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  <front>
    <journal-meta><journal-id journal-id-type="publisher">TC</journal-id><journal-title-group>
    <journal-title>The Cryosphere</journal-title>
    <abbrev-journal-title abbrev-type="publisher">TC</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">The Cryosphere</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1994-0424</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/tc-14-4525-2020</article-id><title-group><article-title>The cryostratigraphy of the Yedoma cliff of Sobo-Sise Island (Lena delta)
reveals permafrost dynamics in the central Laptev Sea coastal region during
the last 52 kyr</article-title><alt-title>Cryostratigraphy of the Sobo-Sise Yedoma</alt-title>
      </title-group><?xmltex \runningtitle{Cryostratigraphy of the Sobo-Sise Yedoma}?><?xmltex \runningauthor{S.~{Wetterich} et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Wetterich</surname><given-names>Sebastian</given-names></name>
          <email>sebastian.wetterich@awi.de</email>
        <ext-link>https://orcid.org/0000-0001-9234-1192</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Kizyakov</surname><given-names>Alexander</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-4912-1850</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Fritz</surname><given-names>Michael</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-4591-7325</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Wolter</surname><given-names>Juliane</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Mollenhauer</surname><given-names>Gesine</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-5138-564X</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4">
          <name><surname>Meyer</surname><given-names>Hanno</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-4129-4706</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Fuchs</surname><given-names>Matthias</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-3529-8284</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5">
          <name><surname>Aksenov</surname><given-names>Aleksei</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-4950-4571</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff6">
          <name><surname>Matthes</surname><given-names>Heidrun</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-9913-7696</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Schirrmeister</surname><given-names>Lutz</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-9455-0596</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4 aff7">
          <name><surname>Opel</surname><given-names>Thomas</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-1315-8256</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Permafrost Research, Alfred Wegener Institute Helmholtz Centre for
Polar and Marine Research, Potsdam, Germany</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Cryolithology and Glaciology, Faculty of Geography, Lomonosov Moscow
State University, Moscow, Russia</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Marine Geochemistry, Alfred Wegener Institute Helmholtz Centre for Polar
and Marine Research, Bremerhaven, Germany</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>Polar Terrestrial Environmental Systems, Alfred Wegener Institute
Helmholtz Centre for <?xmltex \hack{\break}?>Polar and Marine Research, Potsdam, Germany</institution>
        </aff>
        <aff id="aff5"><label>5</label><institution>Polar Geography, Arctic and Antarctic Research Institute, St.
Petersburg, Russia</institution>
        </aff>
        <aff id="aff6"><label>6</label><institution>Atmospheric Physics, Alfred Wegener Institute Helmholtz Centre for
Polar and Marine Research, Potsdam, Germany</institution>
        </aff>
        <aff id="aff7"><label>7</label><institution>PALICE, Alfred Wegener Institute Helmholtz Centre for Polar and Marine
Research, Bremerhaven, Germany</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Sebastian Wetterich (sebastian.wetterich@awi.de)</corresp></author-notes><pub-date><day>10</day><month>December</month><year>2020</year></pub-date>
      
      <volume>14</volume>
      <issue>12</issue>
      <fpage>4525</fpage><lpage>4551</lpage>
      <history>
        <date date-type="received"><day>26</day><month>June</month><year>2020</year></date>
           <date date-type="rev-request"><day>24</day><month>July</month><year>2020</year></date>
           <date date-type="rev-recd"><day>22</day><month>September</month><year>2020</year></date>
           <date date-type="accepted"><day>18</day><month>October</month><year>2020</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2020 </copyright-statement>
        <copyright-year>2020</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://tc.copernicus.org/articles/.html">This article is available from https://tc.copernicus.org/articles/.html</self-uri><self-uri xlink:href="https://tc.copernicus.org/articles/.pdf">The full text article is available as a PDF file from https://tc.copernicus.org/articles/.pdf</self-uri>
      <abstract><title>Abstract</title>
    <p id="d1e215">The present study examines the formation history and
cryolithological properties of the late-Pleistocene Yedoma Ice Complex (IC) and
its Holocene cover in the eastern Lena delta on Sobo-Sise Island. The
sedimentary sequence was continuously sampled at 0.5 m resolution at a
vertical Yedoma cliff starting from 24.2 m above river level (a.r.l.). The
sequence differentiates into three cryostratigraphic units: Unit A, dated
from ca. 52 to 28 cal kyr BP; Unit B, dated from ca. 28 to 15 cal kyr BP; Unit
C, dated from ca. 7 to 0 cal kyr BP. Three chronologic gaps in the record are
striking. The hiatus during the interstadial marine isotope stage (MIS) 3 (36–29 cal kyr BP) as
well as during stadial MIS 2 (20–17 cal kyr BP) might be related to fluvial
erosion and/or changed discharge patterns of the Lena river caused by
repeated outburst floods from the glacial Lake Vitim in southern Siberia
along the Lena river valley towards the Arctic Ocean. The hiatus during the
MIS 2–1 transition (15–7 cal kyr BP) is a commonly observed feature in
permafrost chronologies due to intense thermokarst activity of the deglacial
period. The chronologic gaps of the Sobo-Sise Yedoma record are similarly
found at two neighbouring Yedoma IC sites on Bykovsky Peninsula and
Kurungnakh-Sise Island and are most likely of regional importance.</p>
    <p id="d1e218">The three cryostratigraphic units of the Sobo-Sise Yedoma exhibit distinct
signatures in properties of their clastic, organic, and ice components.
Higher permafrost aggradation rates of 1 m kyr<inline-formula><mml:math id="M1" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> with higher organic-matter (OM) stocks (29 <inline-formula><mml:math id="M2" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 15 kg C m<inline-formula><mml:math id="M3" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, 2.2 <inline-formula><mml:math id="M4" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.0 kg N m<inline-formula><mml:math id="M5" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>; Unit A) and mainly coarse silt are found for the interstadial MIS
3 if compared to the stadial MIS 2 with 0.7 m kyr<inline-formula><mml:math id="M6" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> permafrost
aggradation, lower OM stocks (14 <inline-formula><mml:math id="M7" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 8 kg C m<inline-formula><mml:math id="M8" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, 1.4 <inline-formula><mml:math id="M9" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.4 kg N m<inline-formula><mml:math id="M10" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>; Unit B), and pronounced peaks in the coarse-silt and medium-sand
fractions. Geochemical signatures of intra-sedimental ice reflect the
differences in summer evaporation and moisture regime by higher ion content
and less depleted ratios of stable <inline-formula><mml:math id="M11" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O  and stable <inline-formula><mml:math id="M12" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D isotopes  but
lower deuterium excess (<inline-formula><mml:math id="M13" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>) values during interstadial MIS 3 if compared to
stadial MIS 2. The <inline-formula><mml:math id="M14" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math id="M15" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D composition of MIS 3 and
MIS 2 ice wedges shows characteristic well-depleted values and low <inline-formula><mml:math id="M16" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values,
while MIS 1 ice wedges have elevated mean <inline-formula><mml:math id="M17" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values between
11 ‰ and 15 ‰ and surprisingly low
<inline-formula><mml:math id="M18" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math id="M19" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D values. Hence, the isotopic difference
between late-Pleistocene and Holocene ice wedges is more pronounced in <inline-formula><mml:math id="M20" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> than
in <inline-formula><mml:math id="M21" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> values.</p>
    <p id="d1e413">The present study of the permafrost exposed at the Sobo-Sise Yedoma cliff
provides a comprehensive<?pagebreak page4526?> cryostratigraphic inventory, insights into
permafrost aggradation, and degradation over the last approximately 52 kyr as well as their climatic and morphodynamic controls on the regional scale
of the central Laptev Sea coastal region in NE Siberia.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e425">During sea level low stands of the last glacial period, vast areas of the
eastern Siberian arctic shelves were exposed and formed the unglaciated
Beringia land bridge between the Eurasian–Scandinavian and Kara–Barents ice
sheets and the North American Laurentide ice sheet (Hopkins, 1959).
Beringia hosted a unique cold-adapted ecosystem with no analogue in modern
times – the tundra–steppe that maintained the late-Pleistocene mammoth
fauna (Hopkins, 1982). Beringian environments were characterized by
permafrost formation in widespread ice wedge polygonal networks (Sher,
1997). The ice wedge polygons grew syngenetically, i.e. contemporaneously
with deposition of ice-rich clastic and organic material. Generally, ice wedge formation takes place after thermal contraction cracking of the frozen
ground in wintertime, consecutive infill of the cracks by meltwater in
spring, and immediate refreezing and expansion (Leffingwell, 1915). The
vertical ice veins formed by annual repetition of this mechanism widen the
wedge ice, which in addition grows upwards with ongoing deposition. For
about 70 kyr during the marine isotope stages
(MISs) 4, 3, and 2, the Beringian tundra–steppe environment accumulated up to
50 m thick ice wedge polygon sequences that are named the Yedoma Ice Complex (IC; Tumskoy, 2012) in Russian
stratigraphy. The Yedoma IC was first
described by Soloviev (1959) in central Yakutia, while Katasonov (1954/2009)
and Romanovskiy (1959)  undertook first cryostratigraphic research of the Yedoma
IC in the eastern Siberian lowlands. Yedoma IC formation is characterized by
cryogenic cyclicity (Popov, 1953; Vasil'chuk, 2013) that is expressed in
distinct horizons, which formed in relation to the deposition rate of inter-annual variations in active-layer depth and resulted in freezing events
that built a respective uppermost portion of perennially frozen ground
(<?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2014). Diagnostic for the Yedoma IC are the presence of
syngenetic ice wedges, the oversaturation of the sediment with pore ice, and
segregated ice (excess ice) forming lenticular and reticulate cryostructures
within mainly fine-grained deposits (for an overview see Schirrmeister et
al., 2013).</p>
      <p id="d1e432">After deglaciation at the end of the last glacial maximum (LGM), sea level
rise and subsequent inundation of the eastern Siberian shelves flooded large
parts of Beringia, whose remaining areas were further affected by intense
permafrost degradation caused by deglacial warming. The LGM distribution of
the Yedoma domain included currently submerged shelf areas (1.9 million km<inline-formula><mml:math id="M22" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>)
and the modern maximum extent of Yedoma deposits on land (1.4 million km<inline-formula><mml:math id="M23" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>). This amounts to an area of about 3.3 million km<inline-formula><mml:math id="M24" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> where
Yedoma IC formation potentially took place (Strauss et al., 2017 and
references therein). In the modern terrestrial Yedoma domain, up to 70 %
of the area is affected by thermokarst (Strauss et al., 2013), which is the
degradation of ice-rich permafrost due to thaw, ground subsidence, and
erosion. In Eurasia, Yedoma IC deposits are most widespread in the
accumulative lowlands of northern and central Yakutia, less on Taimyr and
Chukotka (Romanovskiy, 1993; Kunitsky, 2007; Konishchev, 2011; Grosse et
al., 2013). The most widespread distribution of the IC is characteristic of
lowland plains at altitudes of less than 100 m above sea level (a.s.l.). The inland
Yedoma IC has, however, also been found in e.g. the Yana uplands exposed in
the Batagay megaslump (Kunitsky et al., 2013; Murton et al., 2017; Opel et
al., 2019). In North America, deposits similar to the Siberian Yedoma IC
occur in lower parts of the Arctic foothills, in the northern part of Seward
Peninsula, in interior Alaska, and in the Yukon Territory (Péwé,
1955; Sanborn et al., 2006; Kanevskiy et al., 2011).</p>
      <p id="d1e462">Ongoing research of the Yedoma IC employs its clastic component to unravel
material sources, transformation, transportation, and sedimentation processes
by applying mineralogy, grain-size analysis, and endmember modelling
approaches (e.g. Murton et al., 2015; Schirrmeister et al., 2011a;
Schirrmeister et al., 2020; Strauss et al., 2012) to reveal the depositional
history. The organic component of the Yedoma IC bears information on the
Beringian environment and its variability over time in floral and faunal
fossil records (e.g. Sher et al., 2005). The organic matter (OM) preserved
in the Yedoma IC was studied for its carbon stocks (e.g. Strauss et al., 2013;
Zimov et al., 2006) and carbon vulnerability to estimate its degradability
upon thaw (e.g. Stapel et al., 2016; Strauss et al., 2015). To obtain
chronologies of Yedoma IC formation, radiocarbon (<inline-formula><mml:math id="M25" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">14</mml:mn></mml:msup></mml:math></inline-formula>C) dating of
organic remains is commonly applied (e.g. Schirrmeister et al., 2002a;
<?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2014). The ground-ice component comprises intra-sedimental ice and wedge ice, which together constitute the major share of up to about
80 percent per volume (vol %) of the Yedoma IC (Strauss et al., 2013).
Cryostructures of intra-sedimental ice as well as its stable-water-isotope
composition host information of past freezing conditions (e.g. Dereviagin
et al., 2013; Schwamborn et al., 2006). The stable-isotope composition of
wedge ice is more often used in palaeoclimate studies and serves as a proxy for
winter climate conditions and moisture sources because the wedge ice derives
mainly from winter precipitation (e.g. Lachenbruch, 1962; Opel et al.,
2018).</p>
      <?pagebreak page4527?><p id="d1e478">The present study in the eastern Lena delta fills a geographic gap in the
extensive Yedoma IC studies in the Laptev Sea coastal region, which were
executed during the last approximately 2 decades in joint Russian–German research
(Khazin et al., 2019; Meyer et al., 2002a, b; Schirrmeister et al.,
2002a, 2011a, 2017; Sher et al., 2005; Strauss et al., 2013, 2015; Tumskoy,
2012; <?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2005, 2008a, 2011, 2014). Our study seeks (1) to
capture and to characterize the entire cryostratigraphic inventory of frozen
deposits and ground ice of the Sobo-Sise Yedoma cliff; (2) to estimate
permafrost aggradation and degradation timing, extent, and processes on
Sobo-Sise Island in the context of widespread Yedoma IC occurrence in the central
Laptev Sea coastal region; (3) to decipher regional winter climate
conditions and moisture sources; and (4) to disentangle the relation of
permafrost dynamics controlled by large-scale climate variability and
regional to local geomorphologic conditions and processes.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Study area</title>
      <p id="d1e493">The Lena delta stretches along the shore of the Laptev Sea between about 72 and
74<inline-formula><mml:math id="M26" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N and 123 and 130<inline-formula><mml:math id="M27" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E (Fig. 1) and is the largest
Arctic river delta (Walker et al., 1998). The terrestrial surface of the
delta differentiates into three geomorphological units (or terraces;
Grigoriev, 1993). The Holocene-aged first terrace comprises the north-eastern
and the south-western parts of the delta and is mainly covered by wet
polygonal tundra and thermokarst basins (Morgenstern et al., 2008). The
second terrace in the north-western part of the delta is composed of fluvial
dry sands dated to MIS 3–2 (Schirrmeister et al., 2011b) and is
characterized by numerous NNW–SSE-oriented lake basins and less expressed
polygonal surface morphology (Morgenstern et al., 2008). The third terrace
of MIS 4-2 age occurs in the southern part of the delta. The study area on
Sobo-Sise Island in the south-eastern part of the delta belongs to the third
geomorphologic terrace that is shaped by remnants of the late-Pleistocene Yedoma
IC and its degradation features. According to a landform classification of
Sobo-Sise by Fuchs et al. (2018), 43 % of the land surface is occupied
by Yedoma uplands and partly degraded Yedoma slopes, 43 % is thermokarst
basins, and 14 % is lakes. The studied Yedoma cliff in the northern part
of Sobo-Sise facing the Sardakhskaya channel is remarkable for its rapid
shoreline retreat of up to 22.3 m yr<inline-formula><mml:math id="M28" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (based on remote-sensing time
series from 1965–2018; Fuchs et al., 2020) with a mean annual retreat rate of 9.1 m yr<inline-formula><mml:math id="M29" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> over the observation period. The resulting annual OM release
into the Lena river amounts to at least <inline-formula><mml:math id="M30" display="inline"><mml:mrow><mml:mn mathvariant="normal">5.2</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mn mathvariant="normal">6</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> kg organic C and <inline-formula><mml:math id="M31" display="inline"><mml:mrow><mml:mn mathvariant="normal">0.4</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mn mathvariant="normal">6</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> kg N per year for the period 2015–2018 (Fuchs et al., 2020).
Furthermore, the Sobo-Sise Yedoma undergoes elevation changes due to thaw
subsidence between <inline-formula><mml:math id="M32" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>2 cm yr<inline-formula><mml:math id="M33" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (based on Sentinel-1 InSAR, 2017, for
the entire Sobo-Sise Island; Chen et al., 2018) and <inline-formula><mml:math id="M34" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>3.4 cm yr<inline-formula><mml:math id="M35" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>
(based on on-site rLiDAR at the studied Yedoma cliff; Günther et al.,
2018), indicating ongoing permafrost degradation. Thus, the Sobo-Sise Yedoma
represents a typical OM source in land-to-ocean pathways. It is
characterized by substantial OM stocks and fast permafrost degradation
(Fuchs et al., 2020) accelerated by Arctic warming (Fritz et al., 2017). The
Yedoma cliff rises to about 27.7 m above river level (arl; Fuchs et al.,
2020) and stretches about 1.66 km in the NW–SE direction (Fig. 1). It is
likely that the Yedoma IC extends up to about 12 m below the river level as
deduced by Fuchs et al. (2020) from near-shore bathymetry in front of the
cliff.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><?xmltex \currentcnt{1}?><label>Figure 1</label><caption><p id="d1e609">Study area <bold>(a)</bold> in north-eastern Siberia showing the study
site on Sobo-Sise Island in the eastern Lena delta (red dot no. 5) and
further locations mentioned in the paper: Bykovsky Peninsula (1: site
Mamontovy Khayata; and 2: B–S site), Lena delta (3: Kurungnakh-Sise Island;
4: Samoylov Island), Buor Khaya Peninsula (6), Bol'shoy Lyakhovsky Island
(7), Mamontov Klyk (8), Duvanny Yar (9), and Lake Vitim (10). More details of
the eastern Lena delta and the Yedoma IC sites studied nearby Sobo-Sise
Island are shown in panel <bold>(b)</bold>. Profile locations are indicated in <bold>(c)</bold> at
the Yedoma IC cliff on Sobo-Sise Island (image based on GeoEye-1 scene dated
08 July 2014). Panels <bold>(a)</bold> and <bold>(b)</bold> are based on ESRI ArcGIS Living
Atlas of the World, layer World Topo Base (2020).</p></caption>
        <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://tc.copernicus.org/articles/14/4525/2020/tc-14-4525-2020-f01.jpg"/>

      </fig>

      <p id="d1e633">The modern climate of the Lena delta as recorded by ongoing monitoring on
Samoylov Island in the central delta reveals a mean annual air temperature
of <inline-formula><mml:math id="M36" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>12.3 <inline-formula><mml:math id="M37" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (1998–2017; Boike et al., 2019). Mean monthly air
temperatures reach 9.5 <inline-formula><mml:math id="M38" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C in July and <inline-formula><mml:math id="M39" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>32.7 <inline-formula><mml:math id="M40" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C in
February. The average annual rainfall amounts to 169 mm and the average
annual winter snow cover to 0.3 m (2002–2017; Boike et al., 2019). Between
2006 and 2017, permafrost has warmed by 1.3 <inline-formula><mml:math id="M41" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C at the zero-annual-amplitude depth of 20.75 m (Boike et al., 2019), while the permafrost maximum
depth in the region reaches 500–600 m (Grigoriev, 1993). Unfrozen
underground (talik) is, however, assumed below the main channels of the Lena
delta and below thermokarst lakes exceeding 2 m water depth.</p>
      <p id="d1e688">The modern vegetation of Sobo-Sise Island is mainly characterized by dwarf
shrub – moss – tussock tundra communities occupying varying habitats of the
land surface of Yedoma uplands, pingos, floodplains, and thermokarst basins.
Common species belong to the genera <italic>Salix</italic>, <italic>Dryas</italic>, <italic>Saxifraga</italic>, <italic>Polygonum</italic>, <italic>Carex</italic>, <italic>Poa</italic>, <italic>Trisetum</italic>, <italic>Equisetum</italic>, and <italic>Luzula</italic> and unspecified mosses
and lichen according to Raschke and Savelieva (2017).</p>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Material and methods</title>
<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Fieldwork</title>
      <p id="d1e734">We sampled profiles at different positions of the Yedoma cliff including
three vertical sediment profiles and six horizontal ice wedge profiles to
cover the entire exposed permafrost inventory (Fig. 2). The sequence was
cryolithologically described according to French and Shur (2010), and frozen
samples were obtained using a hammer and axe at 0.5 m resolution via rope
descending. Vertical overlaps of the three profiles of sedimentary polygon
fillings of the exposure ensured complete sampling coverage of the cliff
(Fig. 2). Sample positions of profiles SOB18-01 and SOB18-03 were measured
as depths in metres below surface (m b.s.) and transferred to heights from the
measured height of 24.2 m a.r.l. at the cliff edge above the profiles. Sampling
positions of the lowermost profile SOB18-06 were directly measured as
heights in metres above river level. Height measurements in metres above river level correspond to those above sea
level (m a.s.l.), given the proximity of Sobo-Sise Island at the Sardakhskaya
channel in the eastern part of the Lena delta to the Laptev Sea (Fig. 1b).
In total, 61 sediment samples were taken (<?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2019). The
gravimetric ice or water content was measured in the field as the difference
between wet and dry weights after careful drying on a field oven and is
given as weight percent (wt %).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><?xmltex \currentcnt{2}?><label>Figure 2</label><caption><p id="d1e743">Profile positions of sediment profiles SOB18-01 (circles),
SOB18-03 (diamonds), and SOB18-06 (stars) as well as ice wedge profiles
(triangles) sampled at the Sobo-Sise Yedoma cliff in 2014 (SOB14 ice wedge profiles) and
2018 (SOB18 ice wedge profiles). Cliff edge line elevation (relative to river level) was
retrieved from ArcticDEM (10 m spatial resolution; Mosaic v3.0 10m: tile
59_43; Porter et al., 2018).</p></caption>
          <?xmltex \igopts{width=441.017717pt}?><graphic xlink:href="https://tc.copernicus.org/articles/14/4525/2020/tc-14-4525-2020-f02.png"/>

        </fig>

      <p id="d1e752"><?xmltex \hack{\newpage}?>Three horizontal ice wedge profiles at the Yedoma IC cliff were sampled in
2018 at different height levels (Fig. 2). An additional three ice wedge
profiles sampled in 2014 were analysed and included in the present study.
Ice wedge profile SOB18-02 was taken at 19.7 m a.r.l. on rope by ice screw at
15 cm resolution between the sediment profiles SOB18-01 and SOB18-03 in the
uppermost part of the cliff (Fig. 3b). The ice wedge SOB18-09 derives from
the central western part of the Yedoma and was sampled at 2 m a.r.l. at beach
level (Fig. 3f). The ice wedge profiles SOB18-08 and SOB14-IW4 were sampled
at the upper western slope of the Yedoma towards the western alas basin at
9.4  and 9 m a.r.l., respectively (Fig. 3e, h). Ice wedge profiles in the
lower part of the cliff were obtained at 2.5 m a.r.l. (eastern slope,
SOB14-IW3) and at 2 m a.r.l. (western slope, SOB14-IW5; Fig. 3g, i). Except
for profile SOB18-02, all ice wedge profiles were taken by chainsaw either
in blocks for subsampling in the cold lab at 1.5 to 2 cm resolution or i<?pagebreak page4529?>n
slices in the field at varying resolutions of 4 cm (SOB18-08, SOB18-09) and
of 15 cm (SOB14-IW3), depending on fieldwork logistics (<?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al.,
2019).</p>
</sec>
<sec id="Ch1.S3.SS2">
  <label>3.2</label><title>Laboratory analyses</title>
<sec id="Ch1.S3.SS2.SSS1">
  <label>3.2.1</label><title>Sediment and organic-matter analyses</title>
      <p id="d1e775">Upon arrival in the laboratory, the sediment samples were freeze-dried
(Zirbus Subliminator 3–4–5), manually homogenized, and split for further
analyses. The grain-size distribution (GSD) was measured using a laser
diffraction particle analyser (Malvern Mastersizer 3000). GSD was calculated
with the internal software of the laser diffraction particle analyser and
further analysed using GRADISTAT 8.0 (Blott and Pye, 2001) for
sand–silt–clay distribution, arithmetic mean in micrometres, and sorting in phi
(<inline-formula><mml:math id="M42" display="inline"><mml:mi mathvariant="italic">φ</mml:mi></mml:math></inline-formula>). Further details of GSD sample preparation and laboratory
procedures are given in Schirrmeister et al. (2020). The sample SOB18-03-03
was not included in the data interpretation because of analytical artefacts.</p>
      <p id="d1e785">To attempt an unmixing of the measured grain-size distributions into
underlying characteristic grain-size sub-populations associated with
specific sedimentological deposition and transformation processes, a robust
endmember modelling approach (EMMA) following Dietze and Dietze (2019) was
applied to a total of 56 GSD matrices from profiles SOB18-01, SOB18-03, and
SOB18-06, representing the Yedoma IC and excluding the uppermost Holocene
cover. EMMA is a type of eigenspace analysis with the capacity to transform
the resulting endmember components so that the loadings of the endmembers
can be interpreted as grain-size distributions (see details in Dietze et
al., 2012). Each sample used in the analysis is then represented as a linear
combination of the identified endmembers, where the scores provide a
quantitative estimate of how much an endmember contributes to a sample. The
used R package EMMAGeo (Dietze and Dietze, 2019) additionally allows the
identification of robust endmembers (rEMs) using a multiple-parameter
approach, where rEMs are those that occur independently from model
parameters. A Monte Carlo approach is then used for assessing the
uncertainties associated with the scores computed for each sample. Overall
class-wise explained variance is 63 %, with the lowest <inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> occurring for
the very fine and very coarse classes (Fig. S1 in the Supplement). Overall, sample-wise
explained variance is 91 %, with only one sample with an explained
variance below 80 % (Fig. S1).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><?xmltex \currentcnt{3}?><label>Figure 3</label><caption><p id="d1e801">Field photographs of the sampling locations of the sediment
profiles <bold>(a–d)</bold> and the ice wedge profiles <bold>(b, e–i)</bold> at the Sobo-Sise Yedoma
cliff. Photographs are provided by the authors of this study.</p></caption>
            <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://tc.copernicus.org/articles/14/4525/2020/tc-14-4525-2020-f03.jpg"/>

          </fig>

      <p id="d1e817">Mass-specific magnetic susceptibility (MS) as a proxy for sediment content
of magnetizable minerals was measured using a Bartington Instruments MS2
equipped with an MS2B sensor. MS data are expressed in SI units (10<inline-formula><mml:math id="M44" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">8</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> m<inline-formula><mml:math id="M45" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> kg<inline-formula><mml:math id="M46" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>). Total nitrogen (TN) and total organic-carbon (TOC)
content of the samples were measured with elemental analysers
(ElementarVario EL III for TN and ElementarVario MAX C for TOC; analytical
accuracy <inline-formula><mml:math id="M47" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.1 wt %). The ratio of TOC and TN is referred to as <inline-formula><mml:math id="M48" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">C</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">N</mml:mi></mml:mrow></mml:math></inline-formula>.
Stable-carbon (<inline-formula><mml:math id="M49" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>C)- and stable-nitrogen (<inline-formula><mml:math id="M50" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">15</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>N)-isotope
analysis was undertaken using a Thermo Scientific Delta V Advantage isotope ratio MS equipped with a Flash 2000 organic elemental analyser using helium
as a carrier gas. Values are given as per mil (‰)
difference from the Vienna Pee Dee Belemnite (VPDB) standard for <inline-formula><mml:math id="M51" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>C and from nitrogen in ambient air (AIR) for <inline-formula><mml:math id="M52" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">15</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>N. The
accuracy was better than <inline-formula><mml:math id="M53" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>0.15 ‰ for <inline-formula><mml:math id="M54" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>C and <inline-formula><mml:math id="M55" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>0.2 ‰ for <inline-formula><mml:math id="M56" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">15</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>N.
Further details on OM analyses are given in Davidson et al. (2018). In
total, 61 sediment samples were analysed for the parameters described above
(Table 1).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><?xmltex \currentcnt{1}?><label>Table 1</label><caption><p id="d1e957">Data of the three cryostratigraphic units A, B, and C of the
Sobo-Sise Yedoma cliff, summarizing minimum (MIN), mean (MEAN), and maximum
(MAX) values as well as standard deviation (SD) of sedimentological,
organic-matter, stable-isotope, and hydrochemical analyses. </p></caption><oasis:table frame="topbot"><?xmltex \begin{scaleboxenv}{.78}[.78]?><oasis:tgroup cols="16">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right" colsep="1"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="right"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:colspec colnum="11" colname="col11" align="right" colsep="1"/>
     <oasis:colspec colnum="12" colname="col12" align="right"/>
     <oasis:colspec colnum="13" colname="col13" align="right"/>
     <oasis:colspec colnum="14" colname="col14" align="right"/>
     <oasis:colspec colnum="15" colname="col15" align="right"/>
     <oasis:colspec colnum="16" colname="col16" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry namest="col2" nameend="col6" align="center" colsep="1">Unit C (MIS 1 Holocene cover) </oasis:entry>
         <oasis:entry namest="col7" nameend="col11" align="center" colsep="1">Unit B (MIS 2 Yedoma IC) </oasis:entry>
         <oasis:entry namest="col12" nameend="col16" align="center">Unit A (MIS 3 Yedoma IC) </oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M57" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">MIN</oasis:entry>
         <oasis:entry colname="col4">MEAN</oasis:entry>
         <oasis:entry colname="col5">MAX</oasis:entry>
         <oasis:entry colname="col6">SD</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M58" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8">MIN</oasis:entry>
         <oasis:entry colname="col9">MEAN</oasis:entry>
         <oasis:entry colname="col10">MAX</oasis:entry>
         <oasis:entry colname="col11">SD</oasis:entry>
         <oasis:entry colname="col12"><inline-formula><mml:math id="M59" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col13">MIN</oasis:entry>
         <oasis:entry colname="col14">MEAN</oasis:entry>
         <oasis:entry colname="col15">MAX</oasis:entry>
         <oasis:entry colname="col16">SD</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Mean grain size <?xmltex \hack{\hfill\break}?>(<inline-formula><mml:math id="M60" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">4</oasis:entry>
         <oasis:entry colname="col3">53</oasis:entry>
         <oasis:entry colname="col4">66</oasis:entry>
         <oasis:entry colname="col5">82</oasis:entry>
         <oasis:entry colname="col6">13</oasis:entry>
         <oasis:entry colname="col7">16</oasis:entry>
         <oasis:entry colname="col8">52</oasis:entry>
         <oasis:entry colname="col9">113</oasis:entry>
         <oasis:entry colname="col10">303</oasis:entry>
         <oasis:entry colname="col11">64</oasis:entry>
         <oasis:entry colname="col12">40</oasis:entry>
         <oasis:entry colname="col13">28</oasis:entry>
         <oasis:entry colname="col14">46</oasis:entry>
         <oasis:entry colname="col15">75</oasis:entry>
         <oasis:entry colname="col16">12</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Sorting, log  (<inline-formula><mml:math id="M61" display="inline"><mml:mi mathvariant="italic">ϕ</mml:mi></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">4</oasis:entry>
         <oasis:entry colname="col3">2.2</oasis:entry>
         <oasis:entry colname="col4">2.4</oasis:entry>
         <oasis:entry colname="col5">2.5</oasis:entry>
         <oasis:entry colname="col6">0.1</oasis:entry>
         <oasis:entry colname="col7">16</oasis:entry>
         <oasis:entry colname="col8">2.0</oasis:entry>
         <oasis:entry colname="col9">2.4</oasis:entry>
         <oasis:entry colname="col10">2.8</oasis:entry>
         <oasis:entry colname="col11">0.2</oasis:entry>
         <oasis:entry colname="col12">40</oasis:entry>
         <oasis:entry colname="col13">1.9</oasis:entry>
         <oasis:entry colname="col14">2.1</oasis:entry>
         <oasis:entry colname="col15">2.3</oasis:entry>
         <oasis:entry colname="col16">0.1</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">MS  (HF)</oasis:entry>
         <oasis:entry colname="col2">4</oasis:entry>
         <oasis:entry colname="col3">19</oasis:entry>
         <oasis:entry colname="col4">32</oasis:entry>
         <oasis:entry colname="col5">66</oasis:entry>
         <oasis:entry colname="col6">23</oasis:entry>
         <oasis:entry colname="col7">16</oasis:entry>
         <oasis:entry colname="col8">31</oasis:entry>
         <oasis:entry colname="col9">53</oasis:entry>
         <oasis:entry colname="col10">71</oasis:entry>
         <oasis:entry colname="col11">9</oasis:entry>
         <oasis:entry colname="col12">41</oasis:entry>
         <oasis:entry colname="col13">23</oasis:entry>
         <oasis:entry colname="col14">40</oasis:entry>
         <oasis:entry colname="col15">58</oasis:entry>
         <oasis:entry colname="col16">9</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">TN  (wt %)</oasis:entry>
         <oasis:entry colname="col2">4</oasis:entry>
         <oasis:entry colname="col3">0.2</oasis:entry>
         <oasis:entry colname="col4">0.6</oasis:entry>
         <oasis:entry colname="col5">0.8</oasis:entry>
         <oasis:entry colname="col6">0.3</oasis:entry>
         <oasis:entry colname="col7">14</oasis:entry>
         <oasis:entry colname="col8">0.1</oasis:entry>
         <oasis:entry colname="col9">0.2</oasis:entry>
         <oasis:entry colname="col10">0.4</oasis:entry>
         <oasis:entry colname="col11">0.1</oasis:entry>
         <oasis:entry colname="col12">41</oasis:entry>
         <oasis:entry colname="col13">0.2</oasis:entry>
         <oasis:entry colname="col14">0.3</oasis:entry>
         <oasis:entry colname="col15">0.7</oasis:entry>
         <oasis:entry colname="col16">0.1</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">TC  (wt %)</oasis:entry>
         <oasis:entry colname="col2">4</oasis:entry>
         <oasis:entry colname="col3">3.2</oasis:entry>
         <oasis:entry colname="col4">12.5</oasis:entry>
         <oasis:entry colname="col5">27.1</oasis:entry>
         <oasis:entry colname="col6">10.3</oasis:entry>
         <oasis:entry colname="col7">16</oasis:entry>
         <oasis:entry colname="col8">0.7</oasis:entry>
         <oasis:entry colname="col9">2.6</oasis:entry>
         <oasis:entry colname="col10">5.4</oasis:entry>
         <oasis:entry colname="col11">1.3</oasis:entry>
         <oasis:entry colname="col12">41</oasis:entry>
         <oasis:entry colname="col13">2.5</oasis:entry>
         <oasis:entry colname="col14">5.0</oasis:entry>
         <oasis:entry colname="col15">15.6</oasis:entry>
         <oasis:entry colname="col16">2.7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">TOC  (wt %)</oasis:entry>
         <oasis:entry colname="col2">4</oasis:entry>
         <oasis:entry colname="col3">3.0</oasis:entry>
         <oasis:entry colname="col4">11.3</oasis:entry>
         <oasis:entry colname="col5">25.5</oasis:entry>
         <oasis:entry colname="col6">9.9</oasis:entry>
         <oasis:entry colname="col7">15</oasis:entry>
         <oasis:entry colname="col8">0.5</oasis:entry>
         <oasis:entry colname="col9">2.1</oasis:entry>
         <oasis:entry colname="col10">5.1</oasis:entry>
         <oasis:entry colname="col11">1.3</oasis:entry>
         <oasis:entry colname="col12">41</oasis:entry>
         <oasis:entry colname="col13">1.7</oasis:entry>
         <oasis:entry colname="col14">4.5</oasis:entry>
         <oasis:entry colname="col15">15.1</oasis:entry>
         <oasis:entry colname="col16">2.6</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">TOC/TN</oasis:entry>
         <oasis:entry colname="col2">4</oasis:entry>
         <oasis:entry colname="col3">13.8</oasis:entry>
         <oasis:entry colname="col4">18.5</oasis:entry>
         <oasis:entry colname="col5">30.6</oasis:entry>
         <oasis:entry colname="col6">8.0</oasis:entry>
         <oasis:entry colname="col7">14</oasis:entry>
         <oasis:entry colname="col8">7.2</oasis:entry>
         <oasis:entry colname="col9">10.5</oasis:entry>
         <oasis:entry colname="col10">13.6</oasis:entry>
         <oasis:entry colname="col11">2.4</oasis:entry>
         <oasis:entry colname="col12">41</oasis:entry>
         <oasis:entry colname="col13">9.1</oasis:entry>
         <oasis:entry colname="col14">12.9</oasis:entry>
         <oasis:entry colname="col15">21.7</oasis:entry>
         <oasis:entry colname="col16">2.5</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M62" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>C  (‰) vs. PDB</oasis:entry>
         <oasis:entry colname="col2">4</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M63" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>28.32</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M64" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>28.01</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M65" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>27.76</oasis:entry>
         <oasis:entry colname="col6">0.24</oasis:entry>
         <oasis:entry colname="col7">15</oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M66" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>27.37</oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M67" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>26.07</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M68" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>25.22</oasis:entry>
         <oasis:entry colname="col11">0.59</oasis:entry>
         <oasis:entry colname="col12">41</oasis:entry>
         <oasis:entry colname="col13"><inline-formula><mml:math id="M69" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>29.89</oasis:entry>
         <oasis:entry colname="col14"><inline-formula><mml:math id="M70" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>27.29</oasis:entry>
         <oasis:entry colname="col15"><inline-formula><mml:math id="M71" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>25.97</oasis:entry>
         <oasis:entry colname="col16">0.91</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M72" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">15</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>N  (‰) vs. AIR</oasis:entry>
         <oasis:entry colname="col2">4</oasis:entry>
         <oasis:entry colname="col3">1.26</oasis:entry>
         <oasis:entry colname="col4">2.14</oasis:entry>
         <oasis:entry colname="col5">2.89</oasis:entry>
         <oasis:entry colname="col6">0.69</oasis:entry>
         <oasis:entry colname="col7">14</oasis:entry>
         <oasis:entry colname="col8">0.54</oasis:entry>
         <oasis:entry colname="col9">1.91</oasis:entry>
         <oasis:entry colname="col10">3.19</oasis:entry>
         <oasis:entry colname="col11">0.97</oasis:entry>
         <oasis:entry colname="col12">41</oasis:entry>
         <oasis:entry colname="col13">1.20</oasis:entry>
         <oasis:entry colname="col14">2.24</oasis:entry>
         <oasis:entry colname="col15">3.69</oasis:entry>
         <oasis:entry colname="col16">0.57</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Ice content  (wt %)</oasis:entry>
         <oasis:entry colname="col2">3</oasis:entry>
         <oasis:entry colname="col3">41</oasis:entry>
         <oasis:entry colname="col4">56</oasis:entry>
         <oasis:entry colname="col5">80</oasis:entry>
         <oasis:entry colname="col6">21</oasis:entry>
         <oasis:entry colname="col7">16</oasis:entry>
         <oasis:entry colname="col8">20</oasis:entry>
         <oasis:entry colname="col9">43</oasis:entry>
         <oasis:entry colname="col10">61</oasis:entry>
         <oasis:entry colname="col11">10</oasis:entry>
         <oasis:entry colname="col12">41</oasis:entry>
         <oasis:entry colname="col13">24</oasis:entry>
         <oasis:entry colname="col14">49</oasis:entry>
         <oasis:entry colname="col15">74</oasis:entry>
         <oasis:entry colname="col16">10</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M73" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O   (‰) vs. SMOW</oasis:entry>
         <oasis:entry colname="col2">3</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M74" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>20.98</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M75" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>20.70</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M76" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>20.36</oasis:entry>
         <oasis:entry colname="col6">0.32</oasis:entry>
         <oasis:entry colname="col7">15</oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M77" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>28.69</oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M78" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>26.21</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M79" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>21.58</oasis:entry>
         <oasis:entry colname="col11">2.17</oasis:entry>
         <oasis:entry colname="col12">35</oasis:entry>
         <oasis:entry colname="col13"><inline-formula><mml:math id="M80" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>28.24</oasis:entry>
         <oasis:entry colname="col14"><inline-formula><mml:math id="M81" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>23.88</oasis:entry>
         <oasis:entry colname="col15"><inline-formula><mml:math id="M82" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>20.27</oasis:entry>
         <oasis:entry colname="col16">2.00</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M83" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D  (‰) vs. SMOW</oasis:entry>
         <oasis:entry colname="col2">3</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M84" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>152.9</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M85" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>150.7</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M86" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>148.6</oasis:entry>
         <oasis:entry colname="col6">2.2</oasis:entry>
         <oasis:entry colname="col7">15</oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M87" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>216.6</oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M88" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>199.9</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M89" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>158.8</oasis:entry>
         <oasis:entry colname="col11">16.1</oasis:entry>
         <oasis:entry colname="col12">35</oasis:entry>
         <oasis:entry colname="col13"><inline-formula><mml:math id="M90" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>221.8</oasis:entry>
         <oasis:entry colname="col14"><inline-formula><mml:math id="M91" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>189.6</oasis:entry>
         <oasis:entry colname="col15"><inline-formula><mml:math id="M92" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>163.5</oasis:entry>
         <oasis:entry colname="col16">14.5</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Deuterium excess  (‰) vs. SMOW</oasis:entry>
         <oasis:entry colname="col2">3</oasis:entry>
         <oasis:entry colname="col3">14.3</oasis:entry>
         <oasis:entry colname="col4">14.9</oasis:entry>
         <oasis:entry colname="col5">15.5</oasis:entry>
         <oasis:entry colname="col6">0.6</oasis:entry>
         <oasis:entry colname="col7">15</oasis:entry>
         <oasis:entry colname="col8">3.1</oasis:entry>
         <oasis:entry colname="col9">9.7</oasis:entry>
         <oasis:entry colname="col10">15.3</oasis:entry>
         <oasis:entry colname="col11">3.9</oasis:entry>
         <oasis:entry colname="col12">35</oasis:entry>
         <oasis:entry colname="col13"><inline-formula><mml:math id="M93" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>6.0</oasis:entry>
         <oasis:entry colname="col14">1.5</oasis:entry>
         <oasis:entry colname="col15">12.0</oasis:entry>
         <oasis:entry colname="col16">3.9</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">DOC   (mg L<inline-formula><mml:math id="M94" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">n/a</oasis:entry>
         <oasis:entry colname="col4">33.7</oasis:entry>
         <oasis:entry colname="col5">n/a</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">8</oasis:entry>
         <oasis:entry colname="col8">85.3</oasis:entry>
         <oasis:entry colname="col9">212.4</oasis:entry>
         <oasis:entry colname="col10">588.7</oasis:entry>
         <oasis:entry colname="col11">159.9</oasis:entry>
         <oasis:entry colname="col12">20</oasis:entry>
         <oasis:entry colname="col13">160.9</oasis:entry>
         <oasis:entry colname="col14">366.8</oasis:entry>
         <oasis:entry colname="col15">753.5</oasis:entry>
         <oasis:entry colname="col16">174.0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">EC   (<inline-formula><mml:math id="M95" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:mrow></mml:math></inline-formula> cm<inline-formula><mml:math id="M96" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">n/a</oasis:entry>
         <oasis:entry colname="col4">36</oasis:entry>
         <oasis:entry colname="col5">n/a</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">4</oasis:entry>
         <oasis:entry colname="col8">1129</oasis:entry>
         <oasis:entry colname="col9">1806</oasis:entry>
         <oasis:entry colname="col10">3180</oasis:entry>
         <oasis:entry colname="col11">950</oasis:entry>
         <oasis:entry colname="col12">12</oasis:entry>
         <oasis:entry colname="col13">726</oasis:entry>
         <oasis:entry colname="col14">2245</oasis:entry>
         <oasis:entry colname="col15">5790</oasis:entry>
         <oasis:entry colname="col16">1568</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Chloride   (mg L<inline-formula><mml:math id="M97" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">n/a</oasis:entry>
         <oasis:entry colname="col4">1.5</oasis:entry>
         <oasis:entry colname="col5">n/a</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">4</oasis:entry>
         <oasis:entry colname="col8">61.8</oasis:entry>
         <oasis:entry colname="col9">340.8</oasis:entry>
         <oasis:entry colname="col10">873.1</oasis:entry>
         <oasis:entry colname="col11">370.0</oasis:entry>
         <oasis:entry colname="col12">12</oasis:entry>
         <oasis:entry colname="col13">8.3</oasis:entry>
         <oasis:entry colname="col14">494.9</oasis:entry>
         <oasis:entry colname="col15">1631.9</oasis:entry>
         <oasis:entry colname="col16">534.8</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Sulfate   (mg L<inline-formula><mml:math id="M98" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">n/a</oasis:entry>
         <oasis:entry colname="col4">0.7</oasis:entry>
         <oasis:entry colname="col5">n/a</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">4</oasis:entry>
         <oasis:entry colname="col8">2.5</oasis:entry>
         <oasis:entry colname="col9">101.2</oasis:entry>
         <oasis:entry colname="col10">282.1</oasis:entry>
         <oasis:entry colname="col11">132.2</oasis:entry>
         <oasis:entry colname="col12">12</oasis:entry>
         <oasis:entry colname="col13">3.2</oasis:entry>
         <oasis:entry colname="col14">72.7</oasis:entry>
         <oasis:entry colname="col15">255.1</oasis:entry>
         <oasis:entry colname="col16">80.8</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Ca   (mg L<inline-formula><mml:math id="M99" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">n/a</oasis:entry>
         <oasis:entry colname="col4">3.0</oasis:entry>
         <oasis:entry colname="col5">n/a</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">4</oasis:entry>
         <oasis:entry colname="col8">48.5</oasis:entry>
         <oasis:entry colname="col9">160.2</oasis:entry>
         <oasis:entry colname="col10">334.0</oasis:entry>
         <oasis:entry colname="col11">123.0</oasis:entry>
         <oasis:entry colname="col12">12</oasis:entry>
         <oasis:entry colname="col13">75.4</oasis:entry>
         <oasis:entry colname="col14">147.0</oasis:entry>
         <oasis:entry colname="col15">265.5</oasis:entry>
         <oasis:entry colname="col16">61.7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Fe  (mg L<inline-formula><mml:math id="M100" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">n/a</oasis:entry>
         <oasis:entry colname="col4">3.2</oasis:entry>
         <oasis:entry colname="col5">n/a</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">2</oasis:entry>
         <oasis:entry colname="col8">0.7</oasis:entry>
         <oasis:entry colname="col9">3.2</oasis:entry>
         <oasis:entry colname="col10">5.6</oasis:entry>
         <oasis:entry colname="col11">3.5</oasis:entry>
         <oasis:entry colname="col12">8</oasis:entry>
         <oasis:entry colname="col13">0.1</oasis:entry>
         <oasis:entry colname="col14">6.0</oasis:entry>
         <oasis:entry colname="col15">37.4</oasis:entry>
         <oasis:entry colname="col16">12.7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">K  (mg L<inline-formula><mml:math id="M101" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">n/a</oasis:entry>
         <oasis:entry colname="col4">0.8</oasis:entry>
         <oasis:entry colname="col5">n/a</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">4</oasis:entry>
         <oasis:entry colname="col8">3.0</oasis:entry>
         <oasis:entry colname="col9">5.8</oasis:entry>
         <oasis:entry colname="col10">8.5</oasis:entry>
         <oasis:entry colname="col11">2.5</oasis:entry>
         <oasis:entry colname="col12">12</oasis:entry>
         <oasis:entry colname="col13">3.2</oasis:entry>
         <oasis:entry colname="col14">7.6</oasis:entry>
         <oasis:entry colname="col15">11.7</oasis:entry>
         <oasis:entry colname="col16">2.9</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Mg  (mg L<inline-formula><mml:math id="M102" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">n/a</oasis:entry>
         <oasis:entry colname="col4">1.4</oasis:entry>
         <oasis:entry colname="col5">n/a</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">4</oasis:entry>
         <oasis:entry colname="col8">74.7</oasis:entry>
         <oasis:entry colname="col9">110.5</oasis:entry>
         <oasis:entry colname="col10">164.3</oasis:entry>
         <oasis:entry colname="col11">39.3</oasis:entry>
         <oasis:entry colname="col12">12</oasis:entry>
         <oasis:entry colname="col13">48.8</oasis:entry>
         <oasis:entry colname="col14">144.9</oasis:entry>
         <oasis:entry colname="col15">372.3</oasis:entry>
         <oasis:entry colname="col16">89.8</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Mn  (mg L<inline-formula><mml:math id="M103" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">n/a</oasis:entry>
         <oasis:entry colname="col4">0.3</oasis:entry>
         <oasis:entry colname="col5">n/a</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">4</oasis:entry>
         <oasis:entry colname="col8">0.2</oasis:entry>
         <oasis:entry colname="col9">1.6</oasis:entry>
         <oasis:entry colname="col10">3.8</oasis:entry>
         <oasis:entry colname="col11">1.6</oasis:entry>
         <oasis:entry colname="col12">12</oasis:entry>
         <oasis:entry colname="col13">0.3</oasis:entry>
         <oasis:entry colname="col14">1.3</oasis:entry>
         <oasis:entry colname="col15">2.7</oasis:entry>
         <oasis:entry colname="col16">0.7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Na  (mg L<inline-formula><mml:math id="M104" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">n/a</oasis:entry>
         <oasis:entry colname="col4">1.7</oasis:entry>
         <oasis:entry colname="col5">n/a</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">4</oasis:entry>
         <oasis:entry colname="col8">38.9</oasis:entry>
         <oasis:entry colname="col9">60.9</oasis:entry>
         <oasis:entry colname="col10">92.8</oasis:entry>
         <oasis:entry colname="col11">22.9</oasis:entry>
         <oasis:entry colname="col12">12</oasis:entry>
         <oasis:entry colname="col13">24.4</oasis:entry>
         <oasis:entry colname="col14">105.9</oasis:entry>
         <oasis:entry colname="col15">485.2</oasis:entry>
         <oasis:entry colname="col16">133.4</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup><?xmltex \end{scaleboxenv}?></oasis:table><table-wrap-foot><p id="d1e960">n/a – not applicable</p></table-wrap-foot></table-wrap>

</sec>
<sec id="Ch1.S3.SS2.SSS2">
  <label>3.2.2</label><title>Ground-ice analyses</title>
      <p id="d1e2673">Supernatant water of thawed sediment from 53 samples (Table 1) was decanted
in the field. Hydrochemical characterization included electrical
conductivity (EC), major anions and cations, and dissolved organic-carbon (DOC) concentration. For major ion analyses 17 samples were filtered
through 0.45 <inline-formula><mml:math id="M105" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> CA syringe filters and filled into sample bottles.
HNO<inline-formula><mml:math id="M106" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> (65 % Suprapur) was added to cation samples for conservation.
The cation content was analysed by inductively coupled plasma optical
emission spectrometry (ICP-OES; Perkin-Elmer Optima 3000 XL), while the
anion content was determined by ion chromatography (IC; Dionex DX-320). Ion
concentrations are given in milligrams per litre (mg L<inline-formula><mml:math id="M107" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>). For DOC concentration analyses,
samples were filtered through pre-rinsed 0.7 <inline-formula><mml:math id="M108" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> GF/F glass fibre
filters attached to a rubber-free syringe. The liquids were filled in clear
glass vials with screw caps and PTFE septum and acidified with HCl (30 %
Suprapur). All samples were stored cool and dark. DOC concentrations (mg L<inline-formula><mml:math id="M109" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) were measured in 29 samples with a high-temperature (680 <inline-formula><mml:math id="M110" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) combustion TOC analyser (Shimadzu TOC-VCPH).</p>
      <p id="d1e2739">The oxygen (<inline-formula><mml:math id="M111" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O) and hydrogen (<inline-formula><mml:math id="M112" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D) stable-isotope
compositions of melted samples of intra-sedimental ice and of wedge ice were
measured using a Finnigan MAT Delta-S mass spectrometer (<inline-formula><mml:math id="M113" display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mi mathvariant="italic">σ</mml:mi><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn></mml:mrow></mml:math></inline-formula> ‰ for <inline-formula><mml:math id="M114" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, 1<inline-formula><mml:math id="M115" display="inline"><mml:mrow><mml:mi mathvariant="italic">σ</mml:mi><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0.8</mml:mn></mml:mrow></mml:math></inline-formula> ‰ for <inline-formula><mml:math id="M116" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D; Meyer et al., 2000).
Values are given as per mil (‰) difference from the
Vienna Standard Mean Ocean Water (VSMOW) standard. The deuterium excess
(<inline-formula><mml:math id="M117" display="inline"><mml:mrow><mml:mi>d</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is calculated following Dansgaard (1964) in Eq. (1):
              <disp-formula id="Ch1.E1" content-type="numbered"><label>1</label><mml:math id="M118" display="block"><mml:mrow><mml:mi>d</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="italic">δ</mml:mi><mml:mi>D</mml:mi><mml:mo>-</mml:mo><mml:mn mathvariant="normal">8</mml:mn><mml:mo>×</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>
            In total, 511 samples of wedge ice were analysed for their stable-water-isotope composition. We excluded marginal samples from further
interpretation at the interface of wedge ice to sediment, which showed
indications of isotopic alteration. Furthermore, the sampled ice wedge
profile SOB14-IW4 captured a polygon junction and included ice of two
neighbouring ice wedges. We considered only a full profile of one wedge cut
and sampled perpendicular to its lateral growth direction and neglected the
remaining samples of the second ice wedge, not completely captured due to
its oblique<?pagebreak page4530?> exposition. In total, 412 wedge ice samples were interpreted
from six analysed ice wedge profiles (Table 2).</p>

<?xmltex \floatpos{p}?><table-wrap id="Ch1.T2" orientation="landscape"><?xmltex \currentcnt{2}?><label>Table 2</label><caption><p id="d1e2848">Stable-isotope data of ice wedges of the Sobo-Sise Yedoma
cliff, summarizing minimum (MIN), mean (MEAN), and maximum (MAX) values as
well as standard deviation (SD). Radiocarbon dates of organic material from
inside the wedge ice are further given in Table 3.</p></caption><oasis:table frame="topbot"><?xmltex \begin{scaleboxenv}{.9}[.9]?><oasis:tgroup cols="19">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right" colsep="1"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="right"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:colspec colnum="11" colname="col11" align="right" colsep="1"/>
     <oasis:colspec colnum="12" colname="col12" align="right"/>
     <oasis:colspec colnum="13" colname="col13" align="right"/>
     <oasis:colspec colnum="14" colname="col14" align="right"/>
     <oasis:colspec colnum="15" colname="col15" align="right" colsep="1"/>
     <oasis:colspec colnum="16" colname="col16" align="right"/>
     <oasis:colspec colnum="17" colname="col17" align="right"/>
     <oasis:colspec colnum="18" colname="col18" align="right"/>
     <oasis:colspec colnum="19" colname="col19" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Units</oasis:entry>
         <oasis:entry colname="col2">Age range   (cal yr BP)</oasis:entry>
         <oasis:entry colname="col3">ID</oasis:entry>
         <oasis:entry namest="col4" nameend="col7" align="center" colsep="1"><inline-formula><mml:math id="M119" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O <?xmltex \hack{\hfill\break}?>(‰) vs. SMOW </oasis:entry>
         <oasis:entry namest="col8" nameend="col11" align="center" colsep="1"><inline-formula><mml:math id="M120" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D <?xmltex \hack{\hfill\break}?>(‰) vs. SMOW </oasis:entry>
         <oasis:entry namest="col12" nameend="col15" align="center" colsep="1">Deuterium excess <?xmltex \hack{\hfill\break}?>(‰) vs. SMOW </oasis:entry>
         <oasis:entry colname="col16"><inline-formula><mml:math id="M121" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col17">Slope</oasis:entry>
         <oasis:entry colname="col18">Intercept</oasis:entry>
         <oasis:entry colname="col19"><inline-formula><mml:math id="M122" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4">MIN</oasis:entry>
         <oasis:entry colname="col5">MEAN</oasis:entry>
         <oasis:entry colname="col6">MAX</oasis:entry>
         <oasis:entry colname="col7">SD</oasis:entry>
         <oasis:entry colname="col8">MIN</oasis:entry>
         <oasis:entry colname="col9">MEAN</oasis:entry>
         <oasis:entry colname="col10">MAX</oasis:entry>
         <oasis:entry colname="col11">SD</oasis:entry>
         <oasis:entry colname="col12">MIN</oasis:entry>
         <oasis:entry colname="col13">MEAN</oasis:entry>
         <oasis:entry colname="col14">MAX</oasis:entry>
         <oasis:entry colname="col15">SD</oasis:entry>
         <oasis:entry colname="col16"/>
         <oasis:entry colname="col17"/>
         <oasis:entry colname="col18"/>
         <oasis:entry colname="col19"/>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">C</oasis:entry>
         <oasis:entry colname="col2">NA</oasis:entry>
         <oasis:entry colname="col3">SOB14-05</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M123" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>28.66</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M124" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>27.28</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M125" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>25.85</oasis:entry>
         <oasis:entry colname="col7">0.74</oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M126" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>215.2</oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M127" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>204.4</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M128" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>193.6</oasis:entry>
         <oasis:entry colname="col11">5.8</oasis:entry>
         <oasis:entry colname="col12">12.3</oasis:entry>
         <oasis:entry colname="col13">13.8</oasis:entry>
         <oasis:entry colname="col14">15.0</oasis:entry>
         <oasis:entry colname="col15">0.8</oasis:entry>
         <oasis:entry colname="col16">33</oasis:entry>
         <oasis:entry colname="col17">7.73</oasis:entry>
         <oasis:entry colname="col18">6.55</oasis:entry>
         <oasis:entry colname="col19">0.98</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">C</oasis:entry>
         <oasis:entry colname="col2">NA</oasis:entry>
         <oasis:entry colname="col3">SOB18-08-II</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M129" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>29.06</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M130" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>26.18</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M131" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>24.42</oasis:entry>
         <oasis:entry colname="col7">1.09</oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M132" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>218.7</oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M133" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>195.7</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M134" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>180.5</oasis:entry>
         <oasis:entry colname="col11">9.0</oasis:entry>
         <oasis:entry colname="col12">11.5</oasis:entry>
         <oasis:entry colname="col13">13.8</oasis:entry>
         <oasis:entry colname="col14">16.1</oasis:entry>
         <oasis:entry colname="col15">0.7</oasis:entry>
         <oasis:entry colname="col16">112</oasis:entry>
         <oasis:entry colname="col17">8.20</oasis:entry>
         <oasis:entry colname="col18">19.05</oasis:entry>
         <oasis:entry colname="col19">0.99</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">C</oasis:entry>
         <oasis:entry colname="col2">modern–2 290</oasis:entry>
         <oasis:entry colname="col3">SOB14-04</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M135" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>30.43</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M136" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>27.77</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M137" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>24.06</oasis:entry>
         <oasis:entry colname="col7">1.73</oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M138" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>226.5</oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M139" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>207.1</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M140" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>178.0</oasis:entry>
         <oasis:entry colname="col11">13.7</oasis:entry>
         <oasis:entry colname="col12">13.1</oasis:entry>
         <oasis:entry colname="col13">14.9</oasis:entry>
         <oasis:entry colname="col14">17.0</oasis:entry>
         <oasis:entry colname="col15">0.7</oasis:entry>
         <oasis:entry colname="col16">131</oasis:entry>
         <oasis:entry colname="col17">7.90</oasis:entry>
         <oasis:entry colname="col18">12.24</oasis:entry>
         <oasis:entry colname="col19">1</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">C</oasis:entry>
         <oasis:entry colname="col2">NA</oasis:entry>
         <oasis:entry colname="col3">SOB18-02-II</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M141" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>27.13</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M142" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>25.18</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M143" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>23.38</oasis:entry>
         <oasis:entry colname="col7">1.27</oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M144" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>207.0</oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M145" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>190.3</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M146" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>173.9</oasis:entry>
         <oasis:entry colname="col11">11.1</oasis:entry>
         <oasis:entry colname="col12">9.3</oasis:entry>
         <oasis:entry colname="col13">11.2</oasis:entry>
         <oasis:entry colname="col14">13.2</oasis:entry>
         <oasis:entry colname="col15">1.1</oasis:entry>
         <oasis:entry colname="col16">15</oasis:entry>
         <oasis:entry colname="col17">8.75</oasis:entry>
         <oasis:entry colname="col18">30.04</oasis:entry>
         <oasis:entry colname="col19">1</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">B</oasis:entry>
         <oasis:entry colname="col2">23 470–25 350</oasis:entry>
         <oasis:entry colname="col3">SOB18-02-I</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M147" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>29.37</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M148" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>28.80</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M149" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>27.75</oasis:entry>
         <oasis:entry colname="col7">0.47</oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M150" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>230.3</oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M151" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>224.6</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M152" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>214.1</oasis:entry>
         <oasis:entry colname="col11">4. 5</oasis:entry>
         <oasis:entry colname="col12">4.4</oasis:entry>
         <oasis:entry colname="col13">5.8</oasis:entry>
         <oasis:entry colname="col14">7.9</oasis:entry>
         <oasis:entry colname="col15">0.9</oasis:entry>
         <oasis:entry colname="col16">17</oasis:entry>
         <oasis:entry colname="col17">9.43</oasis:entry>
         <oasis:entry colname="col18">46.99</oasis:entry>
         <oasis:entry colname="col19">0.99</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">A</oasis:entry>
         <oasis:entry colname="col2">30 930–43 270</oasis:entry>
         <oasis:entry colname="col3">SOB14-03</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M153" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>31.00</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M154" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>29.74</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M155" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>27.04</oasis:entry>
         <oasis:entry colname="col7">1.11</oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M156" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>241.6</oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M157" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>230.7</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M158" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>210.8</oasis:entry>
         <oasis:entry colname="col11">8.7</oasis:entry>
         <oasis:entry colname="col12">5.5</oasis:entry>
         <oasis:entry colname="col13">7.2</oasis:entry>
         <oasis:entry colname="col14">8.5</oasis:entry>
         <oasis:entry colname="col15">0.9</oasis:entry>
         <oasis:entry colname="col16">16</oasis:entry>
         <oasis:entry colname="col17">7.81</oasis:entry>
         <oasis:entry colname="col18">1.63</oasis:entry>
         <oasis:entry colname="col19">0.99</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">A</oasis:entry>
         <oasis:entry colname="col2">36 970–48 660</oasis:entry>
         <oasis:entry colname="col3">SOB18-09</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M159" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>31.38</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M160" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>29.66</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M161" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>26.85</oasis:entry>
         <oasis:entry colname="col7">1.08</oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M162" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>244.3</oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M163" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>232.0</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M164" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>213.1</oasis:entry>
         <oasis:entry colname="col11">7.8</oasis:entry>
         <oasis:entry colname="col12">1.7</oasis:entry>
         <oasis:entry colname="col13">5.2</oasis:entry>
         <oasis:entry colname="col14">7.5</oasis:entry>
         <oasis:entry colname="col15">1.1</oasis:entry>
         <oasis:entry colname="col16">78</oasis:entry>
         <oasis:entry colname="col17">7.16</oasis:entry>
         <oasis:entry colname="col18"><inline-formula><mml:math id="M165" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>19.80</oasis:entry>
         <oasis:entry colname="col19">0.99</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">A</oasis:entry>
         <oasis:entry colname="col2">49 610</oasis:entry>
         <oasis:entry colname="col3">SOB18-08-I</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M166" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>30.48</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M167" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>29.62</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M168" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>28.37</oasis:entry>
         <oasis:entry colname="col7">0.80</oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M169" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>237.5</oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M170" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>230.2</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M171" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>218.4</oasis:entry>
         <oasis:entry colname="col11">6.8</oasis:entry>
         <oasis:entry colname="col12">5.1</oasis:entry>
         <oasis:entry colname="col13">6.8</oasis:entry>
         <oasis:entry colname="col14">8.5</oasis:entry>
         <oasis:entry colname="col15">1.2</oasis:entry>
         <oasis:entry colname="col16">10</oasis:entry>
         <oasis:entry colname="col17">8.28</oasis:entry>
         <oasis:entry colname="col18">15.08</oasis:entry>
         <oasis:entry colname="col19">0.97</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup><?xmltex \end{scaleboxenv}?></oasis:table><table-wrap-foot><p id="d1e2851">NA – not available</p></table-wrap-foot></table-wrap>

</sec>
</sec>
<sec id="Ch1.S3.SS3">
  <label>3.3</label><title>Radiocarbon dating and age modelling</title>
      <p id="d1e3840">The geochronology along each profile was established on the basis of 32
accelerator mass spectrometry (AMS) radiocarbon dates from 31 selected
sediment samples (Table 3) using a Mini Carbon Dating System (MICADAS) at
Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research
(AWI). Further details on laboratory procedures and sample pretreatment are
given in Opel et al. (2019). Notably, depending on size, samples were
analysed as graphite or gas targets; the small sample size of some gas
targets causes a reduced age range for which reliable radiocarbon ages can
be obtained (Table 3). The dated material was obtained by hand picking terrestrial plant remains from freeze-dried samples. In a first batch, 26
samples were chosen every 1–1.5 m, representing sediment horizons and their
boundaries. On the basis of the obtained dates, five additional samples were
chosen on either side of suspected hiatuses to verify and delimit them more
reliably. All radiocarbon dates were calibrated using the IntCal13
calibration dataset (Reimer et al., 2013). Ages are given as calibrated
years before present (cal yr BP).</p>

<?xmltex \floatpos{p}?><table-wrap id="Ch1.T3" specific-use="star"><?xmltex \currentcnt{3}?><label>Table 3</label><caption><p id="d1e3846">Radiocarbon ages of organic material from sediments and ice
wedges of the Sobo-Sise Yedoma cliff. The abbreviation “n/a” stands for “not analysed” if ages
were infinite or beyond the calibration limits (Reimer et al., 2013). rbacon-modelled median ages are given for comparison (Fig. S2).</p></caption><oasis:table frame="topbot"><?xmltex \begin{scaleboxenv}{.75}[.75]?><oasis:tgroup cols="8">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="justify" colwidth="7cm"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Sample</oasis:entry>
         <oasis:entry colname="col2">Height</oasis:entry>
         <oasis:entry colname="col3">Lab</oasis:entry>
         <oasis:entry colname="col4">Radiocarbon</oasis:entry>
         <oasis:entry colname="col5">Material</oasis:entry>
         <oasis:entry colname="col6">Calibrated</oasis:entry>
         <oasis:entry colname="col7">Calibrated</oasis:entry>
         <oasis:entry colname="col8">Modelled</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">ID</oasis:entry>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3">ID</oasis:entry>
         <oasis:entry colname="col4">age</oasis:entry>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6">age 2<inline-formula><mml:math id="M172" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula> range</oasis:entry>
         <oasis:entry colname="col7">median age</oasis:entry>
         <oasis:entry colname="col8">median age</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">(m a.r.l.)</oasis:entry>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4">(yr BP)</oasis:entry>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6">(cal yr BP)</oasis:entry>
         <oasis:entry colname="col7">(cal yr BP)</oasis:entry>
         <oasis:entry colname="col8">(cal yr BP)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">SEDIMENTS</oasis:entry>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7"/>
         <oasis:entry colname="col8"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-01-02</oasis:entry>
         <oasis:entry colname="col2">23.7</oasis:entry>
         <oasis:entry colname="col3">AWI2508.1.1</oasis:entry>
         <oasis:entry colname="col4">2389 <inline-formula><mml:math id="M173" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 49</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae remains, moss remains, wood</oasis:entry>
         <oasis:entry colname="col6">234–2700</oasis:entry>
         <oasis:entry colname="col7">2440</oasis:entry>
         <oasis:entry colname="col8">2498</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-01-03</oasis:entry>
         <oasis:entry colname="col2">23.2</oasis:entry>
         <oasis:entry colname="col3">AWI2509.1.1</oasis:entry>
         <oasis:entry colname="col4">3974 <inline-formula><mml:math id="M174" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 49</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae remains, wood</oasis:entry>
         <oasis:entry colname="col6">4257–4568</oasis:entry>
         <oasis:entry colname="col7">4440</oasis:entry>
         <oasis:entry colname="col8">4440</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-01-04</oasis:entry>
         <oasis:entry colname="col2">22.7</oasis:entry>
         <oasis:entry colname="col3">AWI2510.1.1</oasis:entry>
         <oasis:entry colname="col4">5597 <inline-formula><mml:math id="M175" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 50</oasis:entry>
         <oasis:entry colname="col5">Wood</oasis:entry>
         <oasis:entry colname="col6">6295–6472</oasis:entry>
         <oasis:entry colname="col7">6370</oasis:entry>
         <oasis:entry colname="col8">6360</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-01-05</oasis:entry>
         <oasis:entry colname="col2">22.2</oasis:entry>
         <oasis:entry colname="col3">AWI3921.1.1</oasis:entry>
         <oasis:entry colname="col4">13 096 <inline-formula><mml:math id="M176" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 71</oasis:entry>
         <oasis:entry colname="col5">Twig</oasis:entry>
         <oasis:entry colname="col6">15 389–15 970</oasis:entry>
         <oasis:entry colname="col7">15 710</oasis:entry>
         <oasis:entry colname="col8">15 483</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-01-06</oasis:entry>
         <oasis:entry colname="col2">21.7</oasis:entry>
         <oasis:entry colname="col3">AWI3922.1.1</oasis:entry>
         <oasis:entry colname="col4">13 291 <inline-formula><mml:math id="M177" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 33</oasis:entry>
         <oasis:entry colname="col5">Wood</oasis:entry>
         <oasis:entry colname="col6">15 804–16 147</oasis:entry>
         <oasis:entry colname="col7">15 985</oasis:entry>
         <oasis:entry colname="col8">16 028</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-01-07</oasis:entry>
         <oasis:entry colname="col2">21.2</oasis:entry>
         <oasis:entry colname="col3">AWI2511.1.1</oasis:entry>
         <oasis:entry colname="col4">13 841 <inline-formula><mml:math id="M178" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 56</oasis:entry>
         <oasis:entry colname="col5">Dwarf shrub leaf, wood</oasis:entry>
         <oasis:entry colname="col6">16 499–16 996</oasis:entry>
         <oasis:entry colname="col7">16 760</oasis:entry>
         <oasis:entry colname="col8">16 793</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-01-08</oasis:entry>
         <oasis:entry colname="col2">20.7</oasis:entry>
         <oasis:entry colname="col3">AWI3923.1.1</oasis:entry>
         <oasis:entry colname="col4">17 141 <inline-formula><mml:math id="M179" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 113</oasis:entry>
         <oasis:entry colname="col5">Twig</oasis:entry>
         <oasis:entry colname="col6">20 367–20 996</oasis:entry>
         <oasis:entry colname="col7">20 680</oasis:entry>
         <oasis:entry colname="col8">20 419</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-01-09</oasis:entry>
         <oasis:entry colname="col2">20.2</oasis:entry>
         <oasis:entry colname="col3">AWI3924.1.1</oasis:entry>
         <oasis:entry colname="col4">17 219 <inline-formula><mml:math id="M180" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 114</oasis:entry>
         <oasis:entry colname="col5">Twig</oasis:entry>
         <oasis:entry colname="col6">20 469–21 096</oasis:entry>
         <oasis:entry colname="col7">20 770</oasis:entry>
         <oasis:entry colname="col8">20 973</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-01-10</oasis:entry>
         <oasis:entry colname="col2">19.7</oasis:entry>
         <oasis:entry colname="col3">AWI2512.1.1</oasis:entry>
         <oasis:entry colname="col4">18 102 <inline-formula><mml:math id="M181" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 64</oasis:entry>
         <oasis:entry colname="col5">Wood</oasis:entry>
         <oasis:entry colname="col6">21 719–22 197</oasis:entry>
         <oasis:entry colname="col7">21 940</oasis:entry>
         <oasis:entry colname="col8">21 819</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-01-13</oasis:entry>
         <oasis:entry colname="col2">18.2</oasis:entry>
         <oasis:entry colname="col3">AWI2513.1.1</oasis:entry>
         <oasis:entry colname="col4">19 233 <inline-formula><mml:math id="M182" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 68</oasis:entry>
         <oasis:entry colname="col5">Vascular plant leaf, wood</oasis:entry>
         <oasis:entry colname="col6">22 928–23 446</oasis:entry>
         <oasis:entry colname="col7">23 170</oasis:entry>
         <oasis:entry colname="col8">23 357</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-01-15</oasis:entry>
         <oasis:entry colname="col2">17.2</oasis:entry>
         <oasis:entry colname="col3">AWI2514.1.1</oasis:entry>
         <oasis:entry colname="col4">20 767 <inline-formula><mml:math id="M183" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 71</oasis:entry>
         <oasis:entry colname="col5">Wood</oasis:entry>
         <oasis:entry colname="col6">24 669–25 329</oasis:entry>
         <oasis:entry colname="col7">25 070</oasis:entry>
         <oasis:entry colname="col8">24 897</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-01-18</oasis:entry>
         <oasis:entry colname="col2">15.7</oasis:entry>
         <oasis:entry colname="col3">AWI2515.1.1</oasis:entry>
         <oasis:entry colname="col4">23 305 <inline-formula><mml:math id="M184" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 79</oasis:entry>
         <oasis:entry colname="col5">Gramineae roots and leaves, wood</oasis:entry>
         <oasis:entry colname="col6">27 369–27 716</oasis:entry>
         <oasis:entry colname="col7">27 540</oasis:entry>
         <oasis:entry colname="col8">27 555</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-03-02</oasis:entry>
         <oasis:entry colname="col2">17.7</oasis:entry>
         <oasis:entry colname="col3">AWI2516.1.1</oasis:entry>
         <oasis:entry colname="col4">21 326 <inline-formula><mml:math id="M185" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 73</oasis:entry>
         <oasis:entry colname="col5">Wood</oasis:entry>
         <oasis:entry colname="col6">25 481–25 856</oasis:entry>
         <oasis:entry colname="col7">25 680</oasis:entry>
         <oasis:entry colname="col8">25 702</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-03-03</oasis:entry>
         <oasis:entry colname="col2">17.2</oasis:entry>
         <oasis:entry colname="col3">AWI3927.1.1</oasis:entry>
         <oasis:entry colname="col4">24 408 <inline-formula><mml:math id="M186" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 76</oasis:entry>
         <oasis:entry colname="col5">Twigs, fine roots</oasis:entry>
         <oasis:entry colname="col6">28 213–28 705</oasis:entry>
         <oasis:entry colname="col7">28 470</oasis:entry>
         <oasis:entry colname="col8">28 406</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-03-04</oasis:entry>
         <oasis:entry colname="col2">16.7</oasis:entry>
         <oasis:entry colname="col3">AWI2517.1.1</oasis:entry>
         <oasis:entry colname="col4">32 935 <inline-formula><mml:math id="M187" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 117</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae roots and leaves</oasis:entry>
         <oasis:entry colname="col6">35 888–36 506</oasis:entry>
         <oasis:entry colname="col7">36 220</oasis:entry>
         <oasis:entry colname="col8">36 710</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-03-07</oasis:entry>
         <oasis:entry colname="col2">15.2</oasis:entry>
         <oasis:entry colname="col3">AWI2518.1.1</oasis:entry>
         <oasis:entry colname="col4">33 780 <inline-formula><mml:math id="M188" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 216</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae leaves, wood</oasis:entry>
         <oasis:entry colname="col6">37 494–38 767</oasis:entry>
         <oasis:entry colname="col7">38 260</oasis:entry>
         <oasis:entry colname="col8">38 119</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-03-10</oasis:entry>
         <oasis:entry colname="col2">13.7</oasis:entry>
         <oasis:entry colname="col3">AWI2519.1.1</oasis:entry>
         <oasis:entry colname="col4">34 782 <inline-formula><mml:math id="M189" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 236</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae roots, wood</oasis:entry>
         <oasis:entry colname="col6">38 717–39 874</oasis:entry>
         <oasis:entry colname="col7">39 290</oasis:entry>
         <oasis:entry colname="col8">39 269</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-03-13</oasis:entry>
         <oasis:entry colname="col2">12.2</oasis:entry>
         <oasis:entry colname="col3">AWI2520.1.1</oasis:entry>
         <oasis:entry colname="col4">35 965 <inline-formula><mml:math id="M190" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 156</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae stems and roots, one <italic>Carex</italic> seed</oasis:entry>
         <oasis:entry colname="col6">40 158–41 074</oasis:entry>
         <oasis:entry colname="col7">40 610</oasis:entry>
         <oasis:entry colname="col8">40 403</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-03-17</oasis:entry>
         <oasis:entry colname="col2">10.2</oasis:entry>
         <oasis:entry colname="col3">AWI3928.1.1</oasis:entry>
         <oasis:entry colname="col4">36 169 <inline-formula><mml:math id="M191" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 121</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae roots and leaves</oasis:entry>
         <oasis:entry colname="col6">40 411–41 227</oasis:entry>
         <oasis:entry colname="col7">40 840</oasis:entry>
         <oasis:entry colname="col8">41 529</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-03-17</oasis:entry>
         <oasis:entry colname="col2">10.2</oasis:entry>
         <oasis:entry colname="col3">AWI2521.1.1</oasis:entry>
         <oasis:entry colname="col4">15 294 <inline-formula><mml:math id="M192" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 67</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae roots, 1 Asteraceae seed, wood</oasis:entry>
         <oasis:entry colname="col6">18 388–18 731</oasis:entry>
         <oasis:entry colname="col7">18 570</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-06-01</oasis:entry>
         <oasis:entry colname="col2">13.4</oasis:entry>
         <oasis:entry colname="col3">AWI2522.1.1</oasis:entry>
         <oasis:entry colname="col4">36 820 <inline-formula><mml:math id="M193" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 302</oasis:entry>
         <oasis:entry colname="col5"><italic>Drepanocladus</italic> stems and leaves</oasis:entry>
         <oasis:entry colname="col6">40 803–41 943</oasis:entry>
         <oasis:entry colname="col7">41 420</oasis:entry>
         <oasis:entry colname="col8">41 449</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-06-05</oasis:entry>
         <oasis:entry colname="col2">11.5</oasis:entry>
         <oasis:entry colname="col3">AWI2523.1.1</oasis:entry>
         <oasis:entry colname="col4">39 877 <inline-formula><mml:math id="M194" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 421</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae roots and stems, <italic>Drepanocladus</italic> stems and leaves</oasis:entry>
         <oasis:entry colname="col6">42 839–44 333</oasis:entry>
         <oasis:entry colname="col7">43 530</oasis:entry>
         <oasis:entry colname="col8">43 306</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-06-07</oasis:entry>
         <oasis:entry colname="col2">10.5</oasis:entry>
         <oasis:entry colname="col3">AWI2524.1.1</oasis:entry>
         <oasis:entry colname="col4">40 572 <inline-formula><mml:math id="M195" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 316</oasis:entry>
         <oasis:entry colname="col5">Wood</oasis:entry>
         <oasis:entry colname="col6">43 435–44 768</oasis:entry>
         <oasis:entry colname="col7">44 130</oasis:entry>
         <oasis:entry colname="col8">44 079</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-06-10</oasis:entry>
         <oasis:entry colname="col2">9</oasis:entry>
         <oasis:entry colname="col3">AWI2525.1.1</oasis:entry>
         <oasis:entry colname="col4">43 042 <inline-formula><mml:math id="M196" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1726</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae roots and leaves</oasis:entry>
         <oasis:entry colname="col6">43 563–49 664</oasis:entry>
         <oasis:entry colname="col7">46 440</oasis:entry>
         <oasis:entry colname="col8">45 194</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-06-13</oasis:entry>
         <oasis:entry colname="col2">7.5</oasis:entry>
         <oasis:entry colname="col3">AWI2526.1.1</oasis:entry>
         <oasis:entry colname="col4">43 371 <inline-formula><mml:math id="M197" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 431</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae roots and leaves, wood</oasis:entry>
         <oasis:entry colname="col6">45 650–47 586</oasis:entry>
         <oasis:entry colname="col7">46 540</oasis:entry>
         <oasis:entry colname="col8">46 223</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-06-15</oasis:entry>
         <oasis:entry colname="col2">6.5</oasis:entry>
         <oasis:entry colname="col3">AWI2527.1.1</oasis:entry>
         <oasis:entry colname="col4">42 931 <inline-formula><mml:math id="M198" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 414</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae stems, <italic>Drepanocladus</italic> stems and leaves</oasis:entry>
         <oasis:entry colname="col6">45 322–47 028</oasis:entry>
         <oasis:entry colname="col7">46 120</oasis:entry>
         <oasis:entry colname="col8">46 832</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-06-18</oasis:entry>
         <oasis:entry colname="col2">5</oasis:entry>
         <oasis:entry colname="col3">AWI2528.1.1</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M199" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 42 600</oasis:entry>
         <oasis:entry colname="col5">Dwarf shrub leaf, roots</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">n/a</oasis:entry>
         <oasis:entry colname="col8">48 046</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-06-20</oasis:entry>
         <oasis:entry colname="col2">4</oasis:entry>
         <oasis:entry colname="col3">AWI2529.1.1</oasis:entry>
         <oasis:entry colname="col4">45 345 <inline-formula><mml:math id="M200" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 534</oasis:entry>
         <oasis:entry colname="col5">Wood</oasis:entry>
         <oasis:entry colname="col6">47 552–49 976</oasis:entry>
         <oasis:entry colname="col7">48 740</oasis:entry>
         <oasis:entry colname="col8">48 872</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-06-30</oasis:entry>
         <oasis:entry colname="col2">3.2</oasis:entry>
         <oasis:entry colname="col3">AWI2530.1.1</oasis:entry>
         <oasis:entry colname="col4">45 501 <inline-formula><mml:math id="M201" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 542</oasis:entry>
         <oasis:entry colname="col5">Two Cyperaceae seeds and stems, wood</oasis:entry>
         <oasis:entry colname="col6">47 736–[50 000]</oasis:entry>
         <oasis:entry colname="col7">48 900</oasis:entry>
         <oasis:entry colname="col8">49 555</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-06-33</oasis:entry>
         <oasis:entry colname="col2">1.9</oasis:entry>
         <oasis:entry colname="col3">AWI2531.1.1</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M202" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 42 600</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae roots, unspec. wood</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">n/a</oasis:entry>
         <oasis:entry colname="col8">50 872</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-06-35</oasis:entry>
         <oasis:entry colname="col2">0.9</oasis:entry>
         <oasis:entry colname="col3">AWI2532.1.1</oasis:entry>
         <oasis:entry colname="col4">47 021 <inline-formula><mml:math id="M203" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 646</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae stems</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">n/a</oasis:entry>
         <oasis:entry colname="col8">51 877</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-bone-02</oasis:entry>
         <oasis:entry colname="col2">0</oasis:entry>
         <oasis:entry colname="col3">AWI2749.1.2</oasis:entry>
         <oasis:entry colname="col4">13 668 <inline-formula><mml:math id="M204" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 57</oasis:entry>
         <oasis:entry colname="col5">Ivory (<italic>Mammuthus primigenius</italic>)</oasis:entry>
         <oasis:entry colname="col6">16 255–16 751</oasis:entry>
         <oasis:entry colname="col7">16 480</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-08-130</oasis:entry>
         <oasis:entry colname="col2">9.5</oasis:entry>
         <oasis:entry colname="col3">AWI3934.1.1</oasis:entry>
         <oasis:entry colname="col4">4017 <inline-formula><mml:math id="M205" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 26</oasis:entry>
         <oasis:entry colname="col5">Twig, roots</oasis:entry>
         <oasis:entry colname="col6">4421–4565</oasis:entry>
         <oasis:entry colname="col7">4480</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">SOB18-09-100</oasis:entry>
         <oasis:entry colname="col2">2</oasis:entry>
         <oasis:entry colname="col3">AWI3942.1.1</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M206" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 48 500</oasis:entry>
         <oasis:entry colname="col5">Eight <italic>Potamogeton</italic> seeds</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">n/a</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">ICE WEDGES</oasis:entry>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7"/>
         <oasis:entry colname="col8"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-02-B</oasis:entry>
         <oasis:entry colname="col2">19.7</oasis:entry>
         <oasis:entry colname="col3">AWI3925.1.1</oasis:entry>
         <oasis:entry colname="col4">19 483 <inline-formula><mml:math id="M207" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 148</oasis:entry>
         <oasis:entry colname="col5">Lemming droppings</oasis:entry>
         <oasis:entry colname="col6">23 037–23 865</oasis:entry>
         <oasis:entry colname="col7">23 470</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-02-C</oasis:entry>
         <oasis:entry colname="col2">19.7</oasis:entry>
         <oasis:entry colname="col3">AWI3926.1.1</oasis:entry>
         <oasis:entry colname="col4">20 991 <inline-formula><mml:math id="M208" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 46</oasis:entry>
         <oasis:entry colname="col5">Lemming droppings</oasis:entry>
         <oasis:entry colname="col6">25 149–25 538</oasis:entry>
         <oasis:entry colname="col7">25 350</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-08-119</oasis:entry>
         <oasis:entry colname="col2">9.4</oasis:entry>
         <oasis:entry colname="col3">AWI3933.1.1</oasis:entry>
         <oasis:entry colname="col4">46 169 <inline-formula><mml:math id="M209" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 246</oasis:entry>
         <oasis:entry colname="col5">Lemming droppings</oasis:entry>
         <oasis:entry colname="col6">48 981–[50 000]</oasis:entry>
         <oasis:entry colname="col7">49 610</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-09-11/12</oasis:entry>
         <oasis:entry colname="col2">2</oasis:entry>
         <oasis:entry colname="col3">AWI3935.1.1</oasis:entry>
         <oasis:entry colname="col4">32 963 <inline-formula><mml:math id="M210" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 111</oasis:entry>
         <oasis:entry colname="col5">Poales remains, five Poaceae seeds, one <italic>Potamogeton</italic> seed, twigs fragments, moss stems and leaves</oasis:entry>
         <oasis:entry colname="col6">36 494–37 588</oasis:entry>
         <oasis:entry colname="col7">36 970</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-09-29</oasis:entry>
         <oasis:entry colname="col2">2</oasis:entry>
         <oasis:entry colname="col3">AWI3936.1.1</oasis:entry>
         <oasis:entry colname="col4">34 577 <inline-formula><mml:math id="M211" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 103</oasis:entry>
         <oasis:entry colname="col5">Poales remains, dwarf shrub leaf fragments, moss stem</oasis:entry>
         <oasis:entry colname="col6">38 698–39 453</oasis:entry>
         <oasis:entry colname="col7">39 040</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-09-36</oasis:entry>
         <oasis:entry colname="col2">2</oasis:entry>
         <oasis:entry colname="col3">AWI3937.1.1</oasis:entry>
         <oasis:entry colname="col4">45 386 <inline-formula><mml:math id="M212" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 842</oasis:entry>
         <oasis:entry colname="col5">Lemming droppings</oasis:entry>
         <oasis:entry colname="col6">47 047–[50 000]</oasis:entry>
         <oasis:entry colname="col7">48 660</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-09-59</oasis:entry>
         <oasis:entry colname="col2">2</oasis:entry>
         <oasis:entry colname="col3">AWI3938.1.1</oasis:entry>
         <oasis:entry colname="col4">42 315 <inline-formula><mml:math id="M213" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 173</oasis:entry>
         <oasis:entry colname="col5">Poales remains, one Poaceae seed, dwarf shrub leaf, moss stems and leaves</oasis:entry>
         <oasis:entry colname="col6">45 153–46 037</oasis:entry>
         <oasis:entry colname="col7">45 590</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-09-63</oasis:entry>
         <oasis:entry colname="col2">2</oasis:entry>
         <oasis:entry colname="col3">AWI3939.1.1</oasis:entry>
         <oasis:entry colname="col4">46 601 <inline-formula><mml:math id="M214" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 258</oasis:entry>
         <oasis:entry colname="col5">Cyperaceae leaf, twigs</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">n/a</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-09-67</oasis:entry>
         <oasis:entry colname="col2">2</oasis:entry>
         <oasis:entry colname="col3">AWI3940.1.1</oasis:entry>
         <oasis:entry colname="col4">43 792 <inline-formula><mml:math id="M215" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 247</oasis:entry>
         <oasis:entry colname="col5">Lemming droppings</oasis:entry>
         <oasis:entry colname="col6">46 248–47 723</oasis:entry>
         <oasis:entry colname="col7">46 950</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB18-09-79</oasis:entry>
         <oasis:entry colname="col2">2</oasis:entry>
         <oasis:entry colname="col3">AWI3941.1.1</oasis:entry>
         <oasis:entry colname="col4">43 437 <inline-formula><mml:math id="M216" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 252</oasis:entry>
         <oasis:entry colname="col5">Poaceae leaves, five Poaceae seeds, two Fabaceae seeds, one Ericaceae seed, moss stems and leaves</oasis:entry>
         <oasis:entry colname="col6">45 933–47 294</oasis:entry>
         <oasis:entry colname="col7">46 570</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB14-IW3-02</oasis:entry>
         <oasis:entry colname="col2">2.5</oasis:entry>
         <oasis:entry colname="col3">AWI1331.1.1</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M217" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 31 000</oasis:entry>
         <oasis:entry colname="col5">Unidentified organic remains</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">n/a</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB14-IW3-DOC-DAT</oasis:entry>
         <oasis:entry colname="col2">2.5</oasis:entry>
         <oasis:entry colname="col3">COL3809.1.1</oasis:entry>
         <oasis:entry colname="col4">39 574 <inline-formula><mml:math id="M218" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 374</oasis:entry>
         <oasis:entry colname="col5">Unidentified organic remains</oasis:entry>
         <oasis:entry colname="col6">44 041–42 696</oasis:entry>
         <oasis:entry colname="col7">43 270</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB14-IW3-09</oasis:entry>
         <oasis:entry colname="col2">2.5</oasis:entry>
         <oasis:entry colname="col3">AWI1332.1.1</oasis:entry>
         <oasis:entry colname="col4">26 891 <inline-formula><mml:math id="M219" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1025</oasis:entry>
         <oasis:entry colname="col5">Unidentified organic remains</oasis:entry>
         <oasis:entry colname="col6">28 818–33 202</oasis:entry>
         <oasis:entry colname="col7">30 930</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB14-IW3-15</oasis:entry>
         <oasis:entry colname="col2">2.5</oasis:entry>
         <oasis:entry colname="col3">AWI1333.1.1</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M220" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 31 000</oasis:entry>
         <oasis:entry colname="col5">Unidentified organic remains</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">n/a</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB14-IW4-4/12</oasis:entry>
         <oasis:entry colname="col2">10</oasis:entry>
         <oasis:entry colname="col3">COL3818.1.1</oasis:entry>
         <oasis:entry colname="col4">modern</oasis:entry>
         <oasis:entry colname="col5">Unidentified organic remains</oasis:entry>
         <oasis:entry colname="col6">n/a</oasis:entry>
         <oasis:entry colname="col7">n/a</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB14-IW4-7/01</oasis:entry>
         <oasis:entry colname="col2">10</oasis:entry>
         <oasis:entry colname="col3">AWI1326.1.1</oasis:entry>
         <oasis:entry colname="col4">2264 <inline-formula><mml:math id="M221" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 118</oasis:entry>
         <oasis:entry colname="col5">Unidentified organic remains</oasis:entry>
         <oasis:entry colname="col6">1991–2701</oasis:entry>
         <oasis:entry colname="col7">2270</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB14-IW4-7/08</oasis:entry>
         <oasis:entry colname="col2">10</oasis:entry>
         <oasis:entry colname="col3">COL3819.1.1</oasis:entry>
         <oasis:entry colname="col4">1617 <inline-formula><mml:math id="M222" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 92</oasis:entry>
         <oasis:entry colname="col5">Unidentified organic remains</oasis:entry>
         <oasis:entry colname="col6">1325–1713</oasis:entry>
         <oasis:entry colname="col7">1510</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB14-IW4-8/02</oasis:entry>
         <oasis:entry colname="col2">10</oasis:entry>
         <oasis:entry colname="col3">AWI1327.1.1</oasis:entry>
         <oasis:entry colname="col4">1500 <inline-formula><mml:math id="M223" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 115</oasis:entry>
         <oasis:entry colname="col5">Unidentified organic remains</oasis:entry>
         <oasis:entry colname="col6">1182–1692</oasis:entry>
         <oasis:entry colname="col7">1410</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB14-IW4-8/10</oasis:entry>
         <oasis:entry colname="col2">10</oasis:entry>
         <oasis:entry colname="col3">AWI1328.1.1</oasis:entry>
         <oasis:entry colname="col4">1693 <inline-formula><mml:math id="M224" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 116</oasis:entry>
         <oasis:entry colname="col5">Unidentified organic remains</oasis:entry>
         <oasis:entry colname="col6">1362–1866</oasis:entry>
         <oasis:entry colname="col7">1610</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB14-IW4-8/10</oasis:entry>
         <oasis:entry colname="col2">10</oasis:entry>
         <oasis:entry colname="col3">AWI1328.1.2</oasis:entry>
         <oasis:entry colname="col4">1491 <inline-formula><mml:math id="M225" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 106</oasis:entry>
         <oasis:entry colname="col5">Unidentified organic remains</oasis:entry>
         <oasis:entry colname="col6">1184–1615</oasis:entry>
         <oasis:entry colname="col7">1400</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB14-IW4-8/11</oasis:entry>
         <oasis:entry colname="col2">10</oasis:entry>
         <oasis:entry colname="col3">AWI1329.1.1</oasis:entry>
         <oasis:entry colname="col4">2274 <inline-formula><mml:math id="M226" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 119</oasis:entry>
         <oasis:entry colname="col5">Unidentified organic remains</oasis:entry>
         <oasis:entry colname="col6">1996–2703</oasis:entry>
         <oasis:entry colname="col7">2290</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SOB14-IW4-9/07</oasis:entry>
         <oasis:entry colname="col2">10</oasis:entry>
         <oasis:entry colname="col3">AWI1330.1.1</oasis:entry>
         <oasis:entry colname="col4">2234 <inline-formula><mml:math id="M227" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 118</oasis:entry>
         <oasis:entry colname="col5">Unidentified organic remains</oasis:entry>
         <oasis:entry colname="col6">1927–2696</oasis:entry>
         <oasis:entry colname="col7">2230</oasis:entry>
         <oasis:entry colname="col8">n/a</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup><?xmltex \end{scaleboxenv}?></oasis:table></table-wrap>

      <p id="d1e5982">A total of 27 radiocarbon dates were used in the Bayesian age–height model,
which was established using the package rbacon 2.3 (2.3.9.1; Blaauw and
Christen, 2019) in R version 3.6.1 (R Core Team, 2019). Four ages were not
used for the age–height modelling: sample SOB18-03-17 (15 294 <inline-formula><mml:math id="M228" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 67 yr BP)
is most likely redeposited (see Sect. 5.1.1 for discussion), two of the
dates have unspecified infinite ages of <inline-formula><mml:math id="M229" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 42 600 yr BP (SOB18-06-18
and SOB18-06-33), and one further age of 47 021 <inline-formula><mml:math id="M230" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 646 yr BP (SOB18-06-35)
was beyond calibration range (Fig. 4). All three ages do, however, support
the age–height relation as they are of approximate age.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4"><?xmltex \currentcnt{4}?><label>Figure 4</label><caption><p id="d1e6009">Age–height relation of the Sobo-Sise Yedoma cliff exposure shown
in calibrated radiocarbon ages. Note the sampling overlap of the profiles
SOB18-01 (circles), SOB18-03 (diamonds), and SOB18-06 (stars) and their
alignment to cryostratigraphic units A (blue), B (green), and C (orange). The
open diamond indicates one age of redeposited material from sample
SOB18-03-17, and open stars indicate infinite radiocarbon ages of samples
from profile SOB18-06.
</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://tc.copernicus.org/articles/14/4525/2020/tc-14-4525-2020-f04.png"/>

        </fig>

      <p id="d1e6018">Each profile was modelled individually (Fig. S2). Section thickness was
adjusted in relation to sampling<?pagebreak page4531?> frequency along each profile to balance
model performance (Blaauw and Christen, 2019). Sediment profile SOB18-01 was
modelled using 12 <inline-formula><mml:math id="M231" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">14</mml:mn></mml:msup></mml:math></inline-formula>C dates, a section thickness of 10 cm, and a
hiatus at 1.75 m b.s. (22.45 m a.r.l.) and 3.25 m b.s. (20.95 m a.r.l.). Profile
SOB-03 was modelled using seven <inline-formula><mml:math id="M232" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">14</mml:mn></mml:msup></mml:math></inline-formula>C dates, a section thickness of 30 cm,
and a hiatus at 7.25 m b.s. (16.95 m a.r.l.). This model was extrapolated 0.5 m beyond the uppermost (youngest) dated sample to cover the entire profile.
Profile SOB18-06 was modelled using eight <inline-formula><mml:math id="M233" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">14</mml:mn></mml:msup></mml:math></inline-formula>C dates and a section
thickness of 40 cm and was extrapolated 2.3 m beyond the lowermost
radiocarbon age used in the model to cover the lowermost samples of this
profile. SOB18-06 represents the oldest deposits of the dataset and
infringes on the age limit of radiocarbon dating (Fig. S2). The median of
the modelled probability distribution was used to assign an age to each centimetre
along the profiles.</p>
      <p id="d1e6048">Additional age information was obtained from one mammoth tusk found at beach
level below the sediment profile SOB18-01 (Fig. 3c) and from host sediments
of ice wedges SOB18-08 and SOB18-09 (Table 3). Floral and faunal remains
from inside wedge ice were dated where available (Table 3). In total, age
information for five ice wedges was obtained from 22 radiocarbon dates. Of
those, 19 samples were dated at the MICADAS facility mentioned above, and
three samples were dated at the CologneAMS (University of Cologne, Germany),
whose laboratory procedures are given in detail in Rethemeyer et al. (2013).</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Results</title>
<sec id="Ch1.S4.SS1">
  <label>4.1</label><title>Chronostratigraphy</title>
      <p id="d1e6067">The three sediment profiles were sampled in close proximity to cover the
entire exposed permafrost sequence at 0.5 m sampling resolution in spatial
context. The overlap in sampling heights was applied to account for possible
relief diversity during permafrost aggradation (Fig. 2). Profile SOB18-01
covers the uppermost part of the exposure between 24.2 and 15.5 m a.r.l., dated
from 2440 to 27 540 cal yr BP. The adjacent sedimentary polygon filling was
sampled in profile SOB18-03 between 18.8 and 10.2 m a.r.l., dated from 25 680
to 40 840 cal yr BP. The lowermost profile SOB18-06, sampled about 120 m east
of the SOB18-01 between 13.4 and 0.8 m a.r.l., shows ages from 41 420 to
<inline-formula><mml:math id="M234" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 50 000 cal yr BP (Table 3). The overlap in sampling positions of
the three profiles (Fig. 4) and the modelled age–height relation allows for
the deduction of a stacked record that differentiates into three chronostratigraphic
units:</p>
      <p id="d1e6077">Unit A – MIS 3, Yedoma IC (52 to 28 cal kyr BP);</p>
      <p id="d1e6080">Unit B – MIS 2, Yedoma IC (28 to 15 cal kyr BP);</p>
      <p id="d1e6083">Unit C – MIS 1, Holocene cover (7 to 0 cal kyr BP).</p>
      <p id="d1e6087">The stacked sequence is not continuous and shows three temporal gaps in the
record, which are related to changes in the depositional and/or erosional
regimes. Those are discussed in detail in Sect. 5.3. One hiatus is obvious
within Unit A (in profile SOB18-03) between about 36 and 29 cal kyr BP, one
hiatus within Unit B (in profile<?pagebreak page4532?> SOB18-01) between 20 and 17 cal kyr BP, and
one hiatus between units B and C (in profile SOB18-01) between about 15 and
7 cal kyr BP (Fig. 4).</p>
      <p id="d1e6090">Age inversions are often observed in permafrost chronologies given the
effect of cryogenic processes such as cryoturbation within the uppermost
thawed active layer before the material enters the perennially frozen state
(Bockheim, 2007), the high vulnerability of ice-rich permafrost
to thaw, and erosion (Grosse et al., 2011; Günther et al., 2015). An
obvious example for the latter is seen in the Sobo-Sise record, where sample
SOB18-03-17 has an age of 15 294 <inline-formula><mml:math id="M235" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 67 yr BP (18 570 cal yr BP), while the
entire profile SOB18-03 dates from 25 680 to 40 840 cal yr BP (Table 3). We
assume that this age of 18 570 cal yr BP most likely represents a contamination
from thawed sediment, which was redeposited downwards along the cliff and
represents a mixed age of Holocene and older OM. To validate this
assumption, additional plant material from sample SOB18-03-17 was picked and
dated to 40 840 cal yr BP, in line with the lower age limit of profile
SOB18-03.</p>
      <?pagebreak page4534?><p id="d1e6100">Three ice wedge profiles of Unit A were dated. Seven <inline-formula><mml:math id="M236" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">14</mml:mn></mml:msup></mml:math></inline-formula>C dates from ice
wedge SOB18-09 range from 48 660 to 36 970 cal yr BP. We found one infinite age
of <inline-formula><mml:math id="M237" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 48 500 yr BP from the host deposit at the same height level as
the sampling transect. Ice wedge SOB14-IW3 shows ages of 43 270 and of 30 930 cal yr BP and two infinite ages of <inline-formula><mml:math id="M238" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 31 000 yr BP each. Organic
material from ice wedge SOB18-08-I yielded a <inline-formula><mml:math id="M239" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">14</mml:mn></mml:msup></mml:math></inline-formula>C age of 49 610 cal yr BP.</p>
      <p id="d1e6135">The SOB18-02-I wedge ice of Unit B was dated by two ages of 25 350 and of 23 470 cal yr BP. The host deposits at the same height level as the sampling
profile at about 18 to 20 m a.r.l. show an age range from 23 170 to 21 940 cal yr BP that is in general agreement with the assumed SOB18-02-I formation time.
The only direct age information from Unit C wedge ice is available for
profile SOB14-IW4, with eight ages spanning from 2290 cal yr BP to modern
times (Table 3). Indirect age information is available for SOB18-08-II, whose host
deposits at the same height level as the sampling transect were dated to 4480 cal yr BP (Table 3), implying a middle- to late-Holocene formation of this
ice wedge.</p>
      <p id="d1e6138">Relocated material might also enter wedge ice when wintertime frost cracks
are filled with snowmelt transporting OM and preserving it in vertical ice
veins (Opel et al., 2018). This might be the case for the age determination
of 49 610 cal yr BP in ice wedge (IW) SOB18-08-I, which is, however, attributed to Unit A of
MIS 3 age by its isotopic composition.</p>
</sec>
<sec id="Ch1.S4.SS2">
  <label>4.2</label><title>Cryostratigraphy</title>
      <p id="d1e6149">Each cryostratigraphic unit is characterized by its specific clastic,
organic, and ice compositions. Those were captured by field observations
(<?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2019) and analytical data that are described in detail
below and summarized in Figs. 5 and 6 and Table 1. Representation of our
analytical results is based on the modelled age–height relation for each
profile and their stacking by age (Fig. S2).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5" specific-use="star"><?xmltex \currentcnt{5}?><label>Figure 5</label><caption><p id="d1e6158">Sediment properties of the Sobo-Sise Yedoma record and their
variations over time. Dashed horizontal lines indicate the limits of the
cryostratigraphic units A, B, and C. White circles in the plot of grain-size
properties relate to the upper <inline-formula><mml:math id="M240" display="inline"><mml:mi>x</mml:mi></mml:math></inline-formula> axis (mean grain size).</p></caption>
          <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://tc.copernicus.org/articles/14/4525/2020/tc-14-4525-2020-f05.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6" specific-use="star"><?xmltex \currentcnt{6}?><label>Figure 6</label><caption><p id="d1e6176">Intra-sedimental ice properties of the Sobo-Sise Yedoma
record and their variations over time. Dashed horizontal lines indicate the
limits of the cryostratigraphic units A, B, and C.</p></caption>
          <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://tc.copernicus.org/articles/14/4525/2020/tc-14-4525-2020-f06.png"/>

        </fig>

      <p id="d1e6186">Stable-water-isotope records and age information of six horizontal ice wedge
profiles sampled at the Sobo-Sise Yedoma cliff are attributed to the
cryostratigraphic units A, B, and C by position (Fig. 7), isotopic
composition (Table 2), and age (Table 3). Two of the ice wedge profiles
(SOB18-08 and SOB18-02) exhibited stable-isotope compositions pointing to
different stages of ice wedge formation, which formed under contrasting
climatic conditions and therefore represent different time periods. These
differentiations are explained in detail below. Spatial dimensions and other
field observations of the wedge ice are summarized in <?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al. (2019). Note that marginal ice wedge samples that underwent isotopic
exchange with the host sediment (Meyer et al., 2002a) are excluded from
summary statistics given in Table 2, although they are shown in Fig. 7 as grey
symbols for completeness of the raw data.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7" specific-use="star"><?xmltex \currentcnt{7}?><label>Figure 7</label><caption><p id="d1e6195">Horizontal wedge ice profiles of the Sobo-Sise Yedoma
cliff and their alignment to the cryostratigraphic units A (blue graphs), B
(green graphs), and C (orange graphs). Upper graphs refer to the deuterium
excess data and the respective right <inline-formula><mml:math id="M241" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> axis. Please note that data points
shown in grey are excluded from summary statistics in Table 2. Radiocarbon
dates are shown as hollow diamonds and refer to Table 3.</p></caption>
          <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://tc.copernicus.org/articles/14/4525/2020/tc-14-4525-2020-f07.png"/>

        </fig>

<sec id="Ch1.S4.SS2.SSS1">
  <label>4.2.1</label><?xmltex \opttitle{Unit A (MIS 3, Yedoma IC, 52 to 28\,cal\,kyr\,BP)}?><title>Unit A (MIS 3, Yedoma IC, 52 to 28 cal kyr BP)</title>
      <p id="d1e6219">The frozen deposits of Unit A are represented by the entire sediment profile
SOB18-06 and most of sediment profile SOB18-03 (except for its uppermost two
samples that belong to Unit B; Fig. 4). Unit A is evenly composed of grey,
poorly sorted sandy silt (mean grain size of 45 <inline-formula><mml:math id="M242" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 12 <inline-formula><mml:math id="M243" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>) with a
pronounced peak in the coarse-silt fraction and a minor peak in the middle-sand fraction (Fig. 8c).</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F8"><?xmltex \currentcnt{8}?><label>Figure 8</label><caption><p id="d1e6241">Grain-size distribution curves for <bold>(a)</bold> Holocene Unit C, <bold>(b)</bold> MIS 2
Unit B, and <bold>(c)</bold> MIS 3 Unit A of the Sobo-Sise Yedoma cliff. Bold lines
indicate the mean value, and grey shaded areas indicate the 25 % to 75 %
quartile.</p></caption>
            <?xmltex \igopts{width=227.622047pt}?><graphic xlink:href="https://tc.copernicus.org/articles/14/4525/2020/tc-14-4525-2020-f08.png"/>

          </fig>

      <p id="d1e6259">Endmember modelling of grain-size distributions revealed four robust
endmembers (rEMs) for the Yedoma IC units A and B. In Unit A, the coarse-silt rEM2 (primary mode at 31 <inline-formula><mml:math id="M244" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>) dominates, while the fine-silt rEM1
(primary mode at 6 <inline-formula><mml:math id="M245" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>) and fine-sand rEM 3 (primary mode at 76 <inline-formula><mml:math id="M246" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>)
occur less frequently (Fig. 5). The mean magnetic susceptibility of Unit A
is 40 <inline-formula><mml:math id="M247" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 9 SI.</p>
      <p id="d1e6300">The OM of Unit A deposits consists of numerous twigs and grass remains,
black and brownish spots (0.1–0.5 cm in diameter), single peaty lenses
(15–20 cm in diameter), and peat layers (10–20 cm up to 130 cm thick). The
mean TOC and TN values are 4.5 <inline-formula><mml:math id="M248" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2.5 and 0.3 <inline-formula><mml:math id="M249" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.1 wt %, respectively; <inline-formula><mml:math id="M250" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">C</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">N</mml:mi></mml:mrow></mml:math></inline-formula> is 12.9 <inline-formula><mml:math id="M251" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2.5. The corresponding mean stable-isotope values are <inline-formula><mml:math id="M252" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>27.3 <inline-formula><mml:math id="M253" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.9 ‰ for <inline-formula><mml:math id="M254" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>C and 2.2 <inline-formula><mml:math id="M255" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.6 ‰ for <inline-formula><mml:math id="M256" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">15</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>N,
respectively.</p>
      <p id="d1e6380">The organic component represented as DOC in intra-sedimental ice of Unit A
shows large variations between 161 and 754 mg L<inline-formula><mml:math id="M257" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> at a mean value of
367 mg L<inline-formula><mml:math id="M258" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>.</p>
      <p id="d1e6407">The intra-sedimental ice of Unit A amounts to a gravimetric ice content of 49 <inline-formula><mml:math id="M259" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 10 wt %, manifested in lenticular cryostructures and reticulate
and wavy, sometimes structureless cryostructures between the ice layers. The
stable-water-isotope composition of the intra-sedimental ice shows a mean
value of <inline-formula><mml:math id="M260" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>23.9 <inline-formula><mml:math id="M261" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2.0 ‰ for <inline-formula><mml:math id="M262" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and
<inline-formula><mml:math id="M263" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>190 <inline-formula><mml:math id="M264" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 15 ‰ for <inline-formula><mml:math id="M265" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D (Fig. 9a). The <inline-formula><mml:math id="M266" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>
values also vary considerably between <inline-formula><mml:math id="M267" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>6 ‰ and 12 ‰ (mean of 1.5 ‰).</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F9"><?xmltex \currentcnt{9}?><label>Figure 9</label><caption><p id="d1e6480">Stable-water-isotope composition (<inline-formula><mml:math id="M268" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, <inline-formula><mml:math id="M269" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D)
of <bold>(a)</bold> intra-sedimental (excess and pore) ice from units A, B, and C of <bold>(b)</bold> Holocene wedge ice of Unit C and of <bold>(c)</bold> late-Pleistocene Yedoma wedge ice of
units B and A of the Sobo-Sise cliff.</p></caption>
            <?xmltex \igopts{width=184.942913pt}?><graphic xlink:href="https://tc.copernicus.org/articles/14/4525/2020/tc-14-4525-2020-f09.png"/>

          </fig>

      <p id="d1e6516">The electrical conductivity of the intra-sedimental ice of Unit A shows a
large variability between about 730 and 5780 <inline-formula><mml:math id="M270" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:mrow></mml:math></inline-formula> cm<inline-formula><mml:math id="M271" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (mean
2245 <inline-formula><mml:math id="M272" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1570 <inline-formula><mml:math id="M273" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:mrow></mml:math></inline-formula> cm<inline-formula><mml:math id="M274" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) and is thus higher than in units B
and C. The cations Ca and Mg dominate the hydrochemical composition,
suggesting also substantial concentrations of HCO<inline-formula><mml:math id="M275" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> that were,
however, not measured due to limited sample amount. Na and Cl concentrations
also reach higher values and dominate the peak in ion content around 44–43 cal kyr BP (Fig. 6). At this peak increased Fe concentrations are
also notable.</p>
      <p id="d1e6581">The ice wedge SOB18-09 of Unit A reveals an isotopic composition with mean
values of <inline-formula><mml:math id="M276" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>29.7 ‰ in <inline-formula><mml:math id="M277" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, <inline-formula><mml:math id="M278" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>232 ‰ in <inline-formula><mml:math id="M279" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D, and <inline-formula><mml:math id="M280" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> of 5.2 ‰.
SOB14-IW3 shows identical mean values of <inline-formula><mml:math id="M281" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>29.7 ‰ in
<inline-formula><mml:math id="M282" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math id="M283" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>231 ‰ in <inline-formula><mml:math id="M284" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D but a
higher <inline-formula><mml:math id="M285" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> of 7.2 ‰.</p>
      <p id="d1e6663">The eastern part of profile SOB18-08 (differentiated as SOB18-08-I) is
characterized by more depleted values in <inline-formula><mml:math id="M286" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O (by 4 ‰), <inline-formula><mml:math id="M287" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D (by 40 ‰), and <inline-formula><mml:math id="M288" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> (by
4 ‰) if compared to the main part of the profile
(SOB18-08-II), which is attributed to Unit C. Mean values of SOB18-08-I are
<inline-formula><mml:math id="M289" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>29.6 ‰ in <inline-formula><mml:math id="M290" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, <inline-formula><mml:math id="M291" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>230 ‰ in <inline-formula><mml:math id="M292" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D, and 6.8 ‰ in <inline-formula><mml:math id="M293" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>, close
to the respective values of the other two ice wedge profiles of Unit A.</p>
      <?pagebreak page4535?><p id="d1e6731">In summary, the ice wedges of Unit A show most depleted mean values down to
<inline-formula><mml:math id="M294" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>29.9 ‰ in <inline-formula><mml:math id="M295" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O (range from <inline-formula><mml:math id="M296" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>31.4 ‰ to <inline-formula><mml:math id="M297" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>26.9 ‰) and <inline-formula><mml:math id="M298" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>232 ‰ in <inline-formula><mml:math id="M299" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D (range from <inline-formula><mml:math id="M300" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>244 ‰
to <inline-formula><mml:math id="M301" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>213 ‰). They plot mainly below the global meteoric water line (GMWL) and show
low <inline-formula><mml:math id="M302" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> between 5.2 ‰ and 7.4 ‰ in comparison to IWs of units
B and C. The slopes in co-isotopic plots of ice wedge data from Unit A vary
between 7.2 and 8.3 (Fig. 9c).</p>
</sec>
<sec id="Ch1.S4.SS2.SSS2">
  <label>4.2.2</label><?xmltex \opttitle{Unit B (MIS 2, Yedoma IC, 28 to 15\,cal\,kyr\,BP)}?><title>Unit B (MIS 2, Yedoma IC, 28 to 15 cal kyr BP)</title>
      <p id="d1e6811">Unit B comprises the uppermost two samples of sediment profile SOB18-03 and
most of sediment profile SOB18-01 (except its uppermost four samples that
belong to Unit C; Fig. 4). Unit B is composed of brownish grey, poorly sorted
sandy silt (mean grain size 113 <inline-formula><mml:math id="M303" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 64 <inline-formula><mml:math id="M304" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>) and occasional sand
lenses, resulting in a bimodal GSD and pronounced peaks in the coarse-silt
and medium-sand fractions (Fig. 8b).</p>
      <p id="d1e6831">Generally coarser grain-size distributions than in Unit A are characteristic
for Unit B and supported by the EMMA results. The middle-sand rEM4 (primary
mode at 310 <inline-formula><mml:math id="M305" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>) is present in the lower part of Unit B, while fine-silt
rEM1 and coarse-silt rEM2 dominate the upper part of Unit B (Fig. 5). The
fine-sand rEM3 is less frequent in Unit B compared to Unit A.</p>
      <?pagebreak page4536?><p id="d1e6844">The magnetic susceptibility of Unit B has a mean of 53 <inline-formula><mml:math id="M306" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 9 SI. OM is
present as single twig remains (2–4 mm in diameter), dark brown spots,
finely dispersed organic remains, and peaty lenses (5 to 25 cm in diameter).
The mammoth tusk found at beach level below the profile SOB18-01 most likely
originates from Unit B deposits belonging to the faunal component of OM. It
was radiocarbon-dated to 16 480 cal yr BP and thus fits into the age range of
Unit B. This finding fits well into the fossil record of the late-Pleistocene mammoth fauna in the region (Kuznetsova et al., 2019). The OM
content of Unit B is lower compared to that of Unit A, with mean values of
2.1 <inline-formula><mml:math id="M307" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.3 wt % for TOC and 0.2 <inline-formula><mml:math id="M308" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.1 wt % for TN, resulting
in mean <inline-formula><mml:math id="M309" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">C</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">N</mml:mi></mml:mrow></mml:math></inline-formula> of 10.5 <inline-formula><mml:math id="M310" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2.4.</p>
      <p id="d1e6888">The OM isotopic composition exhibits lower mean values than in Unit A of
<inline-formula><mml:math id="M311" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>26.1 <inline-formula><mml:math id="M312" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.6 ‰ for <inline-formula><mml:math id="M313" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>C and 1.9 <inline-formula><mml:math id="M314" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.0 ‰ for <inline-formula><mml:math id="M315" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">15</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>N. The DOC content of
intra-sedimental ice of Unit B is generally lower compared to those of Unit A,
with values from 85 to 589 mg L<inline-formula><mml:math id="M316" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (mean of 212 mg L<inline-formula><mml:math id="M317" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>).</p>
      <p id="d1e6959">The ice content of Unit B is the lowest of all units, with 43 <inline-formula><mml:math id="M318" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 10 wt %. Prevailing cryostructures are lenticular (1–5 cm thick ice layers
in 1–20 cm distance) and reticulate (1–2 mm thick ice lenses 4–12 mm
long) or wavy parallel (1 mm thick ice lenses 4–10 mm long) between the ice
layers. If compared to Unit A, the intra-sedimental ice of Unit B shows
similar mean values and comparable ranges in <inline-formula><mml:math id="M319" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O of <inline-formula><mml:math id="M320" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>26.2 <inline-formula><mml:math id="M321" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2.2 ‰ and in <inline-formula><mml:math id="M322" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D of <inline-formula><mml:math id="M323" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>200 <inline-formula><mml:math id="M324" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 16 ‰ (Fig. 9a). The mean <inline-formula><mml:math id="M325" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> value of about 10 ‰ is much higher than in Unit A, ranging from 3 ‰ to 15 ‰.</p>
      <p id="d1e7023">The hydrochemical composition of intra-sedimental ice of Unit B shows an
upward decreasing trend in ion content with electrical conductivity ranging
from about 3180 to 1130 <inline-formula><mml:math id="M326" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:mrow></mml:math></inline-formula> cm<inline-formula><mml:math id="M327" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (mean: 1810 <inline-formula><mml:math id="M328" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:mrow></mml:math></inline-formula> cm<inline-formula><mml:math id="M329" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>; Fig. 6). Ca and Mg cations dominate the cation composition, while
Cl concentrations decrease upwards.</p>
      <p id="d1e7070">The only IW record of Unit B was obtained in the eastern part of profile
SOB18-02. Like SOB18-08-I, the isotopic composition of SOB18-02-I differs
from the western part of its profile (SOB18-02-II attributed to Unit C) by
more depleted isotopic mean values and a lower <inline-formula><mml:math id="M330" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>: <inline-formula><mml:math id="M331" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>28.8 <inline-formula><mml:math id="M332" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.5 ‰ in <inline-formula><mml:math id="M333" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, <inline-formula><mml:math id="M334" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>225 <inline-formula><mml:math id="M335" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 5 ‰ in <inline-formula><mml:math id="M336" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D, and <inline-formula><mml:math id="M337" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> of 5.8 <inline-formula><mml:math id="M338" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.9 ‰. The values plot below the GMWL, and the co-isotopic
plot shows a slope of 9.4 (Fig. 9c).</p>
</sec>
<?pagebreak page4537?><sec id="Ch1.S4.SS2.SSS3">
  <label>4.2.3</label><?xmltex \opttitle{Unit C (MIS 1, Holocene cover, 7 to 0\,cal\,kyr\,BP)}?><title>Unit C (MIS 1, Holocene cover, 7 to 0 cal kyr BP)</title>
      <p id="d1e7150">The uppermost four samples of sediment profile SOB18-01 represent the
cryostratigraphic Unit C including the uppermost seasonally thawed active
layer (of 0.2 m on 20 July 2018 at the sampling site) that consists of
modern vegetation and peat (Fig. 4). Below the active layer, grey poorly
sorted sandy silt is present. Its grain-size distribution is bimodal with
peaks in the coarse-silt and medium-sand fractions (mean grain size of 66 <inline-formula><mml:math id="M339" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 13 <inline-formula><mml:math id="M340" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>; Figs. 5, 8a). The mean MS is the lowest of all
units, with 32 <inline-formula><mml:math id="M341" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 23 SI, which corresponds to the highest OM content
(present in numerous peaty lenses, 2 to 25 cm in diameter), with mean TOC of
11.3 <inline-formula><mml:math id="M342" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 9.9 wt % and mean TN of 0.6 <inline-formula><mml:math id="M343" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.3 wt %. The <inline-formula><mml:math id="M344" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">C</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">N</mml:mi></mml:mrow></mml:math></inline-formula> is
highest for all units, with a mean value of 18.5 <inline-formula><mml:math id="M345" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 8. The OM stable-isotope composition exhibits the most depleted mean value of <inline-formula><mml:math id="M346" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>28.0 <inline-formula><mml:math id="M347" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.2 ‰ for <inline-formula><mml:math id="M348" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>C of all units and a mean value
of 2.1 <inline-formula><mml:math id="M349" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.7 ‰ for <inline-formula><mml:math id="M350" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">15</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>N. From Unit C
only one measurement of DOC of intra-sedimental ice is available, showing the
lowest value of the entire DOC data with 34 mg L<inline-formula><mml:math id="M351" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>.</p>
      <?pagebreak page4539?><p id="d1e7267">The protective layer underlying the thawed active layer (Kanevskiy et al.,
2017) is characterized by a high ice content of 80 wt %, representing ice
segregation towards the freezing front during the annual freeze–thaw cycles.
The cryostructures are reticulate, with 2–4 mm thick and 4–10 mm long ice
lenses. Below, lenticular (up to 10 mm thick ice layers at 2–8 cm distance)
and reticulate (1–4 mm thick ice lenses, 6–12 mm long) cryostructures are
present. The stable-water-isotope composition of intra-sedimental ice is less
depleted than in units A and B, with mean values of <inline-formula><mml:math id="M352" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>20.7 <inline-formula><mml:math id="M353" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.3 ‰ in <inline-formula><mml:math id="M354" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math id="M355" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>151 <inline-formula><mml:math id="M356" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2 ‰ in <inline-formula><mml:math id="M357" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D, and shows only low variation (Fig. 9a),
likely due to the low sample number (<inline-formula><mml:math id="M358" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:math></inline-formula>). The <inline-formula><mml:math id="M359" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> value is highest for all
units, with about 15 ‰.</p>
      <p id="d1e7336">The hydrochemical composition in intra-sedimental ice of Unit C was
characterized in only one sample, which shows a very low electrical
conductivity of 36 <inline-formula><mml:math id="M360" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:mrow></mml:math></inline-formula> cm<inline-formula><mml:math id="M361" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, and major ion concentrations of less
than 2 mg L<inline-formula><mml:math id="M362" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> except for Ca and Fe.</p>
      <p id="d1e7374">One complete IW profile (SOB14-IW4) and two profile parts (SOB18-08-II and
SOB18-02-II) belong to the cryostratigraphic Unit C of Holocene cover
deposits. We furthermore consider the Holocene ice wedge profile SOB14-IW5
from the lowermost part of the Yedoma slope that might represent a former
thermokarst basin (alas) level overlying the Yedoma IC. The isotopic composition
of SOB14-IW4 shows mean values of <inline-formula><mml:math id="M363" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>27.8 ‰ in <inline-formula><mml:math id="M364" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, <inline-formula><mml:math id="M365" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>207 ‰ in <inline-formula><mml:math id="M366" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D, and 14.9 ‰ in <inline-formula><mml:math id="M367" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>. Less depleted values in <inline-formula><mml:math id="M368" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O of <inline-formula><mml:math id="M369" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>27.3 ‰, <inline-formula><mml:math id="M370" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>26.2 ‰, and <inline-formula><mml:math id="M371" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>25.2 ‰ are found in profiles SOB14-IW5, SOB18-08-II, and
SOB18-02-II, respectively. The according <inline-formula><mml:math id="M372" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D mean values from these
three profile are <inline-formula><mml:math id="M373" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>204 ‰, <inline-formula><mml:math id="M374" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>196 ‰,
and <inline-formula><mml:math id="M375" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>190 ‰, with <inline-formula><mml:math id="M376" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values of 13.8 ‰,
13.8 ‰, and 11.2 ‰. All wedge ice
records of Unit C are clearly distinguished from those of units A and B by
less depleted <inline-formula><mml:math id="M377" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math id="M378" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D and <inline-formula><mml:math id="M379" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values well above 10 ‰ (Table 2). They plot predominantly above the GMWL. The
co-isotopic plot reveals a large range of 7 ‰ in <inline-formula><mml:math id="M380" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O from <inline-formula><mml:math id="M381" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>30.4 ‰ to <inline-formula><mml:math id="M382" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>23.4 ‰
and of 53 ‰ in <inline-formula><mml:math id="M383" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D from <inline-formula><mml:math id="M384" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>227 ‰ to <inline-formula><mml:math id="M385" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>174 ‰. The respective slopes
vary between 7.7 and 8.8 (Fig. 9b).</p>
</sec>
</sec>
</sec>
<sec id="Ch1.S5">
  <label>5</label><title>Discussion</title>
<sec id="Ch1.S5.SS1">
  <label>5.1</label><title>Cryolithological properties of the Sobo-Sise Yedoma IC and its Holocene
cover</title>
<sec id="Ch1.S5.SS1.SSS1">
  <label>5.1.1</label><title>Permafrost aggradation rates and deposition history</title>
      <p id="d1e7582">Excluding the chronological gap between about 36 and 29 cal kyr BP within Unit
A, we assume continuous permafrost aggradation of the MIS 3 Yedoma IC on
Sobo-Sise from at least about 52 to 36 cal kyr BP, which is represented by a
16 m thick permafrost sequence. The resulting aggradation rate of the MIS 3
Yedoma IC amounts to about 1 m kyr<inline-formula><mml:math id="M386" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. The continuous permafrost
aggradation assumed from the MIS 2 Yedoma IC between about 28 and 20 cal kyr BP,
excluding the hiatus within Unit B (from 20 to 17 cal kyr BP), formed a
5 m thick sequence at a rate of about 0.7 m kyr<inline-formula><mml:math id="M387" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. If compared
to the Bykovsky Yedoma IC record (site Mamontovy Khayata; Schirrmeister et
al., 2002a), higher aggradation rates are obvious: about 1.5 m kyr<inline-formula><mml:math id="M388" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for MIS 3 (12 m thick sequence between 46 and 38 cal yr BP) and about
0.85 m kyr<inline-formula><mml:math id="M389" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for MIS 2 (6 m thick sequence between 28 and 21 cal kyr BP). Thus, less permafrost aggradation during MIS 2 than during MIS 3
is also seen on Bykovsky Peninsula. However, it should be noted that the
syngenetic growth of ice-oversaturated permafrost such as the Yedoma IC is not
only controlled by clastic and organic sedimentation but further triggered
by formation of pore and segregation ice that contributes 49 <inline-formula><mml:math id="M390" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 10 wt % in MIS 3 and 43 <inline-formula><mml:math id="M391" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 10 wt % in MIS 2
deposits to the Yedoma IC on
Sobo-Sise. The volumetric ice content based on the absolute ice content
(assuming ice saturation if the ice content is <inline-formula><mml:math id="M392" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 20 wt %)
according to Strauss et al. (2012) amounts to 66 <inline-formula><mml:math id="M393" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 9 vol % and 65 <inline-formula><mml:math id="M394" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 8 vol % for MIS 3 and MIS 2, respectively (Fuchs et al., 2020). At
this rather equal volumetric share of intra-sedimental ice during MIS 3 and
MIS 2, mainly organic accumulation seems to have controlled the difference
in permafrost aggradation rates. It should further be noted that growing ice
wedges deform the frozen deposits in between by material transport from the
polygon centre toward the rim and upward push (Mackay, 1981). Thus, the
vertical thickness of the sediment layers, determined now, might exceed the
initial thickness due to the formation of intra-sedimental (excess) ice but
also due to lateral material transport by the growing ice wedges. The MIS 1
cover deposits accumulated the uppermost 1.4 m since about 6.4 cal kyr BP.
Due to freeze–thaw cycles in the active layer and thaw subsidence on the
modern Sobo-Sise Yedoma surface of several centimetres per year (Chen et
al., 2018), the aggradation rate for Unit C has not been calculated.</p>
      <p id="d1e7669">The MIS 3 Yedoma IC of Unit A is characterized mainly by coarse silt and
partly by fine sand. This is also seen in the prevalent rEM2 and rEM3 of
Unit A and differs from the bimodal grain-size characteristics of the MIS 2
Yedoma IC of Unit B, with pronounced peaks in the coarse-silt and medium-sand
fractions represented predominantly by rEM4 and rEM2 (Figs. 8, 10, S1). Such changes in grain-size distributions of the MIS 3 and MIS 2 Yedoma IC
may point to different material sources and/or transport processes. A study
by Schirrmeister et al. (2020) of Yedoma IC deposition history, sources, and
material transport mechanisms includes the neighbouring study sites on
Bykovsky Peninsula and Kurungnakh-Sise Island (Fig. 1) but lacks a
differentiation into the MIS 3 and MIS 2 Yedoma IC as undertaken for data from
Sobo-Sise. Therefore, a direct comparison per formation period is of less
use to disentangle changes in sedimentation over time, although some general
information can be deduced. The medium-sand rEM4 grain-size class of the
Sobo-Sise data relates to high-energy transport including saltation in
meltwater run-off or fluvial water (rEM2 in Schirrmeister et al., 2020). The
fine-sand rEM3 represents overbank deposits or settled suspensions in
temporarily flooded sections during floodplain deposition (rEM4 in
Schirrmeister et al., 2020), while the coarse-silt rEM2 (rEM5 in
Schirrmeister et al., 2020) might relate to<?pagebreak page4540?> floodplain deposition as well
but could also originate from aeolian sources (Vandenberghe, 2013) or frost
weathering processes (Schwamborn et al., 2012). The fine-silt rEM1 (rEM8 in
Schirrmeister et al., 2020) reflects low-energy settling of suspended
material from aeolian or pedogenic sources under still-water conditions,
which is characteristic in low-centre polygon ponds. Thus, the Yedoma IC of
Sobo-Sise formation during MIS 3 with prevailing fine sand (rEM3) and coarse
silt (rEM2) derived mainly from floodplain-related or meltwater run-off
alluvial deposition processes but possibly also includes aeolian and
frost-weathering components. The same coarse-silt rEM2 dominates the
grain-size distributions from MIS 2 deposits with a pronounced peak (Figs. 8,
10, S1). We therefore assume a depositional regime similar to that
in MIS 3 for this time. MIS 2 deposition, however, shows a second pronounced
peak in medium sand (rEM4), pointing to occasional high-energy material
transport in alluvial fan environments with strong meltwater run-off and/or
fluvial transport. Sparse vegetation cover as deduced from LGM climate
conditions in the area (Andreev et al., 2011) might have promoted the
potential for high transport energy in a barren landscape. The differing
grain-size compositions at the three location on Bykovsky, Sobo-Sise, and
Kurungnakh-Sise reflect local diversity in accumulation processes, for
example with higher fluvial input on Kurungnakh-Sise Island, but generally
support the multi-process and multi-source regional Yedoma IC formation
(Schirrmeister et al., 2020).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F10"><?xmltex \currentcnt{10}?><label>Figure 10</label><caption><p id="d1e7674">Grain-size distribution curves and endmember modelling (EMMA) of
both Yedoma IC units A and B from the Sobo-Sise Yedoma cliff. EMMA revealed
four robust endmembers (rEMs), rEM1 has its primary mode at 5.91 <inline-formula><mml:math id="M395" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> in
the fine silt, rEM2 has its primary mode at 31.1 <inline-formula><mml:math id="M396" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> in the coarse silt.
The rEMs 3 and 4 have their primary modes in the fine sand (76 <inline-formula><mml:math id="M397" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>) and
middle sand (310 <inline-formula><mml:math id="M398" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>), respectively.</p></caption>
            <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://tc.copernicus.org/articles/14/4525/2020/tc-14-4525-2020-f10.png"/>

          </fig>

<?xmltex \hack{\newpage}?>
</sec>
<sec id="Ch1.S5.SS1.SSS2">
  <label>5.1.2</label><title>Organic-matter stocks and decomposition</title>
      <p id="d1e7733">The OM characteristics of the Sobo-Sise Yedoma IC differentiate into twofold-higher organic-carbon (TOC mean of 4.5 <inline-formula><mml:math id="M399" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2.6 wt %) and 50 % higher
nitrogen (TN mean of 0.3 <inline-formula><mml:math id="M400" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.1 wt %) content in Unit A (MIS 3) if
compared to those of Unit B (MIS 2), with mean TOC of 2.1 <inline-formula><mml:math id="M401" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.3 wt %
and mean TN of 0.2 <inline-formula><mml:math id="M402" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.1 wt %. The resulting <inline-formula><mml:math id="M403" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">C</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">N</mml:mi></mml:mrow></mml:math></inline-formula> ratios are slightly
higher in Unit A, with 12.9, than in Unit B, with 10.5 (Table 1). A more
productive tundra–steppe environment during MIS 3 (Unit A) with higher OM
accumulation at comparable decomposition rates if compared to MIS 2 (Unit B)
is deduced.</p>
      <p id="d1e7776">Furthermore, Unit A has significantly higher carbon and nitrogen densities,
with a mean of 29 <inline-formula><mml:math id="M404" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 15 kg carbon m<inline-formula><mml:math id="M405" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> and 2.2 <inline-formula><mml:math id="M406" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.0 kg nitrogen m<inline-formula><mml:math id="M407" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> compared to 14 <inline-formula><mml:math id="M408" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 8 kg carbon m<inline-formula><mml:math id="M409" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> and 1.4 <inline-formula><mml:math id="M410" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.4 kg nitrogen m<inline-formula><mml:math id="M411" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> in Unit B. Consequently, the OM input into the Lena
river by fast erosion of the Yedoma cliff of Sobo-Sise (up to 22.3 m yr<inline-formula><mml:math id="M412" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>; Fuchs et al., 2020) is mainly controlled by Unit A, which stores
twice the amount of carbon compared to Unit B and which is exposed over
about two-thirds of the cliff height (Fig. 4).</p>
      <p id="d1e7868">The Holocene cover of Unit C shows highest TOC (mean 11.3 <inline-formula><mml:math id="M413" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 9.9 wt %), TN (mean 0.6 <inline-formula><mml:math id="M414" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.3 wt %), and <inline-formula><mml:math id="M415" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">C</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">N</mml:mi></mml:mrow></mml:math></inline-formula> (mean 18.5 <inline-formula><mml:math id="M416" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 8.0) of
the record, although with large variability (Table 1) mainly due to the low
number of samples (<inline-formula><mml:math id="M417" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:math></inline-formula>) in Unit C. However, for active-layer samples in
the Holocene cover layer of Sobo-Sise, Fuchs et al. (2018) detected mean
values with high variability, too, with 6.7 <inline-formula><mml:math id="M418" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 7.4 wt %, 0.4 <inline-formula><mml:math id="M419" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.1 wt %, and 15.8 <inline-formula><mml:math id="M420" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 12.3 for TOC, TN, and <inline-formula><mml:math id="M421" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">C</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">N</mml:mi></mml:mrow></mml:math></inline-formula>, respectively,
indicating a general heterogeneity in OM accumulation in the uppermost soil
layer. If compared to the neighbouring Yedoma IC sites on Bykovsky Peninsula
(Schirrmeister et al., 2002a) and Kurungnakh-Sise Island (Schirrmeister et
al., 2003; <?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2008a), the same pattern in OM properties over
time from MIS 3 to MIS 1 supports regionally similar variations in
palaeoenvironmental conditions.</p>
      <p id="d1e7954">In relict permafrost, the stable-carbon- and stable-nitrogen-isotope composition of
organic matter is strongly controlled by the original botanical composition
and further altered by decomposition (Weiss et al., 2016). The latter leads
preferentially to loss of isotopically lighter <inline-formula><mml:math id="M422" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">12</mml:mn></mml:msup></mml:math></inline-formula>C and <inline-formula><mml:math id="M423" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">14</mml:mn></mml:msup></mml:math></inline-formula>N and
thus relatively enriches the fraction of the heavier isotopes <inline-formula><mml:math id="M424" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">13</mml:mn></mml:msup></mml:math></inline-formula>C and
<inline-formula><mml:math id="M425" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">15</mml:mn></mml:msup></mml:math></inline-formula>N by leaching and mineralization processes (Tahmasebi et al., 2018).
This fractionation towards less depleted isotopic carbon and nitrogen
compositions over time occurs before the OM enters the perennially frozen
state. Thus, the permafrost aggradation rate during distinct periods further
influences the rate of OM decomposition. However, the differences seen per
unit in the Sobo-Sise Yedoma record are minor for <inline-formula><mml:math id="M426" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">15</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>N, with
mean values of around 2 ‰ for all three units (Table 1,
Fig. 11). The <inline-formula><mml:math id="M427" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">13</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>C unit mean values vary over about 2 ‰ (between about <inline-formula><mml:math id="M428" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>28 ‰ and <inline-formula><mml:math id="M429" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>26 ‰)<?pagebreak page4541?> and are most depleted for Unit C (MIS 1). Due to
these only little variations and the range overlap, no significant
differences in OM decomposition can be interpreted from the stable-carbon-
and stable-nitrogen-isotope composition for the three units.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F11"><?xmltex \currentcnt{11}?><label>Figure 11</label><caption><p id="d1e8033">Stable-carbon- and stable-nitrogen-isotope composition of organic matter
from cryostratigraphic units A, B, and C of the Sobo-Sise Yedoma cliff.</p></caption>
            <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://tc.copernicus.org/articles/14/4525/2020/tc-14-4525-2020-f11.png"/>

          </fig>

</sec>
<sec id="Ch1.S5.SS1.SSS3">
  <label>5.1.3</label><title>Intra-sedimental ice characteristics</title>
      <p id="d1e8050">The highest DOC concentrations up to 754 mg L<inline-formula><mml:math id="M430" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> in MIS 3 together with
the highest average <inline-formula><mml:math id="M431" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">C</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">N</mml:mi></mml:mrow></mml:math></inline-formula> ratios indicate OM preservation (Figs. 5, 6). Rapid
sediment and OM accumulation rates, as indicated by the radiocarbon-based
age–depth relationship, lead to effective syngenetic permafrost formation so
that particulate and dissolved OM is rapidly incorporated into permanently
frozen deposits. Hence, OM degradation is minimized, and labile or soluble
dissolved-organic-matter (DOM) fractions have not been drained or flushed out from rapidly aggrading
permafrost.</p>
      <p id="d1e8077">The stable-water-isotope (<inline-formula><mml:math id="M432" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math id="M433" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D) and major ion
compositions as well as DOC concentrations of Sobo-Sise intra-sedimental ice
reflect the general cryostratigraphy and have palaeoclimate implications.
Preservation of pore water during formation of segregated ice occurs via a
wide range of processes. Nevertheless, several studies (e.g. Mackay, 1983;
Murton and French, 1994; Kotler and Burn, 2000; Schwamborn et al., 2006;
Fritz et al., 2012) have shown that <inline-formula><mml:math id="M434" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math id="M435" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D
isotopes in intra-sedimental ice can still reflect environmental and climatic
changes when considered with caution and/or focused on pore ice (Porter et
al., 2019; Porter and Opel, 2020). Higher <inline-formula><mml:math id="M436" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math id="M437" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D
but lower <inline-formula><mml:math id="M438" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values are found in MIS 3 compared to MIS 2 (Figs. 6, 9).
Relatively warm summers during the MIS 3 interstadial might explain the
lower <inline-formula><mml:math id="M439" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values in associated intra-sedimental ice due to a higher water loss
by evaporation (i.e. kinetic fractionation). This would lead to a water
reservoir in polygon ponds and soil moisture that becomes successively
depleted in <inline-formula><mml:math id="M440" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">16</mml:mn></mml:msup></mml:math></inline-formula>O and <inline-formula><mml:math id="M441" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">1</mml:mn></mml:msup></mml:math></inline-formula>H compared to the original precipitation.
Increased temperature and precipitation amplitudes during MIS 3 (Andreev et
al., 2011; Pitulko et al., 2017) may have led to frequent drying and
re-wetting in polygon tundra and thus to enhanced kinetic fractionation.
Another process of kinetic fractionation producing the same pattern are
multiple freeze–thaw cycles of soil moisture in the active layer
(Throckmorton et al., 2016).</p>
      <p id="d1e8167">Elevated ion (Mg, Ca, Na, Cl) concentrations with EC up to 5800 <inline-formula><mml:math id="M442" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:mrow></mml:math></inline-formula> cm<inline-formula><mml:math id="M443" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> in the MIS 3 record (Unit A; Fig. 6) are likely caused by
frequent drying and re-wetting in polygonal tundra in times of higher summer
temperature and precipitation amplitudes during the interstadial compared to
the MIS 2 stadial (Unit B). Meyer et al. (2002a) found similarly elevated EC
values of 5500 <inline-formula><mml:math id="M444" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:mrow></mml:math></inline-formula> cm<inline-formula><mml:math id="M445" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> in MIS 3 deposits on Bykovsky Peninsula.
Modern surface waters in central Yakutia at high continentality show EC
values of up to 5710 <inline-formula><mml:math id="M446" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:mrow></mml:math></inline-formula> cm<inline-formula><mml:math id="M447" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (<?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2008b) and even
up to 7744 <inline-formula><mml:math id="M448" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:mrow></mml:math></inline-formula> cm<inline-formula><mml:math id="M449" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (Pestryakova et al., 2018). Ion-rich pore
waters have also been found in MIS 3 deposits at Buor Khaya Peninsula
(Schirrmeister et al., 2017) but with different composition and including a
distinct saline horizon. In contrast, ion composition in the Sobo-Sise
Yedoma IC remained stable throughout MIS 2 and MIS 3 and is dominated by Mg,
Cl, and Ca in both units. Therefore, we assume that water and sediment
sources did not change over time but reflect higher evaporation during
warmer summers in MIS 3 if compared to MIS 2.</p>
</sec>
</sec>
<sec id="Ch1.S5.SS2">
  <label>5.2</label><title>Palaeoclimatic implications from regional wedge ice records</title>
      <p id="d1e8272">Sobo-Sise ice wedge stable isotopes show a complex pattern that at least in
parts can be related to the fact that Holocene ice wedges formed
epigenetically within older late-Pleistocene deposits and penetrated
pre-existing ice wedges. This may be related to subsidence and
thermo-erosional processes that thaw permafrost, lower the surface, and
complicate the stratigraphic attribution of the wedge ice. The stable-isotope composition of ice wedge profiles sampled in the central (SOB18-02)
and western parts (SOB18-08) of the Sobo-Sise cliff allows the differentiation of
late-Pleistocene and Holocene wedge ice.</p>
      <?pagebreak page4542?><p id="d1e8275">Generally, late-Pleistocene wedge ice is characterized by well-depleted
<inline-formula><mml:math id="M450" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math id="M451" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D values (mean values between <inline-formula><mml:math id="M452" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>30 ‰ and <inline-formula><mml:math id="M453" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>29 ‰ as well as <inline-formula><mml:math id="M454" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>232 ‰ and <inline-formula><mml:math id="M455" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>225 ‰, respectively; Fig. 9c) and low <inline-formula><mml:math id="M456" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values (means between 5 ‰ and
7 ‰; Table 2). In contrast, a striking feature of
Holocene ice wedges is their significantly elevated mean <inline-formula><mml:math id="M457" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values between
11 ‰ and 15 ‰ (Table 2), accompanied by
surprisingly low <inline-formula><mml:math id="M458" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math id="M459" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D values (mean values
between <inline-formula><mml:math id="M460" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>28 ‰ and <inline-formula><mml:math id="M461" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>25 ‰ as well as <inline-formula><mml:math id="M462" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>207 ‰ and <inline-formula><mml:math id="M463" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>190 ‰, respectively;
Fig. 9b). In some instances, Holocene <inline-formula><mml:math id="M464" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math id="M465" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D
values reach the range of the late-Pleistocene ice wedges (Table 2). This is
true for both the oldest Holocene ice wedge stage, i.e. the toes of ice
wedge SOB14-IW5 at the ice complex alas slope and the late-Holocene to
modern ice wedges on the top of the ice complex (e.g. SOB14-IW4). Hence, the
isotopic difference between late-Pleistocene and Holocene ice wedges is more
pronounced in <inline-formula><mml:math id="M466" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> than in <inline-formula><mml:math id="M467" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> values.</p>
      <p id="d1e8419">All co-isotopic regression slopes are highly correlated (<inline-formula><mml:math id="M468" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M469" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 0.97) and vary between 7.16 and 9.43 (Table 2). While the ice
wedges of units C (MIS 3) and A (MIS 1) show relatively coherent patterns,
the Unit B ice wedge SOB18-02-I sticks out with a value of 9.43 (Fig. 9b
and c), likely related to a comparably low internal isotope variability.
Hence, we assume that the isotopic composition of all ice wedges carries
palaeoclimate information for the winter season and is not significantly
altered by secondary-fractionation processes.</p>
      <p id="d1e8440">The Sobo-Sise ice wedge stable isotopes of units A and B fit mostly well
into the regional pattern of the central Laptev Sea coast and the Lena delta
(Fig. 1) as well as in the large-scale pattern as presented by Opel et al. (2019) and reflect cold and stable winter climate conditions during the last
glacial. Unit A (MIS 3) Sobo-Sise ice wedges (mean <inline-formula><mml:math id="M470" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O:
<inline-formula><mml:math id="M471" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>29.7 ‰; mean <inline-formula><mml:math id="M472" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D: <inline-formula><mml:math id="M473" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>231.8 ‰) are slightly less depleted compared to those of Bykovsky Peninsula (mean
<inline-formula><mml:math id="M474" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O: <inline-formula><mml:math id="M475" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>30.8 ‰; mean <inline-formula><mml:math id="M476" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D:
<inline-formula><mml:math id="M477" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>242.8 ‰) to the east and Kurungnakh-Sise Island (mean
<inline-formula><mml:math id="M478" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O: <inline-formula><mml:math id="M479" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>31.6 ‰; mean <inline-formula><mml:math id="M480" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D:
<inline-formula><mml:math id="M481" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>247.6 ‰) to the west (Opel et al., 2019). In contrast,
ice wedge <inline-formula><mml:math id="M482" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values are slightly higher at Sobo-Sise (mean <inline-formula><mml:math id="M483" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>:
5.7 ‰) compared to Bykovsky (mean <inline-formula><mml:math id="M484" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>:
3.7 ‰) and Kurungnakh-Sise (mean <inline-formula><mml:math id="M485" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>:
5.3 ‰). For ice wedges of the MIS 2, the pattern is
similar, with slightly less depleted <inline-formula><mml:math id="M486" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> values for Sobo-Sise (mean
<inline-formula><mml:math id="M487" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O: <inline-formula><mml:math id="M488" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>28.8 ‰; mean <inline-formula><mml:math id="M489" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D:
<inline-formula><mml:math id="M490" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>224.6 ‰) and slightly higher <inline-formula><mml:math id="M491" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values (mean <inline-formula><mml:math id="M492" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>:
7.4 ‰) compared to Bykovsky (mean <inline-formula><mml:math id="M493" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O:
<inline-formula><mml:math id="M494" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>30.6 ‰, mean <inline-formula><mml:math id="M495" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D: <inline-formula><mml:math id="M496" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>239.5 ‰; mean <inline-formula><mml:math id="M497" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>: 5.1 ‰; Meyer et al., 2002a), while no data are
available for Kurungnakh-Sise. As the sampled ice wedges likely cover
different parts of the MIS 3 and MIS 2 Yedoma IC and therefore different
time slices, the slight differences should not be spatially interpreted in
terms of winter temperature differences.</p>
      <p id="d1e8664">The stable-isotope compositions of the studied Sobo-Sise ice wedges do not
show any significant differences between ice wedges of units A and B,
corresponding to MIS 3 and 2, respectively. This might indicate that the
globally cold LGM is not reflected in the Sobo-Sise ice-wedge-based winter
climate record and would be in accordance with both the regional scale, when
compared to Bykovsky Peninsula (Meyer et al., 2002a) or to other study sites
in the Laptev Sea region (<?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2011), and the Arctic scale (Porter and Opel, 2020). In this context, we observe (1) a
depositional gap temporally coinciding with peak LGM conditions for the three
sites at the regional scale and (2) that extremely depleted LGM ice wedge isotopes
have been found only at Bol'shoy Lyakhovsky Island further east (Fig. 1;
<?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2011). As such it is not sufficiently resolved yet
whether this is due to a less cold LGM climate in the region or whether the
LGM cold period is not captured by the studied ice wedge profiles that do
not preserve a continuous record.</p>
      <p id="d1e8675">In accordance with Holocene ice wedge records at Bykovsky and
Kurungnakh-Sise, the Sobo-Sise ice wedges of Unit C show distinctly warmer
winters and significantly changed moisture generation pattern compared to
the late-Pleistocene records. Overall Holocene mean ice wedge <inline-formula><mml:math id="M498" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>
values on Sobo-Sise are enriched by about 1.8 ‰ to 2.7 ‰ for <inline-formula><mml:math id="M499" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and 23 ‰ to
30 ‰ for <inline-formula><mml:math id="M500" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>D over MIS 2 and MIS 3 ice wedges,
respectively. The mean Holocene ice wedge <inline-formula><mml:math id="M501" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> value (14.2 ‰)
is about 7 ‰ and 8 ‰ higher compared
to MIS 2 and MIS 3, respectively, indicating substantial changes in the
moisture generation and transport patterns (e.g. Meyer et al., 2002a).
Similar changes have been observed on Bykovsky Peninsula (Meyer et al.,
2002a), while Holocene ice wedges at Kurungnakh-Sise show more enriched mean
<inline-formula><mml:math id="M502" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> values and lower mean <inline-formula><mml:math id="M503" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values (Schirrmeister et al., 2003;
<?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2008a). It has to be noted that the Holocene ice wedge
stable-isotope compositions for both Sobo-Sise and Bykovsky exhibit
significantly more depleted <inline-formula><mml:math id="M504" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> values and significantly higher <inline-formula><mml:math id="M505" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>
values compared to other ice wedge study sites along the Siberian Arctic
coastal lowlands (Opel et al., 2019). Holocene minimum <inline-formula><mml:math id="M506" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> values even
fit well into the typical MIS 3 and MIS 2 isotopic range. It is, however,
unlikely, that this particular region, i.e. the eastern Lena river delta and
the western Tiksi Bay, is characterized by a significantly colder winter
climate. Hence, other potential explanations have to be considered, such as
regional specifics of the water cycle. The significantly depleted <inline-formula><mml:math id="M507" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>
values and increased <inline-formula><mml:math id="M508" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values of Holocene ice wedges show some similarities
to early-winter precipitation (October to December) that is, in particular,
characterized by distinctly increased <inline-formula><mml:math id="M509" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values (e.g. Kurita, 2011; Bonne et
al., 2020). Hence, the Holocene ice wedge stable-isotope composition might
be explained by an over-representation of early-winter snow in the meltwater feeding ice wedge cracks. This could be related to specific moisture
generation and transport patterns influencing the precipitation in this
particular region. A second option could be the contribution of moisture
from local sources such as evaporation of isotopically depleted and high-deuterium excess Lena river water (Juhls et al., 2020) in the period of ice
build-up, resulting in a substantial snow cover development in the early
winter season. Only little mixed-ocean and substantial open-water areas
with a mainly freshwater signature could explain why this pattern of low <inline-formula><mml:math id="M510" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> and
high <inline-formula><mml:math id="M511" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values for Holocene ice wedges could so far only be observed
in the eastern Lena delta region.</p>
</sec>
<?pagebreak page4543?><sec id="Ch1.S5.SS3">
  <label>5.3</label><title>Chronostratigraphy of the Yedoma IC in the central Laptev Sea coastal
region</title>
      <p id="d1e8794">The geochronological record of the Sobo-Sise Yedoma IC spans the last approximately
52 cal kyr BP based on the stacked age–height modelling. Older parts of the
Yedoma IC are likely to be found up to several metres below the modern river
level (Fuchs et al., 2020), as has also been reported from other sites in
the eastern Lena delta (Pavlova and Dorozhkina, 2000) and from Bykovsky
Peninsula (Schirrmeister et al., 2002b). The lowermost sample of the
Sobo-Sise record had a finite age of 47 021 <inline-formula><mml:math id="M512" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 646 yr BP (SOB18-06-35) but
is beyond the limit of calibration. However, it supports the modelled age
range of the record down to 51.8 cal kyr BP. The entire record exhibits three
substantial chronological gaps, which are from about 36.7 to 28.4 cal kyr BP,
from about 20.4 to 16.8 cal kyr BP, and from about 15.5 to 6.4 cal kyr BP (Fig. 12).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F12" specific-use="star"><?xmltex \currentcnt{12}?><label>Figure 12</label><caption><p id="d1e8806">Comparison of interpreted chronology gaps (shown as shaded
rectangles) in the Yedoma IC records from Bykovsky Peninsula (Mamontovy
Khayata; Schirrmeister et al., 2002a, 2011a), Sobo-Sise Island (this study),
and Kurungnakh-Sise Island (Schirrmeister et al., 2003; <?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al.,
2008a). Infinite radiocarbon dates or dates to be calibrated beyond the
limit of 50 cal kyr BP (Reimer et al., 2013) are minimum ages and given as
hollow symbols. Age evidence from optically stimulated luminescence (OSL) and Be-10 dating for repeated
megafloods (namely numbers II and III) from the glacial Lake Vitim along the
Lena valley into the Arctic Ocean (Margold et al., 2018) is shown for
comparison.</p></caption>
          <?xmltex \igopts{width=412.564961pt}?><graphic xlink:href="https://tc.copernicus.org/articles/14/4525/2020/tc-14-4525-2020-f12.png"/>

        </fig>

      <p id="d1e8819">Taking into account that the exposure conditions and the applied sampling
and dating resolution largely define the quality of the resulting
geochronological record, we compare our Yedoma IC dataset from Sobo-Sise
Island (32 <inline-formula><mml:math id="M513" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">14</mml:mn></mml:msup></mml:math></inline-formula>C dates over 24 m profile length) to similar ones with a
resolution much better than 1 m in the vertical dimension, i.e. those from
the Mamontovy Khayata site on Bykovsky Peninsula (51 <inline-formula><mml:math id="M514" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">14</mml:mn></mml:msup></mml:math></inline-formula>C dates over 37 m profile length; Schirrmeister et al., 2002a; Grosse et al., 2007) and
Kurungnakh-Sise Island in the central Lena delta (19 <inline-formula><mml:math id="M515" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">14</mml:mn></mml:msup></mml:math></inline-formula>C dates over 19 m profile length; Schirrmeister et al., 2003; <?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2008a).
However, the sampling approaches differed. On Bykovsky and Kurungnakh-Sise
the exposures were sampled during different years at highly dynamic thaw
slumps over a rather large lateral extent, i.e. up to several hundreds of
metres. Exposed baidzherakhs (thaw mounts of former polygon centres) at
different height levels were sampled. In contrast, the permafrost sampling
at the vertical Yedoma cliff on Sobo-Sise was performed in three nearby
(i.e. within about 120 m) overlapping profiles, resulting in complete
coverage of the exposed permafrost sequence.</p>
      <p id="d1e8854">If compared to nearby studied Yedoma profiles to the east, on Bykovsky
Peninsula in the central Laptev Sea, and to the west, on Kurungnakh-Sise
Island in the central Lena delta, a similar pattern is striking. In detail,
the Bykovsky record spans from about 60 ka BP and shows the smallest gaps of
all considered records from 38 to 32.5 cal kyr BP, from 21 to 18 cal kyr BP,
and from 12.5 to 9 cal kyr BP (Fig. 12). The Kurungnakh-Sise record shows two
large age gaps from 37 to 21 cal kyr BP and from 20 to 9 cal kyr BP (Fig. 12),
found in two independent sampling campaigns (Schirrmeister et al., 2003;
<?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2008a).</p>
      <p id="d1e8861">The hiatus overlap recognized at all three Yedoma sites studied in the
region, i.e Bykovsky, Sobo-Sise, and Kurungnakh-Sise (Fig. 1), results in
three gaps of likely overarching relevance that are found during MIS 3 from
36 to 32.5 cal kyr BP, during MIS 2 from 20.5 to 18 cal kyr BP, and during MIS
2–1 transition from 12.5 to 9 cal kyr BP (Fig. 12).</p>
      <p id="d1e8864">To explain the observed gaps in the chronological records, two mechanisms
that need to be discussed are (1) no or extremely low deposition during a
certain period of time, and/or (2) thaw and erosion of a certain sequence
after deposition. Both mechanisms might be related to a variety of processes,
spanning from global or regional climate variations over time to local
geomorphologic-disturbance processes that are not necessarily or solely
climate-triggered. To disentangle the general hiatus of three time periods
at three Yedoma IC sites in the Lena-Laptev region, the following discussion
lines can be drawn.</p>
<sec id="Ch1.S5.SS3.SSS1">
  <label>5.3.1</label><title>Interstadial climate variability and consecutive local disturbance vs.
fluvial erosion during MIS 3</title>
      <p id="d1e8874">The proposed regional overlap hiatus in MIS 3 Yedoma IC deposits spans 3500
years (36–32.5 cal kyr BP; Fig. 12). The interstadial climatic variability
during MIS 3 deduced from permafrost sequences of NE Siberia was subject to
previous studies which assume an MIS 3 climatic optimum expressed by warm
summer conditions mainly based on botanic proxy data (e.g. Anderson and
Lozhkin, 2001; Andreev et al., 2011; Murton et al., 2015, 2017; Pitulko et
al., 2017). The proxy record, however, varies in both duration and timing at
different Yedoma IC study sites from the western Laptev coast to the Kolyma
lowland (see Fig. 11 in <?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2014). If warmer summer climate
conditions during the MIS 3 interstadial led to partial Yedoma IC thaw and to
the observed overall depositional gap 36–32.5 cal kyr BP by deepening of
the active layer and related surface subsidence, resulting in degradation
rates exceeding aggradation rates, the timing of the MIS 3 climatic optimum
is of specific interest. The nearby Yedoma IC site on Bykovsky Peninsula
allows for proxy-based reconstruction of MIS 3 interstadial environmental
conditions. Here, warm conditions with mean summer temperatures <inline-formula><mml:math id="M516" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 12 <inline-formula><mml:math id="M517" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C and the occurrence of standing water are deduced for around
40–39 cal kyr BP from fossil findings of e.g. <italic>Callitriche hermaphroditica</italic>, which is a temperate aquatic
plant (Kienast et al., 2005), supported by findings of diverse ostracod
faunae that inhabited low centre polygon ponds during the same time period
(<?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2005). However, all evidence from Bykovsky records for
the MIS 3 climate optimum predates the observed hiatus by about 7000 to 6000 years, which makes it unlikely that the observed MIS 3 gap was driven by
regional climate. The MIS 3 hiatus in the Kurungnakh-Sise Yedoma IC spans
even more, from about 37 to 21 cal kyr BP, missing substantial parts of the
MIS 3 (Schirrmeister et al., 2003; <?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2008a), but again only
after the supposed MIS 3 climatic optimum that is likewise reflected in the Bykovsky
Yedoma palaeontological record by warm summer conditions and the
presence of low-ca<?pagebreak page4544?>ntered polygon tundra, providing a broad landscape mosaic
of ecological niches for e.g. insects and plants, indicating dry and warm
conditions in drained positions and for aquatic organisms inhabiting polygon
ponds (Khazin et al., 2019; <?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2008a). The observed MIS 3
hiatus in the Bykovsky, Sobo-Sise, and Kurungnakh Yedoma IC records is not
during the MIS 3 climatic optimum but instead falls within a period of late-MIS
3 climate instability as expressed in Dansgaard–Oeschger (D–O) events
recorded in the Greenland ice cores (e.g. Dansgaard et al., 1993; NGRIP
members, 2004). But it is unknown whether D–O events have impacted the eastern
Siberian Arctic, and the lack of deposits and coarse chronology in the Yedoma
IC records prevents conclusions on a linkage to these palaeoclimatic
events to be drawn.</p>
      <p id="d1e8912">Another possible explanation for the MIS 3 hiatus is proposed by Margold et
al. (2018), who found evidence for repeated cataclysmic outburst floods from
the glacial Lake Vitim in southern Siberia into the Vitim river valley and
further into the Lena river valley towards the Arctic Ocean. The flooding
events were dated by multiple techniques including optically stimulated
luminescence dating and cosmogenic nuclide dating (Be-10 bedrock exposures
and Be-10 depth profiles). The reconstructed flood chronology spans over the
last 60 kyr, of which the timing of megaflood II at around 34 ka fits into the
chronologic gap observed in the Yedoma IC chronology of Bykovsky, Sobo-Sise,
and Kurungnakh around 36–32.5 cal kyr BP (Fig. 12). Thus, fluvial impact by
the proposed megaflood event might have affected the continuity of the
Yedoma IC chronologies by eroding considerable parts of the sequences. But
except for the chronology gaps, no direct erosional features such as fluvial
sand or pebble layers have been observed in the outcrops. Thus, direct
erosion seems unlikely at the studied locations, and the flooding events here may have only changed the hydrological regime (e.g. by developing new
discharge paths similar to the channels in today's Lena delta) for a
certain time period and by doing so prevented the deposition of fluvially
transported material in the areas of the studied Yedoma IC outcrops. If so,
this could have stopped or minimized Yedoma IC accumulation at the study
sites.</p>
</sec>
<sec id="Ch1.S5.SS3.SSS2">
  <label>5.3.2</label><title>LGM climate vs. fluvial erosion during MIS 2</title>
      <p id="d1e8923">The second distinct overlapping hiatus in the Yedoma IC chronologies of
Bykovsky Peninsula, Sobo-Sise, and Kurungnakh-Sise islands occurred during
MIS 2 20.5–18 cal kyr BP (Fig. 12) and falls partly in the last-glacial-maximum (LGM) period around 26.5–19 cal kyr BP (Clark et al., 2009). The LGM
environments of the Laptev Sea coastal region are characterized by cold and
dry summer conditions and represented in pollen records by grass-dominated
communities with Caryophyllaceae, Asteraceae, Cichoriaceae,<?pagebreak page4545?> and <italic>Selaginella rupestris</italic> (Andreev et
al., 2011). Further palaeontological evidence for cold and dry summers is
provided by plant macrofossils and insect fossil records from the Bykovsky
Yedoma IC (Kienast et al., 2005; Sher et al., 2005), while the LGM is almost
not captured in the Kurungnakh-Sise Yedoma IC record (Schirrmeister et al.,
2003; <?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2008a). The less productive summer conditions most
likely hampered OM accumulation, while reduced ice wedge growth might be
related to less winter precipitation and stronger wind activity affecting
snow drift and sublimation, both leading to reduced Yedoma IC formation
during MIS 2 if compared to MIS 3 as also seen in the lower permafrost
aggradation rate (see Sect. 5.1.2). However, no permafrost aggradation
during MIS 2 at all seems unlikely in the larger study region since it has a
good depositional representation at several Yedoma IC sites (Duvanny Yar: Murton et al., 2015; Yana lowland: Pitulko et al., 2004, 2017; Bol'shoy
Lyakhovsky: <?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2011; Mamontov Klyk: Schirrmeister et al.,
2008; Fig. 1). On Bol'shoy Lyakhovsky Island (north-east of the central
Laptev Sea region), a shift from accumulation on top of the MIS 3 Yedoma IC
to valley positions was found and explained by a lowered erosion base due to
LGM sea level lowstand and associated changes in the hydrological system of
areas with higher relief inclination (<?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2011). As seen in
Fig. 12, the MIS 2 chronologic time gap is larger in the central Lena delta
(about 11 kyr between about 20 and 9 cal kyr BP on Kurungnakh-Sise) if
compared to the eastern Lena delta (about 3 kyr between about 20 and 17 cal kyr BP on Sobo-Sise) and to Bykovsky Peninsula (about 3 kyr between about 21
and 18 cal kyr BP at Mamontovy Khayata; site no. 1 in Fig. 1). Additionally,
Grosse et al. (2007) reported an observation at the northern end of Bykovsky
Peninsula, where the 22 m thick MIS 3–2 Yedoma IC (dated from about 53  to
23 cal kyr BP) is discordantly covered by 3 m thick sand with organic
interlayers of probably shallow fluvial origin dated to about 16 cal kyr BP
(site B-S in Grosse et al., 2007; site no. 2 in Fig. 1). For the large gap
in the Kurungnakh-Sise MIS 2 Yedoma IC record, it might also be possible that
the MIS 2 gap likely induced by fluvial erosion of megaflood III (Margold et
al., 2018) further combines with the deglacial (MIS 2–1) gap, and any
possible deposition in between was eroded by the latter.</p>
</sec>
<sec id="Ch1.S5.SS3.SSS3">
  <label>5.3.3</label><title>Deglacial thermokarst during MIS 2–1</title>
      <p id="d1e8949">The global late-glacial to early-Holocene warming manifested the transition
from glacial to interglacial conditions. The effect of warming on permafrost
conditions is largely captured by an increase in ground temperature, a
deepening of the seasonally thawed active layer, surface subsidence, and
activation of thermokarst and thermo-erosional processes (e.g. <?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et
al., 2009). The resulting ground ice melt and permafrost thaw led to
reorganization of the post-Beringian periglacial landscapes and
accumulation areas remaining after the opening of the Bering Strait around
11 cal kyr BP (Jakobsson et al., 2017) and the subsequent Holocene sea level
rise and shelf inundation (Bauch et al., 2001; Klemann et al., 2015). The
large-scale warming pulse terminated the accumulation of the Yedoma IC
during the late-glacial period, as seen in the age gaps of the Yedoma IC
records considered here (Fig. 12), leading to an overlap hiatus 12.5–9 cal
ka BP. Similar late-glacial Holocene hiatuses are found for many other
chronostratigraphic records of Yedoma ICs (Fig. 1) such as in the Kolyma
lowland at the Duvanny Yar site (Murton et al., 2015), on the New Siberian
Islands (Schirrmeister et al., 2011a; <?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al., 2009, 2014), on Buor
Khaya Peninsula (Schirrmeister et al., 2017), and on Mamontov Klyk
(Schirrmeister et al., 2008). During the late-glacial to early-Holocene
warming, intense thermokarst within the degrading Yedoma IC created new
accumulation areas, i.e. thermokarst basins and thermo-erosional valleys,
which dominate the modern surface morphology in Arctic lowlands by more than
50 % of the modern surface on Bykovsky Peninsula (Grosse et al., 2005;
Fuchs et al., 2018) and on the Sobo-Sise (Fuchs et al., 2018) and Kurungnakh-Sise islands (Morgenstern et al., 2011).</p>
      <p id="d1e8960">Dated records of thermokarst deposition commonly fit into the hiatus that
represents the end of Yedoma IC formation. Late-glacial to early-Holocene
thermokarst deposits on Bykovsky Peninsula are dated from about 10 to 1 cal kyr BP (Schirrmeister et al., 2002a), on Kurungnakh-Sise Island from about 15 cal kyr BP to modern times (Morgenstern et al., 2013), and on Sobo-Sise Island from
about 7.4 cal kyr BP to modern times (Fuchs et al., 2018). Thermo-erosional valleys
as erosional features of Yedoma IC degradation were dated on Bykovsky from 5
to 1 cal kyr BP (Schirrmeister et al., 2002a). However, Holocene cover
deposits on top of the Yedoma IC are common and also observed on Sobo-Sise, where
they were dated from 9.8 to 1.3 cal kyr BP (Fuchs et al., 2018) and from 6.4
to 2.4 cal kyr BP (Unit C in this study). In summary, overall climate warming
at the transition from glacial to interglacial conditions promoted extensive
Yedoma IC thaw and created new accumulation areas in thermokarst basins and
thermo-erosional valleys. Both the IC degradation and the change in
deposition processes caused the hiatus on top of the Yedoma IC of the Laptev
Sea coastal region.</p>
</sec>
</sec>
</sec>
<sec id="Ch1.S6" sec-type="conclusions">
  <label>6</label><title>Conclusions</title>
      <p id="d1e8973">Late-Pleistocene permafrost of the Yedoma Ice Complex type is widespread in
the eastern Siberian Arctic, but sediment sequences are often discontinuous due
to (1) the vulnerability of ice-rich permafrost to thaw under warming
conditions, (2) surface erosion in times of arid and windswept conditions,
and (3) periglacial processes such as cryoturbation and internal
reorganization of polygonal landscapes. We identified three different
cryostratigraphic units at the<?pagebreak page4546?> Sobo-Sise Yedoma IC. Unit A (52–28 cal kyr BP) represents the depositional environment during interstadial MIS 3 and is
characterized by coarse silt and fine sand, while Unit B (28–15 cal kyr BP),
representing the stadial MIS 2 conditions, is dominated by coarse silt and
middle sand and lower organic-matter (carbon, nitrogen) content compared to
Unit A. In addition, Unit A has higher permafrost aggradation rates (1 m kyr<inline-formula><mml:math id="M518" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) compared to Unit B (0.7 m kyr<inline-formula><mml:math id="M519" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>). The sedimentary properties
of both units support the hypothesis of multi-process and multi-source
regional Yedoma IC formation, here mainly triggered by ice wedge polygon
formation under floodplain conditions with varying input shares of
cryogenic, fluvial, pedogenic, and aeolian origin. The Yedoma IC is
discordantly overlain by organic-rich Holocene deposits of Unit C (7–0 cal kyr BP).</p>
      <p id="d1e9000">The wedge ice records cover all three cryostratigraphic units as shown by
radiocarbon-dated organic matter from inside the ice. The stable-isotope
composition of the Sobo-Sise wedge ice in comparison to other regional
records shows similar patterns, with, for example, no indication of an LGM cold period
in MIS 2 wedge ice. Thus, MIS 3 and MIS 2 ice wedges have rather similar
isotopic compositions, as also observed on Bykovsky Peninsula. A further
regional peculiarity is low-<inline-formula><mml:math id="M520" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and high-deuterium excess in
Holocene records that might represent a contribution of a regional
isotopically depleted water source, e.g. Lena water.</p>
      <p id="d1e9014">The chronostratigraphy of the Sobo-Sise cliff revealed three hiatuses, at about
36–29, 20–17, and 15–7 cal kyr BP, which are in
accordance with hiatuses, from two other Yedoma IC deposits in close vicinity
on Bykovsky Peninsula and Kurungnakh-Sise Island. Similar patterns but
different duration found at these locations indicate a regional signal of
disturbance, leading to either low accumulation or erosion of deposited
material. We hypothesize that the first two regional hiatus overlaps
(36–32.5 and 20.5–18 cal kyr BP) are related to megafloods
proposed by Margold et al. (2018), although more evidence is needed to
confirm this hypothesis. The last overlap hiatus in the regional
chronostratigraphy (12.5–9 cal kyr BP) is caused by climate-driven
permafrost thaw and consecutive change in accumulation areas during the
late-glacial-to-Holocene transition, as was observed in many other Yedoma
IC deposits in north-eastern Siberia. Thus, the Sobo-Sise Yedoma record
represents a rather typical example of late-Pleistocene ice complex
formation under western Beringian conditions, superimposed in its preservation
by thaw events that were fluvially triggered during MIS 3–2 and
climate-triggered during MIS 2–1.</p>
</sec>

      
      </body>
    <back><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d1e9021">Original data will be available at PANGAEA after final acceptance of the
paper: <ext-link xlink:href="https://doi.org/10.1594/PANGAEA.919470" ext-link-type="DOI">10.1594/PANGAEA.919470</ext-link> (<?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> et al.,
2020).</p>
  </notes><app-group>
        <supplementary-material position="anchor"><p id="d1e9031">The supplement related to this article is available online at: <inline-supplementary-material xlink:href="https://doi.org/10.5194/tc-14-4525-2020-supplement" xlink:title="pdf">https://doi.org/10.5194/tc-14-4525-2020-supplement</inline-supplementary-material>.</p></supplementary-material>
        </app-group><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e9040">SW conceptualized the research. SW, MiF, TO, and LS designed the fieldwork,
which was performed with the help of AK and AA. AK performed the climbing and
sediment sampling of the Yedoma cliff, while SW, MiF, TO, and LS performed
the wedge ice sampling. Laboratory work and data analyses were carried out
by SW, MiF, TO, HaM, LS, GM, JW, MaF, and HeM. SW wrote the
paper with input from all co-authors.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e9046">The authors declare that they have no conflict of interest.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e9052">The fieldwork of this study received great logistic support in summer 2018
from the Tiksi hydrobase (Dmitry Mel'nichenko) and AWI logistics (2018 LENA expedition; Volkmar Assmann and Waldemar Schneider). The laboratory analyses
were expertly conducted by Antje Eulenburg, Mikaela Weiner, Lutz
Schönicke, and Dyke Scheidemann (AWI Potsdam) as well as by Elizabeth
Bonk and Torben Gentz (MICADAS, AWI Bremerhaven). Ingmar Nitze (AWI Potsdam)
helped retrieve the cliff edge line for Fig. 2, and Janet Rethemeyer
(CologneAMS) provided three radiocarbon dates.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d1e9057">This research has been supported by the Deutsche Forschungsgemeinschaft (DFG
grant no. WE4390/7-1 to Sebastian <?xmltex \hack{\mbox\bgroup}?>Wetterich<?xmltex \hack{\egroup}?> and grant no. OP217/4-1 to Thomas Opel), the Horizon 2020 EU
framework programme for research and innovation (grant
agreement no. 773421, NUNATARYUK project, to Michael Fritz), the NERC-BMBF
project CACOON (grant no. 03F0806A to Matthias Fuchs), the Russian Foundation for Basis Research (RFBR grant no. 8-05-60080 to Alexander Kizyakov), and the Moscow State University (MSU) research programme (grant no. AAAA-A16-116032810095-6 to Alexander Kizyakov). <?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>The article processing charges for this open-access <?xmltex \hack{\newline}?> publication  were covered by a Research <?xmltex \hack{\newline}?> Centre of the Helmholtz Association.</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d1e9074">This paper was edited by Ylva Sjöberg and reviewed by Martin Margold and one anonymous referee.</p>
  </notes><ref-list>
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    <!--<article-title-html>The cryostratigraphy of the Yedoma cliff of Sobo-Sise Island (Lena delta) reveals permafrost dynamics in the central Laptev Sea coastal region during the last 52&thinsp;kyr</article-title-html>
<abstract-html><p>The present study examines the formation history and
cryolithological properties of the late-Pleistocene Yedoma Ice Complex (IC) and
its Holocene cover in the eastern Lena delta on Sobo-Sise Island. The
sedimentary sequence was continuously sampled at 0.5&thinsp;m resolution at a
vertical Yedoma cliff starting from 24.2&thinsp;m above river level (a.r.l.). The
sequence differentiates into three cryostratigraphic units: Unit A, dated
from ca. 52 to 28&thinsp;cal&thinsp;kyr&thinsp;BP; Unit B, dated from ca. 28 to 15&thinsp;cal&thinsp;kyr&thinsp;BP; Unit
C, dated from ca. 7 to 0&thinsp;cal&thinsp;kyr&thinsp;BP. Three chronologic gaps in the record are
striking. The hiatus during the interstadial marine isotope stage (MIS) 3 (36–29&thinsp;cal&thinsp;kyr&thinsp;BP) as
well as during stadial MIS 2 (20–17&thinsp;cal&thinsp;kyr&thinsp;BP) might be related to fluvial
erosion and/or changed discharge patterns of the Lena river caused by
repeated outburst floods from the glacial Lake Vitim in southern Siberia
along the Lena river valley towards the Arctic Ocean. The hiatus during the
MIS 2–1 transition (15–7&thinsp;cal&thinsp;kyr&thinsp;BP) is a commonly observed feature in
permafrost chronologies due to intense thermokarst activity of the deglacial
period. The chronologic gaps of the Sobo-Sise Yedoma record are similarly
found at two neighbouring Yedoma IC sites on Bykovsky Peninsula and
Kurungnakh-Sise Island and are most likely of regional importance.</p><p>The three cryostratigraphic units of the Sobo-Sise Yedoma exhibit distinct
signatures in properties of their clastic, organic, and ice components.
Higher permafrost aggradation rates of 1&thinsp;m&thinsp;kyr<sup>−1</sup> with higher organic-matter (OM) stocks (29&thinsp;±&thinsp;15&thinsp;kg&thinsp;C&thinsp;m<sup>−3</sup>, 2.2&thinsp;±&thinsp;1.0&thinsp;kg&thinsp;N&thinsp;m<sup>−3</sup>; Unit A) and mainly coarse silt are found for the interstadial MIS
3 if compared to the stadial MIS 2 with 0.7&thinsp;m&thinsp;kyr<sup>−1</sup> permafrost
aggradation, lower OM stocks (14&thinsp;±&thinsp;8&thinsp;kg&thinsp;C&thinsp;m<sup>−3</sup>, 1.4&thinsp;±&thinsp;0.4&thinsp;kg&thinsp;N&thinsp;m<sup>−3</sup>; Unit B), and pronounced peaks in the coarse-silt and medium-sand
fractions. Geochemical signatures of intra-sedimental ice reflect the
differences in summer evaporation and moisture regime by higher ion content
and less depleted ratios of stable <i>δ</i><sup>18</sup>O  and stable <i>δ</i>D isotopes  but
lower deuterium excess (<i>d</i>) values during interstadial MIS 3 if compared to
stadial MIS 2. The <i>δ</i><sup>18</sup>O and <i>δ</i>D composition of MIS 3 and
MIS 2 ice wedges shows characteristic well-depleted values and low <i>d</i> values,
while MIS 1 ice wedges have elevated mean <i>d</i> values between
11&thinsp;‰ and 15&thinsp;‰ and surprisingly low
<i>δ</i><sup>18</sup>O and <i>δ</i>D values. Hence, the isotopic difference
between late-Pleistocene and Holocene ice wedges is more pronounced in <i>d</i> than
in <i>δ</i> values.</p><p>The present study of the permafrost exposed at the Sobo-Sise Yedoma cliff
provides a comprehensive cryostratigraphic inventory, insights into
permafrost aggradation, and degradation over the last approximately 52&thinsp;kyr as well as their climatic and morphodynamic controls on the regional scale
of the central Laptev Sea coastal region in NE Siberia.</p></abstract-html>
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