-formula><mml:math id="M166" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M167" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, fits a wide range of observations and can be applied to
natural settings. We note that additional parameters have been shown to
influence grain growth. For example, Arena et al. (1997) showed that the
presence of pores can be thought of as changing the <inline-formula><mml:math id="M168" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> value in the grain growth law. Further, the evolution of microstructure during
deformation (compared to static grain growth) can result in changes in
<inline-formula><mml:math id="M169" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (Roessiger et al., 2014). Thus, if <inline-formula><mml:math id="M170" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> varies with the microstructure (bubble size/bubble topology), and this scales with grain size, then <inline-formula><mml:math id="M171" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> will be proportional to some function of grain size <inline-formula><mml:math id="M172" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:mi>d</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. In our formulation, we essentially lump all these effects into the empirically fit <inline-formula><mml:math id="M173" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> value, which is mathematically similar to a <inline-formula><mml:math id="M174" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> term
with a power-law relationship to grain size.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><?xmltex \currentcnt{1}?><label>Table 1</label><caption><p id="d1e2584">Flow law and model parameters.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="4">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="left"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Symbol</oasis:entry>
         <oasis:entry colname="col2">Description</oasis:entry>
         <oasis:entry colname="col3">Value</oasis:entry>
         <oasis:entry colname="col4">Units</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M175" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Dislocation creep exponent</oasis:entry>
         <oasis:entry colname="col3">4</oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M176" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">GBS creep exponent</oasis:entry>
         <oasis:entry colname="col3">1.8</oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M177" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Dislocation creep prefactor (<inline-formula><mml:math id="M178" display="inline"><mml:mo lspace="0mm">&gt;</mml:mo></mml:math></inline-formula> 259, <inline-formula><mml:math id="M179" display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> 259 K)</oasis:entry>
         <oasis:entry colname="col3">6 <inline-formula><mml:math id="M180" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M181" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">28</mml:mn></mml:msup></mml:math></inline-formula>, 4 <inline-formula><mml:math id="M182" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M183" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">MPa<inline-formula><mml:math id="M184" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> s<inline-formula><mml:math id="M185" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M186" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">GBS creep prefactor (<inline-formula><mml:math id="M187" display="inline"><mml:mo lspace="0mm">&gt;</mml:mo></mml:math></inline-formula> 259, <inline-formula><mml:math id="M188" display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> 259 K)</oasis:entry>
         <oasis:entry colname="col3">3 <inline-formula><mml:math id="M189" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M190" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">26</mml:mn></mml:msup></mml:math></inline-formula>, 3.9 <inline-formula><mml:math id="M191" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M192" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">MPa<inline-formula><mml:math id="M193" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.8</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> s<inline-formula><mml:math id="M194" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M195" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Dislocation creep activation energy (<inline-formula><mml:math id="M196" display="inline"><mml:mo lspace="0mm">&gt;</mml:mo></mml:math></inline-formula> 259, <inline-formula><mml:math id="M197" display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> 259 K)</oasis:entry>
         <oasis:entry colname="col3">180, 60</oasis:entry>
         <oasis:entry colname="col4">kJ mol<inline-formula><mml:math id="M198" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M199" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">GBS creep activation energy (<inline-formula><mml:math id="M200" display="inline"><mml:mo lspace="0mm">&gt;</mml:mo></mml:math></inline-formula> 259, <inline-formula><mml:math id="M201" display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> 259 K)</oasis:entry>
         <oasis:entry colname="col3">192, 49</oasis:entry>
         <oasis:entry colname="col4">kJ mol<inline-formula><mml:math id="M202" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M203" display="inline"><mml:mrow><mml:msub><mml:mi>m</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Dislocation creep grain size exponent</oasis:entry>
         <oasis:entry colname="col3">0</oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M204" display="inline"><mml:mrow><mml:msub><mml:mi>m</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">GBS creep grain size exponent</oasis:entry>
         <oasis:entry colname="col3">1.4</oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M205" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Activation energy for grain growth</oasis:entry>
         <oasis:entry colname="col3">42</oasis:entry>
         <oasis:entry colname="col4">kJ mol<inline-formula><mml:math id="M206" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M207" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mi mathvariant="normal">gg</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Grain growth rate constant (lab, lab<inline-formula><mml:math id="M208" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>ice core)</oasis:entry>
         <oasis:entry colname="col3">1.36 <inline-formula><mml:math id="M209" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M210" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">20</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, 9.15 <inline-formula><mml:math id="M211" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M212" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">18</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">m<inline-formula><mml:math id="M213" display="inline"><mml:msup><mml:mi/><mml:mi>p</mml:mi></mml:msup></mml:math></inline-formula>​​​​​​​ s<inline-formula><mml:math id="M214" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M215" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Grain growth exponent (lab, lab<inline-formula><mml:math id="M216" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>ice core)</oasis:entry>
         <oasis:entry colname="col3">7.1, 6.03</oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M217" display="inline"><mml:mi mathvariant="italic">γ</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Average specific grain boundary energy</oasis:entry>
         <oasis:entry colname="col3">0.065</oasis:entry>
         <oasis:entry colname="col4">J m<inline-formula><mml:math id="M218" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M219" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M220" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Fraction of work done by dislocation and GBS creep</oasis:entry>
         <oasis:entry colname="col3">0.005–0.05</oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">to change grain boundary area</oasis:entry>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M221" display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Geometric constant</oasis:entry>
         <oasis:entry colname="col3">3</oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d1e3246">Below we use the grain growth parameters derived exclusively both from the
experiment AL5 and from the joint fit between the experimental and ice core
data (Table 1) in our application of the wattmeter and discuss the influence
of the grain growth exponent on the derived effective stress exponent for
creep in ice.</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Results</title>
      <p id="d1e3258">As described above we have used the theoretical framework of the wattmeter
(Austin and Evans, 2007, 2009) to develop a new grain size evolution model
for ice. In the following section, we will apply this grain size evolution
model (loosely referred to as the wattmeter) to estimate grain size in
several simplified systems where deformation is driven by either an imposed
velocity contrast across a 1-D shear zone or a variation in stress with
depth associated with a fixed surface slope.</p>
<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Steady-state grain size in a shear zone</title>
      <p id="d1e3268">We first use the wattmeter to predict grain size in a steady-state shear
zone deforming at a fixed strain rate. This setup is analogous to constant
strain rate laboratory experiments, such as those by Piazolo et al. (2013)
discussed in the following Section. In this end-member, we calculate
steady-state grain size by iterating between Eqs. (14) and (18) and assuming
the grain growth parameters from our joint fit of the Azuma et al. (2012)
experiments and the GRIP ice core data. In practice, we set an initial shear
stress and grain size. Using these values, we calculate viscosity and use
Eq. (18) to make a new estimate of the shear stress. Based on our new
estimate of shear stress and the corresponding strain rate (calculated from
the flow law), we use the wattmeter to calculate an<?pagebreak page4595?> updated steady-state
grain size (Eq. 14). These new estimates for stress and grain size are then
used to recalculate viscosity, which is in turn fed back in Eq. (18) for the
next iteration. We continue to iterate in this manner until the shear stress
varies by less than 0.1 %.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><?xmltex \currentcnt{3}?><?xmltex \def\figurename{Figure}?><label>Figure 3</label><caption><p id="d1e3273">Effective stress vs. grain size at <bold>(a)</bold> 240 K and <bold>(b)</bold> 265 K calculated for a shear zone of fixed width using the wattmeter. Dark and light blue symbols correspond to the steady-state grain size predicted from a single model simulation at a given strain rate. Dashed red lines show location of the piezometer (Jacka and Li, 1994). Model results are overlain on a deformation mechanism map for ice calculated at the appropriate temperature using the flow law parameters from Goldsby and Kohlstedt (2001). Background contours correspond to strain rate; the thick black line indicates the boundary between GBS-limited creep (upper left) and
dislocation creep (lower right). Under these conditions the location of the
field boundary and piezometer are very similar.</p></caption>
          <?xmltex \igopts{width=355.659449pt}?><graphic xlink:href="https://tc.copernicus.org/articles/15/4589/2021/tc-15-4589-2021-f03.png"/>

        </fig>

      <p id="d1e3288">The result is an estimate of stress and grain size within the shear zone for
any imposed strain rate; Fig. 3a and b show these estimates calculated at
temperatures of 240 and 265 K, respectively. As noted above, the dominant
deformation mechanism in ice is sensitive to both grain size and stress,
with higher stresses and larger grain sizes favoring dislocation creep and
lower stresses and smaller grain sizes favoring GBS-limited creep (Fig. 1).
We illustrate the transition between dislocation and GBS creep (often
referred to as the “field boundary”) using a deformation mechanism map
(Fig. 3). Here we assume that a deformation mechanism acting in kinetic
parallel with other creep mechanisms is the dominant mechanism if it yields
the fastest creep rate. By overlaying the stresses and grain sizes predicted
from the wattmeter on deformation maps calculated at the corresponding
temperature, we show how variations in strain rate lead to a transition in
the dominant deformation mechanism (Fig. 3).</p>
      <p id="d1e3292">The relationship between grain size and stress predicted by the wattmeter
does not change significantly as a function of temperature but has a steeper
slope compared to either the field boundary or the piezometer (Jacka and
Li, 1994). For example, both the 240 and 265 K shear zones predict a
transition from dislocation to GBS-limited creep at a grain size of 0.2–0.3 mm and a stress of 1–2 MPa (Fig. 3). By contrast, the strain rate at which
the shear zone is predicted to cross the field boundary varies from
3 <inline-formula><mml:math id="M222" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M223" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> to 1 <inline-formula><mml:math id="M224" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M225" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> s<inline-formula><mml:math id="M226" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for temperatures of 240 and 265 K, respectively. These results indicate that when grain size is
allowed to vary with the evolving deformation conditions, the dominant
deformation mechanism will not be strongly affected by variations in
temperature, but the strain rate corresponding to a specific grain size (and
stress) will vary due to the Arrhenius behavior of creep (Eq. 16).</p>
      <p id="d1e3345">We also examine the relationship between stress and strain rate in the shear
zone, comparing cases with a fixed grain size to those in which grain size
evolves according to the wattmeter (Fig. 4a). Consistent with the laboratory
experiments shown in Fig. 1, the fixed grain size calculations show a
distinct change in slope corresponding to the transition from a stress
exponent of <inline-formula><mml:math id="M227" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M228" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1.8 in the GBS-limited creep regime to a value of <inline-formula><mml:math id="M229" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M230" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 4 in
the dislocation creep regime (Fig. 4b). By contrast, the wattmeter predicts
a more subdued change in slope in the GBS-limited field corresponding to a
higher effective stress exponent (<inline-formula><mml:math id="M231" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 2.5) than the lab-derived
value of <inline-formula><mml:math id="M232" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M233" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1.8. At higher strain rates and stresses the wattmeter
converges to the dislocation creep stress exponent (Fig. 4b). We discuss the
origin of these differences in the effective stress exponent in Sect. 4.1.</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F4"><?xmltex \currentcnt{4}?><?xmltex \def\figurename{Figure}?><label>Figure 4</label><caption><p id="d1e3400"><bold>(a)</bold> Comparison of strain rate vs. stress predicted for a constant grain size of 1 mm (colored lines) to those predicted by the steady-state grain size calculated from the wattmeter (colored symbols). Dark blue and light blue colors correspond to temperatures of 240 and 265 K,
respectively. Wattmeter calculations correspond to those shown in Fig. 3 for
a shear zone of fixed width. <bold>(b)</bold> Effective stress exponent as a function of strain rate predicted from the model. The effective stress exponent is calculated from the slope of the strain rate vs. stress curve shown in panel <bold>(a)</bold>. For cases with a fixed grain size, the stress exponent transitions from the experimentally derived value for GBS-limited creep (at low strain rate) to the value for dislocation creep (at high strain rate). The effective stress exponent in the GBS-limited creep regime calculated from the wattmeter is higher than the experimentally determined value and remains closer to the Glen law value of <inline-formula><mml:math id="M234" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3 for strain rates typical of natural systems.</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://tc.copernicus.org/articles/15/4589/2021/tc-15-4589-2021-f04.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS2">
  <label>3.2</label><title>Application of the shear zone model to laboratory experiments</title>
      <p id="d1e3432">Piazolo et al. (2013) investigated grain size changes as a function of
strain in a series of experiments conducted at different strain rates. These
experiments are ideal for benchmarking and calibrating the wattmeter as we
can compare the final grain size to the steady-state value in Eq. (14) and
also evaluate the evolution of grain size as a function of time (determined
from the strain given an imposed strain rate) using Eq. (13). Here we
investigate a series of cases using the grain growth parameters from the
joint fit of the Azuma et al. (2012) experiments and the GRIP ice core data,
as well as those derived exclusively from experiment AL5 (Fig. 5). Further,
we vary the fraction of the total work rate that is responsible for
increases in internal energy assuming <inline-formula><mml:math id="M235" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. Following the experimental setup of<?pagebreak page4596?> Piazolo et al. (2013), we
assume an initial grain size of 0.5 mm and use Eq. (13) to calculate grain
size as a function of strain for the strain rates used in the experiments.
Simulations were performed to a strain of 0.2, by which time all cases have
achieved a steady-state grain size.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5" specific-use="star"><?xmltex \currentcnt{5}?><?xmltex \def\figurename{Figure}?><label>Figure 5</label><caption><p id="d1e3459">Comparison of wattmeter to experimental data on grain size
evolution from Piazolo et al. (2013). Calculations are performed assuming a
shear zone with an imposed strain rate corresponding to the laboratory
experiments (1 <inline-formula><mml:math id="M236" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M237" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> s<inline-formula><mml:math id="M238" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> black; 2.5 <inline-formula><mml:math id="M239" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M240" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> s<inline-formula><mml:math id="M241" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> red; 6 <inline-formula><mml:math id="M242" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M243" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">7</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> s<inline-formula><mml:math id="M244" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> blue). Initial grain size is set to 0.5 mm, and grain size evolution is calculated as a function of time and strain using Eq. (13). Panels <bold>(a)</bold>, <bold>(c)</bold>, and <bold>(e)</bold> show results using the grain growth parameters from the joint fit between the laboratory and ice core data (black line in Fig. 2); panels <bold>(b)</bold>, <bold>(d)</bold>, and <bold>(f)</bold> show results using the grain growth parameters from Azuma et al. (2012) experiment AL5. Rows indicate calculations using different values for <inline-formula><mml:math id="M245" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M246" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M247" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M248" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M249" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> ranging from <bold>(a, b)</bold> 0.05, <bold>(c, d)</bold> 0.01, to <bold>(e, f)</bold> 0.005.​​​​​​​</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://tc.copernicus.org/articles/15/4589/2021/tc-15-4589-2021-f05.png"/>

        </fig>

      <p id="d1e3634">As expected, increasing <inline-formula><mml:math id="M250" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula> results in a smaller steady-state grain
size and a more rapid convergence to the steady-state value with increasing
strain (Fig. 5). In general, all cases produce the relative variations in
grain size as a function of strain rate shown by the experimental data;
however, the grain growth parameters derived from experiment AL5 combined
with <inline-formula><mml:math id="M251" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.005</mml:mn></mml:mrow></mml:math></inline-formula>–0.01 provide better fits to the data (Fig. 5e, f).</p>
</sec>
<sec id="Ch1.S3.SS3">
  <label>3.3</label><title>Steady-state grain size in a 1-D vertical column of ice</title>
      <p id="d1e3664">We next investigate predictions of the wattmeter for a 1-D vertical column
of ice in which stress as a function of depth is controlled by the surface
slope and ice density (Eq. 20). This setup is analogous to deformation
within a deforming ice body and thus can be directly compared with grain
size values derived from ice cores. We first simulate a theoretical 1 km
column of ice with a surface slope of 2<inline-formula><mml:math id="M252" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>, ice density of
920 kg m<inline-formula><mml:math id="M253" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, and constant temperature of 253 K. We calculate the
steady-state grain size, velocity, strain rate, and effective stress
exponent as a function of depth assuming <inline-formula><mml:math id="M254" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.01</mml:mn></mml:mrow></mml:math></inline-formula> (Fig. 6a). The effective stress exponent is calculated from
the numerical solution using the local gradient in stress and strain rate
with depth. Grain size decreases with depth due to the increase in stress
lower in the<?pagebreak page4597?> column (which drives recrystallization), while grain growth
dominates near the surface. Compared to cases with a constant grain size,
grain size evolution produces larger gradients in velocity and strain rate
with depth as the fine-grained ice softens near the bed (Fig. 6b, c).
Calculations with grain growth parameters derived from either the joint fit
of the experimental and ice core data or exclusively from
experiment AL5 result in similar grain size profiles, with the joint fit
predicting slightly smaller grain sizes and correspondingly higher strain
rates at the base of the column.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6" specific-use="star"><?xmltex \currentcnt{6}?><?xmltex \def\figurename{Figure}?><label>Figure 6</label><caption><p id="d1e3716"><bold>(a)</bold> Steady-state grain size, <bold>(b)</bold> velocity, <bold>(c)</bold> strain rate, and <bold>(d)</bold> effective stress exponent, <inline-formula><mml:math id="M255" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">eff</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> calculated as a function of
depth. The effective stress exponent is calculated from our model using the
local gradients in stress and strain rate. Red and blue curves correspond to
calculations using the grain growth parameters from the Azuma et al. (2012)
experiment AL5 and the joint fit of the experimental and ice core data,
respectively; shading denotes error bounds based on uncertainty in fit of
the grain growth data. Black curves show constant grain sizes of 1 mm
(solid), 3 mm (dashed), and 10 mm (dotted). The green curve shows calculations
based on the piezometer of Jacka and Li (1994). Note that the effective
stress exponents calculated using the wattmeter fall in a range similar to
the Glen law (<inline-formula><mml:math id="M256" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">eff</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M257" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 2.5–3). <bold>(e–h)</bold> Same as panels <bold>(a)</bold>–<bold>(d)</bold>, comparing cases using different values for <inline-formula><mml:math id="M258" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M259" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M260" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M261" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M262" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://tc.copernicus.org/articles/15/4589/2021/tc-15-4589-2021-f06.png"/>

        </fig>

      <p id="d1e3819">Further, we explore the sensitivity of our results to the range in
<inline-formula><mml:math id="M263" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula> used in our comparison to the laboratory data (<inline-formula><mml:math id="M264" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M265" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.005–0.015). Although <inline-formula><mml:math id="M266" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula> is
poorly constrained (Austin and Evans, 2007, 2009), these values are in the
range determined by applying the wattmeter to recrystallization of quartzite
(Tokle and Hirth, 2021) and olivine (Holtzman et al., 2018). In general,
we find that the differences in the wattmeter predictions due to the
uncertainty in <inline-formula><mml:math id="M267" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula> (Fig. 6e–h) are smaller than the variations
associated with the uncertainty in the grain growth parameters (Fig. 6a–d).</p>
      <p id="d1e3873">The profiles of velocity and strain rate have a similar functional form to
those calculated for a fixed grain size; however, the effective stress
exponent varies significantly between the fixed grain size cases and those
with grain size evolution. With a fixed grain size, the effective stress
exponent varies from <inline-formula><mml:math id="M268" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">eff</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M269" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1.8 at the surface to <inline-formula><mml:math id="M270" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">eff</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M271" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 2.6 to
3.7 at the bed for grain sizes of 1 and 10 mm (Fig. 6d). By contrast, the
wattmeter predicts an effective stress exponent that varies from
<inline-formula><mml:math id="M272" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2.5 at the surface to <inline-formula><mml:math id="M273" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3 at the bed. This
result is insensitive to the choice of <inline-formula><mml:math id="M274" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula> (Fig. 6h). Thus, similar to
the fixed-width shear zone models, the 1-D vertical column predicts
effective stress exponents more similar to the Glen law value compared to
cases with a fixed grain size.</p>
      <p id="d1e3934">Finally, we compare the wattmeter predictions to those using a piezometric
relationship relating grain size directly to stress (Jacka and Li, 1994).
The piezometer predicts significantly larger grain sizes in the shallow
portion of the column compared to the wattmeter but reaches similar values
near the bed (green curves in Fig. 6). Overall, the piezometer results in
smaller strain rates throughout most of the column and a significantly
higher effective stress exponent (<inline-formula><mml:math id="M275" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">eff</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M276" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3.9), similar to
the experimental value for dislocation creep.</p>
</sec>
<?pagebreak page4598?><sec id="Ch1.S3.SS4">
  <label>3.4</label><title>Application of 1-D ice column model to ice core data</title>
      <p id="d1e3964">To investigate how well the wattmeter predicts grain sizes observed in
natural ice cores, we next apply the 1-D vertical column model to grain
sizes measured in the GISP2 ice core (Gow et al., 1997) using the linear
intercept method (Alley and Woods, 1996). For comparison to GISP2, we
assume a column thickness of 3 km and the temperature profile of Clow et al. (1995, 1996), which varies from <inline-formula><mml:math id="M277" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 241 K at the surface to 263 K at
the bed. Stress is calculated using a constant ice density of 920 kg m<inline-formula><mml:math id="M278" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>
(Gow et al., 1997) and a surface slope of 0.11<inline-formula><mml:math id="M279" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> (Hvidberg et
al., 1997). We assume <inline-formula><mml:math id="M280" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.01</mml:mn></mml:mrow></mml:math></inline-formula> given the success in using these values to reproduce
the Piazolo et al. (2013) experimental data.</p>
      <p id="d1e4017">One important caveat of the 1-D column models shown in Fig. 6 is that the
timescale to reach a steady-state grain size, particularly in the shallow
portion of the column where strain rates are small, may be greater than
10<inline-formula><mml:math id="M281" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mn mathvariant="normal">4</mml:mn><mml:mo>-</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> years. Thus, to compare our model predictions with the ice core
data, where the shallowest ice is the youngest ice, we use the
time-dependent formulation in Eq. (13) and calculate grain size as a
function of time at each depth assuming a fixed surface slope. The age of
the ice at each depth is taken from Ram et al. (2000). Incorporating time
dependence into our 1-D column calculations does not change the predicted
grain sizes near the base of the column where the ice is sufficiently old
for grain size to reach steady state. However, it significantly reduces
grain sizes in the shallow part of the column, where the young ice does not
have sufficient time to reach steady state (dotted curves, Fig. 7).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7"><?xmltex \currentcnt{7}?><?xmltex \def\figurename{Figure}?><label>Figure 7</label><caption><p id="d1e4036">Grain size calculated as a function of depth within the GISP2 ice
core. Red and blue curves correspond to calculations using the grain growth
parameters from Azuma et al. (2012) experiment AL5 and the joint fit of the
experimental and ice core data, respectively. Solid curves show
time-dependent grain size calculations; dashed curves are the steady-state
grain size. The dashed curve shows the calculation in which we use the bubble-free
grain growth parameters from Exp. 15 of Azuma et al. (2012) and enhance
dislocation creep by a factor of 10 in the lowermost 200 m of ice. The
enhancement in dislocation creep is meant to simulate the development of
fabric in the basal ice. Black dots show observed grain sizes taken from Gow
et al. (1997).</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://tc.copernicus.org/articles/15/4589/2021/tc-15-4589-2021-f07.png"/>

        </fig>

      <?pagebreak page4599?><p id="d1e4046">Overall, we find a good fit between the grain sizes predicted by the
wattmeter and those recorded in the GISP2 ice core. Surface velocities
predicted by the wattmeter (<inline-formula><mml:math id="M282" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 1 m yr<inline-formula><mml:math id="M283" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) are also in agreement
with those observed near the GISP2 site (Hvidberg et al., 1997). There is
little sensitivity to using the grain growth parameters from the Azuma et
al. (2012) AL5 experiment only (red curves, Fig. 7) versus the joint fit to
all experiments and the ice core data (blue curves, Fig. 7). The one major
deviation between the grain size predictions of the wattmeter and the
observed grain sizes occurs at the very base of the core. In this region,
observed grain sizes increase up to <inline-formula><mml:math id="M284" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 10 mm at the bed, while
the wattmeter predicts grain sizes that monotonically decrease to a value of
<inline-formula><mml:math id="M285" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2 mm. These deviations are discussed in Sect. 4.2 below.</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Discussion</title>
      <p id="d1e4091">Grain size is a key microphysical property of ice, controlling not only its
creep behavior but also its fracture toughness, melt permeability, and seismic
attenuation and wave speeds. Thus, knowledge of its variability is critical
to interpreting the physical properties and dynamic behavior of ice sheets
and glaciers. The success of the wattmeter in predicting the grain sizes
observed in both the Piazolo et al. (2013) shear zone experiments (Fig. 5)
and the GISP2 ice core data (Fig. 7) provides a strong indication that the
wattmeter captures the first-order physics of grain size evolution in ice.
We emphasize that the fit of the model to these two very different systems
is achieved using the same model parameters and requires no setting-specific
tuning of the model. In the discussion below, we first consider the
implications of grain size evolution in reconciling the laboratory creep
data with the Glen law. Second, we explore the application of our model to
the interpretation of grain size in ice core data. Finally, we discuss the
implications of grain size evolution on strain enhancement and strain
localization in ice sheets and glaciers.
<?xmltex \hack{\newpage}?></p>
<sec id="Ch1.S4.SS1">
  <label>4.1</label><title>Implications for the Glen law and the stress exponent in ice</title>
      <p id="d1e4102">As illustrated in both the steady-state shear zone models (Fig. 4b) and the
simulations of a 1-D column of ice deforming due to a surface slope (Fig. 6b), the wattmeter results in an effective stress exponent that is
intermediate between the lab-derived values for dislocation and GBS-limited
creep and approaches the <inline-formula><mml:math id="M286" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M287" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 3 value of the Glen law. To interpret these
results, we reconsider the end-member cases of deformation accommodated
solely by either dislocation or GBS-limited creep. In the dislocation creep
regime, deformation is not sensitive to grain size (i.e., <inline-formula><mml:math id="M288" display="inline"><mml:mrow><mml:msub><mml:mi>m</mml:mi><mml:mi mathvariant="normal">disl</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M289" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0 in
Eq. 16), and we expect no difference in creep behavior or the effective
stress exponent as a function of grain size. By contrast, in GBS-limited
creep, strain rate is sensitive to both stress and grain size. Further, the
steady-state grain size calculated by the wattmeter will vary as a function
of stress and strain rate (Eq. 14). Thus, substituting the expression for
steady-state grain size, <inline-formula><mml:math id="M290" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mi mathvariant="normal">ss</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> in Eq. (14), into the flow law (Eq. 16) we
find that strain rate can be related to stress through an effective stress
exponent <inline-formula><mml:math id="M291" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">eff</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> that is proportional to <inline-formula><mml:math id="M292" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M293" display="inline"><mml:mrow><mml:msub><mml:mi>m</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, and the grain
growth exponent <inline-formula><mml:math id="M294" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula>:
            <disp-formula id="Ch1.E21" content-type="numbered"><label>21</label><mml:math id="M295" display="block"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">eff</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mfenced open="(" close=")"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>+</mml:mo><mml:mi>p</mml:mi></mml:mrow></mml:mfenced><mml:mo>+</mml:mo><mml:msub><mml:mi>m</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>+</mml:mo><mml:mi>p</mml:mi><mml:mo>-</mml:mo><mml:msub><mml:mi>m</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
          Using laboratory-determined values for <inline-formula><mml:math id="M296" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M297" display="inline"><mml:mrow><mml:msub><mml:mi>m</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (Table 1) and
the grain growth exponent fit by the laboratory and ice core data (<inline-formula><mml:math id="M298" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M299" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 6.2),
we find <inline-formula><mml:math id="M300" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">eff</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> for GBS-limited creep is equal to <inline-formula><mml:math id="M301" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2.5. This
value corresponds to the effective stress exponent calculated in the shear
zone at low stress and strain rate (Fig. 4b) and is higher than the
laboratory-derived value at a constant grain size.</p>
      <p id="d1e4296">We note that this expression for the effective stress exponent is only valid
in the limit of steady-state grain size. Processes that limit a change of
grain size in the GBS regime will result in a stress exponent closer to the
lab-derived value. For example, some experiments have shown that grain
growth may be limited during GBS creep (Goldsby and Kohlstedt, 2001;
Caswell and Cooper, 2017); moreover, in natural ice impurities may also
limit grain growth (e.g., Alley and Woods, 1996). Future experiments under
different conditions (e.g., initial grain size, impurity and bubble
distribution, deformation mechanism) are necessary to further constrain
these effects on grain growth.</p>
      <?pagebreak page4600?><p id="d1e4299">Comparison of the constant grain size shear zone models to those using the
wattmeter shows that both predict a transition in the effective stress
exponent near the field boundary at strain rates of 10<inline-formula><mml:math id="M302" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> to 10<inline-formula><mml:math id="M303" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> yr<inline-formula><mml:math id="M304" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (Fig. 4b). When grain size is fixed and does not evolve,
<inline-formula><mml:math id="M305" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">eff</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> varies from the lab-derived values for GBS (1.8) and dislocation creep (4) and only coincides with the Glen law (<inline-formula><mml:math id="M306" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M307" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 3 <inline-formula><mml:math id="M308" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.5) over a narrow range of strain rates (e.g., 3 <inline-formula><mml:math id="M309" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M310" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>–3 <inline-formula><mml:math id="M311" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M312" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> yr<inline-formula><mml:math id="M313" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>
for a shear zone temperature of 240 K; Fig. 4b). By contrast, the variation
in <inline-formula><mml:math id="M314" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">eff</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> derived for steady-state grain size from the wattmeter varies
less dramatically with strain rate and is within the range of 3 <inline-formula><mml:math id="M315" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.5
for all strain rates found in natural systems. Thus, the stress dependence
of grain size evolution, when coupled to the composite flow law (Eq. 15),
provides an explanation for why the effective stress exponent in ice is
consistent with the Glen law, even though neither dislocation nor GBS creep
have stress exponents of <inline-formula><mml:math id="M316" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3.</p>
      <p id="d1e4444">Further, when grain size evolves according to the wattmeter, smaller values
of the grain growth exponent <inline-formula><mml:math id="M317" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> will result in larger values of <inline-formula><mml:math id="M318" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">eff</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (Eq. 21), which becomes infinite when <inline-formula><mml:math id="M319" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M320" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> (<inline-formula><mml:math id="M321" display="inline"><mml:mrow><mml:msub><mml:mi>m</mml:mi><mml:mi mathvariant="normal">GBS</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula>). For example, if <inline-formula><mml:math id="M322" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M323" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 2
the effective stress exponent for GBS-limited creep becomes 4.25. In this
scenario, neither dislocation creep nor GBS-limited creep would result in an
effective stress exponent that is consistent with the Glen law value. As
noted above, some observations support a stress exponent <inline-formula><mml:math id="M324" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 3 (Budd
and Jacka, 1989; Cuffey and Kavanaugh, 2011). These data could be
consistent with grain-size-insensitive dislocation creep or grain-size-sensitive creep with a <inline-formula><mml:math id="M325" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> value around 2, similar to bubble-free ice (Azuma et al., 2012). However, with <inline-formula><mml:math id="M326" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M327" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 2 the wattmeter underpredicts the grain size
in the laboratory experiments and significantly overpredicts the grain size
in the GISP2 ice core. This supports our application of the wattmeter using
a <inline-formula><mml:math id="M328" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> value consistent with the larger grain growth exponents inferred from
bubble-rich experiments (Azuma et al., 2012). Intriguingly in the
theoretical limit of grain growth in the presence of inclusions (<inline-formula><mml:math id="M329" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M330" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 3–4;
Evans et al., 2001) the effective stress exponent becomes 3.3–2.9 for
steady-state grain size in the GBS regime.</p>
      <p id="d1e4560">Equation (21) can also be used to predict the effective stress exponent for creep
in other geologic materials that undergo grain-size-sensitive creep and
whose grain size evolution can be predicted by the wattmeter. For example,
Hansen et al. (2012) found that at a constant grain size GBS creep in olivine
is described by flow law parameters <inline-formula><mml:math id="M331" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M332" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 4.1 and <inline-formula><mml:math id="M333" display="inline"><mml:mi>m</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M334" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.73. However, in high-strain experiments when grain size evolution occurred, the effective stress
exponent increased to <inline-formula><mml:math id="M335" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M336" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 5. Plugging the constant grain size parameters for GBS creep into Eq. (21) and assuming a grain growth exponent of <inline-formula><mml:math id="M337" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M338" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 3 for olivine (Karato, 1989), we calculate an effective stress exponent of <inline-formula><mml:math id="M339" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">eff</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M340" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 5.1, consistent with the experimentally determined value from
the Hansen et al. (2012) experiments. This provides additional evidence that
the wattmeter can be used to capture the physics of grain-size-sensitive
creep.</p>
</sec>
<sec id="Ch1.S4.SS2">
  <label>4.2</label><title>Implications for grain size in ice cores</title>
      <p id="d1e4646">Ice cores show three primary grain size regimes (e.g., Gow and Williamson,
1976; Herron and Langway, 1982; Thorsteinson et al., 1997): (1) a zone of
increasing grain size in the upper several hundred meters of ice, (2) a
region of relatively constant to slightly decreasing grain size at
intermediate depths, and (3) a zone of rapidly increasing grain size near
the bed. These variations have frequently been interpreted in terms of the
<italic>tripartite paradigm</italic> or three-stage model (e.g., Alley, 1988, 1992; De la Chapelle et al., 1998), in
which Regime 1 is associated with normal grain growth, Regime 2 reflects a
balance between normal grain growth and polygonization, and Regime 3 is
attributed to migration recrystallization. The later process reflects a
combination of rapid grain boundary migration and the nucleation of new
grains when temperatures exceed 263 K (Duval and Castelnau, 1995).</p>
      <p id="d1e4652">More recent studies (e.g., Faria et al., 2014a) have argued that the
tripartite model may be an oversimplification, as other processes besides
normal grain growth appear to be operating at shallow depths (Kipfstuhl et
al., 2006, 2009). Faria et al. (2014a) refer to the process by which grains
coarsen while simultaneously undergoing deformation as “dynamic grain
growth”. The wattmeter inherently captures the balance between grain growth
and grain size reduction, predicting grain sizes that vary continuously
between Regimes 1 and 2. However, as noted above, the wattmeter does not
explain the increase in grain size observed in Regime 3 near the base of the
GISP2 core (Fig. 7) and other ice cores, such as Byrd (Gow and Williamson,
1976), GRIP (Thorsteinsson, et al., 1997), and Law dome (Li et al., 1998).
The reason is that the higher stresses and higher strain rates near the bed
promote grain size reduction, which dominates the temperature dependence of
grain growth even as ice temperatures approach 263 K. One possible
explanation for this discrepancy is that grain growth kinetics change as ice
enters the pre-melting regime at temperatures <inline-formula><mml:math id="M341" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 263 K due to
enhanced grain boundary mobility and the role of migration recrystallization
in the formation of new grains (Duval and Castelnau, 1995; Hamann et al.,
2007). Further, micro-particles on grain boundaries may become more mobile,
possibly reducing their pinning effect and leading to enhanced grain growth
(Evans et al., 2001).</p>
      <p id="d1e4662">As a simple test of this hypothesis, we substituted the bubble-free grain
growth kinetics from Azuma et al. (2012) experiment T15 (conducted at 263 K)
into the lowermost 200 m of our model for GISP2. The result is to increase
grain sizes in the basal ice to <inline-formula><mml:math id="M342" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 100 mm. This is
approximately an order of magnitude greater than the maximum observed
values. However, fabric development can lead to significant weakening in
regions of high strain, such as near the bed. Approximating this weakening
effect by multiplying the pre-exponential term in the dislocation creep law
by an enhancement factor of 10 (Cuffey and Paterson, 2010) and using the
bubble-free grain growth kinetics provides a good fit to the observations as
shown by the dashed line in Fig. 7. While these results are suggestive,
future work on grain growth kinetics in the pre-melting regime and the
feedback between grain size evolution and strain rate enhancement due to
fabric development is needed to fully explore these effects.</p>
      <p id="d1e4672">Another caveat of our predictions for grain size is that we have made no
attempt to incorporate local-scale heterogeneities in impurity contents. The
role of impurities is well<?pagebreak page4601?> known to influence grain size in ice cores on
multiple spatial and temporal scales. At the centimeter scale, “forest-fire”
bands characterized by high ammonium contents and low electrical
conductivities are observed to correlate with local reductions in grain size
(e.g., Alley and Woods, 1996). Major climatic transitions, such as that
associated with the Holocene and Last Glacial Maximum (LGM), are also seen to
correlate with variations in grain size (e.g., Duval and Lorius, 1980;
Herron et al., 1985; Gow et al., 1997; Li et al., 1998) and zones of
enhanced strain rate (e.g., Fisher and Koerner, 1986). Indeed, Durand et
al. (2006) argue that grain growth pinned by a combination of dust, bubbles
and clathrates is the dominant control on grain size variability in the Dome
Concordia core. While incorporating heterogeneous impurity contents is
beyond the immediate scope of this study, the wattmeter provides a framework
to include such heterogeneities through the use of variable grain growth
parameters tuned for different impurity contents. This further highlights
the need for additional grain growth experiments under various impurity
contents and temperature conditions.</p>
</sec>
<sec id="Ch1.S4.SS3">
  <label>4.3</label><title>Grain size evolution and the origin of enhancement factors to the Glen law</title>
      <p id="d1e4683">While the Glen law provides an excellent description of ice flow in many
settings, certain systems are characterized by larger strain rates than
predicted. In such cases, an ad hoc strain enhancement factor is often
incorporated into the pre-exponential term of the Glen law to account for
the combined effects of grain size, impurities, fabric development, and
shear heating (see Cuffey and Paterson, 2010). For example, matching
velocity profiles across ice streams (e.g., Echelmeyer et al., 1994; Jackson
and Kamb, 1997) and through Pleistocene ice near the base of the Greenland
ice sheet (Dahl-Jensen and Gunderstrup, 1987; Shoji and Langway, 1988;
Lüthi et al., 2002; Ryser et al., 2014) often requires enhancement
factors in the range of 2–10. Cuffey et al. (2000) attempted to quantify
the role of grain size in the enhancement factor based on deformation
recorded in Meserve Glacier, Antarctica. The grain size evolution model
developed here provides additional constraints on the role of grain size in
enhanced flow and strain localization in ice.</p>
      <p id="d1e4686">To illustrate this point, we model deformation within Drill Site D in fast-moving ice near Jakobshavn Isbrae in western Greenland (Iken et al., 1993;
Lüthi et al., 2002). This site experiences surface velocities of
<inline-formula><mml:math id="M343" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 600 m yr<inline-formula><mml:math id="M344" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, and tiltmeter data indicate enhanced strain rates
in temperate ice below the Holocene–LGM transition near the bed. Lüthi
et al. (2002) developed a thermomechanical model for deformation in the
borehole and found that after incorporating the temperature dependence of
ice viscosity, enhancement factors of 1.7–2.6 were required to match the
observations in the pre-Holocene ice below 680 m. Although neither grain
size nor impurity contents were measured in the Site D core, Lüthi et
al. (2002) interpreted the enhanced strain rates to reflect smaller grain
sizes associated with higher impurity contents below the Holocene–LGM
transition.</p>
      <p id="d1e4708">In Fig. 8 we apply the wattmeter to model deformation with Site D using
the same approach as for the GISP2 core (Sect. 3.3) assuming a surface slope
of 2<inline-formula><mml:math id="M345" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>, an ice thickness of 830 m, downhole temperatures
from Iken et al. (1993), and the age model of Lüthi et al. (2002).
Calculated grain sizes vary from <inline-formula><mml:math id="M346" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2 mm near the surface to
<inline-formula><mml:math id="M347" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.5 mm near the bed (Fig. 8a). Comparing the corresponding
strain rates to those calculated for a case using a constant grain size of 1 mm, we predicted enhancement factors of 1.9–2.5 in ice below
<inline-formula><mml:math id="M348" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 700 m depth (Fig. 8c). Further, while there are no
constraints on grain size for direct comparison, the surface velocity
calculated from our model compares favorably with those observed at the Site
D location (Fig. 8b). Thus, without invoking additional pinning effects
beyond those incorporated in the grain growth exponents extrapolated from
the laboratory and GRIP ice core data (Fig. 2), the wattmeter provides a
good match to the available observations.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8"><?xmltex \currentcnt{8}?><?xmltex \def\figurename{Figure}?><label>Figure 8</label><caption><p id="d1e4744"><bold>(a)</bold> Grain size, <bold>(b)</bold> velocity, and <bold>(c)</bold> strain rate enhancement factor calculated as a function of depth for Drill Site D (Lüthi et al., 2002). Red and blue curves correspond to calculations using the grain growth parameters from Azuma et al. (2012) experiment AL5 and the joint fit of the experimental and ice core data, respectively. The black curve in panel <bold>(b)</bold> corresponds
to a case with a constant grain size of 1 mm. Enhancement factor is
calculated as the ratio of the strain rate determined by the wattmeter to
the strain rate calculated assuming a constant grain size of 1 mm.</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://tc.copernicus.org/articles/15/4589/2021/tc-15-4589-2021-f08.png"/>

        </fig>

      <p id="d1e4764">We stress that these results are not meant to imply that elevated impurity
contents have no influence on grain size and deformation rates but simply
that first-order variations in these parameters are successfully captured by
the wattmeter. Moreover, the enhanced strain rates associated with grain
size reduction illustrate the potential importance of grain size evolution
on strain localization. Indeed, the extreme strain localization in ice
stream margins (e.g., Harrison et al., 1998) may be partially accommodated
by grain size reduction, in combination with shear heating (e.g., Suckale et
al., 2014; Perol and Rice, 2015). Further, the development of crystal
fabric in the shear plane will weaken ice (Duval et al., 1983), resulting in
a larger strain rate for the same stress. In the<?pagebreak page4602?> 1-D ice column models,
stress is fixed by the surface slope, resulting in a positive feedback in
which enhanced fabric development will drive further grain size reduction
(due to the enhanced work rate). Future studies that simultaneously measure
deformation, grain size, crystal fabric, and impurity contents – ideally in
regions of high strain rates – will be critical to improving coupled models
of deformation and grain size evolution in ice sheets and glaciers.</p>
</sec>
</sec>
<sec id="Ch1.S5" sec-type="conclusions">
  <label>5</label><title>Conclusions</title>
      <p id="d1e4777">We used the wattmeter (Austin and Evans, 2007, 2009) to calculate the
balance between the mechanical work required for grain growth and for
dynamic grain size reduction. Combining the wattmeter with a composite flow
law for dislocation and GBS creep, we developed a system of coupled
equations that can be used to predict grain size evolution in terms of
temperature, stress, and strain rate. Applying this methodology to grain
sizes recorded in laboratory shear deformation experiments and the GISP2
borehole, we show that this approach successfully predicts grain size over a
wide range of conditions.</p>
      <p id="d1e4780">When grain size evolution is accounted for using the wattmeter, we find that
ice deforms with an effective stress exponent of <inline-formula><mml:math id="M349" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M350" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 3.0 <inline-formula><mml:math id="M351" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.5 at
most natural conditions. This provides an explanation for the long-standing
paradox of why the Glen law so successfully describes flow in glaciers and
ice sheets, even though laboratory experiments show that neither dislocation
creep nor GBS creep have stress exponents consistent with <inline-formula><mml:math id="M352" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M353" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 3. Further,
the wattmeter provides a framework for interpreting settings where the
observed stress exponent is either higher or lower than 3, reflecting
deformation conditions favoring dislocation or GBS creep, respectively.
Additionally, grain size variations driven by local deformation conditions
can cause strain rate enhancement in regions where the Glen law alone cannot
explain observed variations in ice flow. In conclusion, the coupling of
grain size evolution and grain-size-sensitive creep provides a potentially
powerful tool for understanding strain localization and the effective stress
exponent in ice, as well as other geologic materials.</p>
</sec>

      
      </body>
    <back><notes notes-type="codeavailability"><title>Code availability</title>

      <p id="d1e4822">MATLAB<sup>®</sup> code to reproduce the model runs in this study is provided as a Supplement.</p>
  </notes><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d1e4831">GISP2 and GRIP ice core data are available at <ext-link xlink:href="https://doi.org/10.1594/PANGAEA.870454" ext-link-type="DOI">10.1594/PANGAEA.870454</ext-link> (GRIP Members, 2017).  Grain growth data were taken from Table 2 of Azuma et al. (2012); ice deformation data were digitized from Fig. 3 of Piazolo et al. (2014).</p>
  </notes><?xmltex \hack{\newpage}?><app-group>
        <supplementary-material position="anchor"><p id="d1e4838">The supplement related to this article is available online at: <inline-supplementary-material xlink:href="https://doi.org/10.5194/tc-15-4589-2021-supplement" xlink:title="zip">https://doi.org/10.5194/tc-15-4589-2021-supplement</inline-supplementary-material>.</p></supplementary-material>
        </app-group><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e4847">All authors participated in the formulation of the grain size evolution model for ice. MDB developed the model code and performed the simulations. DLG and GH assisted in the interpretation of the model results. MDB prepared the manuscript with contributions from all co-authors.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e4853">The authors declare that they have no conflict of interest.</p>
  </notes><notes notes-type="disclaimer"><title>Disclaimer</title>

      <p id="d1e4859">Publisher’s note: Copernicus Publications remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e4865">We thank Andrew Cross for suggestions on an earlier version of this paper and Josh Rines, Ludovic Räss, and Thibault Duretz for a careful reading of our paper and code.  Thoughtful reviews by Paul Bons, the anonymous reviewer, and the editor Carlos Martin greatly improved this study.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d1e4870">This research was supported by the National Science Foundation (grant nos. OPP-18-38410, EAR-16-6524109, and EAR-16-24178) and the NASA Solar System Workings program (grant no. NNX15AM69G).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d1e4877">This paper was edited by Carlos Martin and reviewed by Paul D. Bons and one anonymous referee.</p>
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    <!--<article-title-html>The role of grain size evolution in  the rheology of ice: implications for reconciling laboratory creep data and the Glen flow law</article-title-html>
<abstract-html><p>Viscous flow in ice is often described by the Glen flow law – a
non-Newtonian, power-law relationship between stress and strain rate with a
stress exponent <i>n</i>&thinsp; ∼ &thinsp;3. The Glen law is attributed to
grain-size-insensitive dislocation creep; however, laboratory and field
studies demonstrate that deformation in ice can be strongly dependent on
grain size. This has led to the hypothesis that at sufficiently low
stresses, ice flow is controlled by grain boundary sliding, which explicitly incorporates the grain size dependence of ice rheology. Experimental studies
find that neither dislocation creep (<i>n</i>&thinsp; ∼ &thinsp;4) nor grain boundary
sliding (<i>n</i>&thinsp; ∼ &thinsp;1.8) have stress exponents that match the value of
<i>n</i>&thinsp; ∼ &thinsp;3 in the Glen law. Thus, although the Glen law provides an
approximate description of ice flow in glaciers and ice sheets, its
functional form is not explained by a single deformation mechanism. Here we
seek to understand the origin of the <i>n</i>&thinsp; ∼ &thinsp;3 dependence of the
Glen law by using the <q>wattmeter</q> to model grain size evolution in ice.
The wattmeter posits that grain size is controlled by a balance between the
mechanical work required for grain growth and dynamic grain size reduction.
Using the wattmeter, we calculate grain size evolution in two end-member
cases: (1) a 1-D shear zone and (2) as a function of depth within an
ice sheet. Calculated grain sizes match both laboratory data  and ice core
observations for the interior of ice sheets. Finally, we show that
variations in grain size with deformation conditions result in an effective
stress exponent intermediate between grain boundary sliding and dislocation
creep, which is consistent with a value of <i>n</i>&thinsp; = &thinsp;3&thinsp;±&thinsp;0.5 over the range
of strain rates found in most natural systems.</p></abstract-html>
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