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  <front>
    <journal-meta>
<journal-id journal-id-type="publisher">TC</journal-id>
<journal-title-group>
<journal-title>The Cryosphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">TC</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">The Cryosphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1994-0424</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>

    <article-meta>
      <article-id pub-id-type="doi">10.5194/tc-10-2763-2016</article-id><title-group><article-title>Surface mass balance and water stable isotopes derived from firn cores on
three ice rises, Fimbul Ice Shelf, Antarctica</article-title>
      </title-group><?xmltex \runningtitle{Surface mass balance and water stable isotopes derived from firn cores}?><?xmltex \runningauthor{C.~P.~Vega}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1 aff2">
          <name><surname>Vega</surname><given-names>Carmen P.</given-names></name>
          <email>carmen.vega@geo.uu.se</email>
        <ext-link>https://orcid.org/0000-0002-2142-0368</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3 aff4">
          <name><surname>Schlosser</surname><given-names>Elisabeth</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Divine</surname><given-names>Dmitry V.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Kohler</surname><given-names>Jack</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5">
          <name><surname>Martma</surname><given-names>Tõnu</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-5894-7692</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff6">
          <name><surname>Eichler</surname><given-names>Anja</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-0206-7463</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff6">
          <name><surname>Schwikowski</surname><given-names>Margit</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-0856-5183</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Isaksson</surname><given-names>Elisabeth</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>Norwegian Polar Institute, 9296 Tromsø, Norway</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Department of Earth Sciences, Uppsala University, Villavägen 16, 752 36, Uppsala, Sweden</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Institute of Atmospheric and Cryospheric Sciences, University of Innsbruck, Innsbruck, Austria</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>Austrian Polar Research Institute, Vienna, Austria</institution>
        </aff>
        <aff id="aff5"><label>5</label><institution>Institute of Geology, Tallinn University of Technology, Tallinn, Estonia</institution>
        </aff>
        <aff id="aff6"><label>6</label><institution>Paul Scherrer Institute, 5232 Villigen PSI, Switzerland</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Carmen P. Vega (carmen.vega@geo.uu.se)</corresp></author-notes><pub-date><day>17</day><month>November</month><year>2016</year></pub-date>
      
      <volume>10</volume>
      <issue>6</issue>
      <fpage>2763</fpage><lpage>2777</lpage>
      <history>
        <date date-type="received"><day>1</day><month>July</month><year>2016</year></date>
           <date date-type="rev-request"><day>6</day><month>July</month><year>2016</year></date>
           <date date-type="rev-recd"><day>8</day><month>October</month><year>2016</year></date>
           <date date-type="accepted"><day>16</day><month>October</month><year>2016</year></date>
      </history>
      <permissions>
<license license-type="open-access">
<license-p>This work is licensed under a Creative Commons Attribution 3.0 Unported License. To view a copy of this license, visit <ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by/3.0/">http://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions><self-uri xlink:href="https://tc.copernicus.org/articles/10/2763/2016/tc-10-2763-2016.html">This article is available from https://tc.copernicus.org/articles/10/2763/2016/tc-10-2763-2016.html</self-uri>
<self-uri xlink:href="https://tc.copernicus.org/articles/10/2763/2016/tc-10-2763-2016.pdf">The full text article is available as a PDF file from https://tc.copernicus.org/articles/10/2763/2016/tc-10-2763-2016.pdf</self-uri>


      <abstract>
    <p>Three shallow firn cores were retrieved in the austral summers of 2011/12 and
2013/14 on the ice rises Kupol Ciolkovskogo (KC), Kupol Moskovskij (KM), and
Blåskimen Island (BI), all part of Fimbul Ice Shelf (FIS) in western
Dronning Maud Land (DML), Antarctica. The cores were dated back to 1958 (KC),
1995 (KM), and 1996 (BI) by annual layer counting using high-resolution
oxygen isotope (<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O) data, and by identifying volcanic horizons
using non-sea-salt sulfate (<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula>) data. The water stable
isotope records show that the atmospheric signature of the annual snow
accumulation cycle is well preserved in the firn column, especially at KM and
BI. We are able to determine the annual surface mass balance (SMB), as well
as the mean SMB values between identified volcanic horizons. Average SMB at
the KM and BI sites (0.68 and 0.70 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) was higher than
at the KC site (0.24 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>), and there was greater
temporal variability as well. Trends in the SMB and <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O records
from the KC core over the period of 1958–2012 agree well with other
previously investigated cores in the area, thus the KC site could be
considered the most representative of the climate of the region. Cores from
KM and BI appear to be more affected by local meteorological conditions and
surface topography. Our results suggest that the ice rises are suitable sites
for the retrieval of longer firn and ice cores, but that BI has the best
preserved seasonal cycles of the three records and is thus the most optimal
site for high-resolution studies of temporal variability of the climate
signal. Deuterium excess data suggest a possible effect of seasonal moisture
transport changes on the annual isotopic signal. In agreement with previous
studies, large-scale atmospheric circulation patterns most likely provide the
dominant influence on water stable isotope ratios preserved at the core
sites.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <title>Introduction</title>
      <p>The Antarctic ice sheet plays a major role in the global
climate system; nevertheless, despite much recent attention, there are still
many unresolved issues around both its mass balance and recent climate
history, particularly in East Antarctica (IPCC, 2013). Estimating mass
balance for the ice sheet from field data is made difficult by the logistical
challenges of collecting in situ data, as well as the enormous size of the
region. Interpretation of satellite data is complicated by the fact that most
of the region is close to balance: even when combining several different
methods, corrections for isostatic rebound and changes in firn density,
relatively poorly known quantities in East Antarctica, can alter the overall
mass-balance estimate from positive to negative (i.e. Shepherd et al., 2012;
Zwally et al., 2015), although the results presented in the latter study are
debated (Scambos and Shuman, 2016). Therefore, given the future projections
of greenhouse gas emissions and the associated temperature rise, the onset of
a possible significant contribution by Antarctica to sea level rise is
difficult to predict accurately (e.g. IPCC, 2013; DeConto and Pollard, 2016).</p>
      <p>While the interior of the continent contains most of the ice volume, the
coastal regions are the most vulnerable part of Antarctica with regard to
climate warming. In addition to increasing atmospheric temperatures, changes
in storm tracks, and the impact of warmer ocean currents penetrating further
south, will all impact the future behaviour of the coastal ice.</p>
      <p>The ice shelves surrounding Antarctica stabilise the grounded interior ice
(e.g. Vaughan and Doake, 1996). There has been significant thinning and even
disintegration of ice shelves over the last decades (e.g. Scambos et
al., 2004; Shepherd et al., 2010; Pritchard et al., 2012; Paolo et
al., 2015), leading to increased outflow of glaciers and ice streams that
feed the shelves. Warmer ocean water has been identified as important to the
ice shelf removal (e.g. Pritchard et al., 2012), highlighting the importance
of the ice–ocean interactions, particularly at the grounding zone.</p>
      <p>Ice rises and ice rumples are elevated small-scale topographic features on
ice shelves, areas of grounded ice surrounded by floating ice. They buttress
the ice shelves and represent an important part of the ice sheet complex
(Paterson, 1994; Matsuoka et al., 2015). Ice flow on ice rises is typically
independent of the surrounding ice shelf, with radial flow due to their
dome-like morphology. Furthermore, ice velocities are generally low on ice
rises; this fact, together with their relatively high surface mass balance
(SMB) due to their location at the coast, make ice rises potentially useful
sites for ice core studies. There are numerous ice rises along the rim of the
Antarctic continent and few of them have been studied for the purpose of ice
core drilling. For more details on ice rises we refer to a recent review
paper by Matsuoka et al. (2015).</p>
      <p>Antarctic ice and firn cores contain valuable information about the climate
and chemical composition of the atmosphere. Numerous ice and firn cores have
been drilled in Antarctica over the past decades. Ice core studies
typically focus either on long timescales, such as the EPICA, Vostok, Dome
Fuji, and WAIS Divide projects (e.g. Watanabe et al., 1999; EPICA community
members, 2006; Wolff et al., 2010; WAIS Divide Project Members, 2013), or on
spatial distribution of climate and glaciological parameters, e.g. within
projects such as ITASE (Mayewski et al., 2005). Most studies are on ice cores
drilled in the dry interior of Antarctica, where the SMB is low; there are
far fewer studies of ice core records from the coastal regions, which are
more sensitive to climatic changes than the interior of the continent. The
higher SMB of coastal sites allows high-resolution records to be obtained,
thus providing the possibility of comparing firn or ice core data to
instrumental records available since the middle of the 20th century (e.g.
Schlosser et al., 2014).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><caption><p>Satellite image of Fimbul Ice Shelf (FIS), East Antarctica
showing the KC, KM, and BI core sites (this study), S100 (Kaczmarska et
al., 2004), M2, G3, G4, and G5 core sites (Schlosser et al., 2014),
Jutulstraumen and Trolltunga. In addition, 50 m contours are shown at each
ice rise, as derived from GPS profiles (V. Goel, personal communication,
2016). Map image is from the MODIS Mosaic of Antarctica (MOA). Information
regarding additional sampling sites and traverses in FIS can be found in
Schlosser et al. (2014).</p></caption>
        <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://tc.copernicus.org/articles/10/2763/2016/tc-10-2763-2016-f01.png"/>

      </fig>

      <p>The primary overall goal of the project Ice Rises is to elucidate the
mass-balance history of three ice rises in a section of Dronning Maud Land
(DML) (Fig. 1) over the past several millennia. Understanding the past
changes in their SMB, specifically during past warm anomalies, will
eventually help to improve the understanding of the impact of the predicted
future atmospheric and oceanic warming on the mass balance of the Antarctic
ice sheet.</p>
      <p>During two Antarctic field seasons, in the austral summer of 2011/12 and
2013/14, a number of glaciological field data were collected at three ice
rises located in Fimbul Ice Shelf (FIS): Kupol Ciolkovskogo (KC), Kupol
Moskovskij (KM), and Blåskimen Island (BI) (Fig. 1). In this paper we
focus on the SMB and water isotope records obtained from these cores with
emphasis on differences between the sites to evaluate their
representativeness for the area. These data are important input to
mass-balance models and can be used to assess the suitability of these
coastal sites as possible drill locations for deeper ice core retrieval.</p>
</sec>
<sec id="Ch1.S2">
  <title>Field area</title>
      <p>Fimbul Ice Shelf (Fig. 1) is one of many ice shelves along the coast of DML.
It measures roughly 36 500 <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="normal">km</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> and is the largest ice shelf in the
Haakon VII Sea. FIS is fed by the fast-flowing ice stream Jutulstraumen,
which has an ice velocity of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">km</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> at the grounding
line, some 200 km inland from the shelf edge (Melvold and Rolstad, 2000;
Rolstad et al., 2000). Jutulstraumen is the largest outlet glacier in DML,
draining an area of 124 000 <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="normal">km</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>, and is, therefore, important to
the mass balance of the ice shelf. FIS is comprised of a fast-moving part
that extends from Jutulstraumen and protrudes into the sea, Trolltunga,
surrounded by the slower-moving ice shelf proper. Trolltunga extends north
across the narrow continental shelf separating the glaciated coast from the
warm water of the coastal oceanic current, making it potentially vulnerable
to basal melting (e.g. Hatterman et al., 2012).</p>
      <p>A number of ice rises varying in size from 15 to 1200 <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="normal">km</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> are found
in the ice shelf. The three ice rises investigated in this study are situated
approximately 200 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">km</mml:mi></mml:math></inline-formula> from each other (Fig. 1). All ice rises are
dome-shaped with elevations ranging from 260 to 400 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">a</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">s</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">l</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> Ice
radar studies at the core sites suggest ice depths from 350 to 460 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">m</mml:mi></mml:math></inline-formula>,
while ice velocities from GPS measurements show values in the order of
2 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> or less at the core sites (J. Brown, V. Goel, and
K. Matsuoka, personal communication, 2016). The northern edges of KM and BI
border the ocean, while KC is surrounded by the ice shelf (Fig. 1). During
three field seasons (2011/12, 2012/13, 2013/14), radar, ice velocity, and
stake data were collected, with the overall goal of studying the evolution of
ice rise mass balance over time. Preliminary data analysis suggests that ice
velocities across the ice rises are asymmetrical and that the SMB
distribution is variable over the three ice rises (Brown et al., 2014).</p>
      <p>The SMB of the ice rises is influenced by precipitation, wind erosion, and
redeposition and by sublimation from the surface and from drifting snow. FIS,
like most East Antarctic ice shelves, is under the climatic influence of the
circumpolar trough; precipitation comes mainly from frontal systems of
cyclones moving eastwards, north of the coast, resulting in easterly or
east-north-easterly surface winds (Schlosser et al., 2008). These events
occur frequently, throughout the year. Precipitation amounts during an event
depend on the temperature and humidity of the involved air masses, with
moisture transport from lower latitudes leading to higher precipitation
amounts than cyclogenesis in the polar ocean. However, the local
meteorological conditions at the ice rises differ from the rest of the ice
shelf: air temperatures are higher due to a weaker temperature inversion in
winter, and wind speeds are higher due to the fact that the ice rises
represent obstacles in the general atmospheric flow (Lenaerts et al., 2014).
Studies have shown that the relative height of the obstacle compared to its
horizontal dimensions, the wind speed, and the static stability of the
atmosphere, determine whether there is more precipitation on the windward or
lee side of the obstacle (Rotunno and Houze, 2007; Houze Jr., 2012). This
refers to precipitation alone: redistribution of snow by wind can strongly
influence the SMB of the ice rises; consequently, large differences in SMB
are expected to be found over relatively short distances close to the ridge
of the ice rise.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><caption><p>Core locations, sampling details, SMB rates derived from the KC, KM,
and BI <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O records as annual average values between summer maxima.
Median water stable isotope deltas (in ‰) quantified in each core are
also shown. Distances from the core locations to the ice shelf edge were
obtained using the GIS package <italic>Quantarctica</italic>
(<uri>www.quantarctica.org</uri>). Both annual layer counting and volcanic
horizons identified in the non-sea-sulphate (<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula>) were used
to obtain timescales for the cores. Significant values (at 95 %
confidence level) are shown in bold. (<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula>, <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula>) refers to
Schlosser et al. (2012, 2014), (<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula>) to Kaczmarska et al. (2004),
and (<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:math></inline-formula>) to Divine et al. (2009).</p></caption><oasis:table frame="topbot"><?xmltex \begin{scaleboxenv}{.9}[.9]?><oasis:tgroup cols="10">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="center"/>
     <oasis:colspec colnum="4" colname="col4" align="center"/>
     <oasis:colspec colnum="5" colname="col5" align="center"/>
     <oasis:colspec colnum="6" colname="col6" align="center"/>
     <oasis:colspec colnum="7" colname="col7" align="center"/>
     <oasis:colspec colnum="8" colname="col8" align="center"/>
     <oasis:colspec colnum="9" colname="col9" align="center"/>
     <oasis:colspec colnum="10" colname="col10" align="center"/>
     <oasis:thead>
       <oasis:row>

         <oasis:entry colname="col1">Site</oasis:entry>

         <oasis:entry colname="col2">Location</oasis:entry>

         <oasis:entry colname="col3">Elevation</oasis:entry>

         <oasis:entry colname="col4">Core length</oasis:entry>

         <oasis:entry colname="col5">Shortest</oasis:entry>

         <oasis:entry colname="col6">Time coverage</oasis:entry>

         <oasis:entry colname="col7">Average</oasis:entry>

         <oasis:entry colname="col8">Slope of</oasis:entry>

         <oasis:entry colname="col9">Median</oasis:entry>

         <oasis:entry colname="col10">Slope of</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4">(Ice depth)</oasis:entry>

         <oasis:entry colname="col5">distance</oasis:entry>

         <oasis:entry colname="col6">(dating error)</oasis:entry>

         <oasis:entry colname="col7">SMB rate</oasis:entry>

         <oasis:entry colname="col8">the linear</oasis:entry>

         <oasis:entry colname="col9"><inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col10">the linear</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4">Ice temp.</oasis:entry>

         <oasis:entry colname="col5">from the ice</oasis:entry>

         <oasis:entry colname="col6"/>

         <oasis:entry colname="col7">(min., max.)</oasis:entry>

         <oasis:entry colname="col8">regression</oasis:entry>

         <oasis:entry colname="col9"><inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mi mathvariant="normal">H</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col10">regression of</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry rowsep="1" colname="col3"/>

         <oasis:entry rowsep="1" colname="col4">10 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">m</mml:mi></mml:math></inline-formula></oasis:entry>

         <oasis:entry rowsep="1" colname="col5">shelf edge</oasis:entry>

         <oasis:entry rowsep="1" colname="col6"/>

         <oasis:entry rowsep="1" colname="col7"/>

         <oasis:entry rowsep="1" colname="col8">(<inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula>)</oasis:entry>

         <oasis:entry rowsep="1" colname="col9"><inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula></oasis:entry>

         <oasis:entry rowsep="1" colname="col10"><inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula>)</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3">m a.s.l.</oasis:entry>

         <oasis:entry colname="col4">m</oasis:entry>

         <oasis:entry colname="col5">km</oasis:entry>

         <oasis:entry colname="col6">years</oasis:entry>

         <oasis:entry colname="col7"><inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col8"><inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col9">‰</oasis:entry>

         <oasis:entry colname="col10"><inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">‰</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>

       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2">70<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>31<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> S,</oasis:entry>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4">20.0</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6">1958–2012</oasis:entry>

         <oasis:entry colname="col7">0.24</oasis:entry>

         <oasis:entry colname="col8"><inline-formula><mml:math display="inline"><mml:mo mathvariant="bold">-</mml:mo></mml:math></inline-formula><bold>0.002</bold></oasis:entry>

         <oasis:entry colname="col9"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>19.4</oasis:entry>

         <oasis:entry colname="col10"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.004</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">KC</oasis:entry>

         <oasis:entry colname="col2">2<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>57<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> E</oasis:entry>

         <oasis:entry colname="col3">264</oasis:entry>

         <oasis:entry colname="col4">(460)</oasis:entry>

         <oasis:entry colname="col5">42</oasis:entry>

         <oasis:entry colname="col6">(<inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>3)</oasis:entry>

         <oasis:entry colname="col7">(0.11, 0.45)</oasis:entry>

         <oasis:entry colname="col8">(<inline-formula><mml:math display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">7</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn>10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>

         <oasis:entry colname="col9"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>150.2</oasis:entry>

         <oasis:entry colname="col10">(<inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>0.01)</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>17.5</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"/>

         <oasis:entry colname="col9">4.8</oasis:entry>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2">70<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>8<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> S,</oasis:entry>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4">19.6</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6">1995–2014</oasis:entry>

         <oasis:entry colname="col7">0.68</oasis:entry>

         <oasis:entry colname="col8">0.004</oasis:entry>

         <oasis:entry colname="col9"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>17.5</oasis:entry>

         <oasis:entry colname="col10">0.03</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">KM</oasis:entry>

         <oasis:entry colname="col2">1<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>12<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> E</oasis:entry>

         <oasis:entry colname="col3">268</oasis:entry>

         <oasis:entry colname="col4">(410)</oasis:entry>

         <oasis:entry colname="col5">12</oasis:entry>

         <oasis:entry colname="col6">(<inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>1)</oasis:entry>

         <oasis:entry colname="col7">(0.39, 0.95)</oasis:entry>

         <oasis:entry colname="col8">(<inline-formula><mml:math display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">9</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn>10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>

         <oasis:entry colname="col9"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>133.6</oasis:entry>

         <oasis:entry colname="col10">(<inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>0.05)</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>15.9</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"/>

         <oasis:entry colname="col9">5.9</oasis:entry>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2">70<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>24<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> S,</oasis:entry>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4">19.5</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6">1996–2014</oasis:entry>

         <oasis:entry colname="col7">0.70</oasis:entry>

         <oasis:entry colname="col8">0.006</oasis:entry>

         <oasis:entry colname="col9"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>17.6</oasis:entry>

         <oasis:entry colname="col10">0.03</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">BI</oasis:entry>

         <oasis:entry colname="col2">3<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>2<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> W</oasis:entry>

         <oasis:entry colname="col3">394</oasis:entry>

         <oasis:entry colname="col4">(460)</oasis:entry>

         <oasis:entry colname="col5">10</oasis:entry>

         <oasis:entry colname="col6">(<inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>1)</oasis:entry>

         <oasis:entry colname="col7">(0.40, 1.21)</oasis:entry>

         <oasis:entry colname="col8">(<inline-formula><mml:math display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn>10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>

         <oasis:entry colname="col9"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>134.5</oasis:entry>

         <oasis:entry colname="col10">(<inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>0.05)</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>16.1</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"/>

         <oasis:entry colname="col9">6.3</oasis:entry>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2">70<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>19<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> S,</oasis:entry>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4">10.0</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.002</oasis:entry>

         <oasis:entry colname="col9"/>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">M2<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col2">0<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>7<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> W</oasis:entry>

         <oasis:entry colname="col3">73</oasis:entry>

         <oasis:entry colname="col4">(–)</oasis:entry>

         <oasis:entry colname="col5">64</oasis:entry>

         <oasis:entry colname="col6">1981–2009</oasis:entry>

         <oasis:entry colname="col7">0.32</oasis:entry>

         <oasis:entry colname="col8">(<inline-formula><mml:math display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">4</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn>10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>

         <oasis:entry colname="col9">–</oasis:entry>

         <oasis:entry colname="col10">–</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>18.9</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"/>

         <oasis:entry colname="col9"/>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2">69<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>49<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> S,</oasis:entry>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4">17.5</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.001</oasis:entry>

         <oasis:entry colname="col9"/>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">G3<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col2">0<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>37<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> W</oasis:entry>

         <oasis:entry colname="col3">57</oasis:entry>

         <oasis:entry colname="col4">(–)</oasis:entry>

         <oasis:entry colname="col5">27</oasis:entry>

         <oasis:entry colname="col6">1993–2009</oasis:entry>

         <oasis:entry colname="col7">0.30</oasis:entry>

         <oasis:entry colname="col8">(<inline-formula><mml:math display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">8</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn>10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>

         <oasis:entry colname="col9">–</oasis:entry>

         <oasis:entry colname="col10">–</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>16.3</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"/>

         <oasis:entry colname="col9"/>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2">70<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>54<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> S,</oasis:entry>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4">16.7</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"><inline-formula><mml:math display="inline"><mml:mo mathvariant="bold">-</mml:mo></mml:math></inline-formula><bold>0.008</bold></oasis:entry>

         <oasis:entry colname="col9"/>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">G4<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col2">0<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>24<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> W</oasis:entry>

         <oasis:entry colname="col3">60</oasis:entry>

         <oasis:entry colname="col4">(–)</oasis:entry>

         <oasis:entry colname="col5">117</oasis:entry>

         <oasis:entry colname="col6">1983–2009</oasis:entry>

         <oasis:entry colname="col7">0.33</oasis:entry>

         <oasis:entry colname="col8">(<inline-formula><mml:math display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">3</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn>10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>

         <oasis:entry colname="col9">–</oasis:entry>

         <oasis:entry colname="col10">–</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>18.6</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"/>

         <oasis:entry colname="col9"/>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2">70<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>33<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> S,</oasis:entry>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4">14.5</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.003</oasis:entry>

         <oasis:entry colname="col9"/>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">G5<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col2">0<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>2<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> W</oasis:entry>

         <oasis:entry colname="col3">82</oasis:entry>

         <oasis:entry colname="col4">(–)</oasis:entry>

         <oasis:entry colname="col5">83</oasis:entry>

         <oasis:entry colname="col6">1983–2009</oasis:entry>

         <oasis:entry colname="col7">0.30</oasis:entry>

         <oasis:entry colname="col8">(<inline-formula><mml:math display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">4</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn>10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>

         <oasis:entry colname="col9">–</oasis:entry>

         <oasis:entry colname="col10">–</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>19.2</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"/>

         <oasis:entry colname="col9"/>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row>

         <oasis:entry namest="col1" nameend="col5">Composite core<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mtext>a, b</mml:mtext></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry rowsep="1" colname="col6" morerows="1">1983–2009</oasis:entry>

         <oasis:entry colname="col7">0.38</oasis:entry>

         <oasis:entry colname="col8"><inline-formula><mml:math display="inline"><mml:mo mathvariant="bold">-</mml:mo></mml:math></inline-formula><bold>0.007</bold></oasis:entry>

         <oasis:entry rowsep="1" colname="col9" morerows="1">–</oasis:entry>

         <oasis:entry colname="col10"><bold>0.06</bold></oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry namest="col1" nameend="col5">(M2, G3, G4, G5) </oasis:entry>

         <oasis:entry colname="col7">(0.15, 0.57)</oasis:entry>

         <oasis:entry colname="col8">(<inline-formula><mml:math display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">2</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn>10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>

         <oasis:entry colname="col10">(<inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>0.02)</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2">70<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>14<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> S,</oasis:entry>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4">100</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"/>

         <oasis:entry colname="col9"/>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">S100<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mtext>c, d</mml:mtext></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col2">4<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>48<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> E</oasis:entry>

         <oasis:entry colname="col3">48</oasis:entry>

         <oasis:entry colname="col4">(–)</oasis:entry>

         <oasis:entry colname="col5">–</oasis:entry>

         <oasis:entry colname="col6">1737–1999</oasis:entry>

         <oasis:entry colname="col7">0.30</oasis:entry>

         <oasis:entry colname="col8"><inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col9"><inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col10"><inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>17.5</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"/>

         <oasis:entry colname="col9"/>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry namest="col1" nameend="col10" align="center">Overlapping period 1996–2012 </oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"/>

         <oasis:entry colname="col5"/>

         <oasis:entry rowsep="1" colname="col6" morerows="2">KC</oasis:entry>

         <oasis:entry colname="col7">0.21</oasis:entry>

         <oasis:entry colname="col8"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.007</oasis:entry>

         <oasis:entry colname="col9"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>19.1</oasis:entry>

         <oasis:entry colname="col10"><inline-formula><mml:math display="inline"><mml:mo mathvariant="bold">-</mml:mo></mml:math></inline-formula><bold>0.27</bold></oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"/>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col7">(0.11, 0.42)</oasis:entry>

         <oasis:entry colname="col8">(<inline-formula><mml:math display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">5</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn>10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>

         <oasis:entry colname="col9">–</oasis:entry>

         <oasis:entry colname="col10">(<inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>0.09)</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"/>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"/>

         <oasis:entry colname="col9">–</oasis:entry>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"/>

         <oasis:entry colname="col5"/>

         <oasis:entry rowsep="1" colname="col6" morerows="2">KM</oasis:entry>

         <oasis:entry colname="col7">0.70</oasis:entry>

         <oasis:entry colname="col8">0.01</oasis:entry>

         <oasis:entry colname="col9"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>17.4</oasis:entry>

         <oasis:entry colname="col10">0.01</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"/>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col7">(0.39, 0.95)</oasis:entry>

         <oasis:entry colname="col8">(<inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>0.01)</oasis:entry>

         <oasis:entry colname="col9">–</oasis:entry>

         <oasis:entry colname="col10">(<inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>0.04)</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"/>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"/>

         <oasis:entry colname="col9">–</oasis:entry>

         <oasis:entry colname="col10"/>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"/>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6" morerows="2">BI</oasis:entry>

         <oasis:entry colname="col7">0.71</oasis:entry>

         <oasis:entry colname="col8">0.01</oasis:entry>

         <oasis:entry colname="col9"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>17.2</oasis:entry>

         <oasis:entry colname="col10">0.03</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"/>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col7">(0.40, 1.21)</oasis:entry>

         <oasis:entry colname="col8">(<inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>0.01)</oasis:entry>

         <oasis:entry colname="col9">–</oasis:entry>

         <oasis:entry colname="col10">(<inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>0.05)</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3"/>

         <oasis:entry colname="col4"/>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col7"/>

         <oasis:entry colname="col8"/>

         <oasis:entry colname="col9">–</oasis:entry>

         <oasis:entry colname="col10"/>

       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup><?xmltex \end{scaleboxenv}?></oasis:table></table-wrap>

<sec id="Ch1.S2.SSx1" specific-use="unnumbered">
  <title>Previous work</title>
      <p>The first scientific work in the study area was conducted during the
British–Norwegian–Swedish Antarctic Expedition in 1949–1952, in which
detailed descriptions of both the geology and morphology of the Jutulstraumen
basin were made, including the ice sheet and ice shelf (Swithinbank, 1957).
Work in the area was continued during the International Geophysical Year
(IGY) 1956/57, at the Norway Station (later renamed SANAE), on the western
edge of the ice shelf between 1956 and 1960 (Lunde, 1961; Neethling, 1970).
In the last three decades Norwegian groups have worked on FIS and
Jutulstraumen under the auspices of the Norwegian Antarctic Research
Expedition (NARE), focusing on spatial and temporal variability of SMB using
shallow firn cores and Ground Penetrating Radar (GPR) (e.g. Melvold et
al., 1998; Melvold, 1999; Isaksson and Melvold, 2002; Sinisalo et al., 2013;
Schlosser et al., 2012, 2014).</p>
      <p>As part of the EPICA project, a 100 m-deep ice core (labelled S100) was
drilled on the eastern part of FIS during NARE 2000/01 (Fig. 1). This
core covers the period AD 1737–2000 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 3 years and shows higher SMB
values in the 19th century than in the 18th and 20th centuries, but otherwise
no significant trends (Kaczmarska et al., 2004). This core is the longest
available high-resolution climate record from this part of coastal DML.</p>
      <p>Rotschky et al. (2007) compiled a SMB map for western DML, including FIS,
but data were not available to resolve fine-scale variability in the area of
the ice rises. More recently, Sinisalo et al. (2013) and Lenaerts et
al. (2014) used field and model data to show that the ice rises have a
substantial role in shaping both local SMB and meteorological conditions.
Finally, Altnau et al. (2015) compile available oxygen stable isotopes and
SMB data for the last three decades; they find a negative SMB trend for the
coastal regions, but a positive trend on the polar plateau over the same time
period. They conclude that atmospheric dynamic effects are more important at
the coast than thermodynamics, the latter being the dominant factor on the
polar plateau, where changes in SMB and stable isotope ratios occur mostly in
parallel.</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <title>Methods</title>
<sec id="Ch1.S3.SS1">
  <title>Sampling</title>
      <p>Three shallow (ca. 20 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">m</mml:mi></mml:math></inline-formula>) firn cores were retrieved at FIS (Fig. 1,
Table 1) in January 2012 (KC) and January 2014 (KM and BI) during field
expeditions organised by the Norwegian Polar Institute (NPI). Table 1
presents the location of the drill sites, maximum elevation of the ice rises,
and recovered core lengths. Each core was drilled from the bottom of a 2 m
snow pit; the pit wall was sampled at 5 cm intervals for water stable
isotope analysis. Bulk core density was determined for each subcore piece
(average length <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 45 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">cm</mml:mi></mml:math></inline-formula>) and for each snow pit sample
(20 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">cm</mml:mi></mml:math></inline-formula>). Snow and firn samples were collected following clean
protocols (Twickler and Whitlow, 1997), shipped frozen to NPI, and later to
the Paul Scherrer Institute (PSI), Switzerland, for cutting and chemical
analysis. Sample length ranged from 4 to 8 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">cm</mml:mi></mml:math></inline-formula>, depending on the
sample depth and density. The presence and thickness of ice lenses were
recorded during cold room analysis of the KC core. Major ions (methane
sulfonic acid, MSA), <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">SO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>) were analysed at PSI.
Subsamples for water stable isotopes analysis were shipped to the Institute
of Geology at Tallinn University of Technology (TUT), Estonia.</p>
</sec>
<sec id="Ch1.S3.SS2">
  <title>Water stable isotopes and major ion analyses</title>
      <p>Water stable isotope ratios (<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn>18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn>16</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula> and
<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mi mathvariant="normal">H</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">1</mml:mn></mml:msup><mml:mi mathvariant="normal">H</mml:mi></mml:mrow></mml:math></inline-formula>) were measured at TUT using a Picarro L2120-i
water isotope analyser (cavity ring-down spectroscopy technology) with a
high-precision A0211 vaporiser. Measurements were calibrated against both the
Vienna Standard Mean Ocean Water (VSMOW) and the Vienna Standard Light
Antarctic Precipitation (VSLAP) standards. Reproducibility of <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O
and <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H measurements was <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>0.1 and <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>1 ‰ (for 4–6
replicate measurements), respectively. Measuring both oxygen and hydrogen
water stable isotopes in the ice rises cores yields deuterium excess (<inline-formula><mml:math display="inline"><mml:mrow><mml:mi>d</mml:mi><mml:mo>=</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mi mathvariant="normal">H</mml:mi></mml:mrow><mml:mo>-</mml:mo><mml:mrow class="chem"><mml:mn mathvariant="normal">8</mml:mn><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:mrow></mml:math></inline-formula>).</p>
      <p>Major ions (MSA, <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">SO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>, Table 2) were analysed at
PSI using a Metrohm ProfIC 850 ion chromatography system combined with an 872
Extension Module and autosampler. The precision of the method was around
5 % for all ions (Wendl et al., 2015). In this study we use records of
major ions <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> and MSA to corroborate the dating of the three cores
(see Sect. 4.1), performed by identifying seasonal cycles in the oxygen
isotope record; a detailed palaeoenvironmental analysis at the ice rise sites
using the ion data is the subject of a separate paper in progress.</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <title>Results</title>
<sec id="Ch1.S4.SS1">
  <title>Dating of the firn cores</title>
      <p>Due to higher accumulation rates, the <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O seasonal variability in
the KM and BI cores is better defined than at the more inland KC site
(Fig. 2), and dating uncertainty for the KM and BI cores is, therefore,
lower. Dating of the firn cores is performed by annual layer counting, using
the seasonality of the water stable isotope signal. Since the KM and BI cores
were drilled from the bottom of a snow pit (0.9 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula>), the snow
pit data are used to reconstruct the period between winter 2012 and summer
2014. Winter minima and summer maxima in the <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O record are
identified to obtain a timescale with subannual resolution. Assuming a
uniform distribution of precipitation throughout the year, an equidistant
timescale is adapted between the summer maxima (January) and the winter
minima (July). Well-pronounced seasonal cycles of major ion concentrations
(e.g. MSA and <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>, Fig. 3) are used to corroborate the dating. Based
on annual layer counting, the KM and BI cores cover the periods from winter
1995 to summer 2014 and winter 1996 to summer 2014, respectively. The error
in the dating is estimated as <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>1 year for both of these cores.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T2"><caption><p>Median ion concentrations (in <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">mol</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) in the KC,
KM, and BI firn cores. Ion concentrations at the top 2 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">m</mml:mi></mml:math></inline-formula> of the KC,
KM,
and BI cores were not measured. Non-detected concentrations were set to half
the detection limit for each ion.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="5">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="center"/>
     <oasis:colspec colnum="3" colname="col3" align="center"/>
     <oasis:colspec colnum="4" colname="col4" align="center"/>
     <oasis:colspec colnum="5" colname="col5" align="center"/>
     <oasis:thead>
       <oasis:row>

         <oasis:entry rowsep="1" colname="col1" morerows="1">Median</oasis:entry>

         <oasis:entry colname="col2">Period</oasis:entry>

         <oasis:entry rowsep="1" colname="col3">MSA</oasis:entry>

         <oasis:entry rowsep="1" colname="col4"><inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">SO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry rowsep="1" colname="col5"><inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col2">(year)</oasis:entry>

         <oasis:entry namest="col3" nameend="col5">(<inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">mol</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) </oasis:entry>

       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>

         <oasis:entry colname="col1">KC</oasis:entry>

         <oasis:entry colname="col2">1958–2007</oasis:entry>

         <oasis:entry colname="col3">0.2</oasis:entry>

         <oasis:entry colname="col4">1.8</oasis:entry>

         <oasis:entry colname="col5">9.4</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">KM</oasis:entry>

         <oasis:entry colname="col2">1995–2014</oasis:entry>

         <oasis:entry colname="col3">0.3</oasis:entry>

         <oasis:entry colname="col4">4.5</oasis:entry>

         <oasis:entry colname="col5">57.7</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">BI</oasis:entry>

         <oasis:entry colname="col2">1996–2014</oasis:entry>

         <oasis:entry colname="col3">0.4</oasis:entry>

         <oasis:entry colname="col4">1.9</oasis:entry>

         <oasis:entry colname="col5">19.0</oasis:entry>

       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2"><caption><p><inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O–depth profiles of <bold>(a)</bold> KC, <bold>(b)</bold> KM,
and <bold>(c)</bold> BI. The blue lines indicate the <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values for
the 2 m snow pits at each core site. Seasonal variations are used to date the
KM and BI cores; horizontal lines mark the summer maxima inferred in the KC
core and identified in the KM and BI cores.</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://tc.copernicus.org/articles/10/2763/2016/tc-10-2763-2016-f02.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><caption><p>Seasonality of <bold>(a)</bold> MSA, <bold>(b)</bold> Na<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>+</mml:mo></mml:msup></mml:math></inline-formula>, and
<bold>(c)</bold> <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O for the KM and BI cores. Dashed lines and dotted
lines indicate winter (summer) minima (maxima). An MSA outlier observed in
year 2002 in the KM core was removed from the series since it was 30 times
higher than the median MSA values.</p></caption>
          <?xmltex \igopts{width=355.659449pt}?><graphic xlink:href="https://tc.copernicus.org/articles/10/2763/2016/tc-10-2763-2016-f03.png"/>

        </fig>

      <p>Counting <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O winter minima in the KC core is not as
straightforward as for the KM and BI cores, due to the lower accumulation and
the lower amplitude of the seasonal signal (Fig. 2a). Using <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O
snow pit data available for the surface layers at KC (Fig. 2a), a SMB of
0.19 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> is estimated for the period 2007–2011.
Accordingly, when interpreting the seasonal variability of the <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O stratigraphy, this mean SMB 2007–2011 value was considered a
guideline. Counting the <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O winter minima in the deeper section of
the core suggested 1958 as the date for the bottom of the core
(12.93 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula>). Using the identified winter minima, we can identify
tentative depths for summer maxima (Fig. 2a). Most of the horizontal dashed
lines in Fig. 2a coincide with maxima in the <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, indicating a
good estimate of the annual cycle using winter minima and SMB 2007–2011 as a
reference.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T3" specific-use="star"><caption><p>Volcanic eruptions inferred from the KC <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula>
concentrations. Only volcanoes with a volcanic explosivity index <inline-formula><mml:math display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 3
were considered. The SMB rate was obtained using the timescale obtained by
<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O cycles counting. Ref.: <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">1</mml:mn></mml:msup></mml:math></inline-formula> Karlöf et al. (2000),
<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> Palmer et al. (2001), <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> Nishio et al. (2002), <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msup></mml:math></inline-formula> Stenni et
al. (2002), <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">5</mml:mn></mml:msup></mml:math></inline-formula> Zhang et al. (2002), <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">6</mml:mn></mml:msup></mml:math></inline-formula> Cole-Dai et al. (1997),
<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">7</mml:mn></mml:msup></mml:math></inline-formula> Dibb and Whitlow (1996), <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">8</mml:mn></mml:msup></mml:math></inline-formula> Kohno and Fujii (2002), <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">9</mml:mn></mml:msup></mml:math></inline-formula> Global
Volcanism Program, 2016, <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn>10</mml:mn></mml:msup></mml:math></inline-formula> Legrand and Delmas (1987), <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn>11</mml:mn></mml:msup></mml:math></inline-formula> Vega
(2008), <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn>12</mml:mn></mml:msup></mml:math></inline-formula> Kaczmarska et al. (2004).</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="6">
     <oasis:colspec colnum="1" colname="col1" align="center"/>
     <oasis:colspec colnum="2" colname="col2" align="center"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:colspec colnum="4" colname="col4" align="left"/>
     <oasis:colspec colnum="5" colname="col5" align="left"/>
     <oasis:colspec colnum="6" colname="col6" align="left"/>
     <oasis:thead>
       <oasis:row>

         <oasis:entry colname="col1">Peak no.</oasis:entry>

         <oasis:entry colname="col2">Bottom</oasis:entry>

         <oasis:entry colname="col3">Year in the</oasis:entry>

         <oasis:entry colname="col4">Assigned volcano</oasis:entry>

         <oasis:entry colname="col5">SMB rate</oasis:entry>

         <oasis:entry colname="col6">Ref.</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2">depth</oasis:entry>

         <oasis:entry colname="col3">cycle-counting</oasis:entry>

         <oasis:entry colname="col4">(year of eruption)</oasis:entry>

         <oasis:entry colname="col5"><inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col6"/>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2">m w.e.</oasis:entry>

         <oasis:entry colname="col3">timescale</oasis:entry>

         <oasis:entry colname="col4"/>

         <oasis:entry colname="col5">(period)</oasis:entry>

         <oasis:entry colname="col6"/>

       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1">1a</oasis:entry>

         <oasis:entry colname="col2">3.80</oasis:entry>

         <oasis:entry colname="col3">1993.9</oasis:entry>

         <oasis:entry colname="col4">Pinatubo, Philippines (1991)</oasis:entry>

         <oasis:entry colname="col5">0.21 (1991–2011)</oasis:entry>

         <oasis:entry colname="col6">1, 2, 3, 4, 5, 6, 7</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry rowsep="1" colname="col1" morerows="1">1</oasis:entry>

         <oasis:entry rowsep="1" colname="col2" morerows="1">4.00</oasis:entry>

         <oasis:entry rowsep="1" colname="col3" morerows="1">1992.8</oasis:entry>

         <oasis:entry colname="col4">Cerro Hudson, Chile (1991)</oasis:entry>

         <oasis:entry rowsep="1" colname="col5" morerows="1">0.21 (1991–2011)</oasis:entry>

         <oasis:entry colname="col6">6, 7</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col4">Pinatubo, Philippines (1991)</oasis:entry>

         <oasis:entry colname="col6">1, 2, 3, 4, 5</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1">2</oasis:entry>

         <oasis:entry colname="col2">6.41</oasis:entry>

         <oasis:entry colname="col3">1982.8</oasis:entry>

         <oasis:entry colname="col4">El Chichón, Mexico (1982)</oasis:entry>

         <oasis:entry colname="col5">0.26 (1982–1990)</oasis:entry>

         <oasis:entry colname="col6">8</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry rowsep="1" colname="col1" morerows="1">3</oasis:entry>

         <oasis:entry rowsep="1" colname="col2" morerows="1">9.89</oasis:entry>

         <oasis:entry rowsep="1" colname="col3" morerows="1">1970.3</oasis:entry>

         <oasis:entry colname="col4">Deception island,</oasis:entry>

         <oasis:entry rowsep="1" colname="col5" morerows="1">0.26 (1970–1981)</oasis:entry>

         <oasis:entry rowsep="1" colname="col6" morerows="1">9</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col4">Antarctic Peninsula (1970)</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry rowsep="1" colname="col1" morerows="1">4</oasis:entry>

         <oasis:entry rowsep="1" colname="col2" morerows="1">10.20</oasis:entry>

         <oasis:entry rowsep="1" colname="col3" morerows="1">1968.3</oasis:entry>

         <oasis:entry colname="col4">Deception island,</oasis:entry>

         <oasis:entry rowsep="1" colname="col5" morerows="1">0.16 (1967–1969)</oasis:entry>

         <oasis:entry rowsep="1" colname="col6" morerows="1">10</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col4">Antarctic Peninsula (1967)</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry rowsep="1" colname="col1" morerows="1">5</oasis:entry>

         <oasis:entry rowsep="1" colname="col2" morerows="1">11.91</oasis:entry>

         <oasis:entry rowsep="1" colname="col3" morerows="1">1961.7</oasis:entry>

         <oasis:entry colname="col4">Agung, Indonesia (1963)</oasis:entry>

         <oasis:entry rowsep="1" colname="col5" morerows="1">0.28 (1960–1966)</oasis:entry>

         <oasis:entry colname="col6">10</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col4">Puyehue, Cordón Caulle, Chile (1960)</oasis:entry>

         <oasis:entry colname="col6">11</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">6</oasis:entry>

         <oasis:entry colname="col2">12.64</oasis:entry>

         <oasis:entry colname="col3">1959.1</oasis:entry>

         <oasis:entry colname="col4">Carran-Los Venados, Chile (1955)</oasis:entry>

         <oasis:entry colname="col5">0.33 (1959)</oasis:entry>

         <oasis:entry colname="col6">3, 11, 12</oasis:entry>

       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4"><caption><p>Non-sea-salt SO<inline-formula><mml:math display="inline"><mml:mrow><mml:msubsup><mml:mi/><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> concentrations measured in KC, using the
timescale derived from annual layer counting in the <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O profile.
Potential layers of volcanic eruptions are marked with numbers: 1, 1a
(Pinatubo), 2 (El Chichón), 3, 4 (Deception Island), 5 (Agung, Indonesia;
Puyehue, Chile), 6 (Caran-Los Vernados, Chile) and summarised in Table 3.</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://tc.copernicus.org/articles/10/2763/2016/tc-10-2763-2016-f04.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5"><caption><p>Annual SMB for KC, KM, and BI cores compared to S100 (Kaczmarska et
al., 2004) and the composite FIS core record (Schlosser et al., 2014). The
dashed lines are the linear regression for the entire period covered by the
respective cores.</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://tc.copernicus.org/articles/10/2763/2016/tc-10-2763-2016-f05.png"/>

        </fig>

      <p>Furthermore, volcanic horizons are used to corroborate the dating and
estimate the dating uncertainty. We use maxima (values above the
mean <inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mi mathvariant="italic">σ</mml:mi></mml:mrow></mml:math></inline-formula> level) in the non-sea-salt sulfate (<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula>)
concentrations of the KC core to identify volcanic horizons (Fig. 4).
<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">NssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> was calculated from the mean seawater composition using
<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> as standard ion.

                <disp-formula id="Ch1.Ex1"><mml:math display="block"><mml:mrow><mml:mfenced open="[" close="]"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:mfenced><mml:mo>=</mml:mo><mml:msub><mml:mfenced close="]" open="["><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">SO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:mfenced><mml:mtext>total</mml:mtext></mml:msub><mml:mo>-</mml:mo><mml:mi>k</mml:mi><mml:mo>×</mml:mo><mml:msub><mml:mfenced open="[" close="]"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:mfenced><mml:mtext>total</mml:mtext></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

          where

                <disp-formula id="Ch1.Ex2"><mml:math display="block"><mml:mrow><mml:mi>k</mml:mi><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mfenced open="[" close="]"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">SO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:mfenced><mml:mtext>seawater</mml:mtext></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mfenced close="]" open="["><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:mfenced><mml:mtext>seawater</mml:mtext></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>=</mml:mo><mml:mn>0.06</mml:mn><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

          when ion concentrations are in <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">mol</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>. Peaks in
<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> are assigned to known volcanic eruptions that could alter
snow composition at the drilling site, using the Volcanic Explosivity Index
(VEI) (Global Volcanism Program, Smithsonian National Museum of Natural
History, <uri>http://www.volcano.si.edu/</uri>). The VEI is a relative measure of
the explosiveness of a volcanic eruption based on the volume of released
material, plume height, and qualitative remarks (e.g. by rating an eruption
from gentle to mega-colossal); these parameters are used to construct an
open-ended logarithmic scale starting with VEI <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0. Only eruptions with
VEI <inline-formula><mml:math display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 3 were considered in this analysis (Table 3). We attribute the
<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> peaks in the KC core at depths of 3.8 and
4 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> to the Pinatubo volcanic eruption (1991) (peak 1a, Fig. 4,
Table 3) and Cerro Hudson (peak 1, Fig. 4, Table 3) in agreement with
Cole-Dai et al. (1997). These depths correspond to late 1993 and late 1992
from the annual layer counting timescale, but delays of 1–2 years between
eruption and deposition are commonly observed; the Pinatubo signal has been
reported in the 1993 Antarctic snow layer (Cole-Dai et al., 1997). Another
<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> peak found at 6.41 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> could originate from
the El Chichón volcanic eruption (1982), at a depth corresponding to the
year 1983 based on the annual layer counting. Both, Pinatubo and
El Chichón volcanic horizons have been previously identified in
dielectric profiles of other cores drilled in the region (Schlosser et
al., 2012, 2014). Additional volcanic eruptions potentially observed in the
<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> record and SMB between potential volcanic horizons are
listed in Table 3, e.g. Agung (peak 5). The error in the dating by annual
layer counting is conservatively estimated to be <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>3 years, based on the
maximum difference between the Pinatubo volcanic signals found in the
<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> record (i.e. peak 1a, Table 3) and the eruption date. The
timescale error could be reduced by complementary dating methods, such as
counting annual cycles of chemical species (e.g. MSA and <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>), and
<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup><mml:mi mathvariant="normal">H</mml:mi></mml:mrow></mml:math></inline-formula> measurements for future cores drilled at these sites.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6" specific-use="star"><caption><p><bold>(a)</bold> Number of ice lenses per metre (bars), ice lens
thickness (stems), and density profiles (line) available at KC. Panels <bold>(b, c, d)</bold> are the same as <bold>(a)</bold> but with the <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, MSA, and
<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> profiles (lines) instead of density.</p></caption>
          <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://tc.copernicus.org/articles/10/2763/2016/tc-10-2763-2016-f06.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7" specific-use="star"><caption><p>Water stable isotope data for KC, KM, and BI: <bold>(a)</bold> <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, <bold>(b)</bold> <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H, <bold>(c)</bold> deuterium excess (<inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>).</p></caption>
          <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://tc.copernicus.org/articles/10/2763/2016/tc-10-2763-2016-f07.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8" specific-use="star"><caption><p>Seasonal variations in <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> (black) and <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O (red) in cores
<bold>(a)</bold> KM and <bold>(b)</bold> BI. Dashed lines show <inline-formula><mml:math display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mi mathvariant="italic">σ</mml:mi></mml:mrow></mml:math></inline-formula>.</p></caption>
          <?xmltex \igopts{width=284.527559pt}?><graphic xlink:href="https://tc.copernicus.org/articles/10/2763/2016/tc-10-2763-2016-f08.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9"><caption><p>Mean annual <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O for KC, KM, and BI compared to S100
(Divine et al., 2009) and the composite FIS core record (Schlosser et
al., 2014). The dashed lines are the linear regression for the entire period
covered by the respective cores.</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://tc.copernicus.org/articles/10/2763/2016/tc-10-2763-2016-f09.png"/>

        </fig>

</sec>
<sec id="Ch1.S4.SS2">
  <title>Surface mass balance</title>
      <p>Annual SMB in the cores was calculated from distances between summer maxima
in the <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O record (Fig. 5, Table 1). The average annual SMB for
the full period covered by the KC, KM, and BI cores is estimated to be 0.24,
0.68, and 0.70 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula>, and the average SMB for the common period
covered by all three cores (1996–2012), is 0.21, 0.70, and
0.71 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula>, respectively. The lowest inferred annual SMB values at
KC, KM, and BI were 0.11 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> (1986),
0.39 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> (2005), and 0.40 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>
(2004), respectively, while the highest values were
0.45 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> (1982), 0.95 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> (2011),
and 1.21 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> (2011).</p>
      <p>These SMB values generally agree with other estimates at FIS (Sinisalo et
al., 2013; Schlosser et al., 2014) obtained from shallow cores (1983–2009)
and stakes (2010–2012). Furthermore, the anomalously high snowfall in DML
during 2009 and 2011, recorded by GRACE satellite data (Boening et al., 2012)
and stake data at FIS (Sinisalo et al., 2013), appear to be reflected in
the SMB records of KM and BI (KM: 0.78 and 0.95 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula>; BI: 1.00 and
1.21 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula>, in 2009 and 2011, respectively) (Fig. 5).</p>
      <p>SMB derived from the stake closest to each core site (40 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">m</mml:mi></mml:math></inline-formula> to
1 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">km</mml:mi></mml:math></inline-formula>) at the three ice rises in 2013 are similar to average SMB
values from cores at KC (0.22 and 0.24 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> from the
stake and core data, respectively) and BI (0.73 and
0.70 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>), but differ at KM (0.38 vs.
0.68 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>). Differences in point estimates for single
years are to be expected, given the spatial variability of snow accumulation.
The spatial variability of SMB on the ice rises from stake and GPR data will
be presented elsewhere.</p>
      <p>In all three cores, there are ice layers of varying thickness, indicating
that melt occurs several times per year. We have no evidence, however, for
mass transport between annual layers. Figure 6 shows the number of ice lenses
and thickness related to density, <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, MSA, and
<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> concentrations in the KC core. There is no direct
correspondence between SMB, <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, and the ice layers in the core
from KC (Fig. 6), in agreement with previous results from the core S100
(Kaczmarska et al., 2006). We compare melt features found in the KC core with
the MSA and <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> profiles, but do not find a systematic
association between ice lenses and anomalies in the MSA or
<inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> concentrations, as we could expect from redistribution of
ions by meltwater percolation and refreezing. Some correspondence exists
between the thickest ice layers and peaks in the <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> record
(e.g. at 21, 20, 18, and 13 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">m</mml:mi></mml:math></inline-formula>, Fig. 6) but there are no such peaks in
the MSA record, as would be expected for an ion that it is just as readily
eluted as <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula>. Therefore, while redistribution of ions by
meltwater cannot be ruled out, it is not likely a dominant post-depositional
effect that would significantly influence the seasonal isotopic or chemical
signals at the core sites. It is more likely that the development of ice
lenses is a local process depending on several factors, including air and
snow pack temperatures, and that the combination of post-depositional
processes, such as wind scouring, contribute to the perturbation of the
subannual signal in the KC core site.</p>
      <p>In general, SMB at the sites closest to the coast, KM and BI, is higher than
at KC. The topography of the individual ice rises is a key determining
factor. While KM and BI are relatively symmetrical domes, KC is more
elongated, with a ridge axis stretching from SW to NE (Fig. 1). Therefore,
air transported from the NNE during a precipitation event is lifted over a
longer and gentler slope at KC than at KM and BI, which can lead to a weaker
influence of topography than on the steeper slopes of KM and BI. Wind
redistribution is critical for accumulation patterns. Networks of stake
measurements across KC and KM show an uneven snow distribution, with 3-fold
higher accumulation on the lowest-elevation upwind side, compared to the
summit (Lenaerts et al., 2014). This spatial pattern is well replicated with
the regional atmospheric climate model RACMO2, although an accurate DEM is
critical in such comparisons. Our results suggest that the differences in
accumulation at KM and BI compared to KC and the other core sites at FIS, are
most likely related to topographical effects. This can be further explored by
referring to the study by Altnau et al. (2015) which presents a vast coverage
of SMB and <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O for coastal and inland DML. By inspecting Fig. 2 in
Altnau et al. (2015), it can be observed that high annual SMB values, similar
to those measured at the KM and BI sites, occur in locations associated with
pronounced topographic features, e.g. mountain ranges and troughs, i.e.
anything where orographic lift may induce precipitation in comparison to the
flat areas in the proximities.</p>
      <p>Previous studies from coastal sites in the same area of DML have reported
large temporal and spatial SMB variability (Melvold, 1999; Kaczmarska et
al., 2004; Schlosser et al., 2014). The SMB records from the KM and BI cores
reveal high interannual variability and no significant long-term trend during
the period 1995(1996)–2014. At the more inland KC site, SMB variability is
lower, but there is also a weak, yet significant (at 95 % confidence
level) negative SMB trend of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.002 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">m</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">w</mml:mi><mml:mo>.</mml:mo><mml:mi mathvariant="normal">e</mml:mi><mml:mo>.</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> for the
period 1958–2012. This is in agreement with previous SMB studies done in the
whole region of western DML (Isaksson and Melvold, 2002; Kaczmarska et
al., 2004; Divine et al., 2009; Schlosser et al., 2014), which also document
a negative trend in SMB during the 20th century. A comparison between annual
SMB calculated in the cores taken at KC, KM, BI, S100 (Kaczmarska et
al., 2004), and a composite core constructed averaging the annual SMB from
four firn cores (M2, G3, G4, and G5) retrieved at Trolltunga and Jutulstraumen
(Schlosser et al., 2014) (Table 1), is shown in Fig. 5 (individual SMB
profiles of the cores conforming the composite are shown in Fig. S1a in the
Supplement). Overall, SMB values from the KM and BI cores are higher than for
the KC, S100 cores, and the composite record. Furthermore, the negative trend
at KC agrees well with that found in the S100 and in FIS composite core.
One proposed mechanism for decreasing SMB since the 1980s is the occurrence
of stronger zonal wind flow with lower-amplitude long waves during the same
period. The flow was characterised by the Southern Annular Mode (SAM) index
(Schlosser et al., 2014). During high SAM index phases meridional moisture
flux decreases; consequently, there is less precipitation and SMB in
Antarctica (Schlosser et al., 2014).</p>
      <p>Frezzotti et al. (2013) investigated Antarctic SMB over the last 800 years,
and found that there were statistically non-significant changes in SMB over
most of Antarctica, with no overall clear temporal trend over the longest
timescale. However, they also report a clear increase in SMB (<inline-formula><mml:math display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 10 %)
since the 1960s in regions where the SMB is high, i.e. coastal regions, and
over the highest part of the East Antarctic ice divide. The authors attribute
these dissimilar trends between high SMB locations and the rest of Antarctica
to a higher frequency of blocking anticyclones. These anticyclones increase
precipitation at coastal sites and lead to the advection of moist air at the
highest areas. Strong winds producing snow redistribution and erosion would
account for the reduction on SMB at windy sites. As discussed above, our
results show that the SMB trends at KC is similar to SMB trends reported
elsewhere at FIS and western DML (Isaksson and Melvold, 2002; Kaczmarska
et al., 2004; Divine et al., 2009; Schlosser et al., 2014). No significant
temporal trends in SMB are found at KM and BI.</p>
</sec>
<sec id="Ch1.S4.SS3">
  <title>Water stable isotopes</title>
      <p>Figure 7 shows the raw and annual <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H, and <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>
(deuterium excess) data for the KC, KM, and BI sites. The higher accumulation
rates at KM and BI allow high-resolution water stable isotope records
(average 20 data points per year), whereas resolution at KC is much lower
(average 7 data points per year). Table 1 shows the median values of
<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H, and <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> of the KC, KM, and BI cores. The
<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H signals at KM and BI (Fig. 7b, c) show
pronounced seasonality, with seasonal amplitudes up to 10 and 78 ‰,
for <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H, and up to 10 ‰ for <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>.
Stable isotope ratios for KM and BI are similar, while KC has generally lower
values of <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H than the two other cores. The core
site at BI is 130 m higher than that of KC and KM (see Table 1), such that
differences in isotope ratios can be attributed to local effects. Similar
results were found by Fernandoy et al. (2010) for firn cores drilled in the
hinterland of Neumayer Station, where higher-elevation cores did not always
have lower <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values.</p>
      <p>The present study is among the few that also includes deuterium, and the
first involving such data from FIS. It is difficult to reliably determine
the seasonal cycle of <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> for the analysed cores because we cannot date the
cores accurately at the subannual level, post-depositional processes such as
water vapour diffusion in the firn column may alter the <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> profile, and,
finally, the <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> time series are relatively short. Nevertheless, we use the
derived age models to estimate the intraannual variability in <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> for the two
higher-resolution cores at KM and BI. The results (Fig. 8) suggest that the
absolute values and magnitudes of the seasonal cycle of <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> are in reasonable
agreement with observed and modelled <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> at other coastal Antarctic ice core
locations (Schlosser et al., 2008; Inoue et al., 2016; Schoenemann and Steig,
2016). At both KM and BI, maximum values for <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> occur in austral autumn,
preceding the corresponding seasonal minima in <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O by 3–4 months
and, most likely, air temperatures (Fig. 8). On the other hand, fresh snow
sampling at nearby Neumayer Station suggested a spring maximum for <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>
(Schlosser et al., 2008). We note, however, that, because of the method we
use to construct the core chronologies, the seasonal curve of <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O
is fit to have a maximum (minimum) in the first (sixth) month of the year.
Nonetheless, our timescale does not alter the fact that there is a lag
between <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O peaks. Such an offset is also reported at
coastal locations by Schlosser et al. (2008) and Inoue et al. (2016), and
contradicts the conventional interpretation of winter maxima in <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> being the
result of shifting moisture-source regions to higher latitudes (e.g. Delmotte
et al., 2000; Pfahl and Sodemann, 2014).</p>
      <p>Recent studies show that the relationship between <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> and moisture source
parameters is more complex than previously thought since <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> is also strongly
sensitive to both equilibrium and kinetic fractionation during precipitation
formation (Steen-Larsen et al., 2014; Dittmann et al., 2016; Schoenemann and
Steig, 2016). The <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> measured in precipitation is controlled by different
processes, exerting opposite effects. We hypothesise that the observed <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> to
<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O offsets for coastal locations, which have a relatively
mild climate compared to the plateau, occur due to the effects of
high-latitude moisture entrainment during winter. The influence of local
moisture sources with low <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> may outweigh the thermal effects on equilibrium
and kinetic fractionation during precipitation. However, the seasonal
balance of these effects is likely site specific and the lack of studies on
<inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> controls at coastal locations precludes us from proposing a definitive
explanation to this phenomenon.</p>
      <p>High-correlation coefficients between the annual <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> and austral spring to
summer SAM indices of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.55 (significant at the 95 % confidence level)
for KM and <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.33 (not significant) for BI cores point to the possible role
of seasonal changes in moisture transport and precipitation in the area in
shaping the annual isotopic signal. A positive SAM index is generally
associated with stronger zonal westerlies and comparatively little exchange
of moisture and energy between middle and high latitudes (Marshall et
al., 2013; Schlosser et al., 2016), hence increasing the contribution of
local, less depleted of <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, moisture sources in precipitation
(Noone and Simmonds, 2002). Decreased meridional southward moisture transport
during the positive SAM phase may vary the annual moisture balance towards a
higher fraction of local spring and summer moisture. Compared to moisture
originating from more remote lower-latitude sources, local sources in spring
and summer typically have lower <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> values, leading to generally negative
annual <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> anomalies preserved in the snow. The multidecadal positive trend
in SAM (e.g. Marshall, 2003), which is especially pronounced for austral
summers, may in turn drive the weak negative trend of
0.1 <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">‰</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">decade</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> (not significant at the 95 %
confidence level) in <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> detected in the longer KC core, also contributing to
an observed positive trend in <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O in the regional core network.</p>
      <p>Figure 9 shows the mean annual <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O for the KC, KM, and BI cores
compared to the S100 and composite core from Schlosser et al. (2014)
(individual <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O profiles of the cores conforming the composite are
shown in Fig. S1b). Overall, annual <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values at the three ice
rise cores are higher than at S100 or for the composite core. However, both
the inferred multiannual means and the standard deviations of <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O
for the three ice rise cores fall within the typical range of variability for
other cores from the coastal DML (Altnau et al., 2015).</p>
      <p>The positive linear trends in <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O observed in the KC and BI cores
also agree well with linear trends reported for the S100 and FIS composite
cores (Kaczmarska et al., 2004; Divine et al., 2009; Schlosser et al., 2014).
However, none of the linear trends observed in the KC, KM or BI cores are
significant at the 95 % confidence level. Similar to earlier studies
(e.g. Schlosser et al., 2014) no correlation is found between <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O
of the ice rise cores and measured air temperature at Neumayer Station, the
closest station suitable for comparison. Neumayer is situated on a small ice
shelf, with synoptic conditions similar to FIS; no temporal trend is
found in air temperature since the founding of the station in 1981. Likewise,
no relationship between stable isotopes and SMB is seen in the ice rise cores
(compare with Fig. 5). This confirms previous studies, which find poor
correspondence between SMB and proxy temperatures, suggesting that it is
large-scale atmospheric circulation rather than the thermodynamic
relationship between SMB and temperature that is the determining factor here.
This was also found in a recent study by Fudge et al. (2016), who
investigated the temperature–SMB relationship using data from the WAIS
Divide ice core.</p>
</sec>
</sec>
<sec id="Ch1.S5" sec-type="conclusions">
  <title>Discussion and conclusions</title>
      <p>Hitherto, small ice rises in
Antarctica have not been fully utilised as ice core sites. Based on the data
presented we conclude that the stratigraphic records of water stable isotopes
and major ions (in particular MSA and <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>) are well preserved during
the last decades so that reliable annual dating can be performed, especially
in the KM and BI sites. Neither the stratigraphy nor the chemistry profiles
in the cores suggest that there is substantial surface melting or percolation
at these sites, which would perturb the stratigraphic signal. On the other
hand, the KC core presents less well-preserved annual cycles than the KM and
BI cores. Melt features in the KC core, i.e. the number of ice lenses, ice
lens thickness, and density profiles (Fig. 6), show that most ice lenses are
thinner than 1 cm, with the thickest being 1.5 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">cm</mml:mi></mml:math></inline-formula>. In terms of ice
content per metre of firn, the KC core has in average no more than 3 % of
ice per metre during the period 1958–2012; therefore, it is likely that a
combination of post-depositional effects (e.g. wind scouring), is affecting
the subannual record at this site leading to the lack of well-preserved
seasonal cycles, although the site is still adequate for obtaining core
chronologies by combining annual layer counting and the identification of
volcanic layers.</p>
      <p>Considering the above, the core timescales were constructed based on annual
layer counting of <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn>18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O (KC, KM, and BI) together with the
identification of volcanic layers using the <inline-formula><mml:math display="inline"><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">nssSO</mml:mi><mml:mn mathvariant="normal">4</mml:mn><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>-</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> record (KC).
These approaches appear to provide reliable methods for dating these
firn cores involving dating errors of <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>1 year (KM and BI) and
<inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>3 years (KC). The SMB records from the different sites show that
topography likely leads to local effects that are superimposed on the
regional climate signal. This is particularly the case for the KM and BI ice
rise sites, which have much higher SMB (hence higher variability) than the
KC, S100, and composite cores, with trends also opposing the findings from the
other records. It is, therefore, of great importance to further investigate
whether the data from the KM and BI ice rises have also a regional significance.</p>
      <p>The longest SMB record, from KC, is in general agreement with other regional
ice core records (S100 and the composite core), and shows that the negative
trend observed during the 20th century in the longer S100 core retrieved
nearby (Fig. 1) continues during the first decade of the 21st century. This
decrease in SMB since the 1980s has been proposed to be related to
diminishing meridional moisture flux and, consequently, a decrease in
precipitation and SMB at FIS (Schlosser et al., 2014). The most commonly
used Antarctic SMB maps (e.g. Arthern et al., 2006; Monaghan et al., 2006;
Lenaerts et al., 2012) all have a resolution that is too low to properly
incorporate the high variability that ice rises induces.</p>
      <p>The first data available for <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> at FIS point to a possible role of
seasonal moisture transport changes and precipitation in shaping the annual
isotopic signal at the area, as inferred from the high correlation found
between annual <inline-formula><mml:math display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula> in the KM and BI cores and austral spring-to-summer SAM
indices. When considering the factors behind the water stable isotope values,
the poor correspondence between SMB and proxy temperature derived from water
stable isotopes suggests that large-scale atmospheric circulation patterns
are the determining factors for isotope ratios, in agreement with previous
studies at FIS (Schlosser et al., 2014). Due to the restricted length of
the KM and BI cores, further analysis of the spatial and temporal differences
of SMB and water stable isotopes at these ice rises in a climatic context
would be speculative. However, the ice rises coring sites show potential for
investigating past variations in water stable isotopes given on the
well-preserved profiles, with annual to biannual resolution at the KC site,
and subannual resolution at the KM and BI sites.</p>
      <p>In summary, the ice rises are suitable drilling sites for the retrieval of
longer cores if local influences are kept in mind when reconstructing the
past climate and environmental signals recorded in the cores. The KM and BI
sites are suitable for retrieving high-resolution (i.e. subannual timescales)
ice core records due to their high accumulation rates and well-preserved
physical and chemical properties, bearing in mind that they may also
be strongly affected by local snow deposition patterns. On the other hand,
the KC location could be considered the most representative for the climate
of the area, even if it is not possible to obtain subannual dating
due to the lower annual snow accumulation at that site. Since drifting snow
processes are of major importance on ice rises, detailed knowledge of both
topography and the spatial pattern of SMB are required for deciding
possible future ice core locations. Consequently, the three ice rises
investigated here offer attractive locations for the retrieval of longer ice
cores that would contribute to elucidate the climate and environmental
history of FIS, and to infer its role in a changing climate.</p>
</sec>
<sec id="Ch1.S6">
  <title>Data availability</title>
      <p>For the SMB, water stable isotopes, and chemistry profiles of the KC, KM, BI,
S100, and FIS composite cores, please contact E. Isaksson
(elisabeth.isaksson@npolar.no).</p>
      <p>Information about the Volcanic Explosivity Index (VEI) ia available at
<uri>http://volcano.si.edu/</uri> (Global Volcanism Program, 2016).</p>
      <p>Data set concerning the SAM index is available at
<uri>http://www.nerc-bas.ac.uk/icd/gjma/sam.html</uri> (Marshall, 2003).</p>
</sec>

      
      </body>
    <back><app-group>
        <supplementary-material position="anchor"><p><bold>The Supplement related to this article is available online at <inline-supplementary-material xlink:href="http://dx.doi.org/10.5194/tc-10-2763-2016-supplement" xlink:title="pdf">doi:10.5194/tc-10-2763-2016-supplement</inline-supplementary-material>.</bold></p></supplementary-material>
        </app-group><ack><title>Acknowledgements</title><p>We are grateful to the number of people who helped to collect, transport,
sample and analyse the firn cores and snow pits at FIS. We would like to
thank V. Goel, J. Brown and K. Matsuoka for providing the contour and stake
data. In addition, we thank E. Thomas and M. Frezzotti for their constructive
and thorough revision of the manuscript. Financial support for this work came
from the Norwegian Research Council through NARE and the Centre for Ice,
Climate and Ecosystems (ICE) at the Norwegian Polar Institute in Tromsø,
Norway. <?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>
Edited by: M. van den Broeke <?xmltex \hack{\newline}?>
Reviewed by: E. Thomas and M. Frezzotti</p></ack><ref-list>
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    <!--<article-title-html>Surface mass balance and water stable isotopes derived from firn cores on three ice rises, Fimbul Ice Shelf, Antarctica</article-title-html>
<abstract-html><p class="p">Three shallow firn cores were retrieved in the austral summers of 2011/12 and
2013/14 on the ice rises Kupol Ciolkovskogo (KC), Kupol Moskovskij (KM), and
Blåskimen Island (BI), all part of Fimbul Ice Shelf (FIS) in western
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oxygen isotope (<i>δ</i><sup>18</sup>O) data, and by identifying volcanic horizons
using non-sea-salt sulfate (nssSO<sub>4</sub><sup>2−</sup>) data. The water stable
isotope records show that the atmospheric signature of the annual snow
accumulation cycle is well preserved in the firn column, especially at KM and
BI. We are able to determine the annual surface mass balance (SMB), as well
as the mean SMB values between identified volcanic horizons. Average SMB at
the KM and BI sites (0.68 and 0.70 m<mspace width="0.125em" linebreak="nobreak"/>w. e. <mspace width="0.125em" linebreak="nobreak"/>yr<sup>−1</sup>) was higher than
at the KC site (0.24 m<mspace linebreak="nobreak" width="0.125em"/>w. e. <mspace linebreak="nobreak" width="0.125em"/>yr<sup>−1</sup>), and there was greater
temporal variability as well. Trends in the SMB and <i>δ</i><sup>18</sup>O records
from the KC core over the period of 1958–2012 agree well with other
previously investigated cores in the area, thus the KC site could be
considered the most representative of the climate of the region. Cores from
KM and BI appear to be more affected by local meteorological conditions and
surface topography. Our results suggest that the ice rises are suitable sites
for the retrieval of longer firn and ice cores, but that BI has the best
preserved seasonal cycles of the three records and is thus the most optimal
site for high-resolution studies of temporal variability of the climate
signal. Deuterium excess data suggest a possible effect of seasonal moisture
transport changes on the annual isotopic signal. In agreement with previous
studies, large-scale atmospheric circulation patterns most likely provide the
dominant influence on water stable isotope ratios preserved at the core
sites.</p></abstract-html>
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