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<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" dtd-version="3.0"><?xmltex \makeatother\@nolinetrue\makeatletter?><?xmltex \hack{\allowdisplaybreaks}?>
  <front>
    <journal-meta>
<journal-id journal-id-type="publisher">TC</journal-id>
<journal-title-group>
<journal-title>The Cryosphere</journal-title>
<abbrev-journal-title abbrev-type="publisher">TC</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">The Cryosphere</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1994-0424</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>

    <article-meta>
      <article-id pub-id-type="doi">10.5194/tc-10-2013-2016</article-id><title-group><article-title>Observations of capillary barriers and preferential flow in layered snow during cold laboratory experiments</article-title>
      </title-group><?xmltex \runningtitle{Capillary barriers in snow}?><?xmltex \runningauthor{F. Avanzi et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Avanzi</surname><given-names>Francesco</given-names></name>
          <email>francesco.avanzi@mail.polimi.it</email><email>avanzi.francesco@gmail.com</email>
        <ext-link>https://orcid.org/0000-0003-4235-2373</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Hirashima</surname><given-names>Hiroyuki</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Yamaguchi</surname><given-names>Satoru</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-9972-0443</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Katsushima</surname><given-names>Takafumi</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>De Michele</surname><given-names>Carlo</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-7098-4725</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Department of Civil and Environmental Engineering, Politecnico di Milano, Milano, Italy</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Snow and Ice Research Center, National Research Institute for Earth Science and
Disaster Resilience, Suyoshi-machi, Nagaoka-shi, Niigata-ken, 940-0821, Japan</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Meteorological Risk and Buffer Forest Laboratory, Department of Meteorological
Environment, Forestry and Forest Products Research Institute, Tsukuba-shi, Ibaraki-ken, 305-8687, Japan</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Francesco Avanzi (francesco.avanzi@mail.polimi.it, avanzi.francesco@gmail.com)</corresp></author-notes><pub-date><day>9</day><month>September</month><year>2016</year></pub-date>
      
      <volume>10</volume>
      <issue>5</issue>
      <fpage>2013</fpage><lpage>2026</lpage>
      <history>
        <date date-type="received"><day>10</day><month>October</month><year>2015</year></date>
           <date date-type="rev-request"><day>3</day><month>December</month><year>2015</year></date>
           <date date-type="rev-recd"><day>2</day><month>August</month><year>2016</year></date>
           <date date-type="accepted"><day>10</day><month>August</month><year>2016</year></date>
      </history>
      <permissions>
<license license-type="open-access">
<license-p>This work is licensed under a Creative Commons Attribution 3.0 Unported License. To view a copy of this license, visit <ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by/3.0/">http://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions><self-uri xlink:href="https://tc.copernicus.org/articles/10/2013/2016/tc-10-2013-2016.html">This article is available from https://tc.copernicus.org/articles/10/2013/2016/tc-10-2013-2016.html</self-uri>
<self-uri xlink:href="https://tc.copernicus.org/articles/10/2013/2016/tc-10-2013-2016.pdf">The full text article is available as a PDF file from https://tc.copernicus.org/articles/10/2013/2016/tc-10-2013-2016.pdf</self-uri>


      <abstract>
    <p>Data of liquid water flow around a capillary barrier in snow are still
limited. To gain insight into this process, we carried out observations of
dyed water infiltration in layered snow at 0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C during cold
laboratory experiments. We considered three different finer-over-coarser
textures and three different water input rates. By means of visual
inspection, horizontal sectioning, and measurements of liquid water content
(LWC), capillary barriers and associated preferential flow were
characterized. The flow dynamics of each sample were also simulated solving
the Richards equation within the 1-D multi-layer physically based snow cover
model SNOWPACK. Results revealed that capillary barriers and preferential
flow are relevant processes ruling the speed of water infiltration in
stratified snow. Both are marked by a high degree of spatial variability at
centimeter scale and complex 3-D patterns. During unsteady percolation of
water, observed peaks in bulk volumetric LWC at the interface reached
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 33–36 vol % when the upper layer was composed by fine snow (grain
size smaller than 0.5 mm). However, LWC might locally be greater due to the
observed heterogeneity in the process. Spatial variability in water
transmission increases with grain size, whereas we did not observe a
systematic dependency on water input rate for samples containing fine snow.
The comparison between observed and simulated LWC profiles
revealed that the implementation of
the Richards equation reproduces the existence of a capillary barrier for all
observed cases and yields a good agreement with observed peaks in LWC at the
interface between layers.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

      <?xmltex \hack{\newpage}?>
<sec id="Ch1.S1" sec-type="intro">
  <title>Introduction</title>
      <p>Liquid water in snow rules runoff timing and amount <xref ref-type="bibr" rid="bib1.bibx42 bib1.bibx72 bib1.bibx76" id="paren.1"/>, snowpack mechanical properties and stability in wet
conditions <xref ref-type="bibr" rid="bib1.bibx49 bib1.bibx6 bib1.bibx53 bib1.bibx54 bib1.bibx66 bib1.bibx52 bib1.bibx60" id="paren.2"/>, and snow albedo <xref ref-type="bibr" rid="bib1.bibx22" id="paren.3"/>. Furthermore,
<xref ref-type="bibr" rid="bib1.bibx28" id="normal.4"/>, <xref ref-type="bibr" rid="bib1.bibx27" id="normal.5"/>, and <xref ref-type="bibr" rid="bib1.bibx45" id="normal.6"/> report that
meltwater percolation–storage dynamics in snow and firn might play an
important role in determining the timing of sea-level rise by climate change.
Liquid water in snow can be measured as a volumetric fraction (LWC, or
<inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>), i.e., the ratio between liquid water volume and total snow volume
<xref ref-type="bibr" rid="bib1.bibx26" id="paren.7"/>. LWC is usually expressed in percent of volume (vol % or
just %).</p>
      <p>Water flow in snow emerges as a complex, 3-D process when observed in the
field or in the laboratory. The co-existence of water and ice grains causes
fast metamorphism <xref ref-type="bibr" rid="bib1.bibx11" id="paren.8"/> and phase change, hence melt–freeze and
the possible development of ice lenses when water infiltrates in subfreezing
snow <xref ref-type="bibr" rid="bib1.bibx57" id="paren.9"/>. The interaction with topography can redistribute
water at slope scale <xref ref-type="bibr" rid="bib1.bibx24" id="paren.10"/>. Moreover, water movement is usually
marked by high spatial variability due to the occurrence of preferential flow
or fingering <xref ref-type="bibr" rid="bib1.bibx47 bib1.bibx46 bib1.bibx50 bib1.bibx61 bib1.bibx69 bib1.bibx75 bib1.bibx38" id="paren.11"/>. These processes  complicate the modeling of liquid water in snow, which has
been often simplified in the past by using a simple Darcian theory that
neglects effects of capillary gradients on the flow <xref ref-type="bibr" rid="bib1.bibx12 bib1.bibx71" id="paren.12"/>. In particular, fingering is deemed to play a key role in
ruling water arrival time at snow base, hence runoff <xref ref-type="bibr" rid="bib1.bibx72 bib1.bibx73" id="paren.13"/>
and snowpack stability <xref ref-type="bibr" rid="bib1.bibx66 bib1.bibx53 bib1.bibx52" id="paren.14"/>.</p>
      <p>The exact physics of preferential flow in snow is still not known
<xref ref-type="bibr" rid="bib1.bibx38" id="paren.15"/> and modeling strategies are therefore still preliminary.
For instance, <xref ref-type="bibr" rid="bib1.bibx46" id="normal.16"/> propose an explicit definition of multiple-path
routes, whereas <xref ref-type="bibr" rid="bib1.bibx36" id="normal.17"/> introduce a threshold value for <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>
triggering preferential runoff. <xref ref-type="bibr" rid="bib1.bibx72" id="normal.18"/> report that solving the Richards
equation accounting for suction (<inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula>) gradients improves runoff
estimations at different temporal resolutions, but it also accelerates
meltwater front progress when compared with data from an upGPR and simulations
by a bucket scheme <xref ref-type="bibr" rid="bib1.bibx73" id="paren.19"/>. This result has been attributed to an
unexpected simulation of some effects of preferential flow by the water
scheme used.</p>
      <p>The use of the Richards equation for modeling wetting front instability in porous
media is still a matter of debate <xref ref-type="bibr" rid="bib1.bibx23 bib1.bibx69 bib1.bibx21" id="paren.20"/> due
to the occurrence of peculiar pore-scale processes when water infiltrates as
fingers <xref ref-type="bibr" rid="bib1.bibx23 bib1.bibx21 bib1.bibx38 bib1.bibx9" id="paren.21"/>. Observations
reveal that in soils an unstable infiltration profile may be marked by an
overshoot profile in terms of <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> (saturation overshoot) or <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula>
(capillary pressure overshoot; see
<xref ref-type="bibr" rid="bib1.bibx19 bib1.bibx20 bib1.bibx21 bib1.bibx9" id="altparen.22"/>). Examples of pressure
overshoots have been observed in homogeneous snow samples during preferential
infiltration by <xref ref-type="bibr" rid="bib1.bibx38" id="normal.23"/>. In addition, <xref ref-type="bibr" rid="bib1.bibx34" id="normal.24"/> report
promising attempts to reproduce similar dynamics using a 3-D model; they show
that solving the Richards equation by including spatial heterogeneity of snow
properties and water entry suction (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) enables to simulate
preferential flow effects. These results suggest that preferential flow in
isothermal snow at 0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C might be explained (and modeled) with a
similar approach to the theory of gravity-driven instability of fingers in
soils <xref ref-type="bibr" rid="bib1.bibx37 bib1.bibx38" id="paren.25"/>.</p>
      <p>Unsaturated hydraulic properties of snow may impede water infiltration in a
finer-over-coarser profile. This impedance is usually referred to as a
capillary barrier <xref ref-type="bibr" rid="bib1.bibx40 bib1.bibx69" id="paren.26"/> and is due to the infiltrating
water being generally marked by a very high suction when it initially moves
in the finer layer. This prevents water from entering the lower layer, thus
causing local accumulation of water at the interface (henceforth, simply
ponding), a deceleration in the undisturbed advancement of the wetting front,
horizontal diversion of water, and a delay in the expected travel time of
water. <xref ref-type="bibr" rid="bib1.bibx31" id="normal.27"/>, <xref ref-type="bibr" rid="bib1.bibx7" id="normal.28"/>, <xref ref-type="bibr" rid="bib1.bibx32" id="normal.29"/>, <xref ref-type="bibr" rid="bib1.bibx64" id="normal.30"/>,
<xref ref-type="bibr" rid="bib1.bibx63" id="normal.31"/>, and <xref ref-type="bibr" rid="bib1.bibx40" id="normal.32"/> discuss this process in soils, whereas
<xref ref-type="bibr" rid="bib1.bibx68" id="normal.33"/>, <xref ref-type="bibr" rid="bib1.bibx35" id="normal.34"/>, <xref ref-type="bibr" rid="bib1.bibx69" id="normal.35"/>, <xref ref-type="bibr" rid="bib1.bibx56" id="normal.36"/>, and
<xref ref-type="bibr" rid="bib1.bibx53" id="normal.37"/> report some examples for layered snowpack. According to the
results by <xref ref-type="bibr" rid="bib1.bibx63" id="normal.38"/> in soils, water will enter the underlying
coarser layer when <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula> at the interface decreases to <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>;
at this suction, the coarser soil layer firstly becomes conductive
<xref ref-type="bibr" rid="bib1.bibx64 bib1.bibx40" id="paren.39"/>. A decrease in <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula> during ponding is caused by
the fact that <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula> are related by a hysteretic relation called
the water retention curve (WRC) <xref ref-type="bibr" rid="bib1.bibx15 bib1.bibx77 bib1.bibx2 bib1.bibx78" id="paren.40"/>. In soils, <xref ref-type="bibr" rid="bib1.bibx32" id="normal.41"/> and <xref ref-type="bibr" rid="bib1.bibx7" id="normal.42"/> note also that, after
reaching <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, subsequent flow in the coarser layer will be
marked by fingers if, in steady conditions, the hydraulic conductivity of the
lower layer at <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is greater than the flux through the top
layer <inline-formula><mml:math display="inline"><mml:mi>q</mml:mi></mml:math></inline-formula> (due to mass conservation). Thus, ponding of water above a
capillary barrier is prone to subsequent flow instability, namely, to the
development of preferential channels.</p>
      <p>Understanding water flow around capillary barriers may be an important step
toward efficiently modeling liquid water flow in snow. Furthermore, capillary
barriers can play an important role for triggering wet snow avalanches
<xref ref-type="bibr" rid="bib1.bibx53 bib1.bibx74" id="paren.43"/>. For example, <xref ref-type="bibr" rid="bib1.bibx74" id="normal.44"/> report that
predicted local accumulations of water like those expected during ponding at
capillary barriers can be used to separate avalanche from non-avalanche days.
The position of peak LWC within the snow cover correlates with avalanche
size. These processes also affect the timing of snowmelt runoff
<xref ref-type="bibr" rid="bib1.bibx72" id="paren.45"/>, especially during initial infiltration in dry snow. However,
their characterization in the literature is still very limited
<xref ref-type="bibr" rid="bib1.bibx24" id="paren.46"/>. Indeed, existing real-time observations in the laboratory
or in the field consider a restricted variety of grain size (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>g</mml:mi><mml:mtext>S</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>)
combinations <xref ref-type="bibr" rid="bib1.bibx35 bib1.bibx69" id="paren.47"/>. Under field conditions, LWC
profiles are usually measured using destructive manual methods that strongly
limit the temporal and spatial resolution of profiles. Thus, the evaluation
of promising results from physically based models <xref ref-type="bibr" rid="bib1.bibx33 bib1.bibx53 bib1.bibx72 bib1.bibx73" id="paren.48"/> are often hampered by a lack of a proper
high-resolution experimental database.</p>
      <p>Here, we collected quantitative information about the liquid water flow
around a capillary barrier in snow using laboratory experiments. We
considered nine layered snow samples with different grain size combinations
and different water input rates. We measured, for each sample, the thickness
of the volume of the upper layer affected by ponding of water at the textural
boundary, LWC profiles, wet snow fraction at different depths, and the
arrival time of water at the sample base. These experiments were performed
choosing a quite high vertical resolution of measurements (2 cm) and a broad
set of input rates and textures. All the laboratory experiments are compared
with numerical simulations of the Richards equation in snow by the 1-D
multi-layer physically based snow cover model SNOWPACK, in order to
investigate how well 1-D snowpack models are able to capture the behavior of
water flow over capillary barriers.</p>
      <p>We consider isothermal conditions at 0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, thus avoiding any
investigation about wetting front advancement in subfreezing snow, which
presents additional challenges. Indeed, <xref ref-type="bibr" rid="bib1.bibx47 bib1.bibx48" id="normal.49"/> report that
water infiltration in initially subfreezing snow is marked by an alternation
of wet snow at 0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C and dry snow in subfreezing conditions (see
also <xref ref-type="bibr" rid="bib1.bibx58 bib1.bibx57" id="altparen.50"/>). The impact of these processes on runoff
response time of snow in sub-freezing conditions is still a matter of debate
<xref ref-type="bibr" rid="bib1.bibx48" id="paren.51"/>, especially on seasonal timescales <xref ref-type="bibr" rid="bib1.bibx72" id="paren.52"/>.</p>
</sec>
<sec id="Ch1.S2">
  <title>Methods</title>
<sec id="Ch1.S2.SS1">
  <title>Preparation of samples</title>
      <p>The main prerequisite to observe capillary barriers in initially dry snow is
a finer-over-coarser profile in layering. For this purpose, three
combinations of grain size were considered here: (1) FC, i.e.,
fine-over-coarse snow; (2) FM, i.e., fine-over-medium snow; (3) MC, i.e.,
medium-over-coarse snow. We classify snow with <inline-formula><mml:math display="inline"><mml:mn>0.25</mml:mn></mml:math></inline-formula> mm <inline-formula><mml:math display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>g</mml:mi><mml:mtext>S</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> 0.5 mm as fine, snow with 1 mm <inline-formula><mml:math display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>g</mml:mi><mml:mtext>S</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> 1.4 mm as medium, and snow with <inline-formula><mml:math display="inline"><mml:mn mathvariant="normal">2</mml:mn></mml:math></inline-formula> mm <inline-formula><mml:math display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>g</mml:mi><mml:mtext>S</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> 2.8 mm as coarse. Note that this nomenclature is convenient for
the presented work, but it is not consistent with the international
classification proposed by <xref ref-type="bibr" rid="bib1.bibx26" id="normal.53"/>, which defines for instance medium
snow grain size as <inline-formula><mml:math display="inline"><mml:mn>0.5</mml:mn></mml:math></inline-formula> mm <inline-formula><mml:math display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>g</mml:mi><mml:mtext>S</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> 1 mm.</p>
      <p>Experimental evidence revealed that the area occupied by fingers in snow and
the value of <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> may be both functions of water input rate
<xref ref-type="bibr" rid="bib1.bibx38" id="paren.54"/>. In order for our conclusions to be more general, we
carried out experiments with three different water inputs <inline-formula><mml:math display="inline"><mml:mi>W</mml:mi></mml:math></inline-formula>: these are
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 10, 30 and 100 mm h<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. These water input rates are a
compromise between the need for exploring the properties of capillary
barriers over a broad range of <inline-formula><mml:math display="inline"><mml:mi>W</mml:mi></mml:math></inline-formula>, expected melt rates in natural conditions
<xref ref-type="bibr" rid="bib1.bibx18" id="paren.55"/>, and operational constraints (specifically the expected
duration of the tests). Because the saturated conductivity of snow is rather
high compared with the chosen input rates, most existing instability criteria
<xref ref-type="bibr" rid="bib1.bibx59 bib1.bibx7 bib1.bibx17 bib1.bibx21" id="paren.56"/> will predict unstable flow
in these conditions. Accordingly, <xref ref-type="bibr" rid="bib1.bibx38" id="normal.57"/> have already observed
preferential infiltration in snow with average <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>g</mml:mi><mml:mtext>S</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> between
0.421 and 1.439 mm for different water input rates
(21.7 mm h<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> W <inline-formula><mml:math display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> 205.5 mm h<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>).</p>
      <p>Nine samples were prepared in a cold room at <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>20 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C using refrozen
melt forms (one sample for each of the three grain size combinations and
three water input rates). Henceforth, numbers 1, 2, and 3 differentiate
samples with the same grain size combination but subjected to different water
input rate (10, 30, and 100 mm h<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, respectively). Fragmented snow
particles were firstly partitioned in several classes of grain size.
Afterwards, the three <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>g</mml:mi><mml:mtext>S</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> chosen were sieved a second time to
prepare the samples. Snow was packed in a cylindrical container. The
container was composed by a number of acrylic rings (height equal to 20 mm,
diameter equal to 50 mm) that were previously taped on the external side.
After sieving the lower layer, its dry density (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mrow><mml:mi mathvariant="normal">D</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">L</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) was
measured by gravimetry. The dry density of the upper layer
(<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mrow><mml:mi mathvariant="normal">D</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) was measured by gravimetry at the end of sieving
operations (by considering the difference between sample total weight and
sample weight before sieving the upper layer). After preparation, each sample
was moved to a second cold room at 0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, where it was stored for at
least 12 h to reach initial conditions of dry snow at 0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C.</p>
      <p>We report in Table <xref ref-type="table" rid="Ch1.T1"/> the details of each experiment. Water input
rates are reported both in mm h<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> and in g min<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (samples
diameter equal to 5 cm). The coefficients of variation of
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mrow><mml:mi mathvariant="normal">D</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mrow><mml:mi mathvariant="normal">D</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">L</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> read 0.06 and 0.03. We did not
apply any tamping during sieving operations so we had no direct control on
the values of <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mrow><mml:mi mathvariant="normal">D</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mrow><mml:mi mathvariant="normal">D</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">L</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>. Given the low
variability of these two variables, we point out that this work investigates
how capillary barrier effects and associated preferential flow vary with
grain size only. Future investigations should focus on the generalization of
this work to layers of different density. Some samples (namely, FC2, FM2, and
MC2) are shorter than the others. However, the thickness of the upper layer
is the same for all the samples. This is important as ponding occurs in the
upper layer.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><caption><p>Experimental details: <inline-formula><mml:math display="inline"><mml:mi>W</mml:mi></mml:math></inline-formula> is the applied water input
rate, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mrow><mml:mi mathvariant="normal">D</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the dry density of the upper layer, and
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mrow><mml:mi mathvariant="normal">D</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">L</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the dry density of the lower layer.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="7">
     <oasis:colspec colnum="1" colname="col1" align="center"/>
     <oasis:colspec colnum="2" colname="col2" align="center"/>
     <oasis:colspec colnum="3" colname="col3" align="center"/>
     <oasis:colspec colnum="4" colname="col4" align="center"/>
     <oasis:colspec colnum="5" colname="col5" align="center"/>
     <oasis:colspec colnum="6" colname="col6" align="center"/>
     <oasis:colspec colnum="7" colname="col7" align="center"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1">Sample ID</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math display="inline"><mml:mi>W</mml:mi></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math display="inline"><mml:mi>W</mml:mi></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mrow><mml:mi mathvariant="normal">D</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col5"><inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ρ</mml:mi><mml:mrow><mml:mi mathvariant="normal">D</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">L</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col6">Upper layer</oasis:entry>  
         <oasis:entry colname="col7">Lower layer</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">(mm h<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col3">(g min<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col4">(kg m<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col5">(kg m<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col6">thickness (cm)</oasis:entry>  
         <oasis:entry colname="col7">thickness (cm)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">FC1</oasis:entry>  
         <oasis:entry colname="col2">11.9</oasis:entry>  
         <oasis:entry colname="col3">0.39</oasis:entry>  
         <oasis:entry colname="col4">417</oasis:entry>  
         <oasis:entry colname="col5">465</oasis:entry>  
         <oasis:entry colname="col6">10</oasis:entry>  
         <oasis:entry colname="col7">10</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FC2</oasis:entry>  
         <oasis:entry colname="col2">28</oasis:entry>  
         <oasis:entry colname="col3">0.92</oasis:entry>  
         <oasis:entry colname="col4">449</oasis:entry>  
         <oasis:entry colname="col5">483</oasis:entry>  
         <oasis:entry colname="col6">10</oasis:entry>  
         <oasis:entry colname="col7">8</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FC3</oasis:entry>  
         <oasis:entry colname="col2">113</oasis:entry>  
         <oasis:entry colname="col3">3.7</oasis:entry>  
         <oasis:entry colname="col4">433</oasis:entry>  
         <oasis:entry colname="col5">470</oasis:entry>  
         <oasis:entry colname="col6">10</oasis:entry>  
         <oasis:entry colname="col7">10</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FM1</oasis:entry>  
         <oasis:entry colname="col2">11.9</oasis:entry>  
         <oasis:entry colname="col3">0.39</oasis:entry>  
         <oasis:entry colname="col4">444</oasis:entry>  
         <oasis:entry colname="col5">484</oasis:entry>  
         <oasis:entry colname="col6">10</oasis:entry>  
         <oasis:entry colname="col7">10</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FM2</oasis:entry>  
         <oasis:entry colname="col2">27.7</oasis:entry>  
         <oasis:entry colname="col3">0.91</oasis:entry>  
         <oasis:entry colname="col4">442</oasis:entry>  
         <oasis:entry colname="col5">487</oasis:entry>  
         <oasis:entry colname="col6">10</oasis:entry>  
         <oasis:entry colname="col7">8</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FM3</oasis:entry>  
         <oasis:entry colname="col2">110</oasis:entry>  
         <oasis:entry colname="col3">3.6</oasis:entry>  
         <oasis:entry colname="col4">455</oasis:entry>  
         <oasis:entry colname="col5">510</oasis:entry>  
         <oasis:entry colname="col6">10</oasis:entry>  
         <oasis:entry colname="col7">10</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">MC1</oasis:entry>  
         <oasis:entry colname="col2">11</oasis:entry>  
         <oasis:entry colname="col3">0.36</oasis:entry>  
         <oasis:entry colname="col4">472</oasis:entry>  
         <oasis:entry colname="col5">487</oasis:entry>  
         <oasis:entry colname="col6">10</oasis:entry>  
         <oasis:entry colname="col7">10</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">MC2</oasis:entry>  
         <oasis:entry colname="col2">27.3</oasis:entry>  
         <oasis:entry colname="col3">0.89</oasis:entry>  
         <oasis:entry colname="col4">498</oasis:entry>  
         <oasis:entry colname="col5">480</oasis:entry>  
         <oasis:entry colname="col6">10</oasis:entry>  
         <oasis:entry colname="col7">8</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">MC3</oasis:entry>  
         <oasis:entry colname="col2">111</oasis:entry>  
         <oasis:entry colname="col3">3.6</oasis:entry>  
         <oasis:entry colname="col4">494</oasis:entry>  
         <oasis:entry colname="col5">478</oasis:entry>  
         <oasis:entry colname="col6">10</oasis:entry>  
         <oasis:entry colname="col7">10</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

</sec>
<sec id="Ch1.S2.SS2">
  <title>Data collection</title>
      <p>Before starting each experiment, we placed a thin cotton ring on the top of
the sample to enable the point source of the tracer to spread over the
surface of the upper layer. Then, each experiment was started by supplying
dyed water into samples using a micro-tube pump. The dye used was blue ink,
diluted by a factor of 10 in water at 0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. We monitored <inline-formula><mml:math display="inline"><mml:mi>W</mml:mi></mml:math></inline-formula> during
each experiment by automatically measuring the weight of the tracer reservoir
(1 min resolution). Absolute relative differences between experimental
(Table <xref ref-type="table" rid="Ch1.T1"/>) and reference (10, 30, and 100 mm h<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) values of
<inline-formula><mml:math display="inline"><mml:mi>W</mml:mi></mml:math></inline-formula> range between 6 and 19 % as it is difficult to apply a constant, low input
rate.</p>
      <p>When the tracer reached the base of each sample, tracer supply was stopped.
The arrival time of the tracer at sample base (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mtext>t</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>) was registered
with a manual chronometer watch by visually inspecting samples during the
experiments. Since samples had different heights, we define a specific travel
time as
            <disp-formula id="Ch1.E1" content-type="numbered"><mml:math display="block"><mml:mrow><mml:mi mathvariant="italic">τ</mml:mi><mml:mo>=</mml:mo><mml:msub><mml:mi>t</mml:mi><mml:mtext>t</mml:mtext></mml:msub><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mo>/</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi>h</mml:mi><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          with <inline-formula><mml:math display="inline"><mml:mi>h</mml:mi></mml:math></inline-formula> equal to sample height. Note that <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula> is in min cm<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> as it
is the reciprocal of velocity. After each experiment, pictures of the
external sides of the sample were taken to estimate the approximate thickness
of the upper layer marked by liquid water accumulation (<inline-formula><mml:math display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula>, in cm). Soon
afterwards, we took pictures of the top section of each acrylic ring (by
gradually removing them from the column, snow included). At the same time,
the liquid water mass <inline-formula><mml:math display="inline"><mml:mi>w</mml:mi></mml:math></inline-formula>, in grams, in each of the rings was measured using
a portable calorimeter <xref ref-type="bibr" rid="bib1.bibx39" id="paren.58"/>. These measurements were
translated into profiles of volumetric liquid water content by converting <inline-formula><mml:math display="inline"><mml:mi>w</mml:mi></mml:math></inline-formula>
to <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula>. Fractions of wet areas over total area (<inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula>) were also estimated
for each section by manually delimiting fingers in all the pictures taken and
calculating their extension using the ImageJ software
(<uri>http://imagej.nih.gov/ij/</uri>, v. 1.48; see <xref ref-type="bibr" rid="bib1.bibx1" id="altparen.59"/>).</p>
</sec>
<sec id="Ch1.S2.SS3">
  <title>The comparison with SNOWPACK</title>
      <p>We simulated the dynamics of each sample using the physically based 1-D
multi-layer snow cover model SNOWPACK <xref ref-type="bibr" rid="bib1.bibx8" id="paren.60"/>. These simulations
aim at comparing observations of capillary barrier development with
predictions by a physically based model, as previously done by, e.g.,
<xref ref-type="bibr" rid="bib1.bibx33" id="normal.61"/>, <xref ref-type="bibr" rid="bib1.bibx53" id="normal.62"/>, and <xref ref-type="bibr" rid="bib1.bibx73" id="normal.63"/> mainly using field
observations. The relatively high resolution of LWC measurements (2 cm)
enables a rather detailed discussion of both the physical process and its
simulation by a physically based model. This comparison will not include
preferential flow patterns and arrival times, as the model does not include
an explicit treatment of preferential flow regimes.</p>
      <p>The model discretizes snow using a finite element grid. It simulates the
evolution in time of a broad set of variables along a vertical profile of
snow starting from external forcings. The original version of SNOWPACK
considers a bucket-type approach to simulate water percolation in snow.
Accordingly, water is retained at a given position in the profile until it
exceeds a threshold (see <xref ref-type="bibr" rid="bib1.bibx14" id="altparen.64"/>). After exceeding, excess water
is transmitted downwards. <xref ref-type="bibr" rid="bib1.bibx33" id="normal.65"/> have introduced in SNOWPACK a
water transport model based on the model by <xref ref-type="bibr" rid="bib1.bibx67" id="normal.66"/> and on an
equilibrium approximation of water flow to tackle numerical instability (see
<xref ref-type="bibr" rid="bib1.bibx33" id="normal.67"/> for details). Recently, <xref ref-type="bibr" rid="bib1.bibx72" id="normal.68"/> have also
introduced a discretization of the Richards equation that significantly improves
several aspects of liquid water content simulation in snow. We used the
numerical scheme by <xref ref-type="bibr" rid="bib1.bibx72" id="normal.69"/> in this paper (WE, SNOWPACK version 3.3,
<uri>https://models.slf.ch/</uri>).</p>
      <p>The initial spatial resolution of simulations was set to 2 cm. The time step
was set to 1 min, but the numerical scheme by <xref ref-type="bibr" rid="bib1.bibx72" id="normal.70"/> reduces this
initial time step basing on an iteration rule (see <xref ref-type="bibr" rid="bib1.bibx72" id="normal.71"/> for
details). Snow initial conditions were chosen to replicate the grain type,
size, and density (Table <xref ref-type="table" rid="Ch1.T1"/>), <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> (initially dry), and
temperature (0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) of the physical samples. Using the same sieves
that we used here, <xref ref-type="bibr" rid="bib1.bibx38" id="normal.72"/> obtained a
median grain size (hereinafter,
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>g</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover><mml:mtext>S</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>) for the class 0.25–0.5 mm and the class 1–1.4 mm
equal to 0.406 and 1.463 mm, respectively. <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>g</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover><mml:mtext>S</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> for medium
snow is greater than the upper boundary of the sieve probably because snow
grains used were not perfectly spherical. In the simulation, we therefore set
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>g</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover><mml:mtext>S</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> = 0.406 mm for fine snow, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>g</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover><mml:mtext>S</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> =
1.463 mm for medium snow, and <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>g</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover><mml:mtext>S</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> = 2.926 mm for coarse
snow (by assuming this last value as 2 times the
median medium grain size). Bond
size was assumed equal to one-third of grain radius. Input data were chosen
to replicate experimental conditions in the cold chamber, i.e., a constant
precipitation flux (equal to the measured water input flux <inline-formula><mml:math display="inline"><mml:mi>W</mml:mi></mml:math></inline-formula>, see
Table <xref ref-type="table" rid="Ch1.T1"/>) and a fixed air temperature of <inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mn mathvariant="normal">0</mml:mn><mml:mo>∘</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>C. The threshold
temperature for classifying solid and liquid events was set to
<inline-formula><mml:math display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:msup><mml:mn>0.01</mml:mn><mml:mo>∘</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>C, in order for <inline-formula><mml:math display="inline"><mml:mi>W</mml:mi></mml:math></inline-formula> to be classified as liquid. Wind speed and
solar radiation were set to 0, while incoming longwave radiation was
calculated as <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="italic">σ</mml:mi><mml:msup><mml:mi>T</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>, where <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="italic">σ</mml:mi><mml:mo>=</mml:mo><mml:mn>5.67</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn>10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">8</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> W m<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> K<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> and <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>T</mml:mi><mml:mo>=</mml:mo><mml:mn>273.15</mml:mn></mml:mrow></mml:math></inline-formula> K. Parametrizations for snow
permeability, unsaturated hydraulic conductivity, water retention curve,
residual water content, and averaging method for hydraulic conductivity at
the interface were all kept at the default settings discussed for SNOWPACK in
<xref ref-type="bibr" rid="bib1.bibx72 bib1.bibx73" id="normal.73"/>.</p>
      <p>Particular attention is paid to the comparison between observed and simulated
LWC peak over the interface between layers, as this is an important variable
involved in capillary barrier formation and in wet snow avalanche forecasting
<xref ref-type="bibr" rid="bib1.bibx74" id="paren.74"/>. Another key feature of capillary barriers is the vertical
profile in LWC <xref ref-type="bibr" rid="bib1.bibx33" id="paren.75"/>. However, choosing a single snapshot of
simulated LWC for the comparison with our observations is problematic, as the
model is 1-D and, at this stage, does not include an explicit treatment of
preferential flow patterns. These are expected to play a key role in water
flow around capillary barriers as water concentrates in fingers that are
characterized by a higher-than-average unsaturated hydraulic conductivity
(due to a higher-than-average LWC). It follows that restricting this
comparison to a single profile (i.e., only one time step) may be misleading
as possible differences between observations and simulations might be due to
a process that is currently not treated by the model. This may limit a
comparison aiming at assessing the capability of a model to reproduce
capillary barriers. Thus, we will compare observed profiles of LWC with model
results at two different times. The first one (WE1) is the observed arrival
time of water at sample base; the second one (WE2) is the simulated arrival
time of water at sample base, which is chosen by identifying the instant when
<inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> at sample base reaches <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3 vol % in the simulation
<xref ref-type="bibr" rid="bib1.bibx54" id="paren.76"/>. Note that WE1 and WE2 for each sample were obtained from
the same simulation.</p>
      <p>On the one hand, WE1 is advantageous as supplied mass in experiments and in
simulations matches because both profiles refer to the same time step. On
the other hand, flow in the lower layer will be at the beginning spatially
variable, strongly accelerated, and highly fingered <xref ref-type="bibr" rid="bib1.bibx38" id="paren.77"/>,
which are all features that are not explicitly included in the 1-D model and
that might hamper the application of the Richards equation. Thus, when
considering WE1, we will focus on the profile over the interface, where the
peak of LWC develops. Conversely, WE2 enables a comparison of a full profile
of LWC, but the simulated mass of liquid water will be greater than observed
due to the possible mismatch between observed and expected arrival time of
water in simulations <xref ref-type="bibr" rid="bib1.bibx72" id="paren.78"/>. This is particularly evident in the
upper layer of FC and FM samples, as water speed in fine snow during matrix
flow is slow. Thus, when considering WE2, we will focus on the profile in the
lower layer. Because liquid water flow in MC samples turned out to be highly
fingered (see next section), observations in these samples are compared only
with WE2 (full profile), which is probably less affected by effects due to
preferential flow, including the time arrival of water at a certain point of
the profile. Note that both model version and the evaluation methodology are
different from the preliminary results reported in the discussion paper
<xref ref-type="bibr" rid="bib1.bibx4" id="paren.79"/>.</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <title>Results and discussion</title>
<sec id="Ch1.S3.SS1">
  <title>Overview</title>
      <p>Figure <xref ref-type="fig" rid="Ch1.F1"/> reports the horizontal sections of all the samples
(2 cm vertical resolution) at the end of the experiments (i.e., when dyed
water arrived at sample base). Dyed water is visible as blue stains.
Generally, the darker the color is, the greater local LWC is
<xref ref-type="bibr" rid="bib1.bibx69" id="paren.80"/>. We report in Fig. <xref ref-type="fig" rid="Ch1.F2"/> three examples of samples
at the end of the experiment. These are FC2 (as an example of FC tests), FM2
(as an example of FM experiments), and MC1 (as an example of MC experiments).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T2"><caption><p>Experimental results: observed ponding layer
thickness <inline-formula><mml:math display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula>, experiment duration <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mtext>t</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, and specific travel time
<inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula>. As for <inline-formula><mml:math display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula>, approximated lower and upper values are reported due to
spatial heterogeneity in this variable.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="4">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:colspec colnum="4" colname="col4" align="left"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1">Sample ID</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> (min–max)</oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mtext>t</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">(cm)</oasis:entry>  
         <oasis:entry colname="col3">(min)</oasis:entry>  
         <oasis:entry colname="col4">(min cm<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">FC1</oasis:entry>  
         <oasis:entry colname="col2">2–3</oasis:entry>  
         <oasis:entry colname="col3">92</oasis:entry>  
         <oasis:entry colname="col4">4.6</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FC2</oasis:entry>  
         <oasis:entry colname="col2">3–4</oasis:entry>  
         <oasis:entry colname="col3">50</oasis:entry>  
         <oasis:entry colname="col4">2.8</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FC3</oasis:entry>  
         <oasis:entry colname="col2">2–3</oasis:entry>  
         <oasis:entry colname="col3">14.5</oasis:entry>  
         <oasis:entry colname="col4">0.725</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FM1</oasis:entry>  
         <oasis:entry colname="col2">2–3</oasis:entry>  
         <oasis:entry colname="col3">90</oasis:entry>  
         <oasis:entry colname="col4">4.5</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FM2</oasis:entry>  
         <oasis:entry colname="col2">2–3</oasis:entry>  
         <oasis:entry colname="col3">40</oasis:entry>  
         <oasis:entry colname="col4">2.2</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FM3</oasis:entry>  
         <oasis:entry colname="col2">1–2</oasis:entry>  
         <oasis:entry colname="col3">13.5</oasis:entry>  
         <oasis:entry colname="col4">0.675</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">MC1</oasis:entry>  
         <oasis:entry colname="col2">0–1</oasis:entry>  
         <oasis:entry colname="col3">8</oasis:entry>  
         <oasis:entry colname="col4">0.4</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">MC2</oasis:entry>  
         <oasis:entry colname="col2">1–1</oasis:entry>  
         <oasis:entry colname="col3">8.45</oasis:entry>  
         <oasis:entry colname="col4">0.47</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">MC3</oasis:entry>  
         <oasis:entry colname="col2">0.5–1</oasis:entry>  
         <oasis:entry colname="col3">5.3</oasis:entry>  
         <oasis:entry colname="col4">0.265</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><caption><p>Sections of all the samples (rings diameter equal to
5 cm, 2 cm vertical resolution) at the end of each experiment. Each column
refers to a different sample (as indicated in the last row), while each row
refers to the same depth from sample top surface (depth indicated by the
number on the right side of each row). For all the samples, the interface
between layers is located at a depth equal to 10 cm.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://tc.copernicus.org/articles/10/2013/2016/tc-10-2013-2016-f01.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2"><caption><p>Three samples at the end of the experiments: FC2 (on
the left, as an example of FC samples), FM2 (at the center, as an example of
FM samples), and MC1 (on the right, as an example of MC samples).</p></caption>
          <?xmltex \igopts{width=199.169291pt}?><graphic xlink:href="https://tc.copernicus.org/articles/10/2013/2016/tc-10-2013-2016-f02.jpg"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3"><caption><p>Measured <inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula> profiles. <inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula> is the ratio between wet and
total area for all the sections in Fig. <xref ref-type="fig" rid="Ch1.F1"/>. <bold>(a)</bold>
FC samples; <bold>(b)</bold> FM samples; <bold>(c)</bold> MC samples.
The vertical coordinate refers to the depth of the section from sample top
surface. Serial numbering 1–3 represent the three different input rates.</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://tc.copernicus.org/articles/10/2013/2016/tc-10-2013-2016-f03.png"/>

        </fig>

      <p>Table <xref ref-type="table" rid="Ch1.T2"/> reports observations in terms of thickness of the
upper layer marked by liquid water accumulation (<inline-formula><mml:math display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula>), arrival time of water
at the base of each sample (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mtext>t</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>), and specific travel time of water
in snow (<inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula>). In Figs. <xref ref-type="fig" rid="Ch1.F3"/> and <xref ref-type="fig" rid="Ch1.F4"/>, profiles of wet snow
fractions <inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula> and LWC are given. In Fig. <xref ref-type="fig" rid="Ch1.F4"/>, each point represents
bulk LWC in the underlying 2 cm. As an example, any value reported at a
depth equal to 8 cm is bulk LWC between 8 and 10 cm. This represents the
LWC measured immediately over the interface between layers.</p>
      <p>Figure <xref ref-type="fig" rid="Ch1.F5"/> compares observed and SNOWPACK-based profiles of
volumetric LWC for each sample. Each point represents bulk LWC in the
underlying 2 cm. As described in Sect. <xref ref-type="sec" rid="Ch1.S2.SS3"/>, two simulated
profiles are reported for FC and FM samples (WE1 and WE2), whereas only WE2
is reported for MC samples. Dashed lines indicate the parts of the simulated
profiles that are not considered in the discussion (see again
Sect. <xref ref-type="sec" rid="Ch1.S2.SS3"/>).</p>
</sec>
<sec id="Ch1.S3.SS2">
  <title>Development of capillary barriers</title>
      <p>Figure <xref ref-type="fig" rid="Ch1.F1"/> confirms that liquid water movement through a
finer-over-coarser snow texture is subjected to ponding and horizontal
diversion of water when the wetting front comes to the textural interface. In
FC and FM samples, horizontal spreading of water at the interface introduces
a clear textural transition in wetness between finer and coarser layers (see
Fig. <xref ref-type="fig" rid="Ch1.F2"/>). In four out of six samples of these two classes, a
homogeneously blue area is observed even at a depth equal to 8 cm (i.e.,
2 cm above the interface). MC samples show a more variable behavior. Indeed,
almost no water spreading was observed for MC1 (see also
Fig. <xref ref-type="fig" rid="Ch1.F2"/>), whereas marked horizontal redistribution of water is
visible in MC2 and MC3. MC samples show a smaller <inline-formula><mml:math display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> than FC and FM samples.</p>
      <p>The difference between FC–FM and MC samples in terms of ponding behavior may
be explained considering the retention properties of snow with different
grain size. <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> for medium and coarse snow can be estimated
from grain size using the relation reported in <xref ref-type="bibr" rid="bib1.bibx38" id="normal.81"/> and
<xref ref-type="bibr" rid="bib1.bibx34" id="normal.82"/>: <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub><mml:mo>∼</mml:mo><mml:mn>0.025</mml:mn></mml:mrow></mml:math></inline-formula> m in coarse snow and <inline-formula><mml:math display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn>0.04</mml:mn></mml:mrow></mml:math></inline-formula> m in medium snow. In contrast, <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula> in fine snow for 5 and
10 % LWC is <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.22 and 0.21 m, respectively, and <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula> in medium
snow for 5 and 10 % LWC is <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.09 and 0.08 m, respectively. This
implies that for typical low saturation values in snow, the difference
between the suction pressure in the finer snow and the water entry pressure
of the coarser snow is larger for fine snow. Furthermore, unsaturated
conductivity of coarser snow is likely to quickly decrease with increasing
<inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula>, as already observed in soils <xref ref-type="bibr" rid="bib1.bibx63" id="paren.83"/>. It follows that, at
the same <inline-formula><mml:math display="inline"><mml:mi>W</mml:mi></mml:math></inline-formula>, the greater the mismatch between unsaturated properties of
finer and coarser snow is, the larger the mass of water accumulated and
horizontally diverted until the underlying layer is able to convey the
supplied flux. These approximate values of suction in snow were estimated
using the WRC parametrization in snow by <xref ref-type="bibr" rid="bib1.bibx78" id="normal.84"/>, assuming a
residual LWC equal to 2.4 vol % <xref ref-type="bibr" rid="bib1.bibx77 bib1.bibx34" id="paren.85"/> and
considering 5 and 10 vol % as reference values for relatively low
saturation. Note that the WRC by <xref ref-type="bibr" rid="bib1.bibx78" id="normal.86"/> refers to a drying
process and this may cause some additional uncertainty when estimating <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula>
for a wetting process, due to hysteresis. Indeed, <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula> for a primary
wetting process is expected to be smaller than <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula> for a primary drying
process. Available data of hysteresis in snow are, however, very preliminary
<xref ref-type="bibr" rid="bib1.bibx2" id="paren.87"/>. A specific discussion about the role of hysteresis for
interpreting these results is given in Sect. <xref ref-type="sec" rid="Ch1.S3.SS4"/>.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4"><caption><p>Measured LWC (vol %). <bold>(a)</bold> FC samples;
<bold>(b)</bold> FM samples; <bold>(c)</bold> MC samples. Each point
represents bulk LWC in the underlying 2 cm. This convention is consistent
with Figs. <xref ref-type="fig" rid="Ch1.F1"/> and <xref ref-type="fig" rid="Ch1.F3"/>. Serial numbering 1–3 represent
the three different input rates.</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://tc.copernicus.org/articles/10/2013/2016/tc-10-2013-2016-f04.png"/>

        </fig>

      <p>All layering types are characterized by similar LWC profiles with the only
difference in absolute values for LWC (Fig. <xref ref-type="fig" rid="Ch1.F4"/>). LWC increases with
depth in the upper layer, it presents a marked peak at the textural boundary,
and it decreases again below the capillary barrier. Peaks in LWC at the
interface may be associated with capillary barriers as water ponds until
<inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula> reaches <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and the underlying layer becomes conductive
<xref ref-type="bibr" rid="bib1.bibx63" id="paren.88"/>: similar examples are reported or discussed in, e.g.,
<xref ref-type="bibr" rid="bib1.bibx69" id="normal.89"/>, <xref ref-type="bibr" rid="bib1.bibx33" id="normal.90"/>, <xref ref-type="bibr" rid="bib1.bibx53" id="normal.91"/>, <xref ref-type="bibr" rid="bib1.bibx5" id="normal.92"/>, and
<xref ref-type="bibr" rid="bib1.bibx73 bib1.bibx74" id="normal.93"/>. All FC–FM samples yield a similar LWC in the upper
layer at the interface: <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 33 vol % in FC samples and
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 34–36 vol % in FM samples. Again, this may be explained by
considering that the peak of LWC at the boundary is ruled by the retention
properties of snow with different grain size and by their contrast (see
<xref ref-type="bibr" rid="bib1.bibx40" id="normal.94"/> for a similar discussion in soils). Note that such values of
LWC are much greater than those usually reported in field profiles
<xref ref-type="bibr" rid="bib1.bibx26" id="paren.95"/>. LWC drives, among others, snow settling <xref ref-type="bibr" rid="bib1.bibx49" id="paren.96"/>
and wet snow metamorphism <xref ref-type="bibr" rid="bib1.bibx11" id="paren.97"/>. Both processes experience a
dramatic acceleration with increasing LWC. This supports the idea that
capillary barriers may play an essential role for snow stability in wet
conditions <xref ref-type="bibr" rid="bib1.bibx74" id="paren.98"/>.</p>
      <p>In MC samples, a smaller, but distinct, peak in LWC was measured at the
interface: in MC1, LWC over the boundary is <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 4.5 vol %, whereas LWC
values immediately above and below are 2.7 and 1.7 vol %, respectively. In
MC2 and MC3, the peak in LWC over the interface is <inline-formula><mml:math display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">9</mml:mn></mml:mrow></mml:math></inline-formula> vol %. A
smaller peak of LWC in MC layering is attributed to the small difference
between unsaturated hydraulic properties in medium and coarse snow (for
example, a smaller difference between <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula> in medium snow and
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> in coarse snow). Note again that this difference could be
even smaller than expected if hysteresis were explicitly taken into account
<xref ref-type="bibr" rid="bib1.bibx2" id="paren.99"/>. The observed peaks in MC samples are generally greater than
the peak value observed by <xref ref-type="bibr" rid="bib1.bibx69" id="normal.100"/> during snowmelt infiltration
through a 1.5 over 2.5 mm transition in an artificially sieved snowpack.
This difference may be due to (microstructural) heterogeneity in snow,
infiltration rate, experiment durations, and the larger measurement area of
the TDR system used by <xref ref-type="bibr" rid="bib1.bibx69" id="normal.101"/> compared to a calorimeter (see
Sects. <xref ref-type="sec" rid="Ch1.S3.SS4"/> and <xref ref-type="sec" rid="Ch1.S3.SS5"/>).</p>
      <p>The occurrence of capillary barrier causes horizontal redistribution of
water. Thus, spatial homogenization of liquid water patterns at the interface
is promoted. Indeed, <inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula> increases with depth over the boundary (where <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> for all FC and FM samples; see Fig. <xref ref-type="fig" rid="Ch1.F3"/>). However, sections in
Fig. <xref ref-type="fig" rid="Ch1.F1"/> reveal a remarkable spatial variability of this process
at centimeter scale. For example, some pockets of dry snow persist at depths equal
to 8 cm in samples FC2 and FC3 (i.e., 2 cm above the interface). Other
indications are the observed spatial variability of <inline-formula><mml:math display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> in each sample
(Table <xref ref-type="table" rid="Ch1.T2"/>) and the differences of coloring in some sections at
depths equal to 8 or 10 cm (e.g., FC2, FC3, and FM3), which can be linked to
differences in LWC <xref ref-type="bibr" rid="bib1.bibx69" id="paren.102"/>. Isolated clusters of liquid water
surrounded by dry snow are also visible in MC1 and MC2. All these
observations show that the distribution of liquid water above a capillary
barrier has a marked 2-D (or even 3-D) structure at local scale, probably due
to heterogeneity in snow microstructure. The difference in wet areas in MC
samples for different water input rates might be on the contrary an effect of
water input rate on <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, as observed in snow by
<xref ref-type="bibr" rid="bib1.bibx38" id="normal.103"/>.</p>
</sec>
<sec id="Ch1.S3.SS3">
  <title>Preferential flow patterns and travel time of water in snow</title>
      <p>Observed profiles of <inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula> suggest that water movement in samples was marked by
high spatial variability and that this variability is lower in fine snow
layers than in medium or coarse snow. Overall, preferential flow turns out as
the predominant pattern of water infiltration in snow <xref ref-type="bibr" rid="bib1.bibx61" id="paren.104"/>.
We observed that new fingers created during the percolation, and that
sometimes fingers stopped their vertical percolation at some locations but
continued to develop at others. The movement of fingers in the lower layer
was very rapid and represented a small fraction of the total duration of each
experiment (typically in the range of minutes).</p>
      <p><xref ref-type="bibr" rid="bib1.bibx38" id="normal.105"/> report that the total area of preferential flow (hence
<inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula>) in snow samples made by vertically homogeneous snow decreases with
increasing grain size but increases with increasing input flux. We also
observed a decrease in <inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula> with increasing <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>g</mml:mi><mml:mtext>S</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, whereas a clear
increase of <inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula> with increasing <inline-formula><mml:math display="inline"><mml:mi>W</mml:mi></mml:math></inline-formula> was detected only for MC samples. On the
one hand, the expected dependency of <inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula> on sublayer unsaturated conductivity
<xref ref-type="bibr" rid="bib1.bibx32 bib1.bibx7" id="paren.106"/> and the possible relation between
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and velocity <xref ref-type="bibr" rid="bib1.bibx20 bib1.bibx21 bib1.bibx38" id="paren.107"/>
support the existence of a relation between <inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math display="inline"><mml:mi>W</mml:mi></mml:math></inline-formula> (albeit both effects
have been mainly observed only in soils). On the other hand, these
experiments included a capillary barrier, contrary to experiments by
<xref ref-type="bibr" rid="bib1.bibx38" id="normal.108"/>, and this represents a major driver of liquid water
content patterns at a more local scale (see the previous Section).
Accordingly, water speed in the upper layer was locally affected by ponding,
whereas inflow rate in the sublayer was driven by breakthrough of water when
reaching <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. Both processes limit the impact of external
water input rate on <inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula>, at least until steady conditions are reached. In MC
samples, the difference in retention properties between layers is lower;
thus, the effect of a capillary barrier is spatially very localized. This may
explain why observations in MC samples agree with previous observations in
homogeneous snow.</p>
      <p>Considering outcomes of different experiments in sand, <xref ref-type="bibr" rid="bib1.bibx21" id="normal.109"/>
reports that finger width might increase with both very high (i.e., close to
saturated conductivity) and very low supplied fluxes, while finger width
keeps constant for a broad range of supplied flux in between. Water input
rates in our experiments span 11 and 113 mm h<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>; these values are very
small when compared with expected values of saturated conductivity in snow
(<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msup></mml:math></inline-formula>–10<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">6</mml:mn></mml:msup></mml:math></inline-formula> mm h<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>; see <xref ref-type="bibr" rid="bib1.bibx38" id="altparen.110"/>). We
therefore suggest that future developments of this work should investigate
the relation between flux and <inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula> extensively, i.e., enlarging the range of
<inline-formula><mml:math display="inline"><mml:mi>W</mml:mi></mml:math></inline-formula> considered during the experiments and/or reaching steady conditions.
Furthermore, additional experiments should be carried out using containers of
different size in order to assess whether the experimental geometry used may
induce possible boundary effects (see also <xref ref-type="bibr" rid="bib1.bibx38" id="normal.111"/> on this).</p>
      <p><inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula> increases with decreasing <inline-formula><mml:math display="inline"><mml:mi>W</mml:mi></mml:math></inline-formula>, as clearly expected
(Table <xref ref-type="table" rid="Ch1.T2"/>). In the case of FM2 (fine-over-medium snow, <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>W</mml:mi><mml:mo>=</mml:mo><mml:mn>27.7</mml:mn></mml:mrow></mml:math></inline-formula> mm h<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>), we can compare the <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula> measured during the
experiment (2.2 min cm<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) with the <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula> observed during the
experiment by <xref ref-type="bibr" rid="bib1.bibx38" id="normal.112"/>, since this is the only <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>g</mml:mi><mml:mtext>S</mml:mtext></mml:msub><mml:mo>-</mml:mo><mml:mi>W</mml:mi></mml:mrow></mml:math></inline-formula>
combination that these two works share. The <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula> measured by
<xref ref-type="bibr" rid="bib1.bibx38" id="normal.113"/> for fine snow and <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>W</mml:mi><mml:mo>=</mml:mo><mml:mn>22.3</mml:mn></mml:mrow></mml:math></inline-formula> mm h<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> is equal to
1.7 min cm<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, while the <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula> for medium snow and <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>W</mml:mi><mml:mo>=</mml:mo><mml:mn>21.7</mml:mn></mml:mrow></mml:math></inline-formula> mm h<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> is equal to 0.7 min cm<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. These results suggest
that <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula> in a FM sample is higher than the <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula> observed in a
homogeneous sample composed by medium snow. This is clearly expected since
permeability in medium snow is higher than in fine snow. However, this <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula>
is even higher than the specific travel time observed in a homogeneous sample
made by fine snow, which is marked by a  low saturated conductivity. This comparison helps to quantify the
relevance of capillary effects in ruling water speed in snow and the arrival
time of meltwater at snow base.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5"><caption><p>Comparison between observed and simulated profiles
of volumetric LWC. <bold>(a)</bold>, <bold>(b)</bold>, and <bold>(c)</bold> refer
to samples FC1, FC2, and FC3. <bold>(d)</bold>, <bold>(e)</bold>, and
<bold>(f)</bold> refer to samples FM1, FM2, and FM3. <bold>(g)</bold>,
<bold>(h)</bold>, and <bold>(i)</bold> refer to samples MC1, MC2, and MC3. Note that
panels <bold>(g)</bold> and <bold>(h)</bold> have a different horizontal range from
the others. Each point represents bulk LWC in the underlying 2 cm. As
described in Sect. <xref ref-type="sec" rid="Ch1.S2.SS3"/>, two simulated profiles are reported
for FC and FM samples (WE1 and WE2), whereas only WE2 is reported for MC
samples. Dashed lines indicate the parts of the profiles that are not
considered in the discussion (see again Sect. <xref ref-type="sec" rid="Ch1.S2.SS3"/>).</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://tc.copernicus.org/articles/10/2013/2016/tc-10-2013-2016-f05.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS4">
  <title>The comparison with SNOWPACK</title>
      <p>According to Fig. <xref ref-type="fig" rid="Ch1.F5"/>, SNOWPACK clearly reproduces an increasing
LWC with depth in the upper layer and a peak of LWC at the interface at WE1.
Furthermore, LWC profiles below the barrier are generally in good agreement,
once water has reached the base in the simulation (WE2). Point differences
between observed and simulated LWC at the interface at WE1 read
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2–5 vol % in FC1-FC2, <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3–8 vol % in FM1-FM2, and
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.1–5 vol % in MC samples. A larger difference
(<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 9–13 vol %) is found for higher input rates. However, note that
FC3 and FM3 were subjected to an extremely high water input rate compared
with natural conditions.</p>
      <p>Previous evaluations of SNOWPACK already show that the inclusion of the
Darcy–Buckingham equation in snow enables a correct prediction of the onset
of capillary barriers at textural discontinuities <xref ref-type="bibr" rid="bib1.bibx33 bib1.bibx53 bib1.bibx73" id="paren.114"/>. Here, we enlarged previous findings by considering a
broad set of snow textures and input rates and a relatively high resolution
of measurements. Note that the version of SNOWPACK used does not implement a
parametrization of water entry suction <xref ref-type="bibr" rid="bib1.bibx72" id="paren.115"/>, but the model is
anyway able to provide a sufficiently good performance in reproducing the
profile around a capillary barrier. Results by <xref ref-type="bibr" rid="bib1.bibx64" id="normal.116"/>,
<xref ref-type="bibr" rid="bib1.bibx63" id="normal.117"/>, <xref ref-type="bibr" rid="bib1.bibx40" id="normal.118"/>, and <xref ref-type="bibr" rid="bib1.bibx20" id="normal.119"/> show that <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">ψ</mml:mi></mml:math></inline-formula> and
<inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">θ</mml:mi></mml:math></inline-formula> at an infiltrating front (hence, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) may follow a
wetting WRC. Both variables are also strictly coupled with unsaturated
conductivity <xref ref-type="bibr" rid="bib1.bibx55 bib1.bibx63" id="paren.120"/> and the impedance mismatch given by
the low unsaturated conductivity of the coarser layer compared to the applied
flux plays a key role in delaying water on the barrier. SNOWPACK currently
includes a parametrization of both a WRC and unsaturated conductivity and
solves the Richards equation. It may be that implementing the Richards equation in
1-D is sufficient to mimic some essential features of capillary barriers in
snow (e.g., ponding) even without an explicit calculation of
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. Note that an increase in LWC with depth as well as abrupt
transitions in LWC at the interface may occur even in equilibrium, i.e., when
suction increases with height. This is due to the different retention
properties of fine, medium, and coarse snow. Furthermore, suction profiles
over the barrier may depend on applied flux too <xref ref-type="bibr" rid="bib1.bibx64 bib1.bibx63" id="paren.121"/>. Thus, a more detailed analysis of capillary barrier dynamics in
snow necessarily needs observations of suction profiles during infiltration;
this represents an important step of future research.</p>
      <p>Another important limitation for this discussion may be the present lack of
an exhaustive investigation of WRC hysteresis in snow <xref ref-type="bibr" rid="bib1.bibx2" id="paren.122"/>. As
already noted, the absence of a proper parametrization of hysteresis may
hamper the estimation of expected LWC at <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> during ponding
(i.e., wetting), if different WRCs for a wetting and a drying process are not
known. Also, the hysteretic behavior of the WRC is considered an important
factor in driving preferential flow in general, since for example it promotes
the persistence of fingers in soils <xref ref-type="bibr" rid="bib1.bibx43 bib1.bibx21" id="paren.123"/>. The magnitude
of hysteresis is also related with the magnitude of capillary and saturation
overshoot <xref ref-type="bibr" rid="bib1.bibx20 bib1.bibx38" id="paren.124"/>, although it is not the prime cause
of instability <xref ref-type="bibr" rid="bib1.bibx21" id="paren.125"/>. In this context, note that, according to
<xref ref-type="bibr" rid="bib1.bibx40" id="normal.126"/>, hysteresis plays a less important role than the difference in
unsaturated hydraulic properties between the finer and the coarser layer when
studying the general properties of capillary barriers in soils and how they
depend on layer parameters; this may again support the idea that the existing
implementation of unsaturated flow in a complex 1-D model may be sufficient
to mimic LWC distribution around a capillary barrier. A possible improvement
may be represented by the set of parametric models proposed by
<xref ref-type="bibr" rid="bib1.bibx44" id="normal.127"/> for porous media, which includes hysteresis.</p>
      <p>Observations show that both breakthrough of liquid water below a capillary
barrier and wet conditions in the upper layer or in fingers may present a
high spatial variability at centimeter scale. This is because natural snow is
spatially heterogeneous <xref ref-type="bibr" rid="bib1.bibx34" id="paren.128"/> and this may affect 3-D patterns
of capillary barriers (e.g., see the already discussed pockets of dry snow in
FM3). Alternation of dry and wet snow can sensibly decrease the bulk LWC in a
ring, although local LWC can still be very high. This may partially explain
some differences between observations and 1-D simulations. For example,
predicted peak LWC in FC3 and FM3 is <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 43–46 vol %, which is close
to saturated conditions (the porosity of fine snow in both samples is
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.5) but greater than observations. An approximate estimation of LWC
at <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ψ</mml:mi><mml:mi mathvariant="normal">WE</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> in fine snow (obtained assuming continuity of suction
at the interface) reads 50 vol %, which is closer to SNOWPACK simulations
than data. Thus, saturated conditions might be reached at a very local scale,
while bulk LWC in each ring can be lower due to heterogeneity in wetness at a
larger scale. Another example is water flow below the interface, which showed
a high degree of spatial variability. The good agreement between the model
and the data (at WE2) might suggest that at this measurement resolution
differences in LWC between a highly channeled flow and a matrix-only
simulation balance; that is, fingers are usually highly saturated
<xref ref-type="bibr" rid="bib1.bibx69" id="paren.129"/> but occupy only a small fraction of total volume. Thus,
the average LWC at ring scale is much lower than saturation and close to
matrix conditions.</p>
      <p>This result suggests that an exhaustive process understanding of the physics
of capillary barriers in snow and water flow instability may need that a
proper measurement and/or modeling scale are established to clearly separate
model–data significant discrepancies and effects due to the sampling strategy
(see <xref ref-type="bibr" rid="bib1.bibx10" id="normal.130"/> for a definition). Importantly, the spatial resolution
needed to capture 3-D patterns of capillary barriers might be smaller than
that usually used to sample LWC in the field (see again Fig. <xref ref-type="fig" rid="Ch1.F1"/>).
Increasing the spatial resolution of LWC measurements is challenging as
measuring LWC in snow is still marked by high uncertainties <xref ref-type="bibr" rid="bib1.bibx13 bib1.bibx25 bib1.bibx65 bib1.bibx3" id="paren.131"/>. It is only recently that undisturbed,
non-destructive, and repetitive measurements of LWC have been obtained
<xref ref-type="bibr" rid="bib1.bibx29 bib1.bibx30 bib1.bibx60 bib1.bibx41" id="paren.132"/>. A promising alternative might
be given by pore-scale measurements of liquid water flow <xref ref-type="bibr" rid="bib1.bibx2 bib1.bibx70" id="paren.133"/>.</p>
      <p>This discussion also reveals the role played by heterogeneity
<xref ref-type="bibr" rid="bib1.bibx34" id="paren.134"/> in introducing possible differences in LWC between 3-D
(bulk) and 1-D conditions. Additional uncertainty in this comparison may be
caused by instrumental precision (see next Section), ambiguity in the
identification of the correct snapshot of LWC for this comparison, possible
air trapped in voids at saturation <xref ref-type="bibr" rid="bib1.bibx77" id="paren.135"/>, and possible boundary
effects due to the experimental geometry. To summarize, we suggest that
additional investigations should be carried out to establish proper
frameworks for the high-resolution comparison of complex models and
laboratory (or field) observations.</p>
</sec>
<sec id="Ch1.S3.SS5">
  <title>The role of instrumental precision</title>
      <p>A mass balance between supplied and measured liquid water mass reveals that
the measured mass ranges between 93 and 176 % of supplied mass in eight out of
nine samples, while in MC1 measured mass is 434 % of supplied mass. Note that
in this last sample the total mass supplied is nonetheless very small due to
the short duration of this experiment (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2.88 g).</p>
      <p>This discrepancy can be explained by instrumental noise. Melting calorimetry
has been widely used to measure LWC for decades <xref ref-type="bibr" rid="bib1.bibx79" id="paren.136"/>, but
<xref ref-type="bibr" rid="bib1.bibx13" id="normal.137"/> points out that this method may be inaccurate as it implies
the calculation of a difference between large numbers <xref ref-type="bibr" rid="bib1.bibx62" id="paren.138"/>.
According to <xref ref-type="bibr" rid="bib1.bibx41" id="normal.139"/>, absolute errors in measuring LWC using
calorimetry span 1 and 5 %. The instrument we used here (the so-called
Endo-type snow-water content meter) was proposed by <xref ref-type="bibr" rid="bib1.bibx39" id="normal.140"/>. They
note that measured LWC span <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>2 % of known LWC (by weight) in 87 % of
the cases. By comparing measurements by the Endo-type calorimeter with those
by a dielectric device in snow pits (see <xref ref-type="bibr" rid="bib1.bibx39" id="normal.141"/> for details),
they note that this device returns alternatively higher or lower LWC if
compared with high and low readings by the dielectric device.</p>
      <p>We estimated an absolute error for these experiments by comparing the
height-integrated LWC measured using calorimetry within each sample with the
ratio between supplied liquid water volume and total volume of samples. The
absolute difference spans 0.8 and 2.97 vol %, thus it is consistent with
the literature <xref ref-type="bibr" rid="bib1.bibx41" id="paren.142"/>. Measured and simulated LWC by SNOWPACK are
also in fair agreement (see previous section) which underlines the above
mentioned range of absolute error, since SNOWPACK bases an energy
conservation on mass.</p>
      <p>Capillary barriers and associated preferential flow represent a large
challenge for LWC measurements. On the one hand, peaks in LWC at the
interface are rather high and this is a problem for those instruments that
may lose accuracy for high LWC, such as a snow fork <xref ref-type="bibr" rid="bib1.bibx65" id="paren.143"/>. On the
other hand, bulk LWC in fingered snow may be very low, as water accelerates
and occupies a small fraction of total volume. This means that such
experiments need an instrument that guarantees a comparable performance for
both high and low LWC. This may represent a benefit of the Endo calorimeter
(see Fig. 4 in <xref ref-type="bibr" rid="bib1.bibx39" id="altparen.144"/>), which seems also appropriate given the
small dimension of each ring. Furthermore, <xref ref-type="bibr" rid="bib1.bibx25" id="normal.145"/> report that the
absolute error in measuring water content using dielectric methods spans 0.2
and 0.9 vol %, while <xref ref-type="bibr" rid="bib1.bibx65" id="normal.146"/> note that the expected difference
between measurements taken using a Denoth meter and a snow fork is
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 vol %. Thus, measuring low LWC is generally very challenging for several existing techniques.
Finally, a highly fingered flow may be missed and/or disturbed by using
larger instruments <xref ref-type="bibr" rid="bib1.bibx62" id="paren.147"/>. For future experiments, we will also
consider alternative portable techniques, such as a dilution method
<xref ref-type="bibr" rid="bib1.bibx16 bib1.bibx41 bib1.bibx51" id="paren.148"/>.</p>
</sec>
</sec>
<sec id="Ch1.S4" sec-type="conclusions">
  <title>Conclusions</title>
      <p>We focused on the systematic observation of capillary barriers and associated
preferential flow during laboratory experiments in a cold chamber. We sieved
nine samples of finer-over-coarser snow. These samples were subjected to
controlled supply of dyed water until water arrived at sample base. Liquid
water patterns in stratified snow were characterized using visual inspection,
LWC measurements, and horizontal sectioning. Results were also compared with
SNOWPACK simulations.</p>
      <p>Overall, results confirmed that a finer-over-coarser transition in snow
layering causes ponding of water when it arrives at the textural boundary.
Measured peaks in LWC over the boundary are large with respect to usual
measurements in the field (up to <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 33 vol % in fine-over-coarse
samples and <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 34–36 vol % in fine-over-medium samples), while peaks
in medium-over-coarse samples are usually <inline-formula><mml:math display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> 10 vol %. Differences
in peak LWC between samples were explained by varying unsaturated hydraulic
properties of snow with different grain sizes. A more detailed analysis of
horizontal sections revealed marked variability of wetness conditions at centimeter
scale, thus suggesting that local LWC might even be greater than measured.</p>
      <p>Horizontal sectioning of samples confirmed that preferential flow seems the
dominant process in water transmission in snow. The area occupied by fingers
(<inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula>) increases with grain size, while no definitive result was obtained to
establish a relation between <inline-formula><mml:math display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula> and water input rate. This is explained by
the strong perturbation introduced by the capillary barrier in liquid water
content patterns when compared with previous observations in homogeneous snow.</p>
      <p>The comparison with SNOWPACK showed that, in general terms, the
implementation of the Richards equation clearly reproduces the existence of a
capillary barrier and yields a good agreement with observed peaks in LWC at
the interface. The marked spatial variability of liquid water content in snow
represents a source of uncertainty when comparing measurements at a
relatively high resolution with a 1-D model. Future steps of this work will
compare these measurements with a 3-D simulation of liquid water infiltration
in snow <xref ref-type="bibr" rid="bib1.bibx34" id="paren.149"/>.</p><?xmltex \hack{\newpage}?>
</sec>
<sec id="Ch1.S5">
  <title>Data availability</title>
      <p>The data sets plotted in Fig. 3 and 4 are available upon request to the
authors.</p>
</sec>

      
      </body>
    <back><notes notes-type="authorcontribution">

      <p>Francesco Avanzi, Hiroyuki Hirashima, and Satoru Yamaguchi designed the
experiments, Francesco Avanzi and Satoru Yamaguchi performed the experiments,
Hiroyuki Hirashima performed SNOWPACK simulations, and Francesco Avanzi prepared
the manuscript with the contribution of all coauthors.</p>
  </notes><ack><title>Acknowledgements</title><p>Fruitful discussions about this work with Atsushi Sato and Yoshiyuki
Ishii are acknowledged. We would like to thank the staff of the Snow and Ice
Research Center, National Research Institute for Earth Science and Disaster
Prevention, for helpful discussions. Francesco Avanzi is grateful for the support received
during his research period at the Snow and Ice Research Center in Nagaoka. We
would like to thank Sugai Yusuke for his assistance during experimental
activities. We acknowledge the Editor Guillaume Chambon, Christoph
Mitterer, and an anonymous referee for their constructive comments on the
manuscript, which improved the impact and the overall quality of the
paper.
<?xmltex \hack{\\\\}?>Edited by: G. Chambon<?xmltex \hack{\\}?>
Reviewed by: C. Mitterer and one anonymous referee</p></ack><ref-list>
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<abstract-html><p class="p">Data of liquid water flow around a capillary barrier in snow are still
limited. To gain insight into this process, we carried out observations of
dyed water infiltration in layered snow at 0 °C during cold
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textures and three different water input rates. By means of visual
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stratified snow. Both are marked by a high degree of spatial variability at
centimeter scale and complex 3-D patterns. During unsteady percolation of
water, observed peaks in bulk volumetric LWC at the interface reached
 ∼  33–36 vol % when the upper layer was composed by fine snow (grain
size smaller than 0.5 mm). However, LWC might locally be greater due to the
observed heterogeneity in the process. Spatial variability in water
transmission increases with grain size, whereas we did not observe a
systematic dependency on water input rate for samples containing fine snow.
The comparison between observed and simulated LWC profiles
revealed that the implementation of
the Richards equation reproduces the existence of a capillary barrier for all
observed cases and yields a good agreement with observed peaks in LWC at the
interface between layers.</p></abstract-html>
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